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By Irina A. Pulyaeva

Hydrogenetic Fe-Mn crusts are ubiquitous in the ocean basins and play an important role in marine mineral-deposit research because of their widespread occurrence and high concentrations of valuable and rare metals. Directed research, which started in the last quarter of the 20th century, has provided significant results, with substantial amounts of data produced on Fe-Mn crusts structure, composition, and distribution in the global ocean. Detailed study of several seamounts has given confidence about the scale of Fe-Mn crust development and their characteristics. Now, commercial interests gain more and more attention. However, at the same time some theoretical questions related to Fe-Mn crust history including controls on metal sources and concentrations have not yet been answered. Here, we present the overview of age, composition, distribution, and geological setting of hydrogenetic Fe-Mn crusts from Pacific and Atlantic seamounts and discuss the geological evolution and conditions that led to the formation of potentially economic concentrations of metals. The age, composition, and distribution of Fe-Mn crusts in the Atlantic and Pacific oceans were determined by using a Fe-Mn deposits database compiled from our original data, published papers, published databases, and other international sources. Comparative analysis of Fe-Mn deposits from the Atlantic and Pacific oceans shows that there are similarities in basic characteristics of crust formation in both oceans. Simultaneously, there are significant differences in the scale of Fe-Mn crust distribution and composition that can be explained by differences in geological settings and characteristics of the deposition environment.

Jan 1, 2011

By Andrea Koschinsky

Ferromanganese crusts have traditionally been considered a potential ore for Co, whereas ferromanganese nodules have typically been considered a potential ore for Ni and Cu. However, both nodules and crusts sequester high concentrations of many metals (Table 1) from sediment pore waters and seawater, many of which are essential for high-tech applications. The resource potential of these rare and valuable metals is poorly known and they are the subject of considerable current research. The need for adequate and dependable supplies of these metals is essential for the development of new technologies. The rare-earth elements have recently received much attention in the scientific and popular press because of their use in so many high-tech applications and because more than 95% of the production comes from China (e.g., Service 2010); consequently, there is concern about the possibility of a significant decrease or even curtailment in exports from China. The lack of a primary source and the inadequate supply of Te have prohibited the development of a Cd-Te photovoltaic solar-cell industry (Hein et al. 2010). Inadequate supplies of many of the elements listed in Table 1 are limiting the development of key high-tech industries, forcing the use of alternative metals that [ ] may result in less efficiency or less favorable properties for a product. The rare-earth elements, Te, and other elements listed in Table 1 occur in high abundances in marine hydrogenetic and diagenetic ferromanganese deposits. Here, we look at the mechanisms by which these rare and valuable metals are incorporated into different genetic types of marine ferromanganese deposits.

Jan 1, 2010

By G. Cherkashov

The geodiversity of seafloor massive sulfides (SMS) deposits at the slow- and ultra-slow spreading ridges is of great variety (Fouquet et al., 2010). Tectonics and magmatism are the two principal factors which control SMS formation and localization. The geological setting of SMS deposits is determined by their position relative to the rift valley and by the types of rocks hosted (Table 1). Depending on the first parameter, SMS deposits could be localized at [ ] the axial volcanic ridge or at the flank of the rift valley. Basalts, deep-seated gabbro, and serpentinized peridotites are distinguished among the hosted rocks. The outcrops of deep-seated rocks are exposed at the flanks of the rift valley. The tectonic mechanism of the lower crust and mantle rocks exhumation process is connected with very large offsets along the detachment faults, resulting in a forming oceanic core complex (OCC) (Smith et al., 2006; MacLeod et al., 2009). The SMS related to OCCs are represented by such ore clusters as Ashadze, Logatchev, Semyenov, and some others (Table 1) and are increasing steadily in number. This fact in combination with widespread OCC formation at the slow-spreading ridges (Escartin et al., 2008) and high grades of metals in SMS related to OCCs has provoked considerable scientific and economic interest in these types of deposits. It could be mentioned in this regard that the first two applications to the International Seabed Authority for prospecting and exploration of sulfides have been submitted for the areas in the spreading centres with wide distribution of the core complexes.

Jan 1, 2011

By Nobuyuki Okamoto

Ferromanganese crusts on the seamounts in the Pacific Ocean are potential resources of cobalt, nickel, platinum and REEs. Particularly, those of the Republic of Marshall Islands and the Federated States of Micronesia (FSM) waters are believed to be of the highest resources potential area in the Pacific Ocean. The total six cruises using the Japanese Research Vessel Hakurei Maru No. 2 were carried out in the seamounts of the Marshall Islands in 1996, 1998 and 2002, and of the FSM in the 1997, 1998 and 2005 for evaluation of economic potential for cobalt-rich ferromanganese crusts as part of the Japan-SOPAC joint project. During these cruises numerous data such as bathymetric, geological, geophysical and environmental data were obtained. Geophysical exploration with backscatter mapping and side scan sonar, visual imaging using towed TV camera and geological sampling using dredge bucket and/or benthic multi-coring system (BMS) were conducted on these seamounts. In this presentation, we will report the mode of distribution of the crusts and calculated resource estimation based on the results of these geological and geophysical shipboard survey and land-based analyses. Keywords: ferromanganese crusts, Marshall Islands, Micronesia, resource potential

Jan 1, 2011

By Amy Gartman

"Seafloor hydrothermal systems result in the emission of abundant particles and nanoparticles into seawater1. Many of the elements in these particles settle locally, although some are transported distally to the global ocean2. Although broad similarities exist, the mineralogy, size and therefore reactivity of particles emitted varies between sites in the global ocean, and even within sites at the same vent field. The particle geochemistry of these vent fields is a critical but little understood component both from a perspective of baseline characterization and potential environmental impacts.The mining of seafloor massive sulfides formed from hydrothermal venting will generate a new class of particulates in the deep ocean. Broadly, black smoke and SMS tailings exhibit similarities including abundant Cu, Fe and Zn sulfides, and a large number of submicron particles. In addition to the major minerals, minor minerals including As, Bi, and Pb are present, especially in back arc settings. However despite broad similarities, natural “black smoke” and crushed sulfides created during mining operations differ significantly in size class, morphology, abundance, and reactivity. A comparison of these two classes of particulates will be presented, including chemical composition and reactivity to dissolution and oxidation."

Jan 1, 2017

By G. A. Tret’yakov, V. A. Simonov, I. Yu. Melekestseva, V. V. Zaykov, N. N. Ankusheva

The Kyzyl-Tashtyg massive sulfide polymetallic deposit is situated 120 km north-east of Kyzyl (the capital of Tuva Republic, Russia). It is located in the Ulug-O volcanic zone which is interpreted as the northern segment of the Kaa-Khem rift in Sayano-Tuva marginal sea, one of the Paleoasian Ocean margin (Fig. 1) [Zaykov, 2006]. Since its discovery in 1946 the deposit has been studied by many researchers. Significant information was published by Kuzebny et al. [2001] and Zaykov [2006] who proposed volcanogenic-sedimentary genesis. A single reference in English about Kyzyl-Tashtyg is available [Herrington et al., 1999].

By Yuta Yamamoto

Seafloor massive sulfides (SMS) which contain Au, Ag, Cu, Zn, and Pb have been interested in as a target of commercial mining these 15 years. Japan has large potential of SMS and a national R&D project for the mining has been active these 5 years. However, the economy of SMS mining is very bad, because the waste tailing disposal cost is very expensive in Japan. A slurry flushing method is experimentally examined in this study for the improvement of the economy. During the flushing, because of density difference between the metal-rich ore and the waste rock, a kind of gravity separation is possible. The results suggest a possibility of the actual application.

Sep 14, 2011

By Valcana Stoyanova

Deep-sea mining of polymetallic nodules are expected to produce serious impact on benthic ecosystem due to removal of nodules, sediments and associated fauna by means of collector, and subsequently, by the resettlement of sediment plume which may affect seabed biota outside mining tracks through blanketing, smothering and feeding interruption. The scale and magnitude of the exact impact of commercial operations is not known at present, but its assessment strongly required acquisition of the adequate environmental baseline information. During the past two decades, IOM carried out a total of 20 research cruises in the eastern part of Clarion-Clipperton Zone (CCZ) with purpose to obtain essential data and information on polymetallic nodules and to prepare for future development their deposits. Whilst evaluating the nodule coverage at particular station from both seafloor photographs and box-core recoveries it was ascertain that the ground-truth data plotted against the photo data indicated substantial differences between two methods. Understanding of this phenomenon has not only the methodology meaning related to the efficiency of the using photoprofiling techniques during exploration of nodules, but also it could be of environmental importance because the similarity between natural sediment blanketing occurrence in studied area and expected re-deposition and blanketing of sediments which will be disturbed during mining operations.

Jan 1, 2011

By T. Semkova, G. Cherkashov, V. Rashidov, L. Anikeeva, G. Gavrilenko, G. Glasby

The Kurile Arc consists of at least 100 submarine volcanoes and 5 submarine calderas located mainly in the rear arc (Figure 1). The arc is seismically very active, particularly in the south, and is characterized by extensive volcanism and hydrothermal activity. At least one subaerial volcano on the arc (Medvezhy located on Iturup island) has an extremely shallow magma chamber and is intensely active.

By Jorge MRS Relvas

Recent research both on active and fossil systems has demonstrated that shallow subseafloor replacement processes are not only viable depositional mechanisms for massive sulfide mineralization, but likely contributed as a major component of the mineralization occurring in large VHMS deposits and in many present-day seafloor hydrothermal systems. In the giant Neves Corvo deposit, as in many others VHMS deposits of the Iberian Pyrite Belt, there is overwhelming evidence for silicate-sulfide replacement processes being largely responsible for the efficiency of the ore-forming systems and huge size of the deposits. Textural evidences at all scales, coupled with a well-constrained mass-balance geochemical analysis, indicate that extensive replacement in the lavadominated volcanic rocks of the footwall sequence, and disseminated replacement mineralization in the volcaniclastic and/or sedimentary units were major mechanisms of ore formation in the Neves Corvo deposit. Shallow metal deposition prior to fluid discharge on the seafloor is likely to play a major role in seafloor massive sulfide mineralization. This premise should be envisaged as critical in evaluating the economic potential of seafloor resources, and should certainly be part of the equation when plans for seafloor mineral exploration missions are drawn.

Sep 14, 2011

By Richard Petters

Williamson and Associates, Inc of Seattle, Washington has recently built a remotely operated seafloor coring system for Nichiyu Giken Kogyo Ltd and the Metal Mining Agency of Japan (MMAJ). The system is designed to core to depths of 20 meters in 6,000 meters of water and will be operated from MMAJ's research vessel Hakurei-Maru No. 2 The corer uses rotary rod coring methods and will recover a core diameter of 44 mm. To facilitate coring through soft or unstable formations, the corer has the ability to set casing. The corer is fitted with thrusters for positioning during landing and telescoping legs for leveling. The system is operated through a 12 km electro-optical cable. Data displayed to the operator provides the operator with real-time feed back and control over the coring process. The operator has independent proportional control over bit weight, advance rate, rotary speed, and flushing water flow. The process of making up, breaking down and storing the drill string is automated and is controlled by a logic driven software routine. The system is currently undergoing trials in Japan. This presentation will discuss the drill's capabilities and should be of interest to those in need of a tool for assessing the thickness of marine mineral deposits.

Jan 1, 1996

By Robert G. Ditchburn, Cornel E. J. de Ronde, Bernard J. Barry

The age of mineralization, its mode of formation, the time elapsed to amass an economic deposit, its capacity for sustainable extraction and, ultimately, its grade and tonnage, are key aspects in the economic viability of volcanic massive sulphide (VMS) deposits (Ditchburn et al, 2004). Radiometric dating methods applied at GNS Science have been recently refined with the purpose of efficiently determining the ages of seafloor VMS mineralization along active intraoceanic arcs. These developments include: determining the longevity of seafloor hydrothermal systems, details of individual chimney and massive sulfide mound growth, and insights into deep-seated processes, such as the transfer of elements from magmas to their overlying hydrothermal systems. In our pursuit to better understand seafloor hydrothermal systems along intraoceanic arcs, we have thus far compiled age information for three volcanic centres of the Kermadec arc (South Pacific) and one of the Mariana arc (NW Pacific).

By Alexander Malahoff

Field observations and sampling of land-based and submarine hydrothermal and geothermal sites show a definite link between the geological setting, fluid geochemistry and specialized assemblages of microorganisms found at these settings. Three initial sites have been chosen as a basis for these studies. The first site is located on hydrothermal vents in pit craters on the submarine volcano Lo?ihi (Hawai?i) at a water depth of 1,300 meters. The second site is within the geothermally active vents, ponds and lakes of the Taupo Volcanic Zone of New Zealand. The third site extends along the chain of volcanically and hydrothermally active volcanoes of the Kermadec-Tonga arc and back-arc system. To focus our work in New Zealand, a geomicrobiology field and experimental center has been established in Wairakei, New Zealand, with the relevant genomics, proteomic and bioinformatics work being conducted at the University of Hawaii. As part of a partnership between the University of Hawai?i, the Institute of Geological & Nuclear Sciences (GNS) and Victoria University of Wellington, a new interdisciplinary graduate course in geomicrobiology will be taught at Victoria University beginning next year. Since mineral-microbial interactions have been occurring for the past few billion years and these interactions have led to where one generates the other, a metal-bacteria research program has been initiated at GNS using arsenic-gold and other metal-bacterial interaction processes as a research objective. In this research program, we have completed the full genome of a new species of marine bacterium Idiomarina loihiensis from the Lo?ihi hydrothermal vents and identified specialized microorganisms living in pH 0.3 geothermal vent waters of White Island, New Zealand. The multidisciplinary approach to study the process of accumulation of metals in the hydrothermal systems clearly shows the path of how bacterial-mineral interaction can precipitate metal deposits. These studies will lead to new avenues for biomining, bioremediation and the understanding of the origins of life.

Jan 1, 2004

By The DY125-33(Leg 2) Science Parties, Chuanshun Li, Xuefa Shi, Bing Li

"The slow-spreading Mid-Atlantic Ridge (MAR), with a length of ~1.26*104km (Bird, 2003), is the longest mid-ocean ridge on this plant. Separated by the large, left-stepping Equatorial fracture zones, it then be divided into two approximately equal-length parts: Northern Mid-Atlantic Ridge (NMAR, ~6292km) with an average spreading rate of 24mm/yr, and Southern Mid-Atlantic Ridge (SMAR, ~6332km) of 33mm/yr (calculated from PB2002 model, Bird, 2003). Previous works (e.g. Fouquet 1997, Hannington et al., 2011) suggest that slow-spreading ridge could support hydrothermal activities and further favorable for the development of extensive seafloor massive sulfide deposits (SMS). Unlike the NMAR for which large part has been explored for SMS (Hannington et al., 2011; Beaulieu et al., 2015), the SMAR is amongst the least hydrothermal explored spreading ridges until now (Haase et al., 2005, Beaulieu et al., 2015), though both of them show significant similarities in terms of spreading rate, ridge morphology, segmentation, etc. (Macdonald et al., 2001, Sandwell et al., 2014, Tucholke et al., 2008).Before this work, several hydrothermal cruises had been to SMAR since British and German programs starting in 2002, some hydrothermal fields, along with systematic geophysical data, were newly investigated, and types of geologic setting that can host hydrothermal activity were firstly identified (e.g. German et al., 2008; Haase et al.,2005; Haase et al.,2009; Devey et al.,2010; Schmidt et al.,2011).."

Jan 1, 2017

By James R. Hein

Manganese nodules from the Cook Islands (CI) Exclusive Economic Zone (EEZ) are compositionally different from other nodule fields. CI nodules have relatively high cobalt concentrations and low nickel, copper, and manganese concentrations (e.g. Hein and Petersen, 2013). This reflects the predominantly hydrogenetic (seawater source) origin for metals in the CI nodules versus dual seawater-pore water sources for most other nodules. The concentrations of many critical and strategic metals have not been previously analyzed for CI nodules, so comparisons with other nodule fields have been limited. To address this, we analyzed a set of nodules distributed throughout the CI EEZ for a complete set of 67 elements, including all of the metals that may be of economic interest, such as the rare earth elements (REEs), yttrium, tellurium, niobium, zirconium, tungsten, titanium, and others (see selected elements in Table 1). In addition, we recalculated the tonnages of nodules and contained metals from nodule abundance areas (in square kilometers) determined by GIS ArcMap calculations based on JICA/MMAJ (2001) nodule distributions. The nodule tonnage calculated and summed from each abundance sector yields a total inferred resource estimate of 9.66 billion tonnes of nodules covering an area of 1.21 million square kilometers; using a cut-off of 6 kilograms of nodules per square meter, yields a median tonnage of 8.59 billion tonnes of nodules covering 687,647 square kilometers (Table 2).

Sep 14, 2011

By Thomas Kuhn

The detailed investigation of both active and inactive submarine hydrothermal systems has gained tremendous progress during the last decades because of the increasing usage of remotely operated vehicles (ROV) as well as manned submersibles. Special aspects like the targeted sampling of chimney structures and vent fluids as well as the analysis of zonations of near-surface structures like sulfides mounds was only possible with the usage of such vehicles. However, the availability of such vehicles has been very limited because of the few number of deep-water ROVs and manned submersibles which need both a trained crew and a special research vessel. This was especially true for the German science community which did not have such devices at its disposal until recently. With the ROV QUEST 5 which is based at the University of Bremen (c/o. Prof. Dr. G. Wefer, Dr. V. Ratmeyer) this major drawback has now been eliminated.

Jan 1, 2003

By Alexander Malahoff

A shipboard research system capable of operating in waters of up to 2,000 meters has been designed and implemented by the Hawai'i Undersea Research Laboratory (HURL) of the University of Hawai'i. It uses a remotely-operated ocean bottom survey camera system, an ROV, the Pisces V submersible, and a submersible emergency recovery system, all aboard the 222- foot R/V Ka'imikai-o-Kanaloa. All systems are operated from the stern of Ka'imikai with a mounted Caley telearm and articulated A-frame system. The system was designed for multipurpose use of the ship for launch and recovery of the Pisces V submersible on a lift recovery line (with or without diver assistance), or night-time operations with an electro-optical cable using either the HURL ocean floor sidescan or photo and video system operated at 10 meters above the ocean floor. The 1.14-inch diameter cable is also used to operate an ROV system. The garage/ROV system can also act as a submersible rescue system with a submersible lift capability. The ship is equipped with a SeaBeam and shallow penetration sediment profiling systems. This integrated system approach to deep ocean floor research will make it possible for HURL to carry out research pro- grams on seamount ocean resources and ocean chemistry and climate in Hawai'i and the equatorial Pacific.

Jan 1, 1995

By Hyung-woo Kim

This paper concerns about steering characteristics of pilot mining robot, named MineRo II, crawling on extremely cohesive soft soil using dynamic simulation software. The MineRo-II for deep-seabed manganese nodules, which aims at the use for pilot mining test, was manufactured in 1/5 scale of commercial mining capacity (see Fig. 1).

Sep 14, 2011

By Henrik Schiellerup, Irene Zananiri, Johan Nyberg, Thomas Kuhn, Luis Somoza, Teresa Medialdea, Maria Judge, Pedro Ferreira, Gerry Stanley, Javier González

The GeoERA Co-Fund action is a joint contribution of 48 national and regional Geological Survey Organisations from 33 European countries “Establishing the European Geological Surveys Research Area to deliver a Geological Service for Europe (GeoERA)”. This is an ERA-NET action under Horizon 2020. The aim of GeoERA is to fund transnational projects contributing to the best use and management of the subsurface, addressing the following four themes: Geo Energy, Ground Water, Raw Materials and Information Platform. The European Commission recognises the significance of raw materials through its Raw Materials Initiative (RMI), the European Innovation Platform on Raw Materials (EIP-RM) and Horizon 2020 funding, specifically through Societal Challenge 5 – Climate Action, Environment, Resource Efficiency and Raw Materials. The GeoERA Raw Materials Theme will contribute to research and innovative developments for minerals inventory, minerals yearbook, exploration, mapping, modelling, metallogeny and critical raw materials in the pan-European framework including the sea. A major element in Europe’s long term economic strategy is to ensure security of supply for strategic and critical metals as part of the Blue Growth Strategy developing sectors that have a high potential for sustainable jobs and growth as seabed mining. The project MINDeSEA results of the collaboration between eight GeoERA Partners and four Non-funded Organizations at various points of common interest for exploration and investigation on seafloor mineral deposits. The Geological Surveys of Spain, Germany, Greece, Ireland, Norway, Portugal, Sweden and Ukraine are organisations with responsibility for coastal, marine geological investigation and mineral resources studies and mapping in their respective countries. The Non-funded participants: the Instituto Português do Mar e da Atmosfera; the United States Geological Survey; the All-Russia Scientific Research Institute for Geology and Mineral Resources of the Ocean; and the Geosciences Institute, host important databases, they have an international reputation for excellence in both science and technology, and are internationally-known experts on seafloor mineralisation and hydrothermal systems. This project addresses an integrative metallogenetic study of principal types of seabed mineral resources (hydrothermal sulfides, ferromanganese crusts, phosphorites, marine placers and polymetallic nodules) in the European Seas. The work program includes all the regional seas around Europe comprising the Atlantic Ocean, the Mediterranean Sea, the Baltic Sea and the Black Sea (Fig. 1). The MINDeSEA working group has both knowledge of and expertise in such types of mineralisation, providing exploration results, sample repositories and databases to produce innovative contributions. The importance of submarine mineralisation systems is related to the abundance and exploitation-potential of

Jan 1, 2018

By Andrea Koschinsky

Recent technological breakthroughs in the fields of ceramics, medicine, aerospace engineering and electronics (semi- and superconductors) are constantly creating new uses and an ongoing increasing demand for a variety of rare valuable trace metals. These so-called high-tech elements such as hafnium (Hf), titanium (Ti,) niobium (Nb), tantalum (Ta), zirconium (Zr), molybdenum (Mo), vanadium (V) and the rare earth elements (REE), many of them of strategic importance, occur inter alia at elevated and potentially economic concentrations in marine ferromanganese nodules and ferromanganese crusts, making those deep sea deposits potential future resources of these metals. As these metals are mostly present in the lattice of the manganese and iron phases, which are strongly intergrown, rather than in separate mineral phases within the nodules and crusts (Koschinsky and Hein, 2003), reductive dissolution of the host phases is a prerequisite to release and dissolve the valuable metals. To evaluate the association of these rare valuable metals with their mineral carrier phases, sequential leaching experiments were carried out on selected samples in a first step in our project.

Jan 1, 2011