Search Documents

By R. Augsten, K. K. Feng, K. C. Cheng

"Methane emission and the desorption characteristics of vertical borehole coal samples of Greenhills multiple seams in the vicinity of Elkford, British Columbia were investigated. Three vertical boreholes at depths of 335 m, 380 m and 395 m were drilled along the west wall of an active open pit mine and 44 core samples from various coal seams were obtained for desorption studies.The results are presented in three tables and illustrated with six figures. The methane content was found to increase significantly at depths greater than 200 m. The adsorption equation by Kim and the properties of the coal have been used to predict the methane content and these were compared with the measured values by the direct method.IntroductionThe coalification of plant material in the sedimentary rock produces different ranks of co al and gases of various composition. The gas mixtures are retained in coal beds and rock strata under pressure. The gas content in a coal bed varies considerably depending on the rank of coal and the depth of overburden. The gas content is defined as the volume of gases adsorbed in a unit weight of coal materials. The net amount of gases remaining in a coal seam depends on the difference in the rate of generation of methane by geo-thermal heat and the rate of diffusion of the gases out of the coal bed through sedimentary cover. The major factor that causes the change in rank and the liberation of gases is the temperature, which is governed by the thermal conductivity of sedimentary cover and the heat flux through the underlying rocks. The rate of diffusion of the gases out of the coal is governed by the porosity of the overlying rocks and the degree of fracture. The measured values of gas content in major North American coal beds are from zero up to 24 cm3 per gram of coal(1,2). A gas content of 2.5 to 9 cm3/g is considered ""gassy"" and that of 9 cm3/g or higher is considered ""very gassy"" for underground mining(3). Normally, the gas mixtures released from bituminous coal in Canada contain 90 to 98% methane and the remainder is made up of CO2, N2, 02, H2, He and other hydrocarbons(4)."

Jan 1, 1984

By Claude Bazin, Patricia Obiang

"The slurry density (pulp percentage of solids) and the size of the grinding media are often used for the optimization of an operating ball mill. In many cases a change of ball size is made at the slurry density used with the original ball size. But is the optimum slurry density changing with grinding media size? Laboratory grinding tests were conducted to answer that question and results indicate that more than likely there is no need to adjust mill slurry density when adjusting the size of a grinding media in a ball mill. Full scale behaviour could be different because slurry density affects the slurry transportation through the mill and the classifier operation.INTRODUCTIONOre preparation begins with a fragmentation step that liberates valuable minerals or exposes mineral surface to the environment. The size reduction step of a mineral processing operation is energy demanding and the optimisation of this process should always be an objective for the plant metallurgists. Various approaches could be considered for improving the operation of a grinding circuit. For a close grinding circuit an adequate tuning of the classifiers operation may lead to substantial savings (McIvor, 1988). Once a grinding mill is in operation, few variables remain to be considered for process optimization. The ball charge is usually maintained to achieve a target power drawn by the grinding mill motor. The rotation speed is seldom considered (McIvor, 1983; Bazin and Lavoie, 2000) as a change of mill speed usually implies a costly pinion change. If the liner and lifter configuration is critical for SAG and AG mills (Latchireddi et al., 2005), few discussions are available for ball mills (Fuerstenau and Abouzeid, 1985; McIvor, 1983). The mill feed size distribution can also be adjusted but this implies changing the upstream processes, which transposes the optimization process to another level. Modification to grinding media shape is a possible avenue (Cooper et al., 1994), but it remains that slurry density and grinding media size are probably the most frequently considered variables for the optimization of a ball mill."

Jan 1, 2007

By Gordan Marrs, O. Matwijenko

"The Kidd Creek metallurgical site has been highly integrated to maximize revenues from its base metals mines. The site's operations include a Concentrator processing 4.3 million tonnes per year of copper-zinc ore, a Copper complex producing 100,000 tonnes per year copper cathode and a Zinc Plant producing 130,000 tonnes per year of zinc metal. To improve operating efficiency with increasing emphasis on productivity, process control, process automation and process optimization have been augmented and expanded during the last decade.New microprocessor based control systems provided the opportunity for the capturing of an expanded number of process related measurements. As supervisory computers were already in place, databases could be generated with only increased disc space and database management programs required. Once the data had been accumulated and stored, a method was then required for handling, screening and sorting large volumes of information in relatively quick and easy terms in order that the stored information could be used. By 1984, a decision to use personal computers for accounting, engineering and management reporting provided the vehicle necessary to handle this data. Using commercially available software, large volumes of stored process data can be downloaded from existing databases, filtered, sorted, analyzed, graphed, displayed, projected, reported and distributed. All this can be performed in very little time."

Jan 1, 1989

By H. E. Pawson

"COMMON METHODS OF ELIMINATION: The four methods most frequently used to dispose of cyanide wastes are:1. Oxidation2. Dilution with water or with cyanide free wastes3. Acidification and dilution of resulting gas with air4. Alkaline ChlorinationMost operators practice a combination of the first two methods, allowing oxidation and dilution of cyanide waste in tailings ponds. Then, pond effluent is introduced to a stream for further dilution andoxidation which is expected to take care of the cyanide. This method oftreatment does work to a certain degree. Atmospheric oxidation in tailings ponds and in receiving streams chemically breaks down the cyanide radical to form carbon dioxide and nitrogen.2(CN) + 202 2 CO2 + N2The monetary advantage to this method is obvious to the operator but too frequently though, climatic conditions are ignored. Length of winter, and reduced flow of the receiving stream in summer, adversely restricts the result of this combined method. For those of us who rely mainly on dilution it would be wise to remember that 70 million pounds of water are required to dispose of one pound of sodium cyanide (1).The third method outlined involves addition of acid in a closed vessel and venting resulting gas to atmosphere with or without air dilution by mechanical means. Cost, safety and some form of secondary treatment to complete destruction of cyanide remaining in the solution usually make this method prohibitive.The alkaline chlorination method is the one most commonly accepted for treating cyanide bearing wastes since it is felt that cyanide is completely eliminated in this manner."

Jan 1, 1973

By Robert Cluff

The Campo Morado precious-metal-bearing, volcanogenic massive sulphide district occurs in a Lower Cretaceous felsic volcanic sequence in a northerly trending belt in the Guerrero Terrane in northeastern Guerrero, Mexico. During upper Cretaceous to Early Tertiary greenschist-facies regional metamorphism, the rocks were deformed strongly into a northeast-verging fold-and-thrust belt. The deposits belong to a low-sulfidation, volcanogenic massive sulphide system formed in a subaqueous environment, and are of the siliciclastic type. Most are on the flanks of felsic domes or in adjacent basins and many are associated with heterolithic volcaniclastic rocks. The Reforma and possibly the El Rey massive sulphide deposits are interpreted to be overturned, and the Naranjo, El Largo, and Estrella de Oro deposits and the El Profundo occurrence to the south are upright. The G9 deposit and the La Lucha and San Rafael occurrences are in an over-thrust plate further to the southwest. In several of the deposits, zinc, lead, silver, and gold are concentrated near the stratigraphic top, and copper is concentrated near the stratigraphic base; copper also is concentrated in replacement bodies near the top of some domes. Major minerals are pyrite, quartz, ankerite, sphalerite, chalcopyrite, and galena. Gold and silver occur in argentian gold, and silver also occurs in tennantite/freibergite and galena. Underlying stockwork zones contain disseminated and vein quartz, pyrite, chlorite, and ankerite, with locally abundant chalcopyrite and/or sphalerite. Exploration since 2004 has enlarged greatly the El Largo and the high-grade G-9 deposits, and slightly enlarged the El Rey deposit. The cumulative in situ massive sulphides for the Reforma, Naranjo, El Rey, El Largo, and G9 deposits exceed 45 Mt.

May 1, 2006

By E. J. Sides

In this paper, the argument is put forth that the codes used for public reporting of mineral resources and mineral reserves have some significant limitations with regard to the information provided to investors on the short- to medium-term value of mining properties. Such limitations include a) failure to explicitly incorporate a time element and b) failure to state explicitly the quantity and quality of mineral product that will be produced for sale. A time-value framework for reporting mineral assets is proposed in order to overcome these limitations. The proposed system is based on two classification axes: a) an X-axis representing time in years during which the value of the asset is likely to be realized and b) a Y-axis representing the value identified by a mining or exploration company\u2019s activities. The potential benefits of this system are discussed, including the ability to incorporate factors, such as permitting and construction times, directly into the magnitude of the reported mineral assets. The proposed framework would assist in the standardization of mineral assets reporting in such a manner that they could eventually be more readily included in financial statements. Year of Publication: Not explicitly mentioned in the document.

Jan 1, 2010

By Gregg S. Hill, Bert J. Huls

"This paper on coarse particle recovery (CPR) summarizes a process to capture coarse particles that are not recoverable by regular flotation. Several porphyry copper operations in the world operate analogous circuits that recover non-floated copper from tailings; however, the case presented here is unique in that extensive underlying test work has allowed us to elucidate some fundamental principles behind recovery enhancement. This paper discusses an overview of the flow sheet that is proposed to Minera Escondida Ltda., the nature of copper in the feed to the CPR circuit, and the various unit operations within the recovery circuit. Details of the technology behind each unit operation will be presented in later publications.INTRODUCTIONSince 1996 BHPBilliton and MEL (Minera Escondida Ltda.) have developed a process to recover copper from coarse particles in the rougher tailings. Copper recovery from fresh tailings is not new. Several operations in Chile, such as Chuquicamata, El Teniente (AMEC, 2003), Mantos Blancos and others have operated various forms of tailings circuits. Both Chuquicamata and El Teniente practice cascade flotation scalping off froth containing fine copper particles after allowing sufficient retention time, air inducement and, sometimes, additional reagent addition. Chuquicamata tailings are not segregated but floated in sequential cascade and conventional large cell arrangements. At the Valle Central operation of El Teniente a coarse fraction of mill tailings is ground and floated, with the rejects recombined with fine tailings and subjected to cascade flotation through a sequence of concrete launders as the tailings flow towards their final deposition area. Mantos Blancos cyclone the rougher tailings and blend the underflow with scavenger concentrate from elsewhere in the principal circuit prior to flotation in Wemco Cells. Kemess in BC, Canada operates a 160 m3 Outokumpu cell to reduce the tailings sulfur content (Rasmussen, et.al, 2004)."

Jan 1, 2005

By D. Hatfield

"Flotation plants typically aim to maximise recovery at or above a target grade. As the ore from the mine varies, operators increase or decrease the mass pull in different flotation banks by adjusting air and level set points in order to achieve target concentrate grade. A methodology has been developed to maximise overall recovery at target grade by determining the optimal mass pull for each bank. However, the approach of targeting equal grade for each ore type in the deposit leads to sub-optimal overall recovery. This is because some ore types sacrifice a large amount of recovery to reach target grade while others easily achieve target grade and can be processed at higher than target grade for little or no loss in recovery. Processing different ore types at different grades and blending the concentrates therefore gives a higher overall recovery.This paper presents a case study where an 80 year production forecast was made for a large Chilean copper concentrator in feasibility stage. A circuit model was created using SGS’s Integrated Geometallurgical Simulator (IGS) for the different ore types to be processed. The model was calibrated from standard rougher flotation tests (MFT), cleaner tests and from the results of plant surveys of similar operations. The pull rates for each bank in the circuit were determined to achieve an optimal graderecovery curve for each ore type. These curves were combined at different concentrate grades for each ore type to obtain the mathematically optimal overall recovery at target grade. The paper shows a methodology for obtaining an optimal combination of operating conditions for each ore type to maximise overall recovery at a set combined concentrate grade."

Jan 1, 2013

By Claude Bazin

"Laboratory semi-batch flotation tests were conducted using two different sulphide ore samples. The size reduction was adjusted to cover a wide range of flotation feed size distributions. Results show that similar recoveries can be achieved independently of the fineness of grind. This result suggests that possible energy savings could be achieved by a redistribution of the power between the grinding and regrinding mills. The behaviour of the selectivity curves shows that some gangue minerals are more sensitive to particle size than other ones, implying the existence of preferential associations between minerals in the ore.INTRODUCTIONInteractions between grinding and flotation have been studied for many years, and still a robust model to link the two processes lacks to be developed (Girard et al., 2005; Bazin et al., 2001). The ore size reduction liberates mineral grains, while flotation separates them into valuable minerals and gangue. The more size reduction that is applied to the ore the more important is the mineral liberation but also the production of fine particles that can pose problems during flotation (Trahar and Warren, 1976). The definition of the grinding requirement for flotation is a complex problem (Rickelton and Dell, 1977; Sosa Blanca et al., 2000; Morrison, 1993; Wei and Gay, 1999).This paper analyzes the effect of the fineness of grind using semi-batch flotation test results. The first two sections describe the test procedure and the results. The third section analyzes the results in terms of liberation and selectivity, and proposes a possible redistribution of power between grinding and regrinding mills."

Jan 1, 2006

By R. Maxwell

"At Opemiska Copper Mines we have, over the past four years, operated 300 cu. ft. and 700 cu. ft. flotation cells as roughers, scavengers and cleaners and found them competitive with conventional flotation cells on a cu. ft. basis on all phases of flotation.The economics are very much in favour of the large cells for the following reasons:Power consumption is 35 to 40%, of conventional machinesMaintenance cost is about 20 to 25% of conventional machinesSpace required is about 30 to 35% of conventional machinesInstallect cost is about 40%, of conventional machinesTo put the above in more concrete terms below is what we are doing at Opemiska:1. Increasing mill capacity from 2000 to 3000 T.P.D. and will use only 5Cff, of the flotation space for 3000 tons that we used for 2000 T.P.D. with conventional flotation machines.2. Will require only 10 flotation cells for 3000 tons against 85 conventional cells for 2000 tons.3. Cells will be, one 2000 cu. ft. rougher, six 700 cu. ft. scavengers (2 banks of 3 each) and one cleaning circuit using three 300 cu. ft. cells.You will note that in this 3000 ton per day plant, we are going to have only ten cells. Had we put in conventional cells for this tonnage, we would have needed 120 cells."

Jan 1, 1970

By D. J. Lucifora

Monitoring-While-Drilling (MWD) is a proven technique that records instantaneous on-drill parameters which can be used to supply contextual information for in-situ, down hole conditions, such as: changes in geology, the presence of pre-existing fractures and dynamic alterations, down hole conditions including bit bailing, bit blockages and bit wear, and improper drill operation. This technique has been widely used in the oil and gas industry and, eventually, it was transferred to the mining industry. A challenge when analyzing and interpreting MWD data is in utilizing proper filtering which enables one to properly eliminate any ?noise? from the signals of interest. Overall the importance of MWD data is that, through the collection of operational field-based data, a dataset can be acquired which allows experimentation and analysis to be carried out. Such a dataset is often impossible to replicate in a laboratory setting. If successful, and through iterative refinement, any promising method can eventually be implemented on-machine and using real-time monitoring techniques. This paper will provide a state of the art review of presently used MWD techniques and applications in industry. The paper?s primary focus will be on shallow, mining-style, blast hole drilling but will also take into account techniques and applications utilized in oil and gas drilling which have not been adopted in the mining industry. In the cases where MWD techniques and applications exist solely in oil and gas drilling the paper will examine and comment on the potential utility of technology transfer to mining applications.

Aug 1, 2013

By D. Wolfe, K. Reid, T. Nunn

"The Aurora North mine has been operating for more than ten years, and is the source of over half of Syncrude’s bitumen production. In order to minimize front-end rejects, and to allow for high throughput, the ore top size at Aurora has been set at a nominal 125 mm. These relatively large lumps have a significant effect on both pump performance and pipeline pressure gradient. Current design methods underestimate the solids de-rating effect of lumpy slurries in pumps, and do not accurately describe the distribution or magnitude of the lump effect on pipeline pressure gradient. Data from the Aurora hydrotransport systems has been compiled, to quantify the effect of lumps on the pump head ratio and pipeline pressure gradient, and how this effect changes as lump ablation occurs along the length of the pipeline. A model has been built, using a logarithmic curve, which predicts the effect of 125 mm lumps on pipeline pressure gradient as a function of velocity and the distance from the start of a hydrotransport pipeline. This model is applicable only to Aurora hydrotransport operation, but similar models could be developed for other operations using the same methods. Using accurate pipeline pressure gradients and pump head ratios when designing future hydrotransport pipeline systems will help improve their reliability and operability."

Jan 1, 2014

By K. Ohto, B. B. Acihikari, H. Kawakita, M. Gurung, S. Alam

Two kinds of adsorbents were prepared from persimmon tannin extract to investigate their adsorption behavior of metal ions from hydrochloric acid solution; one was prepared by treating with concentrated sulfuric acid while another was prepared by immobilizing functional groups of quaternary amine. The former adsorbed only gold(III) and its maximum adsorption capacities was evaluated as high as 1510 g/kg while the latter adsorbed not only gold(III) but also palladium(II) and platinum(IV), the maximum adsorption capacities of which were evaluated as 820, 89 and 101 g/kg, respectively. For both adsorbents, practical adsorption of base metals was not observed.

Jan 1, 2011

By R. N. Murarka

"Hydrocyclone modelling and selection procedure is illustrated. Computerized procedure for hydrocyclone cut size determination for grinding and non-grinding applications is described.A standard procedure for evaluating operating hydrocyclones is described in detail. Many case studies are illustrated comparing actual plant performance with the computer simulation output in terms of overflow product size distributions.INTRODUCTION Cyclones are widely used for applications such as: close circuit grinding, backfill, tailings and dewatering. Normally, cyclones are used for very fine separations where screens are not suitable or too expensive. Figure 1 shows the separation size range of various classifying devices. Cyclones are popular because of their low capital and operating cost. Cyclone selection procedure for different applications depends on the amount of information available on the cyclone feed slurry characteristics. Closed circuit grinding applications will be discussed in detail in this paper. The Cut Size:The size of the material in the feed which reports 50% to each product stream (i.e. underflow and overflow), after correcting for the feed solids by-passing with the underflow liquid, is termed the cut size or ""d50c"". This is often used as the criterion and the basis for cyclone design.When the corrected recovery to underflow of each mesh size in the feed is plotted against the geometric mean size in microns on a log scale, the micron size corresponding to 50% recovery is the d50c size."

Jan 1, 1992

By S. Dessureault

The relatively recent explosion of available data in all business sectors has induced a common expression of “drowning in data, starving for information.” The mining sector is affected by the information age through equipment-based sensors, process monitoring, and traditional enterprise data sources. Information technologists have developed techniques such as data mining that apply new and old statistical algorithms to large datasets. Mine planners and managers can apply these tools for improved planning and control, thereby increasing the use of the highly underutilized information system infrastructure in most modern mines. This paper describes the use of data mining and its enabling technology, data warehousing, in the development of an energy consumption model for large surface mines using real historical data.

Jan 1, 2007

By D. M. Wyslouzil

"Micron or sub-micron size gold inclusions in sulphide minerals cannot be extracted by conventional cyanidation. The gold surfaces must first be exposed by decomposition of the sulphides. As an alternative to roasting, pressure oxidation was found to be a most satisfactory method to decompose the sulphides and expose the gold particles. For cyanidation the pressure oxidation pulp has to be neutralized and stabilized with lime. It was found that thiourea can extract the gold directly from the pressure oxidation pulp without pH adjustment and oxidant addition. The main obstacles against the common use of thiourea are circumvented by a recently described control method of the emf during leaching.INTRODUCTION Amalgamation and cyanidation are the most conventional processes for gold extraction. The prerequisite for gold extraction is the possibility of gold surface to be contacted by mercury or by the cyanide solution. Encapsulated gold has little chance of contact and this leads to poor extractions.The reasons why a gold ore may be refractory are: micron or sub-micron size gold particles included in the sulphide minerals, such as pyrite and arsenopyrite; presence of and association with antimony, arsenic, tellurium and carbonaceous minerals. Some alternative processes, such as double oxidation(1,2), pretreatment with lime , H202, chlorine and Caro's acid, roasting and thiourea leach, have solved some of the problems of ""refractory"", but the sub-micron gold in sulphide minerals still shows little response. Roasting and the cyanidation of the calcine was one of the most successful approaches for this type of gold ore.There are two disadvantages to the roasting process: (1) the generation of sulphur, arsenic, antimony and mercury containing gases is undesirable and the control is extremely expensive; (2) gold particles might be fused in the roasted product and the oxidized base metals in the calcine might reduce the cyanidation efficiency. In recent years the pressure oxidation process has been considered as one of the more effective and satisfactory methods to decompose the sulphide minerals and expose the gold surface to the cyanide leach solution. The pollution problem could be better controlled and the gold extraction is more amenable."

Jan 1, 1985

Adaptive processing is often related to the mineral composition of the mining block currently processed. The portions of waste, ore and secondary product minerals considered are always positive and typically sum to 100% (i.e. a composition). A typical solution to predict block averages of spatially dependent quantities would be block kriging. However, kriging is based on spatial correlations and it has been repeatedly shown that correlations of compositional data are spurious and blurred by the constant sum constraint. Aitchison (1982) proposed a general solution for compositional problems, based on transforming the compositional data to a set of logarithms of ratios of components, and analysing the transformed scores. The transform is chosen to be invertible to ensure that no information is lost in the process. This methodology avoids spurious correlation problems and ensures coherence between results obtained with different subcompositions. Pawlowsky-Glahn and Olea (2004) adapted the approach for point-support geostatistics, allowing the prediction of point compositions from spatially neighbouring data, without the artefacts induced by standard multivariate cokriging. Unfortunately upscaling the results of this approach with block cokriging is not straightforward, because of the nonlinearity of logratio transforms. Furthermore, we have to consider those nonlinearities created by the dependence on the block composition of extraction efficiency and processing costs of the possible processing choices. This paper proposes a solution for predicting the conditional expectations of the benefit of processing the block with each processing choice using geostatistical simulations of the local values of the composition and the resulting block integrals. The computation for a large number of blocks can be done efficiently using Cholesky decomposition. The approach also allows the calculation of prediction errors for expected compositions and expected benefit at almost no additional computational cost. Such compositional approach is necessary, for example when processing choices depend on proportions of certain minerals after other components have been removed; or if processing alters the composition in a multiplicative way, by partially removing a portion of some components.

Aug 1, 2013

By B. S. Fee, R. R. Klimpel

"Froth flotation is the most widely used and economic means of concentrating metal sulfide ores such as those containing copper, lead, zinc, nickel, molybdenum, and pyrite. Also recoverable are other metal species that are often associated with sulfide ores such as cobalt, platinum, gold, silver, etc. Most of the initial developments made with the process of froth flotation in the early 20th century were based on the processing of metal sulfide ores. It is the relative technical and economic ease of floating metal sulfide minerals with small amounts of appropriate frothers and sulfur containing (thio) collectors that has been a major economic driving force behind the rapid expansion in the supply of metals such as copper, lead, zinc, and nickel that has occurred in the world's economy in the last 50 years. This author estimates that 1.6 billion tons of sulfide ores are processed each year (1980) in the free world based on the froth flotation process.While there has been a tendency for the quality of metal sulfide ores in any one geographic location to deteriorate over time due to mining intensity, the overall global supply of sulfide minerals is still very large. Thus, the physical supply side of sulfide ore concentrates has not been under strong technology improvement pressure with increasing metal demands. Part of this is due to the ability of capital to consistently move to new geographic locations having suitable grade sulfide ores. In these moves, the actual froth flotation technology used (including collector chemicals) has had to change little. As an illustration of this trend, of the approximately 80,000 metric tons of thio collectors used commercially (1980) in the free world, almost 98% were known and manufactured in some form 25 years ago (1). This is clearly not typical of reagent development in other process related industries. In addition, the industrial scale practice of froth flotation applied to sulfide ores has proceeded since the 1920 s with often little direct (predictive) scientific explanation due to the extreme complexity of the flotation process. Empirical testing has been a mainstay of industrial flotation reagent development and use. Even today there is often strong disagreement between researchers as to the mechanisms of chemical flotation practices that have been performed successfully at an industrial scale for many years."

Jan 1, 1987

By S. Surapunt, C. M. Nyamai, K. Itagaki

"The use of liquid copper as a medium for zinc extraction has been used in the Warner Process as a method of processing zinc-lead sulphide ore. The recovery of zinc metal is based on the reaction:ZnS(s) + 2Cu(l) = Zn(g) + Cu2S(l)In this method, thermodynamic and phase equilibria investigations of the Cu2S-FeS-ZnS and Cu2S-PbS-ZnS systems are of importance and form the basis for the liquid sulphide phase which appears as a product and is used as a solvent in the Warner Process. Phase relations in the Cu2S-FeS-ZnS and Cu2S-PbS-ZnS ternary systems were determined experimentally at 1473°K to provide a fundamental basis for the new zinc smelting process. The results show that the solid solubility of ZnS in the two systems is very small (2 wt% to 3 wt% ZnS in FeS, 4 wt% ZnS in Cu2S for the Cu2S-FeS-ZnS system; less than 0.5 wt% ZnS in both PbS and Cu2S for the Cu2S-PbS-ZnS system). The Raoultian Activity Coefficient of ZnS in the liquid mixtures and the vapour pressure of zinc over the matte in both systems is relatively large (?° = 7.7 – 15.8, Pzn(atm) = 0.088 – 1.026 for the Cu2S-FeS-ZnS system; ?° = 8.9 – 12.9, PZn(atm) = 0.075 – 0.214 for the Cu2S-PbS-ZnS system). On the FeS-ZnS join, the only phases detected are FeS and iron-rich sphalerite (Zn, Fe)S. The binary join mixture occurs at about 92 wt% FeS-8 wt% ZnS at 1473°K. Electron microprobe examination of the quenched samples indicate about 47 wt% to 48 wt% FeS in sphalerite and about 2 wt% to 3 wt% ZnS in the iron sulphide phase. On the Cu2S-ZnS join, microprobe analysis reveals that the maximum solubility is 4 wt% Zn in liquid Cu2S and 3.6 wt% Cu in solid ZnS. In the Cu2S-PbS-ZnS ternary system, microprobe analysis of the quenched samples indicate on average, 5 wt% ZnS in the liquid phase region. The only phases detected on the PbS- ZnS join are ZnS and PbS. The eutectic phase contains, on average, 13 wt% ZnS. The phase relationships, very low solid solubilities of zinc sulphide in the liquid mixtures of both Cu2S-FeS-ZnS and Cu2S-PbS-ZnS systems, coupled with the high Raoultian Activity Coefficient of ZnS as well as the high vapour pressure of zinc over matte all favour the partitioning of zinc metal into the vapour phase. This new process is cost effective and bypassesthe expensive and tedious conventionaltechnique of zinc production involving oxidationof the sulphide ore by roasting followed bya reduction process to extract the zinc. Theresults indicate that a new zinc smelting technologyusing the Warner Process would bemore efficient and preferable over the traditionalmethods of zinc extraction."

Jan 1, 2002

By F. Lindroos

A cornerstone in the LKAB Green Pellet concept is to produce pellets with a small footprint in terms of energy con-sumption, CO2 emission and emission of other elements harmful to the environment, like dust, sulphur dioxides, nitrogen oxides, chloride and fluorine. The concept also encompasses our determination to make pellet products that contribute to low environmental impact and low energy consumption in our customer?s processes. The presentation will focus on the pelletizing process. It will describe both how we have attempted to decrease the generation of unwanted components in the process gas, and how we have tested or evaluated equipment for external gas cleaning. We will discuss and give examples from recent and on-going efforts and outline some of the future challenges we see, to meet our own environmental standards and also the tough demands imposed by EU and national legislation, while striving to boost production.

May 1, 2011