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By Maurice C. Fuerstenau

INTRODUCTION The term, chelate, from the Greek for 'claw,' has its origin in the pincer-like representation of more than one atom of a single ligand bonded to the same metal atom, forming a ring-like structure. Depending on how many attachments exist on the sphere of coordination around the metal ion, ligands are referred to as bidentate, tridentate, tetradentate, pentadentate and hexadentate According to Calvin and Martell (1952) and Somasundaran and Nagaraj (1984), chelating agents must contain suitable functional groups, and their location within the ligand molecule must enable ring formation that is sterically possible. Typical structures that meet these requirements have been given by Fuerstenau and Herrera-Urbina (1988) and are listed in Figure 1. As noted, the functional groups of these reagents contain electron donor atoms such as oxygen, nitrogen and sulfur. Basic groups, such as amino (-NH,), are those that contain an atom with a lone pair of electrons. Acid groups are those, such as carboxylic (-COOH) which lose a hydrogen ion and coordinate with the metal atom. Examples of each of these types chelating reagents are given in Tables 1-4. The specificity of chelating agents for various metal ions has long been known and was utilized early in the search for new flotation collectors. In 1927, Vivian used ammonium nitrosophenylhydroxylamine as a collector for cassiterite. Holman (1929) tested dimethylglyoxime as a collector for nickel oxide. He also suggested taurin as a collector for oxidized lead ores. DeWitt and von Batchelder (1939) suggested the use of oximes as flotation collectors. Gutzeit (1946) conducted an extensive investigation on the use of chelating agents as collectors and as depressants for gangue minerals. The depressants are those reagents that form soluble chelates with metal ions that could function as

Jan 1, 2005

By Michael Karmis

This paper reviews the fundamental concepts involved in the development, application and validation of ground movement predic¬tion methods developed by Virginia Polytechnic Institute and State University (VPI&SU) over the past 12 years. Prediction techniques have included empirical or semi-empirical methods, such as the profile function, influence function and zone area methods, as well as numerical methods, based on a finite element formulation which utilizes field subsidence data. The former techniques have been integrated in the Surface Deformation Prediction System (SDPS) software package for personal computers, which allows for the calculation of any component of ground movement in any direction. Comparisons between measured and predicted subsidence and strain values are presented for a selection of case studies, which demonstrate the applicability, accuracy and regional validity of these methods for predicting surface deformations due to underground mining.

Jan 1, 1986

By Hans W. Brodbeck

The Advisory Conference on Tunnelling of the OECD, held in Washington, D.C. in June 1970, has established the following definition: "Tunnelling refers to the construction by any method of a covered cavity of predesigned geometry whose final location and use are under the surface, whose cross-sectional area is greater than 2 square metres". (1) The definition makes clear that the term includes all types of underground construction, be it in hard rock, soft ground, under mixed conditions, underwater, etc. Small-sized tunnels in rock therefore constitute but one part of the tunnelling scene. With an ever-growing urbanisation taking place in industrialized as well as developing countries, the demand for small-sized tunnels is, however, rapidly increasing and requires a far-reaching mechanization of excavation and support functions. This trend is accentuated by the fact that small-sized tunnels are far more labor-intensive than large ones, and, with wages raising at a much faster rate than costs for plant and equipment, this will accelerate the introduction of new tunnelling systems. SMALL-SIZED ROCK TUNNELS The main field of application for a tunnelling system for small sized hardrock bores is thus defined. It is in fact the numerous relatively short tunnels required under cities and other populated

Jan 1, 1974

By Mohammad Irshad, Larry H. Heflin

INTRODUCTION The planned 166 kilometer (103 mile) Metro rapid rail transit system in Washington, D.C. is being designed and constructed by the Washington Metropolitan Area Transit Authority. At the present time, 112.6 kilometers (70 miles) of this system is in operation and contains 21 route-kilometers (13 miles) of rock tunneling, and 14.5 route-kilometers (9 miles) of soft ground tunneling. An additional 2.4 kilometers (1.5 miles) of single track tunnels in rock are planned and 6 additional contracts will consist of some 8 kilometers (5 miles) of twin tunnel, resulting in 16 additional linear kilometers (10 miles) of single track tunnel in soft ground. The Authority plans, upon its evaluation and the recommendation of the General Engineering Consultant, to include an alternative design incorporating the convergence confinement method of construction known as the New Austrian Tunneling Method (NATM), for Sections E-5, E-6e and E-8a of the E-Route. The Metro system is constructed in a variety of geological conditions and crosses the boundary of two major geographic provinces. Rock tunneling is to the west of this "fall-line" boundary, soft ground tunneling to the east. The soft ground tunneling portions of Metro construction lie in the coastal plain which consist of a

Jan 1, 1987

By I. K. Gilmore

Texasgulf Inc. currently operates an open pit phosphate mine in the central coastal plain of North Carolina. The area of phosphate deposition lies within the Aurora Phosphate district which consists of an embayment which is in the center of the Neogene phosphate deposition. A variety of solid and liquid fertilizer products are produced at the Texasgulf complex. One of these products is known as North Carolina Natural Phosphate (NCNP). New potential for use of unacidulated natural phosphate, now exists in regions with acid soils due to the discovery of the findings from recent research, cost advantages, and moves to reduce chemical inputs.

Jan 1, 1995

By T. Bednarski, T. McCallum

"Physical impurity transfer in solvent extraction (SX) has a significant impact on operating costs, electrowinning (EW) performance, and cathode quality. Some operations use a wash stage to limit impurity transfer by diluting the entrained pregnant leach solution (PLS) to prevent direct transfer to EW. Wash stage operating conditions vary impacting impurity transfer. A number of factors impact dilution efficiency including mixer continuity, wash aqueous acidity, and organic quality. The impact of these variables on dilution efficiency was studied and compared to current industry practice. INTRODUCTION With the exception of iron, impurity transfer in copper SX is due to PLS carryover in the loaded organic via aqueous entrainment and crud movement. The quantity of impurity transfer is influenced by many variables including operating set points, organic quality, and settler housekeeping. Crud management and treatment is a common practice aimed at minimizing transfer of impurities to EW. Crud is a complex solid-stabilized emulsion of aqueous and organic[9]. As such, it contains a large aqueous component and the associated impurities (from the PLS). A common practice is to remove interfacial crud to prevent movement. Additionally, mixer continuity can be altered to enable compaction and improve the efficiency of interfacial pumping[10]. Understanding the factors impacting aqueous entrainment and optimizing the available controls should be a key focus for any operation. Aqueous entrainment in the loaded organic can be impacted by: • Mixer continuity • Mixer organic/aqueous (O/A) ratio • Mixer speed and impeller type • Organic and aqueous depths • Specific settler flow • Use of settler internals (picket fences, coalescing packs) • Organic quality • Design and operation of loaded organic tanks Conventional thought is to run the E1 mixer in aqueous continuity to reduce aqueous entrainment. Generally, O/A ratios close to 1:1 result in improved metallurgical and physical performance. Mixer speeds should be chosen to achieve acceptable stage efficiencies while minimizing over-mixing. Organic depths can be increased in the E1 stage to increase retention time and minimize aqueous entrainment. Settler internals can also be used, but require maintenance to maintain effectiveness. The quality of the plant organic inventory will impact physical performance. Poor organic quality can lead to higher phase disengagement times increasing impurity transfer to the electrolyte. Additionally, the design and operation of the loaded organic tank can impact impurity transfer[8]. Despite the variables that can be used to reduce aqueous entrainment and crud movement, impurity transfer is still an issue in some operations. For these operations with high PLS impurity concentrations, a wash stage may be beneficial to manage impurity transfer. Understanding factors impacting wash stage performance is important to optimize performance and limit impurity transfer."

Jan 1, 2016

By André G. Journel

As opposed to graphics applications in medical sciences and mechanical engineering, computer imaging of the subsurface faces a severe problem of data shortage. Most graphics softwares include an interpolation algorithm aimed at producing slick graphic output, irrespective of the attribute being interpolated, the quantity and quality of the data available, and what the map is intended for. It is suggested that the power of modern computers be also used in providing representations of the subsurface that accurately reflect actual spatial variability and the large variety of soft information available beyond hard data. Since any subsurface representation is uncertain, a measure of that uncertainty should be provided which can be used for risk analysis.

Jan 1, 1992

By E. Stolarski

The circulating fluid bed (CFB) technology can proudly point to its history of more than a quarter of a century of commercial operations. Over 80 CFB units operate in aluminum calcining, coal combustion and gold roasting. This paper describes the invention of the circulating fluid bed and chronicles its development and evolution from calcining through coal combustion to gold roasting. It presents performance data of Lurgi's CFB units in operation and highlights the six gold roasting plants currently operating throughout the world.

Jan 1, 1998

Iron ores may be upgraded by flotation of iron oxides or siliceous gangue using either cationic or anionic collectors. The electrostatic mechanism of adsorption can account for the complex chemistry involved. In industrial practice, only cationic silica flotation is used at present in North America. Some of the seemingly paradoxical phenomena of cationic silica flotation behaviors in meeting the demand for low silica concentrates are reviewed.

Jan 1, 1989

By W. L. Freyberger

In many papers concerned with fundamentals of the froth flotation process, authors have considered the contents of a flotation cell to be comprised of two immiscible phases, the froth and the pulp. I (Of course, each of these phases is in turn made up of several solid phases plus air and water.) This generalized concept of the flotation system can be extended by considering the cell contents to include two phases: an extracting phase, the air bubbles plus the collector, which removes a selected mineral component from the second phase, the ore pulp. Thus, there is an analogy between a flotation system on the one hand, and chemical extracting systems, such a solvent extraction system or a leaching system, on the other hand. Such extracting systems may be operated in cocurrent or countercurrent fashion. This paper includes first a brief discussion on the general nature of cocurrent and countercurrent operation as applied to froth flotation, and then presents the experimental results of flotation of a specular hematite ore by each method, using a tall oil fatty acid as collector. Cocurrent Flotation A conventional flotation circuit involving roughing, scavenging, and cleaning flotation is illustrated schematically in Figure 1. In such a circuit the col¬lector, or extractant, and new feed ore enter together at the head of the rougher circuit, and flow cocurrently to the scavenger circuit where more collector is added. According to this practice, sufficient collector is added to the head of the rougher (and scavenger) so that the final tailings are of low enough grade to be discarded. Since the flow of collector and ore is cocurrent, the process consists of single stage contact between the extracting phase and the ore pulp. If the scavenger concentrate is recycled to the head of rougher, the overall circuit has some of the characteristics of countercurrent flow. In such a case part of the extractant (collector) is added at the discharge end of the circuit, and may

Jan 1, 1971

By Günter Strappler, Max John

When tunneling through karstic terrain, diverse and complex karst structures are to be expected. By means of drilling ahead of the face using drill jumbos, these structures can be detected to such a degree that by applying proper support measures both open karst cavities and karst holes surrounded by boulders embedded in soft rock can be mastered without causing any break-outs. Support measures such as spiles ahead of excavation, sealing off cavities, back?lling with sand, etc. have to be planned schematically and adapted to the dimensions and formations of the karst structures on site. An essential requirement for a smooth excavation procedure is the availablility of all necessary tunneling equipment for excavation by drill and blast as well as for excavation of soil, with experienced tunnel engineers being in charge of any adaptions on site.

Jan 1, 2003

By Judson H. Whitman

To evaluate intelligently and to market a source of rare earth raw material, it is necessary that the producer understand the requirements of the processor and the manner in which these requirements effect the value and salability of his product. This paper will be an attempt to aid in such an understanding. The majority of rare earth processors are primarily chemical companies, not mining or metallurgical companies, as the complexities of the processing procedures are' much more chemical in nature than metallurgical. The rare earths and the rare earth industry are normally divided into two groups - the ?light? or cerium group and the ?heavy? or yttrium group. They are so named because cerium and yttrium are the most common elements in 'heir respective groups and are so divided on the basis of mineralogical and chemical characteristics. The dividing line of the two groups is not rigidly fixed but usually is considered as being between samarium (atomic number 62) and europium (atomic number 63). Although the two groups are quite similar, processing procedures differ significantly, hence most processors tend to specialize in one group or the other. There is, however, a growing tendency toward participation in both groups.

Jan 1, 1960

By A. D. Davis

The Bear Butte Creek watershed, in the northern Black Hills of South Dakota, shows the effects of past mining activities in the form of dissolved metals and arsenic in stream water. Bear Butte Creek, during normal flow periods, loses all of its discharge to sinkholes that recharge the Madison Limestone aquifer. This work focused on the geochemical transport and fate of arsenic and on understanding ground-water flow conditions in the Madison aquifer through development of a three-dimensional ground-water flow model that was coupled to a geographic information system (GIS). Stream sampling and discharge measurements helped determine sinkhole losses and loading rates. Column laboratory tests provided data on arsenic adsorption and the mixing of stream water with aquifer water, which also was simulated with the geochemical models, pHREEQE and NETPATH. The models and GIS can be updated with new information and will be useful in managing the water quality of the Madison aquifer.

Jan 1, 1997

By F. C. Turin, T. L. Friend, A. G. Mayton, J. S. Jaspal, W. J. Wiehagen

This paper describes the serious injuries that have occurred to bulldozer operators working at domestic coal, metal and nonmetal mines in the United States. A serious injury is defined as one that results in either a fatality or in lost work time. Examined were 873 injury records compiled by the Mine Safety and Health Administration (MSHA). The time period covered was 1988 through 1997. These injuries resulted in 18 fatalities and 31,866 lost work days. All of these injuries occurred to dozer operators while they were performing common production tasks. An injury classification system was developed to code the narrative information that describes the circumstances surrounding the injuries. Jolts and jars accounted, for 604 or 70% of the serious injuries to bulldozer operators, and jolts and jars accounted for 75% of the workdays lost. Vertical jars comprised the largest set (354 incidents) of jolting and jarring injuries. In more than half of these incidents, the operator was backing up the dozer. Working near an edge carries significant risk for fatal injuries. Of 116 incidents where the dozer fell over an edge, rolled over or fell into a hidden void, 14 (12%) resulted in fatal injuries. In cases where the dozer operator either jumped or was thrown out of the cab in a fallover or rollover, seven out of 17 of the operators were killed. This study finds that further reductions in injury risk would require more widespread use of seat belts; consideration (and maintenance) of the seat and seat suspension systems that might reduce injury risk from jolts and jars; research interventions to assess the effect of alternative engineering designs to dampen or isolate the effects of shock and vibration; and continued attention to skilled performance, i.e., the integration of hazard awareness, recognition and response with dozer operational skills.

Jan 1, 2003

By D. A. Lowrie

Environmental concerns and increasing mine development costs have created a need for early information on gold recovery from its host environment. The habit, association, and approximate abundance of minerals which contain unacceptable metallic ions which may be released during process of concentration of gold should be identified in exploration drill core. One case of a "clean" gold orebody is described to show that early petrographic studies contributed to a rapid decision to mine a small deposit by open pit and to custom mill the ore in an already restricted effluent environment. A second example describes identification of an undesirable mercury content and resulting action taken.

Jan 1, 1985

By Michael J. Nicol

Hydrometallurgical processes involve the recovery of metals from ores, concentrates, calcines, mattes and scrap materials by a series of operations involving leaching or dissolution, separation, purification and reduction of metals in aqueous solutions. The underlying theoretical basis of many of these operations is electrochemical in nature and it is the purpose of this review to identify and illustrate, by way of examples from the author's experience and that of others, the central role of interfacial electrochemistry in the understanding, design and control of these operations.

Jan 1, 1993

By Scott Brien, O&apos

Cyclones have become standard unit operations in mineral processing for both dewatering mineral slurries and for making separations at given particle sizes. Conventional cyclones are normally able to make moderately sharp cuts. However, the limited ability to control water flow out of the apex means that cyclones have difficulty handling fluctuations in feed. Underflow-regulated cyclones are cyclones with a rubber boot attached to the underflow. This boot acts as a non-return valve and restricts flow out of the apex of a cyclone. Normally, this type of restriction on a cyclone causes severe difficulties in cyclone operation. However, by adding a siphon arm to the overflow, water flow can be controlled. The siphon arm creates a vacuum that reduces or eliminates the air core, permitting better control of the ratio of water flow out of the overflow and underflow. A Linatex-developed underflow-regulated cyclone was compared to a conventional cyclone for its ability to dewater a sand slurry. The underflow-regulated cyclone produced slurries with solids contents as high as 80% in the underflow. Conventional cyclones produced lower solids content in the underflow under similar conditions.

Jan 1, 1997

In spite of the tremendous amount of research conducted in the last few decades. no single blasting theory has been developed and accepted that adequately explains the mechanisms of rock breakage in all blasting conditions and material types. Given specific test environments, conditions and assumptions, individual researchers have contributed valuable information and insight as inputs into blasting theories, although a simple "plug-in" type formula for predicting optimum fragmentation, muck pile geometry and casting distance, is still largely unresolved. There is as yet, no consistent and widely applicable theory of blasting, but only a number of limited and disconnected theories; many of which are empirical in nature and based on ideal blasting conditions. Blasting theories have been formulated and based on pure speculation, years of blasting experience on a trial-and-error approach, laboratory testing, field investigation, and mathematical and physical models adapted from other disciplines of science.

Jan 1, 1988

By C. Woofter

Quarry operators must continue to change and adapt environmental compliance methods to meet the increasingly demanding regulations. To fulfill industry needs, a computer-based decision support system is being developed to facilitate decision making that mine operators are required to make regarding environmental responsibilities. This system can help to determine permitting and compliance measures needed for air, surface water, groundwater, noise, aesthetics, vegetation, wetlands, hazardous wastes, storage tanks and wildlife habitats during the development, operation, and closure phases of mining. Operators will utilize the system's user-friendly interface consisting of mouse driven responses and limited keyboard entries on a desktop computer. The system is easy to upgrade according to the user's needs and changes in current laws and regulations. Data input models, user interfaces, and support of decision making are explained. The program permits inclusion of the decision maker's own insights through "what-if' analysis, in which the user can change ad hoc entries and check the related consequences. Using this approach, the user has complete control over all steps of the decision making process. A storm water example is selected to demonstrate the potential benefits of the support system to environmental decision makers.

Jan 1, 1995

By Marie-Josée Banwell, Cyriac Sebastian, Giacomo Falorni, Sara Del Conte

Interferometric Synthetic Aperture Radar (InSAR) is a satellite-based monitoring technique that complements other in-situ methods for detecting and measuring surface displacement. Recent advances in data processing algorithms, coupled with the use of high-resolution satellite systems, make it possible to now provide high-frequency InSAR monitoring services, with updated results delivered every time a new satellite image is acquired. The advent of large, continuously updated data sets, however, brings new challenges, including the need to rapidly sift through the data to identify only those points showing relevant ground displacement information. This has been achieved by using trend variation analysis tools, that quickly isolate and highlight only areas of anomalous behavior. The paper focuses on project case studies where continuous InSAR monitoring has proven to be key in identifying displacement trend changes near tunnel alignments.

Jun 13, 2021