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By Charles L. Kimbell

In 1990, the aggregate value of world international export trade in mineral commodities was estimated at more than $64 billion in current (1990) dollars, about 8.4% higher than that in 1989, but still 8.7% below the record high set in 1980. Table 8 provides a data series for the estimated value of world export trade in all mineral commodities from 1979 through 1990, as well as a breakdown of this total into fuel and nonfuel commodities. It is noteworthy that for this 1990 edition, trade data for the year of review were available in time for inclusion, whereas in previous editions, the latest available global trade data were for the year prior to the year of review. Hence, as regards trade, this edition of Minerals in the World Economy updates the 1989 edition by 2 years rather than by only 1. For this reason, it is appropriate to note that the 1989 global total value for inter-national export trade in mineral commodities was almost $596 billion, 11.1 % above the revised 1988 level of more than $536 billion, both figures expressed in current dollars for the appropriate year. Despite the considerable increase in the dollar value of mineral commodity exports, their share of total export merchandise trade declined to 19.1 % in 1990 from 19.7% in 1989. At 19.1%, this share was very near the recent year record low of 19.0% reached in 1988. The year 1990 was the fourth in a row in which the total value of world mineral commodity export trade increased.

Jan 1, 1993

The object of this program was to extend the capabilities of visual paging systems both in size and function. The system developed uses the mine pager phone line for communication, monitoring, and remote control. A central station, using a mini-computer, transmits signals by phase inversion modulation of a 16,384 Hz carrier to as many as 999 remote units. The remote unit addressed returns an echo to indicate that it is functioning and, in the case of monitor units, to convey the monitor data. Magnetically latched display discs, which can be seen from both sides when posted, are used for visual paging. Lists of the addresses of posted pages, unanswered pages, and non-echoing units are prepared by the central station computer. The system was designed to be intrinsically safe and should operate for three months on a 12-volt lantern battery.

Jan 10, 1980

By R. A. Keaens, L. C. IlsLey

For the purpose of this paper a junction box is defined as " a fused switch, inclosed in an explosion-proof compartment, provided with a ready means of connecting or disconnecting a trailing cable without exterior arcing." Junction boxes are intended for use 'at the end of trailing cables and are usually placed outby the last open break through in a coal mine. Where it is not safe to supply current through nips or a trolley, junction boxes suitably spaced along an entry permit tramming and movement of machines with safety, although not with any considerable speed. Junction boxes serve a threefold purpose: (1) They prevent dangerous arcing at the outby end of trailing cables; (2) they afford a safe, practical means of fusing or otherwise protecting the trailing cable; and (3) they provide an efficient means of transmitting power from the power circuit to the trailing cable. The first purpose is the most important from a safety standpoint. Dangerous arcing-that is, arcing capable of igniting gas-frequently takes place where trailing cab1c.s are attached to the power circuit. At either 250 or 500 volts only a very small arc is required to ignite mine gas. The usual method of connecting the trailing cable to the power circuit by cable nips or trolley taps does not make a good electrical connection; hence arcing may be expected at any time. Furthermore, junction boxes eliminate the personal hazard attendant upon the use of trolley taps by removing the possibility of accidental contact with trolley hooks or wire and the liability to injury due to manipulation of the device. In the general scheme of mine ventilation it is assumed that gas will not accumulate where junction boxes are placed, an assumption based on the normal operation of the ventilating system. In many

Jan 1, 1929

By Walter W. Fisher

A kinetic investigation of copper cementation in a revolving drum was undertaken by the Bureau of Mines to explore the effects of a porous copper deposit attached to the iron surface and a fluidized slurry of copper particles surrounding the iron precipitant. The rate of cementation was found to be significantly enhanced by the increased cathodic areas provided by a porous copper deposit or the presence of a fluidized bed of copper particles contacting the iron precipitant. The cementation rate was found to be retarded by increased ionic strength, low pH, and the presence of oxygen. The cementation reaction was first order with respect to precipitant surface area. Copper cementation on iron is visualized to occur by two basic mechanisms. Precipitation may occur through a series of shorted electrochemical cells, whereby cupric ion precipitates on a growing cathodic copper deposit, or, deposition may occur via a fluidized cathode of copper particles contacting the ion precipitant.

Jan 1, 1976

By C. F. Wingquist

As part of an ongoing study to determine how the wear of mining tools affects dust generation, the Bureau of Mines has measured bit tempera-ture rise during cutting of abrasive rock. Radial bit wear-flat tem-peratures generated by linear cutting in Berea Sandstone were measured as a function of cutting depth and speed. Depths of cut (DOC) were 1/8, 1/4, and 1/2 in, and cutting speeds were 10, 40, and 80 in/s, respectively. Temperature sensing was accomplished by emplacement of a miniature thermocouple into the center of the wear flat. Temperatures observed ranged from 2000 to 5000 C. Correlation between depth and temperature was weak. Temperature increased linearly with speed at 1/2-in DOC, but data taken at 1/8-and 1/4-in DOC produced inconclusive results. The results indicated that at least for deeper cuts (1/2 in), bit temperature, and therefore wear, can be reduced by lowering the cutting speed.

Jan 1, 1987

By Eugene V. Cilento, R. Clark Lantz, Kevin A. DiGregorio

"A microscope-based spectrophotometer has been developed to measure superoxide release from single pulmonary alveolar macrophages (PAM) or other phagocytes in culture. Results indicate that PAM respond to stimulation by phorbol myristate acetate (PMA). It appears that some PAM do not release 02 upon stimulation by PMA; however, those that do release 0, show differences in: (I) the total amount of 0, released, (2) the rate of release of 02 and (3) the time delay for release of 02. The significance of measuring 02 release from single cells is two-fold. It allows the simultaneous study of 02 release and electrical potential changes across the membrane of PAM and it allows the study of differences in 02 release among cells. Thus, the function of Normal PAM and the dysfunction of PAM exposed to coal dusts can be more closely studied on single cells.Pulmonary alveolar macrophages (PAM), free cells found in the lungs, protect the lungs by removing inhaled foreign debris and bacteria. The macrophages do this by engulfing and then internalizing the foreign matter (phagocytosis). Stimulation of PAM causes the release of super-oxide radical (02) which has been shown to be the primary metabolite involved in the killing of bacteria by phagocytes (3,8,12). The super-oxide radical is highly reactive and is spontaneously or enzymatically converted to other antibacterial oxidants, including hydrogen peroxide (H202), singlette oxygen ( 02), hydroxyl radical toil'), and hypochlorous acid (HOCl) (2, 3,8,11,12).Exposure of PAM to dusts may lead to dysfunction of this cell-type and to a greater risk of lung damage or infection upon subsequent exposure to toxic dusts. To date, much of the research with this cell-type has used cytotoxicity (cell death) as a measure of dysfunction. Although this is an important end point, PAM dysfunction may occur at doses below those which lead to cell death. In addition, dysfunction has been measured using large numbers of cells. In order to obtain a clear understanding of the mechanisms involved in dysfunction, measurements should be made on single cells. As mentioned earlier, one of the major roles of this cell type is its anti-bacterial actions. Therefore, asessment of release of superoxide radical in single cells is important in determining the functional behavior of PAM before and after exposure to dusts. Since measurements of 02 production have not been made on single cells the purpose of this study is to develop the methodology needed to study release of 02 from single cells.Recent studies have suggested that a relationship exists between the release of 02 and changes in the electrical properties of phagocytes. The change in membrane potential is thought to be the initial step in superoxide production (6,9). Stimulants which cause 02 release also cause changes in the transmembrane potential of phagocytes (9) and in the permeability of the cell membrane to ions (6). For example, stimulants which cause the release of 0, from neutrophils have also been shown to increase the membrane transport of Na+ , K+ and Ca+2 and stimulation of macrophages leads to increases in Na and perhaps Ca permeability with a subsequent change in membrane potential. In some cases, phagocytic activity has been shown to depend upon the extracellular concentrations of these ions (6). Holian and Daniele (7) have shown evidence that the redistribution ofcellular Ca in alveolar macrophages is an initial step leading to 0, release. In order to provide direct evidence that 02- production is related to electrical changes across the plasma membrane of phagocytes, these two phenomena must be analyzed simultaneously on single cells. Ultimately, measurements of 0, release using the methodology developed in this study will be combined with electrophysiological tech¬niques to study both superoxide release and membrane potential changes simultaneiously on single PAM, and to examine the effects of coal and mineral dusts on their physiological fu"

Jan 1, 1988

By R. P. Beyer

A FORTW IV computer program has been written to calculate thermodynamic properties over a desired temperature range from spectroscopic data. This program computes heat capacities, enthalpies, and entropies for monatomic, diatomic, linear, and nonlinear polyatomic gases. This research is part of the Bureau of Mines effort to provide thermodynamic data for the advancement of mineral technology.

Jan 1, 1981

By M. Howard Berliner

In August 1943 the Bureau of Mines completed seven churn-drill holes in an area of old mine workings near Linden, Wis., formerly known as the Argall mine. The work was undertaken as part of a general investigation by the Bureau of the zinc and lead producing area of southwestern Wisconsin at a time when special effort was being made to increase the production of metals necessary for war. The area was selected for investigation on the basis of its favorable geologic structure, past history, and apparent mineralization.

Jan 1, 1948

By Douglas Talley

This report describes a 4-inch diameter borehole probe which contains a low light level TV camera, magnetic compass, light illumination source, bottom/water detector sensor and a pointing angle sensor. The camera viewing angle is at a right angle to the probe's body. All data from the sensor is multiplexed into the closed circuit camera video for transmission on a single 50 ohm coaxial cable to a surface control unit. Likewise control of the probe's power, zoom lens, focus, panning and aperture is accomplished via a down-link multiplexed on the same cable.

Jan 9, 1984

Improve the safety of salt mine workers by providing a means for quickly identifying areas within the mine that?s how an increased potential for gas and salt outbursts. Approach Outbursts occur in salt mines when a high-pressure pocket of gas is intercepted during the mining process, resulting in a sudden and sometimes catastrophic expulsion of gas and salt. In one case, the amount of gas released through such an event caused an explosion that resulted in five fatalities. The U.S. Bureau of Mines has designed and developed a gas outburst prediction system that can quickly determine the potential instability of areas within rock salt mines. The determination is based on noise measurements obtained from samples of the salt as they are dissolved in water. This system improves upon technology currently available because it provides information in only a few minutes instead of in several days. In addition, present prediction systems are not only time consuming, but expensive because they require laboratory conditions and highly trained personnel to operate them and determine results.

Jan 1, 1989

By J. Feldman

This report contains a description of the distillation laboratory at Bruceton, Pa., which was established to aid in the separation and identification of the products produced in the synthetic liquid fuel processes under study there. Compounds present in synthetic liquid fuels may include aliphatic from C1 to C60 or greater. Alcohols, ketones, esters, aliphatic carboxylic acids, saturated hydrocarbons, olefins, and diolefins are all found in Fischer-Tropsch products. Coal-hydrogenation products contain, in addition to aliphatic compounds, a large proportion of naphthenic material and aromatic compounds ranging from benzene to coronene; in addition, appreciable quantities of tar bases and tar acids are present. In designing the laboratory, therefore, provision had to be wade for the greatest amount of flexibility and versatility. A great deal of standardization of basic equipment had also to be designed to permit interchange of parts and services.

Jan 1, 1951

By Constantine C. Popoff

During 1946 several high-grade limestone deposits in western Washington were examined by the Federal Bureau of Mines. The purpose of the examinations was to disclose new sources of industrial limestone and to indicate the commercial potentialities of little-known and undeveloped deposits. These examinations were part of a long-range program of investigation of mineral resources of the Pacific Northwest. The following report on the Whitechuck travortine deposit is one of a series prepared in the course of the investigations.

Jan 1, 1949

By E. E. Maillot

In 1943, diamond drilling by the Bureau of Mines, comprising 11 holes which totaled 1,295.6 feet, showed that the pegmatite at Black Mountain consisted of shallow lenses in interbedded biotite-quartz-schist and impure quartzite. The average thickness of the pegmatite was 9.7 feet. Mineralization had a zonal arrangement. Beryl was most abundant near the footwall contact of the pegmatite. The average estimated beryl content of the pegmatite exposed at the surface was 0.81 percent, and the highest content of any pegmatite area was 1.75 percent. Other economic minerals were scrap mica, feldspar, spodumene, and lepidolite. Representative samples of the Black Mountain deposit failed to yield high-grade boryl concentrates by straight flotation owing to the presence of considerable spodumene. By employing heavy medium separation to remove the spodumene, 75.4 percent of the. BeO wan recovered in a flotation concentrate assaying 10.4 percent BeO.

Jan 1, 1949

By J. Ribovich

The current Bureau of Mines active list of permissible explosives includes 71 brands. Eleven are gelatinous, 56 are the granular type, and four are water-gel explosives, an entirely new type of ammonium nitrate-based explosive for use in coal mines. The list of permissible blasting devices comprises five Cardox models.

Jan 1, 1973

By M. J. Ankeny

All bituminous-coal mines, by the nature of their product and inherent gassy tendencies, are subject to explosions or mine fires. The evolution from large, hand-loading sections employing numerous men and containing open-type equipment, lights, and nonpermissible explosives to small, concentrated mechanical sections with but few well-supervised men utilizing modern preventive equipment has not altered this premise. Mine catastrophes such as Centralia and New Orient No. 2, as well as recent disasters of less magnitude, have refuted the trend of thinking that modern equipment, will prevent or localize explosions and prevent widespread or loss of life.

Jan 1, 1952

By H. E. Powell

The mineral dressing research here reported is part of a continuing program by the Bureau of Mines to develop new or improved concentration processes for oxidized or partly oxidized lead and zinc ores. A sample of low-grade sulfide-oxide, lead-zinc ore from Jasper County, Mo., containing galena, cerussite, pyromorphite, hemimorphite, smithsonite, and sphalerite was concentrated by froth flotation and tabling to a grade of 66 percent lead. Because of the presence of a high content of slime-size values, the overall recovery of lead was limited to 64 percent at this grade. Tests to recover the zinc by froth flotation and by gravity concentration did not give satisfactory results. INTRODUCTION Since its establishment, the Rolla Metallurgy Research Center has con-ducted studies of base metals as a part of its overall program (1, 2, 3, 4, 5,6,7).3/ This research has been, and is, directed to beneficiating complex and submarginal ores, to retreating rejects from commercial installations, and to developing fundamental data.

Jan 1, 1960

By EINAR M. ARENTZEN

This information circular. deais primarily with an engineering descrip- tion of a type of longwall cutting and loading machine developed by Eick- hoff Maschinenfabrik, Bochum, Germany..: This machine is supposed to have been developed and tested during the latter part of 1941 and early 1942. The only source of information is con- tained in certain literature and engineering data, with drawings which were acquired by the Allied Military Authorities when Germany was occupied; and the information will have to be limited because the writer has not seen the machine in the factory or in operation. However, the information may be of interest to the coal-mining industry in this country, and for this reason our Government has decided to publish the data procured so far. The Eickhoff cutting and loading machine is particularly suitable for the longwall mining system. It can only be used under that type of mining system and is not suitable for the more common type known in this country as room-and-pillar work. The material for the description of the machine and its operation was compiled and translated from German drawings and operating instructions. These detailed drawings and instructions are on file with the Bureau of Mines and are available for inspection by any responsible person interested in the details of the construction of the machine.

Dec 1, 1946

By W. T. Millar

Graphite in the Suffern deposits near Hillburn, N. Y., consists of flakes ranging in size from fines to one-half inch in diameter. The Bureau of Mines investigated the Suffern deposits in the spring of 1943. Gneiss outcrops were examined, and five trenches excavated and sampled. The graphite is not confined to any definite zone but occurs in small, local pockets. Eleven samples were collected and combined for laboratory tests. Tests by the Bureau of Mines indicate that the graphite ore can be beneficiated by stage crushing, "skin flotation" of coarse flakes, and wet flotation of minus 10-mesh flakes. Over 90, percent of the graphite was recovered.

Jan 1, 1949

By John P. Harmon

A group of organic chemicals, known as wetting agents, has been developed, primarily for use in the textile industry. These chemicals have the property of reducing the surface tension of water when mixed with it in very dilute solutions. The advantage of lowered surface tension is recognized in dust-control work, and several wetting agents, have been tried by dust-control engineers with varying degrees of success. It is well-known that certain solids, coal for instance, are extremely hard to wet with plain water because of the high surface tension of water and the water-repellent action of coal. If the surface tension of the water is reduced, it can be demonstrated that the coal can be wetted easily. This is accomplished practical and at law cost by dissolving a very small percentage of wetting agent in the water that is to be used for wetting purposes. (Care should be exercised in using a wetting agent to be sure that it will not interfere with a subsequent process.) For some time, the comparative efficiency of various wetting agents has been the subject of considerable work by dust-control men at coal mines, as well as by members of the Bureau of Mines 3/, 4/, 5/, 6/. In this connection, a number of samples of air-borne dust have been collected in the mines. With the exception of dust-control measures conditions of dust generation and dissemination were maintained as, nearly uniform as possible. Samples were collected when water alone was sprayed on the cutter bar of a mining machine; various wetting agents were then successively added to the water and more samples of air-borne dust were-collected.

Jan 1, 1946

By Christopher H. Roe

This Bureau of Mines report reviews the various methods of removing the liquid from tailings slurries that contain very fine grained solids. Gravitational settlement, centrifugation, filtration, and thermal drying methods are discussed in detail. Chemical additives, electrokinetic dewatering, and the rotary trommel screen are also mentioned. Lists of dewatering equipment and suppliers are given in the appendixes to assist the planner who must choose the most efficient, economic, and practical method of dewatering very fine grained mill tailings.

Jan 1, 1984