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By M. Holm

Coal is an important fuel for energy generation, and since there are no adequate alternatives it will also be for the next decades. The deep lying hard coal is important in particular because of its high energy content. Automation of underground mining has led to major improvements in productivity and safety. A fully mechanized longwall shearer workface has already reached a high degree of automation and provides a high productivity for example utilizing the memory cut. Current researches and developments in longwall mining are focused on extending this method by adaptive cutting drum height adjustment. The so-called horizon control is often based on memory cut methods. Horizon control in this way requires information of the environment, which can be provided by models (seam model, cut model) and coal interface detection (CID). Available CID systems only provide an optimal output under specific conditions. The authors propose the shield-data-based horizon control (SDHC) system as an alternative approach. SDHC does not require information from a CID system or an environmental model. All necessary information is provided by roof supports, shearer and process monitoring. The SDHC system was tested in simulation under different seam conditions and yielded promising results which will be presented in this paper. In cooperation with the German mining company RAG the SDHC has already reached an experimental stage. A test assembly was built up at the surface and the SDHC system was implemented on real mining equipment. To make the test scenario as realistic as possible, the SDHC system was only connected to the monitoring system, not to the simulation model. The aim of these tests was to establish the cooperation between all subsystems, find appropriate controller parameters, locate and address safety critical aspects and finally to achieve an automatic cutting drum height adjustment. An introduction of SDHC for shearer guidance is given in this paper. The experimental tests are described and the control results of the realized SDHC system on the test assembly are shown.

Aug 1, 2013

By M. P. Amsden

"Ecstall Mining is a wholly-owned subsidiary of Texas Gulf Sulphur at Timmins, Ontario. The mill tonnage is 10,000 tons per day of two different ores, a copper zinc ore and a silver lead zinc ore, producing about 2400 tons of concentrates per day. These are as a copper concentrate, a high silver zinc concentrate, a low silver zinc concentrate and a silver-lead concentrate. For flotation recovery a very fine grind is required, about 80% minus 325 mesh and the concentrates produced are 40% minus 10 microns.The thickened concentrates are pumped to the filter floor for filtering and drying. The filtering and drying section is separated from the flotation section by a wall and is controlled from a dryer control room by one operator.Two operating panels are located in this control room. One contains stop-start controls for the thickeners, filter motors and vacuum pump motors, and stop-start controls for dryer feed conveyors and dryer product conveyors to concentrate load-out bins, as well as ammeters for conveyor drive motors. Dryer throughput is regulated by Merrick Type L weightometers located on the dryer discharge conveyors and recorded on tons per hour strip charts.The second panel contains the temperature strip charts, furnace drive ammeters, scrubber and exhaust gas controls, burner controls and panel alarms for the four dryers.Filtered concentrates are dried in Nichols-Herreshoff, multiple hearth, dryers consisting of nine hearths (zinc) and seven hearths (copper and lead). There are two dryers for handling zinc concentrates and one each for copper and lead concentrates. The dryers are heated by burning natural gas. Each zinc dryer handles 1,000 t.p.d. and the copper and lead dryers 750 t.p.d. each.Multiple hearth dryers are unusual in the base metal mining industry and the reasons for selecting them in preference to rotary dryers are as follows:1) The concentrates could only be filtered to 15 to 17 percent moisture. These sloppy filter cakes would be extremely difficult to handle in rotary dryers."

Jan 1, 1972

By H. C. Cooke

This paper will discuss two comparatively unrelated subjects; first, a general review of the advances made at the more important properties in the last year; and second, a statement of the conditions controlling the deposition of the copper ores in the Rouyn area, as determined by last summer's field work. FIRST PART Development has been very rapid since I stood before the Institute one year ago to discuss this same subject. Then, there were many properties on which gold had been discovered, any of which might develop into a mine. Further work has eliminated the most of them as possible mines, or at least has shown that before they can attain that status further discoveries must be made on them. Then, all gold veins held forth much the same promise; now the indications are that one particular type of gold vein is of greater prospective value than others. Then, all eyes were turned toward gold as the metal of prime economic importance; now copper has taken the centre of the stage, and gold is distinctly in the background.

Jan 1, 1926

By P. J. Lunder, R. C. Pakalnis

This paper presents the results of research that has been undertaken in order to develop an improved method of determining the strength of hard-rock mine pillars. Pillars are found in various shapes and sizes in all underground mining operations. Prudent engineering design requires that if pillars are to perform as desired, both the pillar strength and the pillar stress must be determined. A detailed pillar stability study has been combined with an extensive database of published pillar case histories (178)resulting in a new “hybrid” pillar strength formula, “The Confinement Formula”, that utilizes classic strength of rock methods combined with empirical methods. “The Confinement Formula” utilizes a “mine pillar friction term” calculated from the average minor/major stress ratio with-in the pillar core. Statistically, the new formula provides better results at predicting pillar strength for the combined database than the best empirically ft pillar methods that currently exist. “The Confinement Formula” allows for the determination of the strength of mine pillars with an increased level of confidence over previously applied methods.

Jan 1, 1997

By Evelynn Stirling

"The paper/presentation will review the evolution of diesel technology from older diesel engines (1990 vintage) through to the latest technology as a result of the ever changing emissions regulations. It will encompass the EPA Tier levels as well as the latest Euro Stage V emissions. The next step with technology will be to address the CO2 emissions, which translates to improving fuel efficiencies of the product as well as other technologies like battery electric, hybrid and fuel cells. As technology progresses it also becomes important to improve connective diagnostic systems to support maintenance practices and improve efficiencies. What will also be presented will be the key emissions changes to the different gaseous and particle mass elements as the products have transitioned from the EPA Tier 3 through to Tier 4 Final regulations. Offering a range of different technologies to the underground mining market matters as not all pieces of equipment will perform optimally due to its duty cycle and application. INTRODUCTION Rudolf Diesel built his first well-known prototype of the high-compression engine in 1897. Since that time, the diesel engine has evolved into one of the world’s most capable and reliable forms of power generation. Diesel engines can be found in a wide variety of vehicles and equipment, powering everything from agriculture and construction equipment to power generators and marine vessels. In the early days the emissions from diesels was very poor and extensive work has been accomplished over the decades to make the product more environmentally friendly. This is more important in underground mining where the space is limited and ventilation is expensive and challenging. DISCUSSION The key driver of the development of diesel technology is the legislation globally around engine emissions. The emission level requirements over the years has forced diesel engine manufacturers to build a deep technical understanding of the system and how to innovate and optimize key elements of the engine. Cummins expertise has been built over the years as the diesel engine has evolved from a relatively simple mechanical engine to an electronic system with advanced air handling, fuel system, after treatment, and controls. Cummins has also continued to expand into systems beyond diesel, including natural gas. Many new components have been added to diesel engines to reduce emissions while improving fuel efficiency and reliability and, at the same time, reduce the total cost of ownership to the customer."

Jan 1, 2019

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By Margaret Anne Stephenson

Today, in Australia, it is increasingly common to see agreements between Indigenous peoples and resource companies being achieved generally as Indigenous Land Use Agreements or agreements pursuant to the ?right to negotiation? process under the Native Title Act 1993 (Cth). Despite progress in this area, resource development on Indigenous lands is not without its challenges for both the resource proponents and the Indigenous parties. History demonstrates that resource development on Indigenous lands has produced struggles between the traditional owners of the land and the resource proponents. In Australia their relationship is generally defined by issues of access to land and assuring continued access to the land for the life of the project. In this context, divisions in Indigenous communities often emerge. The proposed resource project can have the effect of polarising members of an Indigenous community. It may be regarded by some traditional land owners as an advantageous opportunity for the community and by others as a hazard to country and culture. The process of agreement making has proved not only a test for the Indigenous community but also for the resource proponent. In this paper we undertake a contemporary case study of a proposed Australian resource related-development project on Indigenous lands. This project involved a multi-billion gas hub precinct proposed at James Price Point in the Kimberley region in Western Australia. The James Price Point proposal produced a litany of challenges for all parties. The traditional owners faced fundamental social and human rights issues, including a minority opposition to the project, the project's potential cultural heritage impact, the threat of compulsory acquisition of their native title interest by a State government due to an initial failure to settle an agreement, a fracture of their unsettled land claim and a minority rejection of the agreement ultimately reached. Additionally, the ?green? lobby also rejected the proposed gas hub on environmental grounds bringing the green lobby into direct conflict with both the traditional owners in favour of the project and the resource proponent. Ultimately, Woodside announced its decision not to proceed with the proposed gas precinct at James Price Point, in April 2013. In this paper we analyse the complexity of the James Price Point gas hub negotiations with the traditional owners which resulted in an Agreement that promised to deliver substantial benefits for the Indigenous communities. We question why such a favourable and beneficial agreement for the Indigenous community also produced the plethora of challenges and concerns and we consider how future negotiation processes could be better structured to avoid the difficulties that have confronted Indigenous land owners and resource proponents alike.

Aug 1, 2013

By Bruce A. McFarlane

"I WOULD LIKE TO SAY how honoured I am that I have been invited to participate in this panel discussion. I have taken the liberty of narrowing my topic somewhat so that instead of speaking on the Sociology of Professions as a whole I will speak on one aspect of it, that is, on Manpower Problems in the Minerals industry of Canada, with some reference to a new social role for the professionals engaged in this industry. This probably means that I will be encroaching on areas covered or to be covered by other speakers, but I hope that when I do so I will do so from a slightly different vantage point. That is, from a sociological perspective rather than from a historical, industrial, business or professional perspective. I plan to divide my discussion into three areas, namely: (i) problems of ownership and control; (ii) environmental problems; and (iii) manpower and recruitment problems. I do not plan nor am I able to provide clear-cut solutions to the various problems I raise under these three headings. Rather, I hope that my discussion of the problems may form the basis for an extended discussion here and elsewhere. Because of the limitations of time, I will only briefly discuss the first two problem areas noted above – (i) ownership and control and (ii) environmental problems - and I plan to concentrate on the manpower issue."

Jan 1, 1972

By Ajit K. Sinha

"Electromagnetic surveys were conducted over the Yava sandstone-hosted lead deposit in Nova Scotia to evaluate the usefulness of such surveys for detecting and mapping sedimentaryhosted metallic ore deposits. Both transient and multifrequency systems were used for that purpose. The deposit consists of three zones of disseminated galena which also contain minor amounts of pyrite and sphalerite filling the interstices of the sandstone grains. Each zone overlies a basement depression and is separated from the adjacent zone by an intervening basement high. A conductive shale layer underlies the galena-rich sandstone formation at all three zones.Because the concentration of galena (3070 to 4% ) and other sulfides is too low to affect the resistivity of the sandstone formations for detection by ground electromagnetic (EM) methods, the strategy for our survey was to look for areas of basement depressions and the presence of conductive shale in those depressions by EM depth soundings. The presence of the galena-rich sandstone formations could be inferred because of the close association of these two features with the deposits in the Yava area. Both transient and multifrequency EM systems were successful in mapping the basement depressions and detecting conductive shale at the three known mineralized zones. The technique, therefore, seems to offer good prospects for mapping similar stratabound sedimentary-hosted sulfide deposits."

Jan 1, 1993

By D. L. Churcher, R. J. Perry

"In recent years much work has been don e to examine alternate underground backfill support systems with the objectives of improving ground support and reducing mining costs. This report deals with the work conducted at Placer Dome Inc.’s Dome Mine to develop a high density backfill system, taking advantage of the unique properties of this fill material, to address a backlog of large open stopes to sustain stable minewide ground conditions for future generations of Dome miners.IntroductionDome Mine began its existence in 1909 with the discovery of visible gold on a dome shaped outcrop located west of Porcupine Lake in northern Ontario. The orebody beneath this outcrop has supported one of Canada’s premier gold mining operations for 80 years. Production during this time of over 46 000 000 tons of ore has resulted in the recovery of II 500 000 ounces of gold and 2 000 000 ounces of silver. Mining continues today at a production rate of 3500 tons per day, with ore coming from both underground and open pit operations.During the life of the mine, different underground mining methods have been used to extract the ore from a complex deposit consisting of single and multiple vein structures.Cut-and-fill mining was introduced in the 1930s using sand fill and later hydraulic fill for support and to provide a working platform. A total of 1 800 000 tons of sand fill and 7 300 000 tons of hydraulic fill have been placed underground in cut-and-fill stopes. Until the late 1960sshrinkage mining was used extensively, particularly in narrow, steeply dipping zones. Bulk mining with small diameter longholes was introduced about this time, to take advantage of low production costs. Longhole blasting has often been used to recover low grade ore from the walls or sills of old shrink stopes, resulting in large open stopes. Backfilling of these open holes has been restricted to smaller stopes and associated with local ground conditions.In the late 1970s it was recognized that the number of large open holes which were being generated presented serious regional and minewide stability problems for future operations. With higher gold prices, economic ore reserves were being tied up in areas adjacent to multi-level open stope complexes. To stabilize these stopes and allow access, backfilling would be required."

Jan 1, 1990

By Daniel Torres Espinoza, Jose Pinedo

"Ventilation is a vital service in underground mines, required to provide fresh air to the work force and dilute diesel equipment gases (CO, NOx) and diesel particulate matters (DPM). At a Mexican precious metal mine in the state of Chihuahua there is a VOD system implemented using Howden’s control and monitoring system and a state of the art tagging and tracking technology. The JM zone of the mine is ventilated using a push and pull system, using automated regulators on each level to control the air going in and out of the levels. The implementation of advanced control strategies using Howden’s VentSim™CONTROL allows the mine to generate significant savings and increase health and safety of the workers.INTRODUCTIONIn underground mines, ventilation is a requirement in order to maintain the fresh air needed for personnel and equipment. Ventilation regulations dictate the amount of air required underground to carry out day to day operations by limiting the exposure that workers have to toxic gases and other pollutants. Regulations for required airflow in underground operations for diesel pollutants are generally provided on vehicle rated brake horsepower, in Mexico the requirement is 75 cfm/bhp. In underground mines, ventilation services can account to up to 75% of the mine’s energy consumption, and it is very common for fans to operate all the time because of a lack of control infrastructure for the ventilation system. By the implementation of a Ventilation On Demand (VOD) system a mine can reduce this consumption with different control strategies. The main infrastructure required to implement this system consists of remote control of ventilation infrastructure (fans and regulators), a communication network between throughout the mine with the surface and a tracking system for personnel and diesel equipment. Software is required to determine fresh air requirements based on the tracking system data and then send the control commands to the different ventilation infrastructure. In 2015, San Julian Mine acquired Howden’s VentSim™CONTROL (formally SmartEXEC) and the hardware solution to deploy a VOD system at their operation. The VOD system and Fresnillo plc’s San Julian Mine in Chihuahua, Mexico, consists of control of 10 surface exhaust fans, 2 surface intake fans, and 12 underground automated regulators. It also includes the monitoring of 46 flow sensors, 28 CO sensors, 28 NO?? sensors and 42 temperature and humidity sensors, approximately 500 personnel tags, approximately 220 vehicle tracking tags with diesel status (ON or OFF) and approximately 250 tracking zones. This paper discusses the control strategies that have been implemented at San Julian Mine since the system was commissioned and the next steps that will be taken at the mine with the system as they test different level on VOD."

Jan 1, 2019

By R. C. Becker

Welding is playing an important role in the manufacture of construction equipment as used in the mining industry. It provides design possibilities which are unique to this method of manufacture, and normally makes possible lighter weight but stronger products, which can be a definite advantage to a user. Welding is an industry that has experienced major developments over the past decade, all of which have improved our capability to make better welds and make them more economically. International Harvester Company has been introducing these newer welding methods into its manufacturing plants, particularly those producing construction equipment, just as fast as their value has been proven. This paper discusses how modern welding methods are contributing to the manufacture of strip mining equipment.

Jan 1, 1966

By P. C. Santos-Munguía, F. Nava-Alonso, O. Alonso-González

"The gold recovery of a Mexican cyanidation plant, in Sonora, has been decreasing due to the increasing presence of gold tellurides. This work presents the results of different processes aimed to recover the remaining gold from the cyanidation tailings of the operation. The cyanidation in the mine is performed at 0.1 g/L NaCN and pH = 10.3, adjusted with lime. The treatments studied in the laboratory with these tailings were: cyanidation at higher cyanide concentration than that used in the plant, cyanidation with oxygen injection, cyanidation with oxygen and lead nitrate addition, and thiourea leaching. The results obtained with each of these treatments are presented and discussed with the final objective of proposing a method to recover the gold associated with tellurium.INTRODUCTION It has been demonstrated that gold telluride is refractory to the conventional cyanidation process and, for this reason, some alternative methods to recover precious metals from tellurides have been proposed. (Zhang et al., 2010). These include cyanidation with modified conditions or the use of non-cyanide leaching agents. This work presents the gold leaching results of tests performed with a sample of cyanidation tailings obtained from a Mexican deposit containing telluride species. The mine exploits a mesothermal deposit with a molar Te/Au ratio of 1, containing also lead, molybdenum, bismuth and tungsten. Gold is recovered from the ore by standard cyanidation, however, lately the gold recovery has decreased, likely due to the tellurium content of the ore. The sample used in this work was the cyanidation tailings of this deposit. It was treated in the plant by cyanide heap leaching (0.1 g/L NaCN, pH = 10.3 adjusted with lime). Some gold remained after the cyanidation and it was thought that this gold was associated with tellurium. The objective of this work was the recovery of the remaining gold from the tailings by an alternative process."

Jan 1, 2017

By C. Edwards

ABSTRACT The versatility and specificity of rare earth elements (REEs) have led to their use in an everincreasing variety of applications in new technologies; consequently, demand for REEs has increased significantly. However, separating REEs safely and effectively is a complex and expensive process. This paper presents a review of REE mineral processing technologies, providing an update on current capabilities in REE mineral processing and REE extraction from the major commercially valuable REEbearing minerals such as bastnaesite, monazite, and xenotime, as well as the ion-absorption type of REE deposits.

Jan 1, 2013

By R. K. Jonas

Many leading copper and other mineral processors have rapidly adopted advanced controls in last 5-10 years. Almost 600 multivariable predictive controls have been installed in mineral processing, and almost 50% of those are in copper concentrator plants. In most cases, mineral processors rely on 3rd party support to implement these advanced technologies. One challenge facing advanced control user is the selection providers and services for these technologies. The trend has been towards the use of multivariable predictive control and use of technology provider’s services. This paper will discuss status of advanced control, and the merging trends in the mining industry. A review will be presented of how advanced control is being applied in the mining industry over the last decade, and how user challenges are being overcome. Next the emerging uses of multivariable predictive control (such as multi/inter-unit optimization), focusing on the latest trends in concentrator plants. Finally, a review will be made of emerging technology advances in the that can be advantageous to mineral processors. INTRODUCTION Review of advanced control in mineral processing Advanced controls are serving an increasing role to improve processing plant operations and profitability. As advanced control is being installed into more mining processing plants such as copper concentrators, many of these plants are concerned about the selection technologies and vendors to support the installation and maintenance of these controls. In a study by Jonas and Craw (2011), they found that most new users have not had prior experience with advanced controls. It is the author’s experience of almost 30 years in advanced controls that most mineral processers considering advanced controls can benefit from better understanding of the technologies and their support requirements.

Jan 1, 2019

By J. S. Fox

It is generally recognized that the interpretation of bedrock geochemical data in volcanic terrains can be improved by adjusting for rock-type. Various chemical attributes of volcanic rocks have been put forward in the literature as rapid indicators of rock-type, but there is some question as to which of these is the most reliable . Only one such attribute, total iron, seems to have seen systematic use in geochemical mapping in the Flin Flon region. Discriminant analysis of 500 basalts, andesites, dacites and rhyolites suggests that SiO2 is the most important rock-discriminating variable and that MgO, CaO, TiD2, AI2O3 and FeOtot, are successively poorer discriminators. Lithological normalization in the subalkaline volcanic environment should therefore be made over ranges of this variable. Trace-metal data from drill core through the sulphide orebody at Hanson Lake, Saskatchewan are used to demonstrate various approaches to lithological correction, including silica normalization, factor analysis and trend analysis. All of these extract economically important information from the core that is not apparent in the raw data logs. However, silica normalization does not seem to be subject to as many serious limitations as factor and trend analysis in this case, and therefore seems to provide the most reliable basis for the interpretation of subsurface exploration geochemical data.

Jan 1, 1978

By Dong-Hyeun Koh, Yun-Soo Lee, Min-Seok Kim, Hyoung-Wook Kim

High strength AA7068 (Al - 7.88 wt.% Zn - 2.68 wt.% Mg - 2.07 wt.% Cu) aluminum alloy strip was successfully fabricated by horizontal-type twin roll casting. A simulation technique was used to obtain the range of casting conditions for fabricating strip without defects. The cast strip with thickness of about 5 mm was hot rolled, intermediate annealed, cold rolled to final thickness and subsequently annealed at various temperatures. Tensile properties of annealed and the aged specimens were evaluated at ambient temperature. Tensile strength and elongation of the annealed sheet are about 365 MPa and 28%, respectively. Also, the tensile and yield strength after the aging at paint baking condition (180 °C x 0.5 h) are 586 MPa and 551 MPa, respectively. Therefore, it is expected to show good formability prior to press or stamping and also provide high dent resistance after paint baking treatment.

Jan 1, 2015

By Thomas Hauquin, Olivier Deck, Yann Gunzburger

"In this study, 2D numerical modeling of a room-and-pillar mine is conducted along with the calculation of all terms of the mechanical energy balance. Simulations of different geometrical and geomechanical configurations are performed in order to investigate the conditions that favor a high seismic energy release (instability) during the excavation (removal) of one single pillar. At first, classical stressstrain simulations enable us to estimate the elastic and quasi-static response of the mine. Then, owing to the implementation of new functions in the modeling code, the seismic energy released when the pillar is removed is calculated. The obtained values are found to be in agreement with those calculated analytically using a modified energy balance based on the works by Cook (1967) and Salamon (1984).It is shown that the mine’s proneness to release large amounts of seismic energy, after sudden removal of one single pillar, mainly depends on three parameters: the initial extraction ratio of the mine, the depth of the exploited seam and the Young’s modulus of the surrounding rock mass compared to that of the ore. Moreover, it is pointed out that the magnitude of the seismic energy can be greater than that of the stored elastic energy, meaning that the dynamic (seismic) transient stresses should not be neglected when compared to the quasi-static stresses, particularly when trying to prevent the risk of rockburst and collapse in underground mines."

Jan 1, 2015

By B. E. Halbert, K. T. Himbeault, S. L. Fernandes, R. L. J. Phillips, B. J. Topp

The Beaverlodge uranium mining and milling facilities operated from 1952 to 1981 with about 94% of the ore extracted from the main underground mine and 6% from smaller satellite deposits. Decommissioning work occurred from 1982 to 1985 involving periods of shutdown, salvage and reclamation. Transition phase monitoring, leading to eventual delicencing commenced in July 1985. Over the last 15 years, discharge from the tailings management facility (TMF) and a fresh water stream, impacted during the operational phase by tailings spills, has improved in water quality for most parameters of concern. Loadings to the environment of three key contaminants (radium-226, total dissolved solids, and uranium) have consistently been less than during the operational phase with radium-226 having the greatest variability. Outstanding environmental issues associated with the recovering drainage system formerly used for tailings disposal, are being addressed in an enhanced environmental monitoring program to commence in 2000. Changes in water chemistry and the natural re-introduction of aquatic organisms are issues of concern. In the meantime, application for release from selected satellite areas commenced in 1999. This paper reviews the issues which have arisen during the transition phase, outlines how they have and are being addressed, and provides a comparison of original and current predictions of the recovery process under way at the former Beaverlodge mine site.

Jan 1, 2000

By Gary Pattrick

A new class of spongy Au catalysts is studied for the selective catalytic reduction of NOx by propene under leanburn conditions. The spongy catalyst is an unsupported powdered Au that consists of micrometer particles (~5 microns) that have nanometer scale (~10 nm) internal skeletal structures. The effects of alloying 1 ? 50 atom % platinum group metals (M= Pt, Pd, Rh) and 5 wt% first row transition metals (M = Ti, Mn, Fe, Co) were studied. Even low additions of PGMs (1 at.%) cause significant shifts to lower temperature regions of activity and the largest shift is obtained for Rh. For Rh this is interpreted as a strong synergistic interaction between Rh and Au. Possibly related to the Rh effect, Co is the only other metal studied that lowers the temperature of NOx reduction. The other first row transition metals inhibit the reduction reaction.

Oct 1, 2003