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By Laajalehto K

The basic condition necessary for flotation is hydrophobicity of the surface of the mineral to be floated. For sulphides, this condition usually requires treatment with a collector solution. The conditions for this treatment have until recently usually been chosen by the trial and error principle which has indeed been working relatively well under favourable conditions; ie for simple homogeneous ores. However, the present tendency to increasing use of complex and often relatively lean ores sets increasing requirements for the control of the flotation process. This development is the reason for the present rapid development of process control methods in flotation. In addition to the already well-established practices of pH and reagent feed controls, the importance of measuring and controlling the electrochemical potential of the ore particles to be floated is recognised in the case of sufficiently conductive minerals. In fact, the electrochemical potential seems to be the basic quantity determining the flotation behaviour of such relatively well-conducting minerals as sulphides. Since the hydrophobicity of the mineral and, hence, its flotation properties are ultimately determined by the composition and structure of its surface, information on these under different process conditions is important for design and operation of efficient flotation processes. The basic requirement set for the methods used for obtaining this information is high surface sensitivity of the method. The recent rapid development of surface characterisation has produced several methods which fulfil this requirement. Their application to the problem of characterising surfaces of mineral samples in contact with collector solution is, however, often complicated. The main reason for this is the vacuum environment necessary for the measurement. In the case of flotation experiments this means that in most of these methods the measurement cannot be made in situ, but the sample must be extracted from the liquid and subsequently evacuated in the vacuum chamber of the instrument. It is essential to carry out these steps so as to avoid to the extent possible changes in the sample surface. For the purpose of establishing whether this has been accomplished it is important to compare the results of methods operating in vacuum with some available in situ method. An optimal choice of methods seems therefore to be a combination of the available powerful vacuum methods with in situ measurements. The most usual combination seems to be X-ray photoelectron spectroscopy (XPS or ESCA), Fourier transform infrared spectroscopy (FTIR) and electrochemical measurements. This choice combines the unique possibilities for direct elemental and chemical characterisation offered by XPS (Cecile, 1985) with the in situ capability of FTIR and electrochemistry. In the XPS measurements, it is essential to apply a special sample handling technique to avoid loss or damage of some sensitive species of the collector-based layer on the mineral surface. In the following will be given some examples of the application of the XPS technique in combination with electrochemical methods of sample treatment to studies of the layer formed on sulphide substrates in ethyl xanthate (EX)

Jan 1, 1993

By Hu Y, Li D, Qu G

In this paper the structural mechanism of the gold - lixiviant complex is investigated. The results show that there are two common characteristics in the outer orbitals for all the gold lixiviants: a) a (Y -type of HOEO to form the L-*Au co-ordination bond, and b) a it type f LUEOs, with symmetry the same as that of 5d orbitals of Au, to form L

Jan 1, 1993

By J S. Simmons, J G. Skousen

This project evaluated the performance of nine passive treatment methods by studying 137 treatment units in eight eastern states. Performance was normalised according to construction cost, projected service life and kilograms of acid load treated. Results were dimensioned as $/kg of acid load treated/year. These costs were then compared to those of chemical treatment. Sites that achieved acid load reductions at costs below those of chemical treatment were considered successful. In addition to evaluating the performance of the treatment methods, this paper describes the various passive treatment systems, their applications and performance data for individual treatment units.

Jan 1, 2003

Disastrous earthquakes are a reality on the Australiancontinent. Unfortunately it has taken the fatal 1989 New-castle earthquake to demonstrate to all Australians that we do not reside on a "stable continent". While the world accepts the potential of plate tectonics and its associated plate margin earthquakes, particularly around the active Pacific Rim, the realisation of devastating intra-plate, or continental, earthquakes is only now beginning to take effect. The 1989 Newcastle earthquake provides many lessons on which to further fundamental earthquake research and the applications to the future welfare of human civilisation. To mitigate the earthquake hazard in relation to the devastation to life, property and industry, research must be undertaken with the resulting informa-tion to be included in the nation's disaster management programs. The earthquake hazard is everpresent in east-ern Australia and the major step in its quantification is a more realistic determination of earthquake risk estimates through an integrated study of seismology, engineering, insurance and sociology.

Jan 1, 1990

By Ward S. D

When using grinding time for a batch grinding operation as a measure of the energy usefully employed for comminution; the assumptions made are often not valid. A kinetic approach, based on a study of the rate constant, or k, value for the material is more acceptable. The Rosin-Rammler distribution equation has been theoretically derived from the general equation for first-order batch grinding. This relationship, incorporating a term for k, was used in a study of the rod milling of a binary mixture of quartz and limestone.The presence and degree of interaction between the components was considered by comparing the size distribution of the mill product with that predicted by assuming the overall distribution equal to the sum ofthe distributions given by the Rosin-Rammler equations for each component weighted according to its volume fraction in the mixture. The interaction was found to be complex and particularly sensitive to particle size.A simple graphical procedure was devised to predict the size distribution of the mill. Product components and this gave a fairly good approximation to experimental data.

Jan 1, 1976

In another paper the author described the electrolytic preparation of highly-purified lead. One of the most difficult parts, yet perhaps the most essential part, of that research was to ensure, firstly, that the purification process should be effective; secondly, that it should remain effective; thirdly, that the lead should not be contaminated during the tests that were done on it. All this necessitated periodic analyses of the lead.The purpose of this paper is to describe the work done by the author to check the accuracy of some known rapid methods for the estimation of impurities in highly-purified lead, with the intention of applying them to the control of the electrolytic process above-mentioned.METHODS ALREADY IN USEThe literature sets out accurate methods for the estimation of impurities in lead, but these methods are both lengthy and expensive. For example, the method described by Hemingway is used in the Port Pirie laboratory of the Broken Hill Associated Smelters Pty. Ltd., but it requires a sample as large as 1000 grm., and the time required to analyse a sample extends over days, and is too long to allow of quick control over a running process. This method was used by the Associated Smelters to obtain the analyses quoted in another paper by the author.

Jan 1, 1932

By A Prill

Safety First and zero accidents are the targets most mines in Australia are aiming for, but manual processes and procedures limit the capabilities and response time in emergency situations. Even with a high safety focus, accidents and incidents still happen, too often with tragic outcomes. Dangerous areas, narrow roads and winding curves are all daily obstacles that threaten workforce safety. Every unforeseen event, such as traffic collisions and other accidents, puts lives in danger and weakens production. Safety must be guaranteed.

May 5, 2022

By Davies S. G, Jayaweera A

The oxidation of nickel sulphide and copper sulphide concentrates, and coal, has been studied under non-ignition and ignition conditions using Differential Thermal Analysis (DTA) and Thermogravimetry (TG). The non-ignition reaction was favoured by slow heating rates < 10°C min-1), low masses < 10 mg) and an air atmosphere. Under these conditions, the typical stepwise oxidations of the various sulphide minerals present in the concentrate were observed as resolved exothermic peaks in the DTA curves and weight losses in the TG curves. Above a heating rate of 10°C min-1 , sample masses in excess of 10 mg and an oxygen atmosphere, an ignition reaction was induced, as indicated by a major high energy exotherm in the DTA curve and a major rapid weight loss in the TG curve. The ignition temperatures of the minerals under ignition conditions, found for 15 mg samples heated at 20°C min-1, were 434°C for the nickel sulphide concentrate, 372°C for the copper sulphide concentrate, and 230°C for the coal. By plotting a curve for mass against ignition temperature at constant heating rate and extrapolationto zero mass, a value of 470°C was obtained for the mass independent ignition temperature of the nickel sulphide concentrate. Ignition temperatures and extents of reaction at various temperatures were obtained using the TG technique in a novel manner which produced heating rates of 4500°C min-1. Under ignition conditions, the oxidations approximate to flash smelting conditions.

Jan 1, 1985

By P D. Williams

The Phoenix mine is one of NewmontÆs open-pit operations located in Nevada. Mining started in 2005, with the mine producing gold, copper and silver. The mine life is about 20 years. The gold grade estimation uses the Newmont in-house indicator kriging approach to handle the high variability in drill hole composite grades and support mining selectivity. Each block contains up to 200 subblocks with different gold grades. A flotation mill is designed to process oxide and sulfide ores, recovering gold, copper, and silver. An additional copper leach process is currently under study to process low gold and high copper oxide material with low copper recovery in the mill. The metallurgical recoveries and processing costs are dependent on many variables including rock formation, metallurgical domain, cyanide soluble copper and sulfide contents. This paper describes the Newmont in-house indicator kriging procedures and the revenue based mine planning software system implemented at Phoenix mine to address the complexity resulting from multi-process, multi-metal and indicator kriging model.

Jan 1, 2007

Most of you who are attending this conference are probably Student Members of The Institute and well aware of the advantages which flow from student membership. You will probably agree that the major benefits are: ò Low and subsidised membership fees;

Jan 1, 1994

As mines become deeper, the problems of heat in the workplacebecome more acute. An important response from the industry hasbeen the widespread adoption of microclimate cooling such asair-conditioned cabins. However, not all work in mines can becompleted from inside an air-conditioned cabin, and in any event,it is still important to keep the ambient air in the mine outside ofany microclimate to a safe temperature. An important method forbringing workplace temperatures under control is the appropriateuse of refrigeration. The application of refrigeration inmechanised mines has been recently described (Brake, 2001;Brake and Fulker, 2000). This paper provides an overview ofsome of the important engineering considerations in thespecification and selection of mine refrigeration plants. Thepurpose is to provide a basic understanding of refrigerationprinciples, practices, terminology, hazards and opportunities formining engineers or other personnel who may need to beinvolved in the introduction of refrigeration onto a mine site.

Jan 1, 2001

By Gao H

Based on the author's research and plant practice experience of the last decade, several technological approaches have been developed to increase the recovery of gold and silver associated with sulphides. This paper gives a general discussion of some technological problems encountered in this area in five aspects and introduces the different approaches employed in three typical mineral processing plants to increase recovery of associated gold and silver. On the basis of studying occurrence characteristics of gold and silver minerals in sulphide ores and of determining loss locations of gold and silver on flotation process, a remarkable improvement on the recovery of gold and silver in all these three plants was made by choosing proper grinding fineness, using combined collectors of good selectivity, properly decreasing the grade of main metal concentrates, making reasonable arrangement of the products of main metals, or a combination thereof.

Jan 1, 1993

Field investigation of surface subsidence events associated with both active and abandoned underground coal mines in the United States has established criteria that enable the prediction and classification of mine-related subsidence. The key was establishing the role of geology in all types of subsidence and the recognition of beam subsidence in specific geologic settings. The classification is based on overburden thickness, variations in stratigraphy, topography and mine plan. Types of subsidence are Pit, Room, Sag, and Beam. Pit subsidence is associated with three geologic settings: shale overburden, seasonally wet unconsolidated overburden, and perched water table in unconsolidated overburden. Room subsidence occurs where the roof across the width of the room fails to the surface and a shallow depression develops.

Jan 1, 1992

By C Li

Removal of gangue minerals from ilmenite concentrates can beaccomplished by relatively low temperature roasting in controlled gasatmospheres to selectively enhance the magnetic separationcharacteristics of the ilmenite. At roasting temperatures below 800¦C the magnetising reactions are often not consistent with phase equilibria considerations. Metastable phases can nucleate and control the roasting products. In weathered ilmenites the phase assemblages and microstructures in the altered ilmenite grains can influence the roasting reactions. In this paper we give an overview of the phase chemistry of chemically weathered ilmenites and of metastable phases formed by low temperature roasting. We also report the results of roast experiments conducted in a neutral gas atmosphere. Major increases in magnetic properties after short roasting times at low temperatures were obtained for a range of ilmenite concentrates. For example heating a secondary ilmenite concentrate from Western Australia for 15 minutes in nitrogen at 600¦C gave an increase in the three kilogauss magnetic fraction from three to 92 wt per cent. The solid state phase changes accompanying the inert atmosphereroasts were characterised by combining elemental analyses withquantitative phase analyses of the ilmenite concentrates and their roast products. It was found that the phase reaction that is principally responsible for the increase in the magnetic properties of weathered ilmenites involves a transformation of disordered ferrous-containing pseudorutile to an ordered ilmenite-hematite solid solution containing typically ten to 35 mole per cent of the hematite component. Examples are given of the application of the inert atmosphere roast to effect separations of ilmenite from gangue minerals.

Jan 1, 2001

By Anderson D

Investigation of a water inflow into Wongawilli Mine in the Southern Coalfield of New South Wales included algal analysis. The determination of algae in the water suggested an external water source. An alternative hypothesis proposed that algae are inherent in a coal mine environment. Investigations to determine the validity of these hypotheses and provide information on the viability and longevity of algae under adverse conditions were conducted in the mine and the laboratory. Results indicated that a mine environment is not natural to algae and is not conducive to their growth. These findings support the hypothesis of introduction of surface water to the mine workings. They indicate that, in the absence of other available techniques, algae can be an effective tracer for use in the determination of a water source.

Jan 1, 1988

By M Logsdon, T R. Clark, T I. Mudder

Oxidation of pyrite and other metal sulfides is accelerated by the activity of acidophilic iron- and sulfur-oxidising microorganisms. The ideal biocide for controlling biocatalysed acid rock drainage (ARD) would be inexpensive, inhibitory toward sulfide-oxidising bacteria at low concentrations, relatively non-toxic toward non-target organisms, degradable in the environment outside the zone of application, stable and long-lived in the impacted environment, sufficiently mobile to penetrate into piles of waste rock or tailings, and effective regardless of the metal sulfides present. A potent agent for combating ARD that fits these criteria is the thiocyanate anion (SCN-). The objective of this study was to determine the effectiveness of thiocyanate in controlling or preventing ARD within several types of sulfidic waste rock and tailings. Results were evaluated within a context encompassing process water and solids management strategies employed at different precious and base metal mines. Sulfidic rock was treated with solutions of potassium thiocyanate and subjected to accelerated weathering tests in lab-scale humidity cells, trays, and columns. Certain tests also utilised solid phase copper thiocyanate (CuSCN) to evaluate a ærelease on demandÆ strategy. Leach solutions were analysed for parameters indicative of ARD including pH, redox potential, conductivity, acidity, sulfate, iron, and certain heavy metals. Two larger scale field tests were also initiated by personnel at separate mines using, in the first case, ore containing a pyritic component in large columns and, in the second case, waste rock containing base metal sulfides in lined pits. Humidity cell tests showed low concentrations of thiocyanate solution applied to pyritic waste rock could reduce ARD formation by 90 per cent or more compared to untreated controls, with the residual release of ARD components (eg sulfate, Fe, acidity) probably reflective of strictly chemical oxidation of the sulfides by molecular oxygen. Thiocyanate applied at a concentration of 22 mg/kg to waste rock from a base metal mining operation in large laboratory scale columns reduced acidity and sulfate release by 75 per cent to 80 per cent compared to untreated controls. This extent of reduction in ARD may not meet discharge water quality criteria, but has the potential to significantly reduce lime consumption and sludge production in a conventional neutralisation facility. The use of a solid-phase metal thiocyanate compound (CuSCN) at a dosage of 194 mg/kg pyritic ore resulted in the following per cent reductions in leach solution parameters in comparison to controls: sulfate (78 per cent), acidity (93 per cent), dissolved Fe (99.4 per cent), and dissolved arsenic (99.9 per cent). This compound has the further advantage of being relatively stable until needed, dissolving only in the presence of an acidic and oxidising ARD solution. If this line of investigation progresses favorably, it offers the possibility of an ARD prevention technique that may be applicable in some settings. Mine-site pilot scale tests with pyritic ore resulted in reductions in sulfate (56 per cent) and Fe, As (66 - 68 per cent). In sum, thiocyanate at relatively low concentrations dramatically reduced ARD from sulfidic rock in a simulated heap. The pilot test using waste rock containing base metal sulfides has begun only recently. A preliminary process design and cost estimate was made for fullscale application of thiocyanate to waste rock at a hypothetical gold mining operation producing 5000 tpd of ore and 10 000 tpd of sulfide containing waste rock. The combined capital and operating costs for the full-scale thiocyanate application facility were about $US 0.25/tonne of waste rock and $US 0.50/tonne of ore. Although thiocyanate is readily available commercially, it also occurs in process solutions associated with certain types of mining processes. Such solutions after selective treatment might be recycled to sulfidic waste rock or tailings, rather than being treated for thiocyanate degradation.

Jan 1, 2003

A schematic overview of the variables which interact to determine ore reserves precedes consideration, in this context, of some recent views on the concept of a 'production cycle'. Political and governmental action, for whatever motives, is a greater obstacle to future mineral supply than technical problems.

Jan 1, 1979

Deformation of the lithosphere by tectonic forces is investigated from both observational and theoretical standpoints. Global and regional geophysical data bases, coupled with the means for their rapid display and analysis, facilitate recognition of areas of the con- tinents and oceans where the response of the lithosphere to these deforming processes might fruitfully be studied. Gravity anomalies, from Seasat altimeter data and from land and shipboard measurements, provide critical infor- mation on the isostatic state of deformed lithosphere and therefore on its thermal and mechanical properties.

Jan 1, 1987

Human creativity springs from the natural desire of mankind to know and its capability to learn. Explorers and discoverers possess these features in a high degree. They are driven by an unrelenting curiosity to go beyond the boundaries of the known, to explore into the nature of things, to reveal connections between ideas, facts, conceptions, to view things from new angles, to change perceptions. A well-known fact about the construction industry - and underground construction in particular - is that all projects are unique. The degree of complexity due to the intertwining of the variety of project-related parameters is higher than in many other industries, thus forcing contractors as well as suppliers to be truly adaptable and flexible. The enormous advantages of shotcrete as a construction and rock support process and the improvement of materials, equipment and application know-how have made it a very important and necessary tool for modern underground construction works. The development of modem wet shotcreting in particular has enlarged the field of underground construction work. Projects that were impossible to be realised, have now become practicable. Subsurface structures can be placed where they are needed, without regards as to rock and soil conditions.

Jan 1, 1995

The paper outlines the development and objectives of the slim core (50 mm dia.) testing procedures employed at the Company's Central Research Laboratories with particular reference to washability studies required for coalfield evaluation. It shows that when the routine test procedures, that have been developed for cores recovered form the Sydney Coal Basin, were applied to Bowen Basin Coals some of the washing data obtained appeared to be suspect. Though yield indications appeared to be of the right order, product ash, required separating gravity and percentage of near gravity material were found to be at variance with bulk washability data. The results of a correlation study made on an underground seam from the Bowen Basin comparing slim core, hulk sample, and pilot plant washing data are given. The results of a series of studies including washability studies made on slim cores, strip samples, large diameter cores and bulk samples, pilot washing trials and computer simulations of washery circuits treating Lilyvale seam coal from the Bowen Basin are shown.

Jan 1, 1977