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By S. -H. Sohn, M. -K. Cho, G. -G. Hong

In order to evaluate the properties of coating materials for BOF, the effects of dolomites (dolomite and light burned dolomite) addition on durability of coating materials were investigated. In all coating materials, matrix was dicalcium ferrite(C2F) and both free MgO and dicalcium silicate(C2S) were precipitated. Fe203 content must be controlled to improve the adhesion and durability of coating materials for BOF during oxygen blowing process. The amount of dolomites added to BOF slag must be controlled in optimum condition with high refractoriness of C2S to improve the adhesion of coating materials for BOF. The weight ratio of converter slag to dolomite must be below 8 to improve the adhesion and durability of coating materials simultaneously.

Jan 1, 2004

By J. G. Whellock, J. W. Matousek

"In spite of their importance to the economics of many metallurgical projects, the values and technical aspects of precious metals losses in smelting operations are relatively undeveloped subjects. This paper attempts to provide a condensed overview of precious metals losses in pyrometallurgy, using some of the limited production and experimental data available. It is intended for three general groups of metallurgists - operators attempting to improve recoveries, cost-accounting engineers making estimates of metal losses in new or modified smelting plants, and research engineers and students.Distribution coefficients of precious metals, the ratios of metal or matte assays to slag assays, are convenient means of comparing smelting processes and the tendencies of the different metals to enter the slag. For silver in lead blast furnaces this ratio is approximately 250;for gold and the platinum group metals in submerged-arc, electric furnaces it is 900. The ratio for gold and PGMs in converters varies with the degree of oxidation of the charge. The over-all cycle-average for industrial installations is tentatively estimated to be 35.IntroductionThe magnitude of precious metal s losses in pyrometallurgical operation s is difficult to assess. The primary producers are generally reluctant to discuss the subject. The by-product producers (the large sulphide smelters o f copper , nickel, and lead) might be more willing to disclose information, but these have precious metals in their feeds in such dilute quantities that accurate accounting is extremely difficult. It is not until numerous processing steps have been taken t hat the precious metals become sufficiently concentrated to permit acceptably accurate sampling and analytical procedures to be followed. Thus, knowledge of the precious metals contents o f the intermediate mattes and slags may simply be unavailable."

Jan 1, 1990

By F. Parada Luna, F. Parada Torres, J. Salvo, A. Reghezza

In the pyrometallurgical processes of copper concentrates, arsenic is preferentially concentrated in the dusts carried by the gases as a result of their volatility and subsequent condensation in the gas cleaning train. In this work results obtained by alkaline leaching of the dusts from Ministro Hales roasting plant, belonging to Codelco, are presented. For the Ministro Hales plant the alkaline leaching would be an alternative to the recirculation of dusts to the roasting furnace. The experimental study considered NaOH and NaOH plus NaHS leaching of two samples of dusts, with 4.24 and 2.55% arsenic respectively. The results show that it is feasible to extract 90% of the arsenic and 50% of the antimony at room temperature using only NaOH, and when the temperature increases to 95ºC, the extractions of As and Sb increase. Copper remains in the solid residue with less than 1% dissolution, and the NaOH net consumption was approximately 140 kg/t of dust. In leaching tests with NaOH + NaHS, two types of methods were tested, baking plus leaching with water and direct leaching with a NaOH+NaHS solution. With the second method arsenic extraction increased to 95% and copper dissolution was less than 0.01% at 85ºC, NaOH 100 g/L, NaHS 90 g/L, 1.5 h and L/S ratio of 5/1 (L/kg). The bismuth remains stable in the solid in all cases. INTRODUCTION The presence of arsenic in copper concentrates has increased with time and the environmental regulations are becoming increasingly more stringent. In concentrate treatment pyrometallurgical plants, most of the arsenic is volatilized condensing in the gas train and is collected along with the entrained solids to form the flue dusts. Under these conditions, in smelters of copper concentrates with high arsenic content, the dusts are being treated in hydrometallurgical plants to extract and stabilize the arsenic, which also means that most of the copper contained in the dust is co-extracted with the arsenic. This affects the recovery of copper in the smelter and an alternative such as the selective alkaline leaching of arsenic, would allow the copper from flue dust to be recovered.

Jan 1, 2019

By N. Dahata

Earlier research has indicated that an addition of titanium master alloy to aluminum alloys, results in improved fillability, grain refinement and finer pores. B206 alloy differs from other alloys used in automotive industry, with lower titanium level. This paper examines the effect of alloy chemistry (copper and titanium levels) and grain refinement (A1-5`)oTi- 1%B grain refiner) on grain size, microstructure and microporosity in B206 aluminum alloy. In this study, characterization of grain size, microstructure and microporosity was carried out using light optical microscopy (LOM) and scanning electron microscopy (SEM). Results have shown that the addition of 0.05 wt % titanium resulted in grain refinement of B206 alloy. With an increase in titanium to 0.25 wt further grain refinement, much reduced pore size and uniform distribution of pores resulted. These results suggest that B206 with proper addition of titanium has a promise as an alloy for automotive casting.

Jan 1, 2007

By Ashu Garg, Anirban Bhattacharya

"Friction stir spot welding of aluminum alloy AA6061-T6 sheets was performed with circular (plunge depths 0.4 and 0.6 mm), square and triangular tool pin (plunge depth 0.4 mm) with constant 0.2 mm shoulder penetration to characterize various zones of weld nugget. It was observed that the depth of the stir zone formed below the tool pin is comparatively similar for different tool pins but wider for circular tool pin. The size of another stir zone formed at the interface of tool pin and a tool shoulder is observed to be larger for triangular and square tool pin due to the higher swept rate. Predicted strain from finite element analysis, calculated strain rate using Zener-Hollomon relationship and experimentally measured grain size distribution indicates severe amount of plastic deformation in-and-around the nugget/spot region. Finer grains in various stir zones were observed than thermo-mechanically and heat affected zones. Grain size (at distribution peaks) in stir zones varied around 2.54 µm to 3.69 µm for different tool pin profiles as compared to base metal grain size of 20 µm. Microhardness results indicate that the welded region is quite softened than base metal and maximum hardness is mostly observed around the thermo-mechanically affected zone.INTRODUCTION Friction stir spot welding (FSSW) is widely used for joining the sheets of materials like aluminum, copper, magnesium, etc. The process begins by plunging a rotating tool (generally having a pin and a shoulder) into the sheets to be welded. Continuous stirring of the tool and downward plunging force generates localized heat due to friction at the tool-sheet interface and plastic deformation of the sheet metal. The material gets softened and the plasticized material adjacent to the tool pin starts flowing due to the action of tool rotation and tool plunge thereby causing intermixing and bonding between the overlapped sheets. The tool stirring also promotes grain refinement in the weld nugget associated with high strain, strain rate and thermal cycle. The formation of new microstructure also affects the mechanical properties and efficiency of FSSW joints. Studies also showed that the tool pin design and tool shoulder feature exerts a noteworthy influence on the material flow and intermixing during the FSSW process (Reilly et al., 2015; Hirasawa et al., 2010). Sarkar et al. (2016) studied the material flow and intermixing during FSSW using tracer material method and reported that the size and width of flow zone increases with tool penetration depth. The influence of tool rotational speed on microstructure and stir zone temperature was investigated during FSSW of dissimilar AA6061-AA5754 alloys (Gerlich et al., 2007). They reported that the average grain size in stir zone of AA6061 weld increases with increase in tool rotational speed. In another work, Gerlich et al. (2008) studied the local melting and tool slippage during FSSW of Al alloys. Tool slippage was investigated by calculating the strain rate using Zener-Hollomon relation. Garg and Bhattacharya (2017a) studied the effect of dwell time, tool pin profiles and tool rotational speed on shear strength, microstructure, temperature and strain distribution during FSSW of AA6061. In another work, Garg and Bhattacharya (2017b) analyzed the effect of different tool pins and pinless tools on the shear strength and microstructure during similar and dissimilar FSSW of AA6061-T6 and pure Cu. Chang et al. (2004) proposed mathematical relationship between the average grain size and Zener-Hollomon parameter during friction stir processing of Mg alloy. Solhjoo (2010) presented a mathematical approach to determine the critical strain as a function of peak strain required for initiation of dynamic recrystallization in austenitic stainless steel. Fratini and Buffa (2005) also proposed the numerical model to determine the grain size during continuous dynamic recrystallization phenomenon."

Jan 1, 2018

By China University of Mining and Technology, P. Zhang, C. Zhou, C. Duan

"Recovering pyrite from the gangue with high sulfur content is of great significance for both economic development and environment protection in China. Due to the global water shortage and high cost in wet separation processes, it is urgent to explore more efficient energy and water conservation method in mineral processing field. This study has proposed an innovative method based on density difference for fine pyrite enrichment by vibration fluidized bed. In this study, the total sulfur content (TSC) of the gangue sample is 19.18%, and the pyrite is disseminated with fine granularity in the gangue which should be crushed for dissociation. The combination and dissociation experiment of -6mm gangue shows that the dominant density of -6+3mm, -3+1mm and -1+0.5mm comminuted material is +2.9g/cm3. Based on the analysis of characteristic, the effects of various factors on the separation performance were experimental studied. The results show that gas velocity, vibration intensity and bed height all have the significant effects. With the increases of superficial gas velocity, vibration intensity and bed height, the separation performance all presents a decreasing tendency. Additionally, the TSC of -6+3mm, -3+1mm and -1+0.5mm materials are respectively up to 37.94% , 35.43% and 30.61% at the optimum conditions, which are the 1.72?1.90 and 2.29 times as much as the TSC of raw material, respectively. This study demonstrates the vibrated fluidized bed can recovery pyrite from the gangue effectively.INTRODUCTIONWith the increasing mining and separation of coal, the yield of gangue has a further growth tendency, which has become one of the largest reserves of industrial waste (Querol et al., 2008). However, many harmful elements, such as S?NOx and Hg, is existed in the gangue leading the serious damage to the soil and environment (Hao, Yun, Zhanyuan, Sen, & Song, 2013). In addition, the economic would be suffered from the loss resulting in the occupied of arable land caused by the accumulation of gangue (Yeheyis, Shang, & Yanful, 2009; Zhou, Liu, Yan, Fang, & Wang, 2012). Therefore, the government has put forward the policies of ""green mining"" in China (Xing & Gao, 2009; R. Zhang, Ai, Zhou, Ju, & Zhang, 2015; Zheng, Du, Li, Qiu, & Yang, 2015). Among different research areas of coal utilization, extracting the useful minerals has become one of hot topics (Ledin & Pedersen, 1996; P. Patra & Natarajan, 2003; Partha Patra & Natarajan, 2004). At present, many researchers has devoted to the desulfurization of coal all over the world. As result, the sulfur element, which is mainly existed in the presence of pyrite, would transferred in the tailings, namely the gangue. Meanwhile, the pyrite is important raw materials to produce rubber, paper, textile and match. Consequently, recovering the pyrite from the gangue is not only suitable to the requirement of ""green mining"", but it could turn the waste into the treasure having the important significance."

Jan 1, 2016

By K. Esmaieli

The Synthetic Rock Mass (SRM) approach has the potential to capture the mechanical behavior of large rock samples. In order for the method to be used with confidence it is necessary to gain a good understanding of the factors that influences its analysis. This paper reports on a series of numerical experiments, based on field data from a large underground mine, to investigate the influence of intact rock mass strength of a constructed (SRM). A jointed rock mass defined by three fracture sets was simulated by a Discrete Fracture Network (DFN) model. The generated fracture network was subsequently embedded into six different intact rock samples, simulated by a bonded particle model in PFC3D, generating six SRM samples. Each intact rock sample was 7 m × 7 m × 14 m and assigned different mechanical properties. The first intact rock sample was assigned a uniaxial compressive strength of 205 MPa and an elastic modulus of 104 GPa with the UCS and elastic modulus values of the other samples downgraded by 10% until the weakest sample had a UCS value of 121 MPa and an elastic modulus value of 61 GPa. All SRM samples were loaded under uniaxial compression to obtain the complete stress strain curve. It was observed that the compressive strength of the rock mass samples decreased by 10% following the same trend as the rock material strength. However, the elastic modulus of the rock mass samples decreased non-linearly with reduction of the elastic modulus of the rock material. The Poisson's ratio of rock mass samples does not change with decrease of rock material properties. For the post-peak behaviour the results show that both the brittleness index and the residual strength of rock mass samples decreased as the rock material properties degrades.

Aug 1, 2013

By William A. Napier

The Mantaro Phosphate Property is located ~ 250 km east of Lima, Peru in the Andean altiplano near the city of Huancayo, Junin District. The Mantaro deposit is a mineralized zone of phosphatic rock currently defined by surface outcrops, trenches and drilling extending over a strike length of more than 30 km and a width of more than 5 km covering ~27,700 hectares. Mineralization is exposed as three roughly parallel exposures (?mantos?) trending in a northwest-southeast direction along the Mancaspico syncline. Estimated mineral resources1 contained in Manto 1 of the Property (4% P2O5 cut-off) as of February 21, 2010, are: Measured 5.548 million tonnes @ 10.8% P2O5 Indicated 33.975 million tonnes @ 9.9% P2O5 Measured + Indicated 39.523 million tonnes @ 10.0 % P2O5 Inferred² 376.265 million tonnes @ 9.0% P2O5 1Tonnes rounded to the nearest 1,000 and grade to 1 decimal place. 2Inferred material reported with no cut-off and an assumed grade. There is considerable potential to expand the resource base. Mantos 2 and 3 of the deposit have been geologically mapped and exhibit surface mineralization widths similar to Manto 1. Given that the deposit is of marine sedimentary origin, it is reasonable to infer that comparable grades and depth of mineralization are present within Mantos 2 and 3. Based on this assumption, the potential mineral deposits within Mantos 2 and 3 are estimated to be approximately: Manto 2 425-435 million tonnes @ 9% P2O5 Manto 3 280-290 million tonnes @ 9 % P2O5 These potential quantities and grade are conceptual in nature, there has been insufficient exploration to define a mineral resource and it is uncertain if further exploration will result in these targets being delineated as a mineral resource. However, should such conceptual resources be confirmed by trenching and drilling, the Mantaro Phosphate Property would rank as one of the most significant phosphate deposits in the world.

May 1, 2011

By Marcel Vallee, D. C. Gagnon, C. CARBONNEAU, P. ST-JULIEN

The Magdalen Islands archipelago, a cluster of fifteen islands, is located near the centre of the Gulf of St. Lawrence on the thickest portion of the Carboniferous Fundy Basin of the Maritime Pro vinces. The bedrock of the Magdalen Platform includes a thick succession of evaporites of Visean Age, occurring as a series of thickenings, ridges, domes and diapirs reaching a probable vertical thickness of close to 6000 m. The emplacement of 1hese salt structures by flowage has much dislurbed 1he SlrOligraphic sequence of the rocks of the Windsor Group, particularly 1he Havre-aux-Maisons Formation. Subsequent tectonic movemenl has broken the overlying Cap-auxMeules Forma1ion info an assemblage of panels and blocks now slightly tilted. Following detailed gravimetric surveys and more than 30,000 m of diamond drilling, SOQUEM has discovered, at various dep1hs, seven salt domes on four of 1he main islands of the archipelago. These evaporite bodies generally are localized near the cemre of complex anticlinal struclUres where diapiric movements and faulting have disturbed the original stratigraphic succession. At Rocher du Dauphin near Grosse 1/e, in 1he northern part of the archipelago, Seleine a SOQUEM subsidiary is developing a mining complex with an annual capaci1y of 1,250,000 1onnes of deicing salt for 1he Canadian and Eas1ern United Swtes marke1s. The stan of operations is scheduled for April 1982.

Jan 1, 1984

By H. R. Banks

IF you have ever travelled in the valley lying between the Selkirks and the Rockies in the East Koorenay district, you will have noted that the former mountains are rounded and massive, while the serrated peaks of the latter, fingering into the sky, bring an entirely different. picture. These two mountain ranges, with the comparatively level valley between, serve splendidly to introduce the subject for discussion. It is rather strange that, despite the fact that wear is undoubredly the greatest force with which human ingenuity bas to contend, it has come in for very little study from the stand point of pure science. Empiricism has been the sole ally in the fight for improvement! That we may have a clear understanding as to what we mean by wear, I would include in the term the breaking dawn of ail solid matter, from the natural wearing dawn of the mountains previously mentioned, to the hale in the mill pipe-line, which forces one to shut-down-usually at some un-earthly hour-to carry out a repair. It seems a far cry from mountains to mill launders or pipe-lines, but, magnified sufficiently, most of the materials with which we have to deal would show surfaces not unlike those we see around us. The progressive steps of wear, or ?erosion' as our geological friends would prefer to term it, are exemplified in the two ranges of mountains and the valley between. True, the wearing dawn by natural forces is a slow process. The aeons which have passed since first these mountains were formed seem endless. The natural forces pitted against them seem puny in the light of the interminable rime that has been needed to effect the changes. But here, as in the case of the materials with which we are dealing day by day, the combination of many forces ultimately brings about that condition which we describe as 'worn out'. In the case of the mountains, it is when they are finally levelled into plains, and in the case of equipment which we use, it is when that equipment will no longer serve its purpose.

Jan 1, 1943

By V. S. Gischig, G. Preisig

Hydraulic stimulation of deep reservoirs is an essential procedure for developing engineered/enhanced geothermal systems (EGS), but also in other Geo-energy contexts. The goal is enhancing permeability to such a degree that fluid flow rates within the reservoir are sufficiently high for an economically productive reservoir. Two fracture stimulation mechanisms are distinguished that may occur concurrently during the hydraulic treatment: 1) During hydro-fracturing (HF) new tensile fractures are propagated from the borehole by means of a fluid pressure overcoming the minimal principle stress d3 plus the tensile strength T0 of intact rock. In case of a pre-existing fracture oriented normal to d 3 , the fracture can be opened by exceeding d 3 only. Fluid injection is performed via small packed intervals for creating a stack of hydraulic fractures. 2) During hydro-shearing (HS), over-pressure induces slip along pre-existing fractures that are favourably oriented in the stress field for reactivation in shear. Such stimulation is usually performed in a large packed interval or in an open borehole. Which mechanism occurs predominantly during stimulation depends on the rock mass structure and in-situ stress field, but also on the orientation of discontinuities intersecting the open-hole section and thus being pressurized. Both mechanisms also differ in how they affect fracture permeability. While permeability gained by HS is mostly irreversible due to rearrangement of asperity contacts accompanied with shear dilation, permeability enhanced during HF reduces nearly reversible after pressurization unless proppant is used to ensure permanent apertures. In this contribution, we critically discuss the pros and cons of both mechanisms regarding efficiency of enhancing permeability and the associated hazard of induced earthquakes based on literature review and numerical modelling. We review literature that reports on how much permeability required for productive EGS reservoirs and how much permanent permeability can be gained by stimulation. We also compile information regarding the degree of seismicity induced during HFor HS-dominated stimulation procedures, together with conceptual studies that reveal characteristics of seismicity associated with the two mechanisms. Many observations and models indicate that HF may have a higher tendency of being aseismic, while felt seismic events are usually associated with HS. Further, we present a hydro-mechanically coupled fracture flow model that investigates, if and to what degree the stimulation strategy can be designed such that one of the two mechanisms is evoked and dominates over the other. It shows that HS may dominate in presence of larger persistent fractures nearly optimallyoriented in the stress field, even if HF is attempted in short packed intervals. The model further demonstrates that stress transfer during HS promotes the development of permeability across an anisotropic layer of the stimulated rock instead of a large volume. Hence, the study sheds light onto the feasibility of creating productive EGS reservoirs in crystalline rock at several kilometres depths.

Jan 1, 2015

By Olaf Kessler, Jan Kalich, Michael Reich, Julia Osten, Uwe Füssel

Modern automobile bodies consist of different materials, e.g. aluminium alloys and high strength steels. Mechanical joining, e.g. clinching, is very suitable for joining aluminium and steel sheet. But clinching needs a sufficient ductility, which is no longer supplied by high strength steels. Laser-assisted clinching has been shown, to be able to join aluminium and high strength steel sheet successfully. Thereby the steel sheets were heated locally for short times to increase their ductility. Due to the thermal contact between steel and aluminium sheet the aluminium alloys also achieve a local short-time heat treatment. This fact may cause a significant impact, as aluminium sheet in automobile bodies is often used in T4 (or similar) condition and later artificially aged during the paint bake cycle. Aluminium alloys 6016 and 6181 have been short-time heat treated with heating rates up to some 100 K/s. Precipitation and dissolution processes have been monitored in-situ by calorimetry. Mechanical properties have been investigated on as well as after short-time heat treatment by deformation dilatometry. The results show, that suitable short-time annealing parameters during laser-assisted clinching can increase ductility and at the same time act as retrogression for aluminium sheets, resulting in increased strength after aging.

Jan 1, 2015

By S. Esfahani, M. Barati, Y. Kauwachi

"Heat recovery from slag has gained attention due to its high potential in lowering energy intensity of metal extraction processes. A direct method to recover the thermal energy of slag is to use countercurrent air flow that extracts the heat from falling droplets. Often, the solidified slag is aimed to be used as a substitute for Portland cement, thus high cooling rates are required to form an amorphous slag with sufficiently strong hydaulicity. Rapid cooling however involves using large gas flow rates that in turn lower the thermal efficiency of the process. This article presents a mathematical model that was developed to determine the optimum conditions in the heat recovery process and to investigate the effect of the air flow and granule diameter on the cooling rate of the droplets as well as the thermal efficiency of the heat recovery system. INTRODUCTIONMetallurgical slags are the largest by-product of high temperature materials refining and extraction processes. The total amount of metallurgical slag produced in the year 2008 has been estimated at up to 422 million tonnes containing up to 222 TWh/y (Barati and Esfahani, 2011) of thermal energy. Over the past four decades attempts have been made to recover this substantial amount of energy as heat, electricity, or fuel, while none of the proposed method has been commercialized yet.During slow cooling the slag tends to crystallize the constituents (CaO, SiO2, Al2O3, etc.) into a hard, heavy solid. In the past, over 90% (Bengt, 1983) of the molten waste was discharged onto heaps and allowed to cool slowly, then crushed and used in road construction or land filling or as coarse aggregate for concrete. However, later it was found if cooled rapidly, the slag can be used as a substitute for Portland cement. As a result, processes such as wet granulation were created in which molten slag is fragmented with water, forming amorphous (glassy) phases. Despite its effectiveness in producing a suitable material, heat would not be recovered through this process. Thus, dry granulation was introduced in 1930’s and was developed further in 1970 – 1980’s."

Jan 1, 2012

By X. Grant Chen, A. R. Farkoosh, M. Pekguleryuz

Nano-scale Al-(Fe,Mo)-Si dispersoids form during solution treatment in grain interiors (intradendritic regions) of cast Al7Si0.5Cu0.3Mg alloyed with 0.3Mo (wt.%). Unlike the Q-Al5Cu2Mg8Si6 and ?-Al2Cu age-hardening precipitates which coarsen resulting in loss of strength in Al-Si-Cu-Mg alloys, these Mo-containing dispersoids are thermally stable and retain their strengthening effect at elevated temperatures. Consequently, the age-hardened Al7Si0.5Cu0.3Mg0.3Mo (wt.%) exhibits high strength and creep resistance at 300 °C.

Jan 1, 2014

By G. Deschênes

"In 2013, as the prices of precious metals dropped, investors moved their positions to equity markets for higher returns. As a result, the price of gold dropped further to below US$1200 per ounce, prompting additional substantial outflows from gold investments. In response to lagging gold prices, major gold producers initiated large asset write-downs and cost-cutting programmes. In 2015, this trend continues and gold mining stocks are close to lows not seen since the global financial crisis (GFC) of 2008. In the current economic climate many projects have marginal economics, and the number of projects that have competitive development and production costs is declining. A competitive edge is particularly important with the decreasing grades of orebodies, increasing complexity of the mineralogy, and increasingly demanding environmental constraints. In addition, higher cost producers seek to optimize their process t o reduce operating costs.This paper presents some highlights of three case studies on optimization of gold leaching strategies that improved the economics of brownfield projects. Processing of sulphide-bearing ores was optimized by using the synergy between cyanide, lead nitrate, and oxygen. The outcomes were significant reduction of retention times while maintaining or increasing gold extraction and reducing cyanide addition and effluent treatment costs. A stirred tank reactor experimental programme led to direct implementation of reliable leaching strategies from laboratory scale to production. This approach resulted in savings of $2.2 million to $15.2 million on the three brownfield projects discussed in this paper."

Jan 1, 2016

By M. B. Kime

"A set of experimental batch leaching tests studied the effect of pH, time, temperature, and stirring speed on the relative Cu, Co, Ni, and Fe leaching yields of an oxidized copper-cobalt ore sample in an aqueous hydrochloric acid solution. The results were statistically analyzed and modelled using the structural equation modelling method. Models showed that Cu, Co, and Ni leaching yields were strong functions of the leaching time and leaching temperature, whereas the Fe leaching yield depended on the leaching temperature, stirring speed, and pH. Under optimum leaching conditions yields were 99.8% Cu, 82.4% Co, 91.3% Ni, and 30.6% Fe.RÉSUMÉ Une série d’essais expérimentaux de lixiviation en bâchée ont été menés pour étudier l’effet du pH, de la durée d’attaque, de la température et de la vitesse de brassage sur les rendements relatifs de lixiviation du cuivre (Cu), du cobalt (Co), du nickel (Ni) et du fer (Fe) d’un échantillon de minerai de cuivre-cobalt oxydé dans une solution aqueuse d’acide chlorhydrique. Les résultats ont été analysés et modélisés statistiquement à l’aide de la méthode de modélisation par équation structurelle (SEM, de l’anglais structural equation modelling). Les modèles ont montré que les rendements de lixiviation du Cu, du Co et du Ni dépendaient énormément de la durée d’attaque et de la température de la lixiviation ; le rendement de lixiviation du Fe, quant à lui, dépendait de la température de la lixiviation, de la vitesse de brassage et du pH. Dans des conditions optimales de lixiviation, les rendements étaient de 99,8 % pour le Cu, de 82,4 % pour le Co, de 91,3 % pour le Ni et de 30,6 % pour le Fe. INTRODUCTIONThe Katanga province in the Democratic Republic of Congo hosts the northwestern part of the Central African Copperbelt. This region abounds with large, rich deposits of sulfide and oxidized copper-cobalt ores. In general, the main valuable minerals present are malachite (CuCO3Cu(OH)2) and heterogenite (CoO(OH)). Common impurities found in heterogenite are Cu, Ni, Si, Al, Mn, and Fe. The substitution of Co by other cations (e.g., Cu, Ni, and Fe) has an influence on the crystallinity of heterogenite (Deliens, 1974). In general, well-crystallized varieties of heterogenite have lower impurity contents, whereas amorphous heterogenite types usually contain more impurities (Thys et al., 2009). Further, in heterogenite, Co can occur in the 2+ and 3+ oxidation states. The gangue generally consists of quartz (SiO2), talc (Mg3Si4O10(OH)2), kaolinite (SiO2·Al2O3·2H2O), limonite (Fe2O3·3H2O), and goethite (FeO(OH)). Oxidized copper-cobalt ores are often treated by hydrometallurgical methods, whereas sulfide ores are often treated by flotation or pyrometallurgy, depending on their grades. Hydrometallurgical methods typically entail selectively dissolving the metals of interest (Cu, Co, and Ni) in aqueous solutions (leaching), transferring the dissolved metals to an organic solution, and retransferring these to a second aqueous solution (solvent extraction). Copper and nickel are readily dissolved in an acidic aqueous media. In contrast, cobalt is difficult to dissolve, especially if it is present in the third oxidation state; however, this species becomes soluble after it is reduced to Co2+ (Mwema, Mpoyo, & Kafumbila, 2002; Kime & Makgoale, 2016)."

Jan 1, 2017

By Jacek Paraszczak

As the deposits located closer to the surface are getting depleted, more and more Canadian mines produce ore from considerable depths. Deep mining represents a number of serious challenges including high rock temperature. Conventional diesel powered loadhaul- dump machines and trucks so widely used in metal mines constitute an additional source of heat and noxious gases. Due to this, they have a substantial adverse impact on a quantity of fresh air required and a cost of ventilation, particularly since the mines have to meet more and more stringent regulations in this respect. In this context, the paper examines possible alternatives for diesel powered equipment, both these commercially available as those at the stages of prototypes or under development. They are reviewed with regards to their principles, required infrastructure, stage of technology development and its progress. The questions of their flexibility, practicality and economic viability are also addressed. Following the above a potential for their implementation and possible benefits (if any) in the conditions of deep Canadian mines is discussed. The paper concludes with short to medium term predictions concerning the most promising drive alternatives for vehicles destined to operate in deep metal mines.

Feb 1, 2008

By R. A. Lunceford, K. C. Shaver

Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km

Jan 1, 1998

By E. M. Timoshenko, A. V. Tarasov

The results of laboratory, bench-scale and semi-commercial investigations of a method for adding surfactant (technical-grade lignosulphonate) to the process of pressure leaching of nickel-containing pyrrhotite concentrates have been discussed. Lt has been demonstrated that feeding of technical-grade lignosulphonate distributed along the length of an autoclave ensures a reduction in its requirement by a factor of 1.5 to 2 as compared with single-point feeding; it also results in a decrease by 5% in the unit requirement of metallized iron-bearing precipitator in the process of non-ferrous metals precipitation and reduces by 0.05 to 0.1% (abs.) the nickel and copper contents in the tailings of the given process. Technical solutions have been proposed for commercial introduction of the process.

Jan 1, 2004

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999