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By M. L. F. Gameiro

The aim of this study was to check the feasibility of non-dispersive solvent extraction to recover copper from ammoniacal solutions using hollow fibres as contactors. Data of mass transfer using the B3-diketone LIX 54 as extractant was obtained. The influence of tube and shell hydrodynamics on the extraction rate of copper was studied. The overall mass transfer coefficient of copper was calculated from the experimental data by performing steady state material balance. Simultaneous extraction and stripping experiments were carried out using different volume ratios of feed phase to stripping phase. The results obtained showed that practically all the copper content was removed from the ammoniacal feed solutions. The recovery of copper reached nearly 100% in several extraction-stripping experiments.

Jan 1, 2007

By O. Kangal, G. Önal, G. Bulut, A. Gül

The recovery of copper and cobalt from the ancient copper slags, located in Küre-Turkey, is investigated. Fayalitic type of ancient copper slags containing 1.41% Cu, 0.53% Co and 53.16% Fe were subject to the experimental study. Magnetic separation, gravity concentration and flotation test were conducted. The results of magnetic separation and gravity concentration were not satisfactory. However, a concentrate containing 9.57% Cu could be produced with 44.7% recovery by flotation. Copper and cobalt that remained in the flotation tailings was recovered by roasting with sulfuric acid followed by hot water leaching. Complete cobalt dissolution was observed in 1 hour of roasting at 150°C and 3:1 acid/slag ratio, whereas the copper recovery was 83%.

Jan 1, 2004

By Y. Mitsuda, Y. Kayanuma, T. H. Okabe, M. Miyake

A new process to recover platinum group metals (PGMs) from automotive catalyst scrap using metal vapor was developed. To improve the efficiency of the acid dissolution process of PGMs, metal vapor of reactive elements such as magnesium or calcium were contacted with spent automotive catalyst. It was expected that metal vapor would react with metal selectively and form intermetallic compounds. The specimen of the spent catalyst was treated at 1173 K for 3 h, and it was then dissolved in aqua regia for 1 h to recover PGMs. After the reactive metal treatment, 88% of Pt, 81% of Pd, and 72% of Rh in the catalyst scrap was dissolved, while only 77% of Pt, 69% of Pd, and 38% of Rh was dissolved from untreated scraps.

Jan 1, 2004

By V. I. Ryaboy, S. A. Kondratyev

"The paper describes influence of desorbed species (DS) of a number of xanthates and higher dialkyldithiophosphates on the collective ability of these reagents. Adsorbed on mineral DS of the reagents in the form of products of non-stoichiometric interaction between xanthates and heavy metal salts can pass to the gas–liquid interface and remove liquid from the layer between mineral particle and water surface. A high-speed video recording displays the process of spreading of DS of xanthates and dialkyldithiophosphates over water at the moment of local rupture of the water layer. Expansion of “dry” spot on the mineral surface after DS of xanthate capture and displace liquid from the layer has been proved with video images. The comparative analysis of collecting ability and dynamic surface activity of dialkyldithiophosphates shows that these characteristics are in good correlation. The forces exerted by spreading film of the reagent’s DS on liquid in the water layer are evaluated, and the water flow rate from the layer is determined. The line of the reduction in thickness of the water layer behind the front of spreading film of DS of dialkyldithiophosphates and xanthates coincides with the line of the increase in their dynamic surface activity. Their force on the liquid volume in the water layer characterizes collecting ability of the DS film of xanthates and dialkyldithiophosphates. It has been supposed that the collecting ability of DS of a reagent is a part of its overall flotation activity, conditioned by surface tension of solution and, thus, defined by the structure of hydrocarbon fragment of the reagent.INTRODUCTIONIt is believed that collecting ability and selectivity of collecting reagents is mainly governed by adsorption of a reagent at the solid–liquid interface. A few studies have shown that activity of collecting reagents at the gas–liquid interface may have deep influence on their collecting capacity and selectivity. Experimental researches have revealed correlation between surface pressure in a carboxylic acid film on liquid’s free surface and floatability of useful components (Kulkarni & Somasundaran, 1975; 1980; Quast, 2006). According to Quast (2006), it is not always that surface pressure of a reagent film influences collecting ability of carboxylic acid. For instance, pH range of adsorption of tetradecanoic acid on hematite does not coincide with pH range of high surface pressure. So, surface properties of this acid contribute little to flotation efficiency.The correlation between reagent film surface pressure and mineral floatability has been reveled for quartz and cationic reagents, too (Bleier, Goddard, & Kulkarni, 1977). Finch & Smith (1973) showed that combination of adsorption of ion–molecular amine complexes on mineral surface and high surface tension of “fresh bubbles” was favorable for flotation performance. The use of bubbles with reduced surface tension resulted in a decrease in quartz floatability."

Jan 1, 2016

By Kristine Haug

Although most in situ operations in Alberta do not encounter significant problems during resource extraction, there have been a few documented occurrences of oil or steam releases as a result of compromised caprock seals. The objective of the Oil Sands Caprock Integrity Project (OSCRIP) is to characterize the units above and below bitumen zones to determine which geological factors affect the quality of the caprock seal. In addition, geomechanical properties and stress measurements of the bitumen reservoir and overlying units will be examined to provide a better picture of the containment conditions in which in situ operations occur. The information from this study will aid regulatory staff and industry in determining the zone-specific geological and geomechanical factors that could affect the design, operation, and feasibility of in situ recovery projects. The OSCRIP study area (Townships 87 to 99 and Ranges 1 to 13, West 4th Meridian) encompasses the surface mineable area, the northeast extent of the Wabiskaw-McMurray bitumen deposit and the Clearwater Formation, as well as a wide band of the Devonian salt-dissolution zone. Regional geological mapping of the Cretaceous strata focuses on the spatial extent and thickness of the caprock seal. Mapping of the underlying Devonian strata is targeted at better understanding the potential effects of salt dissolution and collapse of overlying strata on the integrity of the caprock seal. Examination of LiDAR (Light Detection And Ranging) bare earth DEM in the study area has revealed localized depressions that may represent sinkholes rooted in subsurface collapse features in Devonian carbonate and evaporite strata. Mapping the location and understanding the timing of salt dissolution-related features and deformation in the Devonian strata will help address questions about the possible effect that geological structures, such as sinkholes, have on the integrity of the caprock, as well as the potential for localized variations in the stress regime of the bitumen zone and overlying units. The stress regime in units above 350 m is such that any induced fractures are believed to be horizontal, and therefore, there would appear to be no mechanisms that would allow these fractures to reach the surface. However, recent incidents have shown that vertical pathways can occur, linking the subsurface to the surface. The final phase of the project will evaluate the changes that may occur in the stress regime under thermal operating conditions in the study area.

Jun 1, 2012

By P. M. Tyroler, W. J. Thoburn, M. R. Alberty

"An initial test of this unique application demonstrated that hot gunned refractory would adhere satisfactorily. Subsequently, it was found that the proportion of material sticking during application increased with increased vessel temperature and when a mix containing pitch was used. About 75 per cent of the latter type adhered when it was applied at 1600°C.TBRC availability increased from an historical average of 62.5 per cent to 64.7 per cent during four campaigns when hot gunning was routinely practiced. Refractory cost was about 20 per cent less than that anticipated without gunning. Average parameters per campaign with gunning ranged as follows: 90 to 108 heats, 10 to 37 applications and 1.4 to 2. 7 hours per application. Prior to gunning, the average number of heats per campaign was 73.IntroductionThe Top Blown Rotary Converter process at Inco's Copper Cliff Nickel Refinery converts copper-nickel-sulphur concentrates to a material suitable for carbonyl refining (1),(2).Operating conditions are particularly hard on refractory. Batch cycles finish at temperatures up to 1650°C, with occasional excursions over 1700°C. New heats are then usually initiated immediately and the refractory is subjected to intense thermal shock from the cold feed. Temperature cycles are also introduced three to four times during a heat when the process is interrupted for scrap charging, temperature measurement or sampling.Abrasion wear results from rotation of the converters at speeds up to 15 RPM and from agitation of the bath with supersonic-velocity oxygen. Mechanical damage also occurs when chunks of scrap or solid matte are processed. Chemical corrosion is also present, as we know from our own laboratory work(2) and reports of operations elsewhere. As a consequence, refractory material and installation form a very large proportion of the converter plant costs. Equally important is the loss of converter availability during rebricking; this significantly reduces plant capacity."

Jan 1, 1981

By A. Ghahreman

Activated carbon is proven to be able to catalyze arsenic oxidation in aqueous solution under acidic conditions. A commercially available granular coconut shell based activated carbon (AC) has been evaluated for catalysis of arsenic oxidation in this study. The rapid small-scale column test (RSSCT) has been developed to simulate and predict the performance of a carbon-based arsenic treatment system in a pilot scale reactor. Effects of residence time, aeration rate, and initial arsenic concentration in the influent solution on the AC catalysis of arsenic oxidation under dynamic and continuous conditions were studied by manipulating these parameters during RSSCTs. The effectiveness of the AC on arsenic oxidation was examined over the course of constant diffusivity based RSSCT operation. Residence time and initial arsenite concentration are proven to be the most effective impacting parameters on the arsenic oxidation process. For the 218 min residence time, the highest steady-state arsenic oxidation efficiency achieved was 98% with 1 g/L As(III) being treated at pH=1 under 0.05 L/min oxygen aeration. In a long-running RSSCT, the oxidation efficiency did not seem to deteriorate over a course of 666 hours operation, corresponding to 13986 mL total influent throughput volume. INTRODUCTION Arsenic is toxic to both animals and plants and inorganic arsenicals are proven carcinogens in humans. The increased extraction of low grade and complex mineral resources has introduced high ratios of arsenic into metallurgical processes. Discharge of arsenic by acid mine drainage resulting from mining activities has added intensive pressure on the need for proper treatment (Lawrence & Higgs, 1999). Since trivalent arsenite is more toxic and has lower affinity to solid surfaces for adsorption, many treatment systems initiate with an oxidation step to convert arsenite to arsenate and reach the ultimate immobilization of arsenic by the following precipitation of arsenate (Nazari, Radzinski, & Ghahreman, 2016). Scorodite precipitation has been studied extensively as a means of arsenic immobilization due to its high stability and negligible potential of releasing arsenic (Filippou & Demopoulos, 1997). As a stable ferric arsenate mineral, crystalline scorodite can contain up to 30 wt% arsenic (Paktunc, Dutrizac, & Gertsman, 2008). Arsenic must be in its pentavalent oxidation state in order for scorodite to be precipitated via oxidizing ferrous ions (Clancy, Hayes, & Raskin, 2013).

Jan 1, 2019

By Laxman M. Amaratunga, Glen G. Hein

"Most mining operations utilize the tailings coarse fraction for backfilling while the fines have been traditionally disposed on surface in tailings ponds. Recently, paste fill has been developed which uses a fraction of the fine tailings (10-30% w/w of <45 µm) in the fill (Brummer and Moss, 1991). This development allows a mining company to use a portion of the fines for backfill, but still requires surface impoundment of the unused tailings. Reactive tailings have the added problem of generating acid after being oxidized in the presence of air and water. Treating acid mine drainage (AMO) from these ponds has proven to be a costly environmental problem and a long term liability.One practical method to reduce the environmental impacts associated with the tailings pond is to modify the physical and chemical prope1ties of the fine tailings so that they can be utilized in an environmentally safe manner. This was accomplished by agglomerating the tailings into pellets and using theses pellets as a coarse aggregate in a total tailings paste fill. This technology does not require any supplemental sand or gravel to be added to the fill.This paper presents the ongoing research into utilizing these tailings agglomerates as a coarse aggregate fraction, in order to create a total tailings paste fill which has supe1ior strength characteristics.IntroductionThe Canadian mining industry produces more than 500 million tonnes of tailings and waste rock annually. The waste rock is usually returned underground for use as rock fill in underground support with the tailings remaining to be disposed of in tailings ponds. Tailings consist of a coarse and fine fraction, and can be either reactive (acid generating) or non-reactive. In an effort to minimize tailings disposal, the coarse fraction has been used underground in backfill along with alluvial sands. This diversion of the coarse fraction, however still requires that the fine fraction be disposed of in tailings ponds. This disposal creates the potential for acid mine drainage (AMO), since in the presence of air and water, reactive sulphide tailings can generate acid. It is therefore an important goal in the mining industry to minimize the disposal of fine tailings into tailings ponds since the treatment of AMO is a costly and long-te1m environmental liability."

Jan 1, 1997

By Mayumi Ito

Mineral processing of rare-earth ore from the Dong Pao deposit, Vietnam, was investigated. The ore contained bastnaesite, (REE (rare earth element)) CO3F, as the valuable mineral and barite, quartz, and fluorite as gangue. To establish a mineral processing flowchart, selective comminution, size classification, and magnetic separation were tested. Bastnaesite shows brittle properties and selective comminution was applied to improve the purity of products. The crushed products were classified by decantation, and the overflow product showed high purity of bastnaesite indicating that bastnaesite becomes fines by crushing and that selective crushing can be used to concentrate the bastnaesite. Magnetic separation for the sink product was carried out and the mag-product showed high recovery rates of bastnaesite, indicating that the combination of size classification and magnetic separation is effective.

Aug 1, 2013

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By E. Dalgaard

During linear friction welding of titanium alloy Ti-5A1-5V-5Mo-3Cr (Ti-5553), the weld zone exhibits beta (B) grain refinement and alpha (a) phase depletion that have the combined effect of deteriorating the mechanical performance of the weldment. In this work, linear friction welded Ti-5553 was subjected to pre- and post- weld heat treatments in order to determine the conditions under which a phase depletion could be mitigated in the weld zone and thermomechanically affected zone (TMAZ). The mechanical response of the welded samples to the heat treatments was determined by performing tensile testing at room temperature. While the pre-weld heat treatments had no significant effect, the post-weld heat treatments were instrumental in restoring the strength of the starting (heat-treated) material.

Jan 1, 2011

By A. J. DeArdo

Linepipe steels have come a long way in the past forty years. In fact, modern, high strength steels for large diameter linepipe applications represent one of the seminal accomplishments in metallurgy of the past half-century. The synergy of advanced steelmaking, alloy design including microalloying, hot rolling, and interrupted accelerated cooling has led to the marvelous steels being used today. The drive for higher performance pipelines has been motivated by the energy sector of our global economy who wanted both higher throughput capacity, i.e., larger diameters and higher pressures, and lower material cost, i.e., relatively thinner gauge wall thicknesses. These requirements led to new steels with higher strengths, better toughness and improved weldability. The goal of this paper is to trace the evolution of linepipe steels from the X60 grades of the small diameter pipelines of the 1960s to the (X80 - X120) grades used in the large diameter pipelines of today. The metallurgical triumphs permitting this success story, e.g., clean steel practices, controlled rolling, microalloying with Nb, and using IAC to obtain low temperature transformation products, will be highlighted and discussed.

Jan 1, 2005

Bahuerachi Project Characteristics Why it?s nicer at Bahuerachi Mexico is a mining country Low political, regulatory and trade risk Low social/permitting risk Proximity to infrastructure Road Power grid (8 km) Rail line (25 km) High grade zones (skarns), CRD and near surface oxide component are sweet spots to the overall system. Size of low grade system points to potential long mine life?and numerous new targets developing. Timelines-2006? 90 to 100 combined RC and core holes to go! MAIN ZONE Drilling ? Goat ?Finish Mid April ? Main Zone, going North, depth of testing dependent, estimated for May ? North Lobe-May ? Commission independent resource estimate by May 06 for results of first pass drilling to date ?tonnesand grades ?Main Zone Milestone. ? Continue infill or expanded drilling to July (minimum) ? 1stpass RC scheduled until September OTHER Targets ? Begin drill testing North Skarn target Mid-April, minimum 5 drill holes, 1,000 meters. Ongoing expansion of target with surface work (mapping) ? Road to Colome(Skarnin north of Main Zone) as part of porphyry program ? Tule(southern) porphyry and skarn system-soils and mapping OUTSTANDING events Metallurgical report on floating and leaching tests (Sulphide/oxides).

May 1, 2006

By A. Moyano

The development of the traditional converting process performed in a PeirceSmith or Hoboken converter is limited by the investment magnitude associated to the fulfillment of the environmental regulations. Thus, the continuous converting process rather than a conceptual process alternative is becoming a necessity for a smelter facing limited converting capacity and/or lacking of fulfillment of the environmental regulation with its maximum converting capacity. The objective of this paper is to present the progress of the Codelco continuous converting process evaluated at pilot-scale level when converting solid mattes or white metal into blister copper. These tests allowed for gathering of relevant data to be considered for a new stage of evaluating the Codelco continuous converting at industrial-scale test. The pilot-scale tests were done in a Teniente Converter pilot scale unit at the Codelco Norte Smelter. The results of processing solid copper mattes (65-75% Cu) and producing low sulfur content blister copper with production of a constant S02 gas concentration, and the production of liquid slag with low copper solubility was achieved and is discussed in the present paper.

Jan 1, 2007

By I. A. Cameron

In 1979, John Peacey and William (Bill) Davenport published The Iron Blast Furnace Theory and Practice billed as "An up to date and comprehensive treatment of blast furnaces from fundamental principles to modern operations" (back cover). As a 1979 graduate of McGill University’s Metallurgical Engineering program, I belonged to the last "beta" student group which completed the prescribed blast furnace course work before The Iron Blast Furnace Theory and Practice was published. As my career developed, I become an international blast furnace consultant and have worked with blast furnace operators and raw material suppliers on 5 continents. The blast furnace is the dominate iron making process responsible for 70% of global steel production. Blast furnace engineers have implemented many improvements by manipulating the blast furnace process metallurgy using the principles presented by Peacey and Davenport to reduce coke consumption and increase oxygen usage and blast furnace productivity. This paper briefly summarizes some key principles presented by Peacey and Davenport (1979), describes process improvements made by blast furnace operators over the 35 years since The Iron Blast Furnace Theory and Practice was published and outlines important future developments in blast furnace technology.

Jan 1, 2014

By Jie Zhu

Coal bumps are a special form of release of geologic strain energy that has already been one of the most dangerous hazards to underground mining safety in China. A number of coal-bump models have been developed to quantify coal failure under assumption that a bump is a kind of non-gas induced outburst. However, some technical experts in charge of micro-seismic and gas monitoring have found unusual gas emissions before and after bump, which suggests that it is possible for gas to trigger coal bumps. Considering the coal reservoir as geological body composed of the coal matrix and gas, a new model based on Lippmann?s bump model is proposed to understand the initiation of coal bumps. The redistribution zone from excavation of a roadway has been calculated and analyzed regarding its relation with mining depth. It is shown that high gas pressure may push the coal seam to overstep the critical state due to extension of the plastic disturbed zone, and this is harmful to the stability of coal seam. This model successfully explains the bump phenomena of the Xinzhouyao mine at shallow depth.

Aug 1, 2013

By R. U. Seneviratne, B. K. Ahlgren

In this paper we follow various technological discoveries and developments in the purification of minerals and metals in the mining industry by ion exchange. For approximately 100 years, ion exchange has been a known and variously applied purification and separation technology used by scientists and producers. It would seem obvious that the producer’s objectives have always been to achieve the highest quality products and the lowest operation costs, but also with the least amount of technological complexity. As a strategy to reach these goals, much effort has been expended in the quest to improve continuous ion exchange (CIX) systems by reducing utility needs and resin degradation or loss while at the same time improving productivity and reliability. Recent developments from a number of companies have pushed equipment boundaries, resulting in a variety of unique commercial equipment designs each with a varying degree of success. The challenge set forth for all new designs has been a truly continuous process with no sacrifice in the afore mentioned benefits. One very recent equipment design based on system symmetry appears to meet many of these objectives with greater flexibility and less complexity resulting in better economics for the producer.

Jan 1, 2014

By Walter Valery, Sergio Vicuna, Roberto Valle, Hamer Arevalo, Ben Burger, Lui Vargas, Alex Jankovic, Jim Seidel, Eduardo Nozawa

This paper describes the design, the first three years of operation and optimization of a large, single stage SAG mill at Minera Yanacocha’s Gold Mill facility located in northern Peru. The Gold Mill was commissioned in March 2008 with a 32’ x 32’ EGL, 16.5MW single stage SAG mill, to process 5 million tonnes per annum high grade oxide Au/Ag ore. Operational control, feed size distribution, grinding media, mill liner, grate and pulp lifter optimisation have allowed the mill to operate 15-30% above design throughput rates, but with a product P80 coarser than design. As part of the optimization, full grinding circuit surveys were conducted. Historical operating data and survey data were analyzed and used to evaluate possible circuit changes and determine alternative operating strategies. A number of changes were implemented which allowed the SAG mill to operate similarly to a large ball mill and achieve finer mill product that was closer to design. This paper summarizes life to date data analysis and improvements made by Minera Yanacocha as well as the grinding circuit optimisation study conducted by Metso Process Technology and Innovation.

Jan 1, 2012

By Martin Wacker

Cameco Corporation, on behalf of a joint venture, is preparing surface and underground facilities at their northern Saskatchewan property in preparation for the future operation of a high-grade uranium mine. The Cigar Lake orebody is situated about 430 metres below surface at the unconformity between metamorphic basement rocks and flat lying sandstone. Major technical factors influencing the mining method selection include ground stability, control of ground water, radiation exposure and ore handling and storage. A decade-long test mine program resulted in the selection and validation of ?jet boring? a non-entry mining method. Cigar Lake?s jet boring mining method involves several major steps; artificial ground freezing of the orebody and surrounding rock, TBM (tunnel boring) type development of access crosscuts below the orebody, installation of cased pilot holes upwards through the ore, and ore extraction using a rotating high pressure water jet within the pilot holes. The resulting cavities are surveyed and backfilled with concrete. The ore slurry will be processed underground and pumped to surface. This paper discusses the jet boring mining method in general terms and includes highlights of the Cigar Lake test mine program completed in 2000.

Apr 1, 2005

By M. Turek

Cost management in the conditions of increasing competition and unforeseen market turbulence constitutes one of the key areas of the enterprise?s activity. In the last two years the demand for hard coal on the domestic and global market of non-renewable resources has increased significantly. Polish hard coal mining industry, as an industry in the stage of decline, received a chance for rejuvenation. However, one of the most significant conditions of seizing this opportunity is the rationalization of mining costs and improvement of production effectiveness. Due to the significance of this issue, the main objective of the paper is to identify the possibilities of improving the production effectiveness in the hard coal mining industry. In order to meet such an objective, in the first part of the paper we measured effectiveness in the Polish hard coal mines in years 2006- 2011. The research encompassed three out of five mining enterprises operating in the country. Then based on the received results, guidelines concerning the improvement of effectiveness of production were created, taking into consideration infrastructural, technical, economic and organizational determinants. Furthermore, opportunities and threats for improving the production effectiveness, stemming from the external conditions have also been indicated.

Aug 1, 2013