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By John R. Benham

The Long Swamp RARE II area contains no prospects, claims, or mines. It has a low potential for ore deposits. There are no geothermal, oil, or gas leases in the area. APPRAISAL There are no mining districts in the study area. The nearest is Chewack Mining District, which is 6 mi (9.6 km) north of the area. This district had numerous claims located for tungsten; the principal tungsten ore mineral was wolframite. Wolframite was found here in 1898 by surveyors of the International Boundary Commission. The area was staked in 1908 and developed during 1915 and 1916. Only in 1936 was ore shipped; the 30 ton (27.2 t) shipment proved to be unprofitable for the claimants (Culver, 1945, p. 41).

Jan 1, 1982

By C. C. Hwang

The Bureau of Mines made time-dependent calculations to determine the size of a stationary source fire within a ventilated duct (or passage-way) necessary to ignite a combustible duct liner. The objective of this work was to gain more understanding of what occurs in duct fires and to determine critical conditions for ignition and propagation of mine fires. Heat transfer to the combustible surface includes both convective and radiated components, while the heat is conducted into the combustible and reradiated to the surroundings. The combustible is assumed to ignite when the net heat transfer to its surface is sufficient to raise the surface temperature to some minimum temperature, defined as the ignition temperature. A nondimensional parameter, which characterizes the source-fire intensity in the presence of ventilation flow, emerges as a parameter for a criterion of the critical conditions. The results of these calculations indicated that the minimum fire size necessary for ignition increases with the ventilation rate and duct cross section. These results are compared with experimental results obtained from fires in a 0.8-by 0.8-by Il-m-long duct and a full-scale gallery (2.4-by 2.4-by 65-m). Agreement between the theory and the experiment is good.

Jan 1, 1988

By Jr. Jacobson

Thermal reactions of l-methylpyrrole, l-butylpyrrole, and l-isopropyl-pyrrole were investigated by a flow method in the temperature range of 4500 to 5750 C. Those of I-butylpyrrole and l-isopropylpyrrole were also investigated in the 3400 to 4000 C range in a static system. The I-substituted pyrroles isomerize by an irreversible reaction to 2-substituted pyrroles. A reversible isomerization reaction shifted the alkyl group from the 2-to the 3-position on the pyrrole ring. All of the isomerization reactions are homogeneous, unimolecular, nonchain, first-order reactions having similar mechanisms and transition states. There is decomposition and cleavage of the longer alkyl side chain when it is in either the 2-or 3-position giving, as products, pyrrole, 2-and 3-methylpyrrole, 2-and 3-ethylpyrrole, pyridines, and hydrocarbons. The decomposition reactions appear to be by free-radical mechanisms. Pyridine homologs are formed by the expansion of the alkylpyrrole: butylpyrrole produces pyridine, and isopropylpyrrole produces 3-methylpyridine. Approximate Arrhenius equations are given for the formation of the decomposition products.

Jan 1, 1966

By J. W. Griffith, J. L. Stauffer, L. M. Demers, D. C. Kuhn, S. Riliog

"The relative activation of eicosanoid production which results from the exposure of the alveolar macrophage (AM) to mineral dusts is thought to be a key factor in the pathophysiology of occupational lung disease. We compared in vitro basal and silicastimulated production of prostaglandin E2 (PGE2) and thromboxane A2 (TXA2) by AM from normal humans and non-human primates (Macaca nemistrina). In addition, we instilled mineral dusts directly into one lung of the non-human primate and evaluated AM eicosanoid production at two week intervals following dust instillation. Unstimulated AM from humans produce more PGE2 and TXA2 than do AM from M. nemistrina. However, in vitro exposure of AM from both species to silica dust produced a qualitatively similar increase in TXA2 production accompanied by no change in PGE2 production. Sequential analysis of AM eicosanoid production following a single bolus exposure to bituminous or anthracite coal dusts, titanium dioxide (Ti()i) dust or crystalline silica showed marked variability among individual non-human primates in qualitative and quantitative aspects of dust-induced eicosanoid production. However, the rank order of potency of the different dusts (silica> anthracite> bituminous) correlated with epidemiological evidence relating the type of dust mined to the incidence of pneumoconiosis. These studies suggest that the non-human primate may serve as a model for the study of both the role of eicosanoids in the etiology of dust-induced occupational lung disease and the biochemical basis for individual variability in the response of lung cells to mineral dust exposure. IntroductionOccupational inhalation of mineral dust can lead to chronic debilitating lung disease ( 1,2). One of the key components of the disease process is thought to be the interaction of mineral dust with the alveolar macrophage (AM) and the subsequent release by the AM of inflammatory and fibrotic substances (3,4). Chronic inhalation of mineral dust, depending on the type and amount of dust, may then produce a situation in which ongoing inflammation, accompanied by the destruction of functional lung tissue by products of activated AM and polymorphonuclear neutrophils, stimulates the production of nonfunctional matrix by lung fibroblasts.The AM produces several oxygenated derivatives of arachidonic acid (AA) which may play important roles in dust-induced lung pathophysiology (5,6). In previous studies in the rat, we found that prostaglandin E2 (PGE2). thromboxane A2 (TXA2) and leukotriene 84 (L TB4) were the major AA metabolites produced by AM (7). PGE2 is associated with pro-inflammatory activity (8) as well as anti-fibrotic activity since it downregulates interleukin -1 (IL-1) and tumor necrosis factor (TNF) release by AM (9-11). TXA2 is known to stimulate platelet activity, cause bronchial and vascular smooth muscle contraction (12) and to possess chemotactic activity (13). LTB4 is chemotactic for neutrophils and monocytes (14) and has been suggested as an additional regulatory factor in the release of TNF by AM exposed to silica dust ( 15)."

Nov 1, 1995

By Charles D. Litton

This U.S. Bureau of Mines report details the results of a series of large-scale experiments where small coal fires were used to ignite the conveyor belt at air velocities ranging from 0.76 to 6.1 m/s. In the tests, electrical strip heaters imbedded within a pile of coal were used to heat the coal to a point of flaming ignition. The flaming coal subsequently ignited the conveyor belt located approximately 5 to 10 cm above the coal pile. During the tests, temperature, CO, and smoke levels were continuously measured in order to determine both alarm time and level as the fire intensity progressed through the stages of smoldering coal, flaming coal, and flaming coal plus flaming belt. Analysis of the data leads to certain conditions of air velocity and sensor alarm levels that are required for early detection of conveyor belt entry fires. Two nomographs are presented, which define sensor alarm levels and sensor spacings as a function of belt entry cross-sectional area and belt entry air velocity.

Jan 1, 2010

By R. S. Conti

This U.S. Bureau of Mines (USBM) report discusses the results of research conducted in the USBM experimental mine at its Lake Lynn Laboratory to determine the alarm times of smoke and carbon monoxide (CO) sensors, and a point type heat sensor (PTIIS) to slowly developing coal-conveyor belt fires. The tests were conducted at air velocities of 0.44 and 0.97 m/s, The data clearly indicate that smoke sensors provide earlier warning of fire than 10 ppm CO sensors, and that 10 ppm CO sensors provide earlier warning than PTHS, A success rate of 1.0 (indicating detection of every test fire) was obtained for both smoke and C8 sensors. For the PTHS, the success rate was 0.57 at the lower air velocity, decreasing to 0 at the higher air velocity, Data are also presented showing the sequence of fire events and detection events at the two air velocities as a function of time. Results show that early detection and warning of underground mine fires will improve the probability of miners' escape.

Jan 1, 2010

By Lindsay D. Norman

Four chloride and seven fixed-nitrogen processes for recovering manganese from domestic resources are described. The chloride processes are divided into two classes (leaching and chloridization) depending upon the major operation responsible for converting the manganese minerals to the chloride from which manganese oxide products are obtained. The fixed nitrogen processes, all of which yield high-grade manganese oxide products, are essentially either leaching or roasting processes. The 11 processes include HC1 leach, HC1 chloridization, HC1 chloride volatilization, CaC12 chloride volatilization, NO2 leach, HNO3 leach, HNO3 ?NO2 leach, H3 ?CO2-H2O system leach, (NH4)2SO4 leach, (NH4)2SO4 roast , and ammonium salt roast .

Jan 1, 1963

By Charles P. Lazzara, Charles D. Litton, Frank J. Perzak

This U.S. Bureau of Mines report details the results of a series of large-scale experiments where small coal fires were used to ignite the conveyor belt at air velocities ranging from 0.76 to 6.1 m/s. In the tests, electrical strip heaters imbedded within a pile of coal were used to heat the coal to a point of flaming ignition. The flaming coal subsequently ignited the conveyor belt located approximately 5 to 10 cm above the coal pile. During the tests, temperature, CO, and smoke levels were continuously measured in order to determine both alarm time and level as the fire intensity progressed through the stages of smoldering coal, flaming coal, and flaming coal plus flaming belt. Analysis of the data leads to certain conditions of air velocity and sensor alarm levels that are required for early detection of conveyor belt entry fires. Two nomographs are presented, which define sensor alarm levels and sensor spacings as a function of belt entry cross-sectional area and belt entry air velocity.

Jan 1, 1991

By James Rowland, Isaac Zlochower, Richard Mainiero, Michael Sapko

The National Institute for Occupational Safety and Health (NIOSH) carried out exploratory laboratoryscale studies to identify factors that may contribute to nitrogen oxides (NOx) production associated with non-ideal detonation of blasting agents. Explosive admixture with drill cuttings, loss of fuel oil in ammonium nitrate and fuel oil (ANFO) from wicking, ammonium nitrate dissolution with water, degree of explosive confinement, ANFO density, and critical diameter were identified as contributing factors to increased NOx production under the laboratory test conditions. Experiments were also conducted to examine the effectiveness of various additives in reducing the NOx production from ANFO, emulsion, and ANFO/emulsion blends. Aluminum powder, coal dust, urea, and excess fuel oil in ANFO formulations were tested and were found to reduce both the nitric oxide (NO) and nitrogen dioxide (NO2) production. Fumes measurements were obtained in the NIOSH underground closed chamber from the detonation of 4.5-kg (10 lbs) charges in schedule 80 seamless steel pipe and from detonations in light weight galvanized steel stove pipe. Some exploratory tests were also conducted with 0.8-kg (1.8 lbs) charges of pulverized ANFO initiated with 0.08-kg (0.18 lbs), 50/50 (Pentolite) boosters (in the NIOSH 12-ft (3.7-m) diameter steel sphere) to measure the degree of fumes production associated with post-detonation oxidation. Ammonium nitrate, emulsion and Pentolite boosters were also detonated in an oxygen-poor environment.

By R. S. Conti, C. D. Litton

This U.S. Bureau of Mines (USBM) report discusses the results of research conducted in the USBM experimental mine at its Lake Lynn Laboratory to determine the alarm times of smoke and carbon monoxide(CO) sensors, and a point type heat sensor (PTHS) to slowly developing coal-conveyor belt fires. The tests were conducted at air velocities of 0.44 and 0.97 m/s. The data clearly indicate that smoke sensors provide earlier warning of fire than 10 ppm CO sensors, and that 10 ppm CO sensors provide earlier warning than PTHS. A success rate of 1.0 (indicating detection of every test fire) was obtained for both smoke and CO sensors. For the PTHS, the success rate was 0.57 at the lower air velocity, decreasing to 0 at the higher air velocity. Data are also presented showing the sequence of fire events and detection events at the two air velocities as a function of time. Results show that early detection and warning of underground mine fires will improve the probability of miners’ escape.

Jan 1, 1995

By Paul S. Schopf

The results of an experimental investigation into the possible use of medium energy acoustic fields (130 to 140 dB) to precipitate 1 to 10 micron particles is presented. The aerosol was produced with a LeMer generator using oleic acid and nitrogen. The sound field was a sinusoidal standing wave field in an acrylic tube, with light transmission data used for concentration determination. The results showed collection efficiencies of up to 80% on 2 micron particles with a residence time of 11.8 seconds at a sound pressure level of 139 dB re 2x10-5 N/m2. A discussion of the possible turbulent mechanism is made, as well as review and comparison with others? work.

Jan 1, 1972

By Charles L. Kimbell

In broadest overview, UN global industrial production indicators released and shown in table 2 suggest that the extractive sector of the world's mineral industry in aggregate registered a very slight upturn in 1991 relative to its 1990 performance. It also shows a continued rebound in the industry from the recessionary period of the mid-to late-1980's. These same indicators as calculated in late 1991, however, reflected a very minor downturn in extractive mineral industry operations between 1989 and 1990. This latter downturn represented a notable revision from the data reported in the immediate previous edition of this chapter, which suggested a tiny upturn. The apparent slight 1991 upturn in extractive sector industrial output generally was not mirrored in the performance of the processing sectors of the global mineral industry. Although the aggregate index for the chemicals, petroleum, coal, and rubber products manufacturers (see table 3) showed a notable gain in 1991, similar indices for nonmetallic mineral products and for base metals registered declines between 1990 and 1991. Examination of regional performance indices shows that the difficulties experienced in 1990 in maintaining output levels within the countries that formerly constituted the CMEA were reinforced by trends toward reduced gains in output levels, if not actual reductions in output, in several other areas. Generally speaking, the traditional developed market economy countries recorded downswings in overall industrial activity in 1991, particularly after midyear, whereas developing market economy countries logged gains. The developed market economy country downturns, however, were not nearly as significant as were the downturns recorded for the former centrally planned economy states - those that before 1992 were either constituent Republics within the U.S.S.R. or the latter's CMEA partners.

Jan 1, 1993

By Kenneth E. Hjelmstad

The U.S. Bureau of Mines (USBM) has developed an electromagnetic (EM) fire warning alarm sys-tem for underground mines. The system generates a magnetic field for through-the-earth signal trans-mission to microreceivers carried by individual miners. EM fields can induce electric currents in metallic conductors; if an EM transmitting antenna and an electric blasting cap array are too close, the field could induce a current in the blasting array and cause an unintentional initiation of the electric detonators. The USBM conducted tests that define the safe and unsafe regions for using electric detonators near the transmitting antenna of the warning alarm system. The minimum safe distance between a transmitting antenna and a blasting array is the distance where the induced electrical current in the blasting array is 50 mA, which is the safe current level specified in Federal mine safety regulations. Tests indicate that at transmitting power levels of 100-and 1,000-W, separation distances of 9 and 21 m, respectively, were required. These distances are small compared with the dimensions of a mine. Thus, the tests indicate that, with proper placement of the transmitting antenna, the warning system can be used safely in the proximity of blasting arrays.

Jan 1, 2010

By J. C. Judd

The Bureau of Mines investigated the recovery of vanadium, uranium, and phosphorus from low-grade phosphorite ores and concentrate by leach-ing with H2S04. Samples containing 0.12 to 0.23 pct V20S, 0.009 to 0.012 pct U30S and 18 to 30 pct P20S were treated by batch-agitation leaching, roasting followed by acid leaching, salt-roasting followed by acid leaching, and leaching under pressure. Maximum recoveries using leaching alone ranged from 78 to 98 pct of the V20S and 74 to 88 pct of the U30S-Leaching under pressure resulted in extractions of 88 to 95 pct of the V20S and 84 to 89 pct of the U30S. Leaching following roasting--with or without NaCI--produced extractions of 97 to 99 pct of the V20S and 86 to 91 pct of the U30a. Depending on the technique(s) employed, phosphate extractions ranged from 89 to 99 pct. Solvent extraction laboratory tests were conducted to selectively re-cover vanadium and uranium values from acid leach solutions. An average of 95 pct -of the U30a was recovered using di(2-ethylhexyl) phosphoric acid, plus trioctylphosphinic oxide. Essentially all of the V20S was recovered with octylphenyl acid phosphate plus isodecanol. The phosphate remained in the raffinate.

Jan 1, 1986

By A. T. Iannacchione

Synopsis Underground stone mining Is an emerging sector of the U.S. mining industry. As this expansion takes mines under deeper cover, and as more efficient mining methods are utilized, effective stone pillar design methods will become even more Important. Current design practices are examined and a discussion of safe mine layouts is presented as a first approach towards weighing the demands for increased production against increased risk. Risks to underground stone-mine workers include rib Instabilities, pillar failures and roof falls. Seventy-two stone-mine pillar designs were examined. Pillars with width to height ratios of less than 1.5 appear more likely to fail when subjected to excessive stress levels. When width to height ratios fall below 1.0 defects in the pillars, such as through-running discon¬tinuities, can have a significant influence on stability. Discontinuity persistence, dip, material properties and orientation are also important determining factors in pillar strength. During the past three years the number of active underground stone mines in the U.S.A. has ranged between 90 and 100. This number is expected to increase as the crushed stone industry responds to growing demands for its products.1 As more of the industry moves to benefit from the advantages of underground mining production from underground stone mines is expected to increase above its current level of approximately 66 000 000 r/year. Parker2 identified four advantages of underground mining operations: (1) surface developments, zoning laws and environmental concerns are often less of an issue; (2) stripping and restoration requirements are eliminated; (3) additional reserves are often available beneath the quarry floor, under pit slopes or under an adjoining property; and (4) space is created for secondary use. Underground mines enjoy the added benefits of work in a constant underground climate, rather than in the variable surface climate, minimization of community concerns by placement of the crushing, sizing and stowing operations underground and reduction of surface vibration concerns through smaller blasts. The drawbacks of underground mining include added health and safety hazards for the stone miners, whose health can suffer from increased exposure to falls of ground, airborne contaminants and fog in large underground openings. Injuries from falls of ground in stone mines have occasionally exceeded the incidence rates for other mineral resources mined underground. 3 Existing underground stone operations, by comparison with stone operations a decade ago, mine more stone at a faster rate and with larger equipment. Because of high demand mines face increased pressure to yield more stone per production blast. A majority of the miners use the V-cut blasting pattern, which limits the depth or pull for each shot to about 4 m. Therefore, to produce more stone, either the mines must work more faces or existing faces must be enlarged. The enlargement of underground openings poses problems in the maintenance o€ strata stability, First, the widths of the mine entries partially control the amount of sag or deflection that any given roof beam can withstand before failure. This deflection can take pi ace quickly after an opening is excavated or much later as weathering processes form additional, thinner beams. Because increased deflection increases the potential for roof beam failure, there is a limit to how wide a room can safely be made. These limits depend on local geological and stress conditions and, to some extent, the cost effectiveness of roof-bolting. Given these room width limitations, underground stone mines have placed more attention on expansion of production through benching where mining thicknesses permit. The heights of rooms partially control the strength characteristics of adjacent pillars: as the room height increases for a given pillar width the pillar width-to-height ratio (w/h) decreases. In general, stone pillars are very strong, but when the width-to height ratio diminishes the potential for pillar rib instabilities and pillar failures increases (see Fig. 1). [ ] In the underground environment the desire to utilize wider rooms, higher benches and multi-level mining results in the potential for unstable ground conditions. Although the number of failed pillars is currently very low, the potential for additional failures will grow if more slender pillars are developed, especially under deeper cover, with wider mining sections and in multi-level operations. It should also be noted that the passage of time acts to decrease the strength of many existing pillars. An examination of current design practices

By G. R. Hopkins

A fifth successive record in fuel efficiency was established by the petroleum-refining industry in 1937, when the average heat requirement per barrel of crude oil run to stills was 554,000 B. t. u. compared with 597,000 B. t. u. in 1936. These amounts represent roughly the heat obtainable from a tenth of a barrel of fuel oil (see fig. 1). Innumerable factors can influence heat consumption at refineries, but only a few are important enough to be subject to statistical measurement. Foremost of these is the ratio of runs to capacity, it being generally recognized that because the fuel demands for other than stills are comparatively inelastic, total heat requirements do not increase in direct proportion to crude runs. Thus, in 1937, crude runs of 1,183,440,000 barrels were 11 percent higher than in 1930; the average operating ratio was 83 percent compared with 79 percent in 1936; but the total heat requirement increased only 4 percent, or from 638,149 billion B. t. u. in 1936 to 663,966 billion B. t. u. in 1937.

Jan 1, 1938

By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By Harley A. Coy

This paper, describing the mining methods and practice at No. 2 mine of the American Zino Co. of Tennessee at Mascot, Tenn., is one of a series of papers issued by the Bureau of Mines presenting the mining methods and costs in various districts throughout the United States. Its purpose is to summarize methods recently put into practice whereby increased efficiency has been effected. These improvements have to do principally with mill-hole mining, slushing, contract labor, and bonuses. In general, this paper supplements earlier articles and brings them up to date. ACKNOWLEDGMENTS The author acknowledges the assistance of M. H. Newman, geologist of the American Zinc, Lead & Smelting Co.; of William Black, assistant superintendent of mines; of P. M. Arthur, director of personnel; and of the engineering staff. The paper has been approved by H. I. Young, vice president and manager of operations.

Jan 1, 1930

By T. G. Carnahan

The Federal Bureau of Mines investigated, on a laboratory scale, a technique for recovery of silver from pregnant solutions generated in the hydro-metallurgical treatment of complex base-metal sulfide concentrates with oxidizing chloride media. This technique provides a means for recovery and simplified reduction of accessory silver to metal from chloride solutions. The method consists of adding NaI or KI to the solution to precipitate AgI, which is then contacted with Na2S to produce Ag2S and to regenerate the iodide salt solution. Silver recoveries range from 99 pct with 20 pct excess iodide precipitant, to 92 pct when the theoretical stoichiometric amount of precipitant is employed. The Ag2S product can be reduced to silver metal by contact with aluminum chips in NaOH solution followed by purification with conventional fire refining techniques.

Jan 1, 1980

By H. Leitch

In laboratory experiments, the Bureau of Mines investigated melting, quenching, and sulfuric acid leaching of alumina from mixtures of albite and anorthite, and from anorthosites containing 26 to 32 percent alumina. Variations in pouring temperature, quenching and leaching conditions, were studied with respect to the extraction of alumina and impurities. Virtually all of the alumina was dissolved by leaching melted and quenched California anorthosite in boiling 16-percent sulfuric acid solutions for 15 to 30 minutes. The leach solutions were readily separable from the solid residue by conventional thickening and filtration techniques. Only 2 to 5 grams of SiO2, Fe2O3, or CaO dissolved per 100 grams of alumina. The quantity of SiOz in solution varied inversely with the duration of the leach and with the concentration of the H2SO4 solution used. Melted and quenched Wyoming and Minnesota anorthosites with SiO2:CaO weight ratios of 4.3 and 3.2, respectively, were less amenable to sulfuric acid leaching than California anorthosite with an SiO2:CaO weight ratio of 5.3. However, excellent results were obtained on the Wyoming and Minnesota anorthosites by the addition of SiO2 to these materials before melting, in quantities sufficient to adjust the SiO2:CaO weight ratios of the furnace charges to between 4 and 6.

Jan 1, 1966