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By J. A. Finch, M. Mimezami, M. S. Hashemi A.

The adsorption of magnesium and calcium ions on sphalerite and pyrite is discussed. These ions are common in process water and often considered be detrimental in sulphide flotation. The study attempts to characterize the adsorption mechanism, which has been less studied than the oxide system. Generally for oxides metal ion uptake occurs when cations are hydrolyzed. Our findings reveal that magnesium and calcium adsorb on sulphides at pH below hydrolysis, but adsorption is not chemical. At higher pH, charge reversal occurs that does correspond to presence of hydrolysis products. Advances

Jan 1, 2009

By Franz Simon

Conventional fine gold electrolytes for barrel applications working electrolytically actually permit significant precious metal savings by corresponding optimizations but the most gold is still deposited on areas of the components where it is not absolutely essential for the desired bonding and soldering applications, i.e. in high current density areas. Therefore an electrolyte working electrolessly has been developed which inevitably leads to a much more uniform thickness distribution since in an electroless process there are no areas favoured by metal deposition and current distribution. The new electrolyte will be presented and its performance will be compared with conventional electrolytes as regards thickness distribution. The potential gold savings will be discussed.

Oct 1, 2003

By M. Brochu

In this paper, we present a computer-vision approach developed for wall-thickness measurements of corroded pipes inspected by double-wall radiography. The main objective of the work is to optimize data collection and film interpretation using computerized image analysis. To date, the system is able to identify the inner and outer contours of a pipe and perform wall thickness measurements at each pixel of a radiograph. This will be presented by analysing pipes having different dimensions. Another important feature of the system concerns the algorithms' adaptability to pipe wall texture. In other words, image analysis is automatically refined around rough or corroded areas. This allows more precise thickness measurements and shape identification in critical sections as will be demonstrated with examples. Finally a brief overview of results exploitation will be given and compared with human interpretation. It will show the reliability of automated image analysis and the many possibilities offered by complete output analysis.

Jan 1, 2005

By Robert B. Parsons

"A study recently completed by the Prospectors and Developers Association, assisted by the author and computerized mine models he developed, presents a strong case that present tax rules severely handicap the junior exploration company relative to the established producer. This month, Tax Notes briefly summarizes the highlights of the study and some of the Association's ideas which came out of the study.IntroductionIn the case of any industry, a particular project or investment will generally generate a more attractive after-tax rate of return to a tax paying entity than to a non-tax paying entity: the ability to shelter current taxable income with tax deductions related to the project or investment can present a definite advantage as compared to shielding taxable income in the future with the same deductions. But, this advantage is probably seen nowhere more clearly than in the mining industry where the tax rules allow for substantial up-front write-off's. Studies show that the junior mining company which is earning no taxable income currently can be seriously disadvantaged, compared to the mining company which is currently generating taxable profit and paying taxes. This is particularly disturbing when one considers the importance of the junior segment of the mining industry. One might well ask where the equity is, in a tax system which causes the junior company to look at a deposit and see rock in the ground, when at the same time the deposit represents a viable mine to an operating company. This inequity and the importance of the junior mining company have been recognized to some extent in the income tax legislation. In recent years, the expansion of the rules for deducting certain earned depletion allowances against any source of income, and changes to improve the flow-through share rules, have gone part way in helping to put the junior on a more equal footing with the operating company. But it is questionable whether or not these helpful changes to the tax rules have done enough to alleviate the apparent inequities in the income tax legislation."

Jan 1, 1985

By J. Ipinza, J. P. Ibáñez, Casas J., S. Cortés

Copper powder generated during the treatment of electro-metallurgical bleeds by reactive electro- dialysis (RED) had totally reduced the content of ferric ions in acidic synthetic electrolytes (Cu (II)- Fe (III) – H2SO4). In batch and columnar experiments 100% of the ferric ions were reduced to ferrous ions with an extremely high kinetics. A preliminary conceptual design for reducing ferric ions based on an integrate RED- Column for treatment of electro-winning bleed system is discussed. This system is able to recover simultaneously sulfuric acid and copper powder, which will reduce ferric ions. INTRODUCTION It is well known the negative effect of ferric ions in the copper electro-winning process. The increase of ferric content in the electrolyte reduces the current efficiency, i.e., there is an increase in the energy consumption, and changes the surface morphology of the copper deposit (Das, Gopala & Krishna, 1996; Vargas & Parra, 2013). The increase of the specific energy consumption due to the loss of current efficiency occurs by the reduction reaction of ferric to ferrous ions in the cathode, at the anode the ferrous ions are slowly oxidized to ferric ions (Shaw, Dreisinger, Lancaster, Richmond & Tomlinson, 2004). To control the level of iron in the electrolyte, bleeds are needed; this bleed electrolyte containing copper, sulfuric acid, cobalt, iron and other impurities normally is waster, which increased the production cost of the plant (Milbourne, 2002; Mckevitt & Dreisinger, 2009). Then, permanent efforts oriented to treat those bleeds to avoid losses of valuables components are made; among them are use ion exchange resins (Shaw et al., 2004; Mackevitt et al., 2009), chemical precipitation (Izadi, Mohebbi, Amiri & Izadi, 2017) and electrodialysis (Cortés, Ipinza & Ibáñez, 2013). The last one allows to the simultaneous recovery of sulfuric acid and copper powder. If one of the valuables obtained by treating the bleed can be used to reduce ferric ion concentration in the electrolyte could be an important asset. This issue at laboratory scale is reported in this work, the use of copper powder, generated by reactive electro-dialysis when treating synthetic acidic electro-metallurgical bleeds, for reducing ferric ions in acidic electrolytes.

Jan 1, 2019

By S. Maleksaeedi

On-site evaluation of strength using hardness is common for different materials. The lack of such relation for aluminum alloys has always been felt. In this work, a finite element analysis of plastic deformation and its distribution in Brinell hardness testing is presented. The analysis has been performed for different strength levels of aluminum alloys. By utilizing the Von Mises equivalent strain in hardness, it is tried to derive a correlation between hardness and strength values for the alloys under consideration. The derived correlation is verified using the experimental values available in literature.

Jan 1, 2004

By Helen Morrison, Chris Staun, James Vaughan

"Mercury is introduced into the Bayer refining process as a trace element in bauxite. During the digestion stage, a portion of the mercury is extracted which partitions between the flash tank off-gas, vapour condensate and bauxite residue streams. A technology or treatment that stabilises mercury in the solid phase during digestion would prevent environmental management issues that may arise from the presence of mercury in condensate and non-condensable gases. This study examines the effect of process additives on the deportment of mercury under Bayer digestion conditions. Bauxite digestion experiments were conducted in batch autoclaves in the presence of additives. Process liquor was analysed for mercury content using a thermal desorption technique. Pyrite and copper hydroxide were evaluated for their suitability as additives.INTRODUCTIONMercury is an ancient metal characterised by electrochemical nobility, volatility, low solubility in water and a liquid state at room temperature (Holleman and Wiberg, 2001). The biogeochemical cycle of mercury is complex. Elemental mercury may enter the atmosphere due its volatility, where it can be transported long distances. After settling and adsorption to sediments, methylation is catalysed through microbial metabolism (Qureshi et al., 2009). Methylated mercury species are potent neurotoxins, and bioaccumulation of mercury is well documented, particularly in seafood (Kozin et al., 2013, Pan et al., 2014, Pollman, 2014). Environmental regulations for mercury emissions are becoming increasingly stringent (UNEP, 2015). Considerable research has already been performed and technologies developed for the remediation of mercury in wastewater and the trapping of mercury from industrial stack emissions. Wastewater technologies usually target ionised mercury using adsorbent, ion exchange and complexation mechanisms (Krishnan and Anirudhan, 2002, Li et al., 2015a, Chiarle et al., 2000), while stack emission technology is dominated by impregnated activated carbon adsorbents (Gao et al., 2013, Zheng et al., 2012). Related developments include piezoelectric amalgamating sensors for in line detection of gaseous elemental mercury in industrial stack emissions (Kabir et al., 2015, Sabri et al., 2011). There is a paucity of research regarding removal of mercury from the Bayer process."

Jan 1, 2016

By R. B. STEWART

A few days ago, while reading a report of the late Dr. Robert Bell in preparation for this afternoon's meeting, I found some impressive figures concerning the magnitude of the Hudson Bay basin. From the waters of the Bay itself, this great territory extends eastward 500 miles, westward l,300 miles to the Rocky mountains, and southward to the source of the Red river. It has a width of 2,100 miles from east to west, and a length of l,500 miles from north to south. Its area is almost three million square miles. It is not, of course, my intention to review the natural resources of this vast territory, but to confine my remarks to that portion of it adjacent to the waters of Hudson bay. A number of erroneous ideas exist in the minds of many concerning this northern country, especially as regards its latitude and climate. Burwell, at the entrance of Hudson strait, is in the latitude of 60 degrees or roughly that of the north of Scotland. The southern end of James bay has about the same latitude as the northern end of Vancouver .island.

Jan 1, 1928

By C. Gu

Flow field design is critical for PEM fuel cells. The flow field design can affect reactant distribution to the catalyst surface, water management, thermal management and current collection. Therefore, it has tremendous impacts on the fuel cell performance and durability as well as reliability and operational flexibility. In this paper, an optical method is used to study the reactant distribution in the flow field channels of two commonly used flow field designs, straight channel design and serpentine channel design. Images of the flow patterns are shown followed by discussions of the flow patterns.

Jan 1, 2005

By Farid Mirahadi

Forecasting productivity of construction operations is a difficult but crucial task in planning construction projects. Over the past decades, many models have been developed to forecast productivity for different construction operations. Models made up of several functional relations and controlled by a specific number of control rules are more in line with human reasoning and logic. Neural-Network-Driven Fuzzy Reasoning (NNDFR) structure as one of these models shows a great performance for modeling datasets among which clear clusters are recognizable. Lack of the compatibility of conventional NNDFR with fuzzy clustering algorithms besides the insufficient attention paid to the optimization of number of clusters in this model, created a potential area for further research. The main contribution of the proposed model is to develop a modified NNDFR system to model construction data. To this end, Fuzzy C-Means (FCM) algorithm is substituted for K-means in NNDFR structure, and its parameters such as the number of clusters and weighting exponent are optimized through genetic algorithm. The proposed model is further verified through simulation of a construction operation in which several qualitative and quantitative factors are considered. Its implementation to the case study shows a considerable improvement of model performance with lower Mean Squared Error (MSE). The developed model assists researchers and practitioners in utilizing historical construction data to forecast productivity of construction operations with a high accuracy that could not be obtained by traditional techniques.

Aug 1, 2013

By Davis. B. R.

There are a number of hydrogen storage systems proposed for automotive applications. However, all of the current suggestions fall short of the DOE targets for storage density and volumetric density. The DOE has suggested that only through radically new ideas will a practical solution to hydrogen storage for automotive applications be realized. This paper provides some background in chemical hydrogen storage and discusses roadblocks to the implementation of some proposed technologies.

Jan 1, 2005

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By K. Soldenhoff, D. Wilkins, E. Ho

In the processing of rare earth ores, a pure, mixed rare earth chloride solution is usually produced and used as the feed to solvent extraction circuits to separate the individual rare earths. Cerium(III) may be separated from the other rare earths by oxidising it to cerium(IV), which precipitates as cerium(IV) hydroxide in chloride liquors. This oxidation step may be inserted either before rare earth separation by solvent extraction or between solvent extraction circuits. Although oxidation of cerium by sodium hypochlorite has been known for many years, detailed conditions for oxidation are not readily available. The effect of hypochlorite addition, temperature, pH and cerium concentration on oxidation of cerium(III) from synthetic solutions was investigated

Jan 1, 2014

By A. Otsuki

"This paper discusses the primary collector adsorption onto a sulphide mineral in mixed collector systems to understand its adsorption mechanism. UV-vis measurements were performed to identify the primary collector concentration adsorbed on pyrite, and the adsorption kinetics under different conditions were compared to distinguish their difference between single and mixed collector systems. Small amount of secondary collector addition prior to the primary collector addition significantly improved the adsorption kinetics of primary one. The result was explained by the combination of two previously proposed mechanisms (i.e., different adsorption site mechanism and multi-layer product mechanism). This study showed UV-vis measurement as an effective tool to study mixed collector adsorption behaviour.INTRODUCTIONCollectors are surfactants composed of heteropolar molecules with a non-polar and a polar group (Lotter & Bradshaw, 2010). In a froth flotation process, the function of collector is to improve the hydrophobicity of target minerals and selectively float them with the aid of gas bubbles. Because of the chemical or physical attraction between the polar group and the mineral surfaces sites, collector molecules adsorb on the particle surface with the non-polar group assigned towards the bulk solution (i.e., water), thus the mineral particle surface becomes hydrophobic (Wills & Napier-Munn, 2006).Thiol collectors are major collectors widely used in sulphide mineral flotation. Potassium amyl xanthate (PAX), dithiocarbamate (DTC), dithiophosphate (DTP), mecaptobenzothiazole (MBT) are some common thiol collectors. Previous studies reported that some mixed collectors systems enhanced the flotation performance (e.g., Bradshaw, 1997; Bradshaw et al., 1998; Rao & Forssberg, 1997). Thiol collector mixtures are often used in the flotation of sulphide ores, and discussed with the synergistic benefits (Bradshaw et al., 1998) which include lowering the total collector dosage requirements, improving the sulphide recovery and the rate of flotation as well as the improving the froth characteristics. The current paper mainly considered the mixture between two thiol collectors (PAX and DTC, considered as a weaker and selective collector, and stronger and less selective collector, respectively (Bradshaw, 1997)) to further understand their adsorption mechanism that should assist in improving the flotation performance of refractory gold ore."

Jan 1, 2016

By M. Duncan

Lightweight, high-pressure cylinders for compressed hydrogen storage are essential components for fuel cell vehicles. Storage volume and mass are two key considerations. Current on-board hydrogen storage systems are based on a maximum pressure of 350 bar. While 350 bar systems are excellent solutions for many applications, some situations require higher storage densities due to space restrictions. As a result, significant research and development work has been expended by cylinder manufacturers, systems providers, testing agencies and automotive manufacturers to develop 700 bar systems with reduced storage volumes. Dynetek Industries Ltd. has proactively developed several 700 bar storage cylinders based on a seamless aluminum liner over wrapped with a carbon fiber composite. This paper presents the challenges and processes involved in the design, testing and certification for Dynetek Industries Ltd. 700 bar cylinders. This paper also provides reasoning for further volume and mass optimization of compressed hydrogen cylinders through the establishment of realistic cylinder usage parameters in standards. In particular, the overly conservative fill life requirement for cylinders is examined.

Jan 1, 2005

By X. F. Liu, O. Buzzi, Y. Sieffert

This study falls in the context of underground coal fires (UCF) where burning coal can elevate the temperature of a rock mass in excess of thousand degrees. The objective of the research was to experimentally investigate the change in mechanical behavior of a rock when subjected to temperatures up to 900 °C. Several blocks of an Australian mudstone were collected from a mining site in New South Wales, Australia. X-ray diffraction and thermal-gravimetric analysis were conducted on powdered rock in order to determine the critical temperatures at which the main mineralogical changes occur. Then, cylindrical specimens were prepared from intact rock blocks for unconfined compression tests. These rock specimens were then treated by heating in a temperature-controlled furnace at temperatures varying from 100 °C to 900 °C. The heating process consisted of two stages: raising temperature with very slow rate of 1 °C per hour followed by a holding period of 24 hours and then a slow cooling process to room temperature. The compression tests were carried out on treated rock specimens to characterize the change in compressive strength. The macroscopical study was complemented by microstructural investigations via optical microscope, scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). Results show that the unconfined compressive strength of mudstone decreases with increasing heating temperature up to 450 °C, beyond which it increases. This can be explained by the combined effects of micro cracks and mineral thermal reactions caused by heating process.

Jan 1, 2015

By B. A. Kjarsgaard, C. J. Mwenifumbo

"Abstract - Natural gamma-ray measurements were made in the GSC Smeaton drillhole as part of the borehole geophysical classification of kimberlite pipe 169. In addition, forty samples of Cretaceous sediments (shales, siltstones, and sandstones) and thirty-five kimberlite samples, selected from the drill core, were analyzed for major and trace elements. These elements included potassium (K), uranium (U), and thorium (Th), which are the main naturally-occurring radioactive elements.Different phases of the kimberlite, and the Cretaceous sediments which show variations in the gamma-ray activity, can be easily delineated on the gamma-ray logs. The gamma-ray logs indicate that the radioactivity in the kimberlite derives mainly from Th, and, to a lesser extent, U. Most of the kimberlite units are enriched in Th and U relative to the Cretaceous sediments, and these radioelements are mainly hosted by accessory apatite and perovskite, and minor zircon. Potassium concentrations are low in the kimberlite. The higher K concentration in the sediments clearly distinguishes the Cretaceous sediments from the kimberlite.The U/K and Th/K ratios show important and distinct differences between the two major types of volcaniclastic kimberlite. Kimberlite lapillistones have higher U/K and Th/K ratios than the olivine crystal tuffs. Furthermore, standardized U/K and Th/K geophysical logs can be used to separate marine reworked olivine shoreface sands from other shallow marine sediments that contain kimberlitic detritus. The identification of different phases and/or stratigraphic facies of kimberlite on the basis of radioelement distributions means that gamma-ray spectrometry can assist exploration, particularly in regard to diamond grade distribution."

Jan 1, 1999

By L. Vinnett, I. Panire, J. Yianatos, F. Ruiz

"The effect of operating variables on the flotation performance at steady-state has been extensively used for modelling and simulation of separation processes. However, the dynamic characterization of key variables such as gas dispersion (Sauter mean diameter of bubbles, D32, and bubble surface area flux, SB) and froth discharge rate is rather scarce. In this paper, an experimental design allowed identifying the dynamic response of the flotation process in a laboratory scale flotation cell, using a two-phase system, airwater. The installation included automatic control for the superficial gas rate, JG, and the pulp level. Gas dispersion was evaluated in terms of the Sauter mean diameter of a bubble population and the bubble surface area flux, SB = 6·JG/D32. The D32 was measured using the McGill Bubble Size Analyzer (MBSA) along with a semiautomated algorithm. In addition, the froth discharge velocity was measured in real-time using a Visiofroth system. The control variables were the superficial gas rate and the frother concentration (Teefroth). The dynamic characterization of the flotation process is useful to design algorithms that allow the direct or indirect control of metallurgical variables such as flotation rate, concentrate grade and mineral recovery.INTRODUCTIONGas dispersion indicates the way the gas entering a flotation machine is dispersed throughout the volume of the equipment (Schwarz & Alexander, 2006). The gas dispersion is typically characterized in terms of the bubble size (dB), gas holdup (eG), superficial gas rate (JG), and bubble surface area flux (SB =6·JG/dB) (Finch et al., 2000). All these variables have significant impact on the metallurgical performance of flotation machines. For example, Perez-Garibay et al. (2014) investigated the effect of the particle size, bubble size distribution, superficial gas rate and collector dosage on the flotation performance, for the separation of a sphalerite mineral. The authors observed that recovery increased with the superficial gas rate ranging from JG = 0.04 to JG = 0.08 cm/s and also a maximum recovery was obtained for bubble size close to 300 µm. Gorain et al. (1998) reported a strong correlation between the flotation rate constant and the bubble surface area flux in a zinc cleaner circuit. Both variables were directly proportional at three froth depths in the range of hF =7 - 45 cm. Dobby & Finch (1986) incorporated the effect of the superficial gas rate and the bubble size on the flotation efficiency by means of a kinetic model for the rate constants. Yianatos & Contreras (2010) developed a model to estimate the carrying capacity in large flotation cells by including the bubble surface area flux."

Jan 1, 2016

By G. Simard, D. Boudeville, A. Leclerc, A. Boivin

"The objective of this work is to study the various parameters that affect the overflow clarity of gravity settlers used in the precipitation circuit of alumina hydrate from the Bayer process. A mathematical model incorporating the size distribution of the feed suspension (Multi Size Group model), its diphasic nature (Schiller Naumann model) and the presence of turbulence (Shear Stress Transport model) has been solved numerically using ANSYS-CFX software. Preliminary results indicate that the overflow clarity is mainly controlled by lateral diffusion of fine particles (~20µm) from the exit of the feed well and by their upward transport from the sediment bed interface. Also the turbulence pattern in the settling zone seems to play a significant role in this vertical transportation. The validity of the model has been verified by comparing the measured solid concentrations from a pilot classifier with the calculated ones. This model could provide mineral processing plant operators and designers with a tool to optimize the configuration of classifiers with respect to the overflow clarity.INTRODUCTIONProblemIn the Bayer process, alumina hydrate precipitation from the saturated liquor is initiated in settler by adding crystallization seeds. Most of the precipitated alumina settles to the bottom of the tank while the liquor and the remaining alumina rise to the top, where they are removed at the overflow. Ideally the overflow clarity, which depends on the operational mode of the classifier, should be controlled within targeted limits."

Jan 1, 2016

By Francois Charette

Corrosion is a significant factor affecting the capacity and working life of ground support. The paper explores a relatively simple method to predict the load capacity of a support system using a Monte Carlo stochastic approach. The analysis uses published field data on existing ground support to evaluate the applicability of the method and its predictive performance. Discussion on corrosion rates found in the field and predicted from laboratory measurement is provided.

Jun 1, 2012