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A thermomechanistic model was developed for the thermal decomposition of the enargite contained in a copper concentrate at 650° to 750°C in a fluidized bed with an inert atmosphere. At the particle level, the model permits one to predict the thermal profile inside the reacting enargite particles, as well as their thermal cycle. At the macroscopic level, a population-based model coupled to the bubbling-bed fluidized bed model allows one to predict the fractional conversion (dearsenification) of an enargite-bearing copper concentrate.

Jan 1, 2002

By R. Poulin, R. C. Pakalnis

Approximately 51 % of all ore production in Canadian underground metal mines is derived directly from open-stope operations. This method requires that large excavations remain open until the ore is extracted with a minimum acceptable level of dilution. A survey of underground mines in 1988 reported that a major factor in their closure was uncontrolled dilution. It has been reported that 40% of openstope operations were experiencing dilution in excess of 20%. This level of dilution has significant implications on the economic viability of a project, especially when one considers that a rate of return on a positive project is generally between 10% and 20%. This paper reports on the various definitions of dilution, on the methods of stope design that are presently used with the objective of reducing dilution and on a recently available survey technique that enables dilution to be quantified.

Jan 1, 1996

By S. Chander

The effect of pretreatment potential on the response of a gold electrode for Eh measurements in sulfide solutions was examined in terms of measured Eh values and electrode response time. The electrode response time is defined as the time required for the electrode to reach a steady-state value. The relationship between measured Eh values and the hydrosulfide ion concentration is established. The effect of pH, the reversibility of the gold electrode in the sulfide solutions, and the reproducibility of measurements are also investigated. A mixed potential theory is proposed to explain the observations.

Jan 1, 1989

By L. B. Rothfeld

Two new coal use technologies are on the verge of commercial acceptance by the utility industry: atmospheric fluidized bed combustion (AFBC) and gasification combined cycle (GCC). Generating plants under construction or in planning will replace older pulverized coal (PC) boilers or substitute for new PC boiler capacity. This paper reports recent developments in the commercialization of AFBC and GCC, emphasizing the potential impact on the coal mining industry. The influence of coal quality characteristics on fuel selection is explored by means of preliminary economic calculations for different coals and competing fuels.

Jan 1, 1987

By C. R. Everly

"The purpose of this paper is to review the most effective methods of reducing chloride transfer and chloride removal in the solution extraction and electrowinning (SX/EW) process. Elevated chlorides in electrolyte have various negative effects including a reduction in current efficiency, increased handling costs at rod plants and smelters, increased anode corrosion, cobalt losses due to increased electrolyte bleed, degradation of HDPE piping, and increased corrosion in the SX/EW plants. Historical controls that Sierrita has used to control chloride transfer, in order of effectiveness, have been chloride gasification at the EW that is directly correlated to amperage and chloride concentration in electrolyte, wash stage bleed and efficiency, width and velocity of aqueous bands, and electrolyte bleeds. Maintaining high bleed rates and high amperage settings has been a challenge with decreasing pregnant leach solution (PLS) grades, so keeping chlorides out of the electrolyte has become imperative. The effectiveness of reducing aqueous entrainment, optimizing wash stage efficiencies, and improving organic quality to reduce the transfer of chlorides to the electrolyte are illustrated in this study. INTRODUCTION The transfer of impurities from PLS feed streams to electrolyte in the Copper Solution Extraction process is a very common problem and is the reason that the wash stage exists in most SX operations. The main impurities affecting the SX process are iron, chloride, nitrate, and manganese. Elevated chlorides in the electrolyte have various negative effects including reduced current efficiency, increased handling costs at rod plants and smelters, increased anode corrosion, increased cobalt losses due to increased electrolyte bleed, degradation of HDPE piping, and increased corrosion in the SX/EW plants. Freeport-McMoRan Sierrita Hydromet is unique in that a high-chloride byproduct stream from the molybdenum process is pumped into the SX raffinate solution pond. This byproduct steam accounts for the majority of chloride introduced to the circuit, and over the years has built up to a point where 4000ppm chloride is consistently in the PLS feed to the SX. Concentrations of chloride over 70 ppm in electrolyte will result in downgraded cathode, so it is important to limit chloride carryover from SX as much as possible. Historically, Sierrita has been able to manage chloride levels with reactive techniques including increasing electrolyte bleeds and rectifier amps. Decreasing copper in PLS has made high amps harder to maintain, and increasing bleed rates have a direct impact on production goals."

Jan 1, 2015

By Adam Levy, Thomas Novak, Sampurna Arya, Joseph Sottile, Kozo Saito

The use of a woven wire-mesh screen as part of a flooded-bed dust-scrubbing system is very popular in the underground coal mining industry. It is used in combination with a demister (mist eliminator) to remove dust from the dust-laden air. A study was conducted to measure the pressure drop across a flooded-bed wire-mesh screen at different airflow rates in onephase (dry) and two-phase (wet) conditions. Two empirical relationships between pressure drop and air velocity were developed for dry and wet conditions, respectively. In both cases, the form of the empirical relationships was found to be similar to relationships given by Sabri Ergun for high velocity non-Darcy single and multi-phase flow through porous media. The experiments were repeated on a reduced-scale model of the wire-mesh screen, and the pressure-velocity relationships obtained from the full-scale prototype experiments were tested. The test results show validation of the full-scale empirical formulas on the small-scale model with an insignificant variation. This paper presents the empirical equations for pressure drop across the wire-mesh screen in dry and wet conditions. Researchers can use these equations as a tool to predict total pressure drops for wire-mesh screens of different scale sizes.

By Adam Levy, Thomas Novak, Sampurna Arya, Joseph Sottile, Kozo Saito

The use of a woven wire-mesh screen as part of a flooded-bed dust-scrubbing system is very popular in the underground coal mining industry. It is used in combination with a demister (mist eliminator) to remove dust from the dust-laden air. A study was conducted to measure the pressure drop across a flooded-bed wire-mesh screen at different airflow rates in onephase (dry) and two-phase (wet) conditions. Two empirical relationships between pressure drop and air velocity were developed for dry and wet conditions, respectively. In both cases, the form of the empirical relationships was found to be similar to relationships given by Sabri Ergun for high velocity non-Darcy single and multi-phase flow through porous media. The experiments were repeated on a reduced-scale model of the wire-mesh screen, and the pressure-velocity relationships obtained from the full-scale prototype experiments were tested. The test results show validation of the full-scale empirical formulas on the small-scale model with an insignificant variation. This paper presents the empirical equations for pressure drop across the wire-mesh screen in dry and wet conditions. Researchers can use these equations as a tool to predict total pressure drops for wire-mesh screens of different scale sizes.

By R. D. Grove, M. F. Elliott, R. L. Weigel

The control of Florida phosphate flotation plants is largely based on the visual observations of experienced operators, both in recognizing good and bad froth conditions and in making judgments about the composition of feed, concentrate and tailing streams. Chemical analyses lag the process by at least two hours and therefore only assist in recalibrating the operators' vision when major deviations occur. An image analysis system has been developed by IMC Agrico Company (IMCA) to improve upon the accuracy and precision of the composition estimation process. It still relies upon the operator taking a representative sample, but provides a measurement in about 15 minutes after that sample is obtained. This paper describes the system and its use and presents comparative results for various process streams.

Jan 1, 1993

When I reached Warren after the "de luxe" South American expedition I had little idea what was in store for me. From the large check Thayer had handed me just before I left New York I was pretty sure the future would be good, and that before long it would involve Anaconda. Evidently, Mr. Thayer had left it to Dr. Ricketts and John Greenway to work out the details The next morning Greenway asked me to come to his office and told me that he and Dr. Ricketts had discussed the question and that Anaconda would make me an offer I could not refuse. They proposed to pay me almost $1000 a month, more than twice my current salary. They had agreed that I should stay with Calumet and Arizona for the rest of the year to help with Bisbee development and anything I could to assist with the New Cornelia plans and construction Of course I could not turn down such a flattering offer, as I had about reached the limit of advancement with a much smaller company in anything save a high executive job, and it would be a long time before I could be ready to change from exploration and geology to operating. Greenway and I agreed that I would stay with him for the remaining eight months of 1916 without any particular title but helping in any way I thought would be most useful. Bisbee and Ajo Study It turned out to be a busy half year, in addition to many good times with my Bisbee friends. The Uplift Club did not meet as regularly as in earlier years, but Mason Ross, Jim Lewis, Bill Gohring, Roy Mitchell, Hubert d'Autremont, Arthur Notman, and I did have many "bull sessions" and poker games. I saw much more of Greenway than before and made many trips with him to Ajo and later to the new

Jan 1, 1976

The concept of optical basicity is now being widely applied to rationalize and predict the chemical properties of slags. It employs signals from a probe ion to indicate the "state" or relative "freeness" of the oxygen ions in the slag, and hence provides a fundamental measure of slag basicity. Values of the bulk optical basicity of a slag can either be measured spectroscopically in samples of transparent solid glassy slag, or calculated very simply and accurately from the chemical composition of the slag. The way in which these values vary in different systems are illustrated as isoptical basicity lines on ternary diagrams, and the patterns obtained are discussed. The difficulties associated with assigning optical basicities to the oxides of transition elements are also reviewed briefly. It has been demonstrated that these bulk values can be used as the basis of a flux control model for steelmaking to achieve end-point chemistries much more reliably. Furthermore, several correlations have been established which allow the prediction of the slag-metal distribution of various solute elements. This approach has been used to predict the phosphorus distribution at the end of steelmaking, and also to custom design fluxes for the ladle and tundish to aid in the control of residual elements in the steel such as suphur, hydrogen and nitrogen.

Jan 1, 1990

By M. E. Lewellyn

A lower moisture content for a clean coal product means increased Btu content, or increased yields at the same Btu content, and lower operating costs. The conventional surfactant-based dewatering aids effeciently lower the moisture content but often the presence of residual surfactant in the filtrate and recycle water causes problems downstream. ACCOAL-DRI 1000, a surfactant-based dewatering aid, was developed to solve this problem by minimizing the downstream effects while efficiently lowering the moisture content. The theory of the use of surfactants in filtration will be discussed as well as the development and field evaluation of this new product.

Jan 1, 1988

By Cloyd D. McDowell

The Federal coal Mine Health and Safety Act of 1969 has been criticized by those who say it goes too far in controlling the activity of private enterprise and by those who say it does not go far enough in eliminating fatalities and accidents in an accident prone industry. Possibly a better evaluation of this legislation lies somewhere in between. From the viewpoint of the coal industry it can be said that through the efforts of those engaged in mining, both the operator and the miner, the year 1969 marked a record year in mine safety with only 190 fatalities and a frequency of 0.84 per million man hours exposure. This outstanding achievement compared to any previous was the result of a determined effort on the part of a concerned industry to improve its reputation as being the most hazardous industry in the nation. After the effective date of the Act, March 31, 1970, the Bureau of Mines assumed complete control of all safety and health activities of the mining industry. Unfortunately, there was no improvement in the safety record of underground mines in 1970 with the total of 255 fatal injuries and a frequency of 1.04 for the year. The number of fatalities declined to 177 in 1971 but the number of underground coal mines had declined from 5,955 to 2,268 during the two year period. Meanwhile, surface mined coal increased from about 38% of total production in 1969 to over 50% in 1971, keeping the annual production of coal at a normal level but involving fewer men.

Jan 1, 1973

By R. Y. Wan

Newmont Gold has advantageously used the capabilities of mineral oxidizing bacteria to develop a process for the pretreatment of low-grade sulfidic and carbonaceous-sulfidic refractory gold ores. The biooxidation process results in the oxidation of the sulfidic minerals with increased exposure of gold for subsequent gold recovery. The biooxidized carbonaceous-sulfidic ores cannot be heap leached with cyanide because of the preg-robbing characteristics of the carbonaceous matter in the ores. Therefore, an alternative heapleach process using ammonium thiosulfate was developed to extract gold from these preg-robbing bioaxidized ores. The ammonium thiosulfate leach process was successfully applied in both laboratory and pilot plant tests. Satisfactory test results were achieved, encouraging the continuation of process development.

Jan 1, 1997

By J. A. Oraniscak

Longwall mining operations continue to increase extraction rates and the potential to generate higher amounts of airborne respirable dust (ARD). The National Institute for Occupational Safety and Health (NIOSH) has gathered data from underground longwall surveys and laboratory crushing tests to identify the important factors influencing the amount of ARD levels generated. Coal-seam characteristics, operational parameters (i.e.,cut sequence, mining height, etc.), extraction rates and dust-control parameters (i.e., airflow, water flow, etc.) were examined to determine their influence on ARD levels measured at longwalls during actual mining operations. ARD generated by a laboratory crusher while crushing bituminous coal samples collected from underground longwalls was also examined to determine if there were cor relations with coal-seam properties. Results from the longwall and laboratory data collected indicated that low-ash, high-volatile coals (low moist fuel ratio or MFR coals) generate higher amounts of ARD. It was found that face ventilation and water application to the coal product are essential elements to controlling longwall ARD levels.

Jan 1, 2000

By Robert Y. Lamarche

INTRODUCTION Production of chrysotile asbestos from the northern Appalachians has been going on for 100 years and, on the basis of known reserves and the present rates of mining, appears assured of continued production for at least another 25 to 30 years. In spite of this, mining companies and government agencies are showing an increasing interest in exploring for chrysotile asbestos throughout this region and elsewhere in the world, implying that increases in the rate of consumption are envisioned. This chapter describes the geologic and tectonic settings surrounding these important chrysotile deposits, with emphasis on those in southern Quebec that yield about 90% of the total production from the northern Appala- chians. Detailed descriptions of a few individual deposits are also given, along with exploration guidelines aimed at facilitating the discovery of additional chrysotile deposits. One section of this chapter deals with the origin and mode of formation of the chrysotile deposits in the light of modern day concepts of plate tectonics. The objectives of this chapter are to give a brief description of the geologic and tectonic settings of the ultramafic rocks in which the numerous chrysotile deposits of the northern Appalachians are found; to describe a few of the individual deposits; to give a few exploration guidelines for those interested in exploring for new asbestos deposits in similar geologic environments; and to propose a new model for asbestos genesis in light of the recently developed theories of global tectonics. As this chapter is based almost entirely on field and laboratory observations, rather than on the study of experimental laboratory models, most of our deductions and suggestions are empirical in nature and may be interpreted in more than one way. The interpretations we have selected seem to offer, we feel, the best explanation of observed geological phenomena (Lamarche and Wicks, 1975). This region had a production capability in 1979 of close to p.5 Mt of chrysotile asbestos with 92% of this tonnage being derived from the deposits of the Eastern Townships of Quebec. With known resources, which now stand at between 36 and 40 Mt of fibers, this production capability seems assured for the next few decades. In spite of all known reserves of chrysotile asbestos, which now stand at between 36 and 40 Mt of fiber in this region alone, mining companies and government agencies are still showing a good deal of interest in exploring for new sources throughout the world. GEOLOGICAL SETTING The asbestos deposits at Baie Verte in eastern Newfoundland, Thetford Mines, Black Lake, Asbestos in southern Quebec, and Belvidere Mountain in Vermont, all occur in partly serpentinized ultramafic rocks that are part of the Lower Paleozoic ophiolite complexes of the northern Appalachians [Cady, Albee, Chidester, 1963, Chidester, Albee, Cady, 1978, Lamarche, 1972,1973, Laurent, 1973,1975, Williams, Hibbard, Bursnall, 1977, Norman and Strong, 1975). The deposits to the northeast of Thetford Mines, on the other hand, are found in a more highly serpentinized ultramafic body known as the Pennington dike, whose spatial, genetic, and chronological links with the ophiolite masses proper have not as yet been adequately resolved. The Appalachian ophiolites are part of an ultramafic belt (or belts), that extends from northwestern Newfoundland, through Quebec and Vermont. Fig. 1, and southwestward as far as the

Jan 1, 1986

By Y. C. Kim

For the past few years, the Cyprus Bagdad Copper Company began experiencing a significant "ore-dilution" problem from its low grade open- pit copper mine located at Bagdad, Arizona. To pinpoint the causes of this dilution, a study was initiated to investigate as well as to improve in-pit ore-waste selection-procedures using conditionally simulated ore-bodies. Prior to the actual use of conditional simulation; a comparison of different estimation methods for a mined-out area in the pit was performed. Specifically, kriging estimates were compared against the original estimates of the company which were based on the polygonal approach. The results of this comparison clearly identified part of the so- called "ore-dilution" problem, which was the initial over-estimation of average ore grades from blast rounds, using the polygonal approach. The results from the use of conditionally simulated orebodies demonstrated that the "ore-dilution" problem can be reduced by more than half if in-pit ore- waste selection is based on the kriged estimates rather than the polygonal estimates. This simulation study also showed that the current use of the polygonal approach has the effect of shipping a larger tonnage of lower grade material to the mill.

Jan 1, 1982

By Anna Marabini

This paper provides a summary of the studies performed over a period of more than fifteen years by the Italian National Research Council's Mineral Processing Institute in Rome to develop applications for the use of chelating reagents in the flotation of metallic minerals. A description is given of the various phases through which the studied progressed, starting with the combined use of commercial chelating reagents and a neutral oil and then moving on to the synthesis of new long-chain chelate collectors for the flotation of sulphide and oxidized Pb, Zn and Cu minerals. After a series of preliminary tests which confirmed the possibility of floating various metallic minerals with commercial reagents containing chelating groups exerting specific action on given cations, the studies were addressed to the development of a theoretical method of choosing chelating groups that exert selective action on one metallic mineral rather than others. The theoretical approach was based on thermodynamic data concerning the chemical equilibria in solution. The validity of the method has been proved in numerous cases by flotation tests on pure minerals. Subsequently the research was directed towards the design and synthesis of reagents with a mixed aliphatic-aromatic structure containing chelating groups for Pb and Zn and an alcoxyl chain of various length, position and configuration. The flotation results obtained on oxidized and mixed Zn-Pb ores provided interesting pointers for designing the nonpolar portion. The structural criteria identified via these studies were interpreted on the basis of chemical and steric considerations. A description is given of a new synthetic chelate collector which is effective in the selective flotation of Cu minerals from complex sulphides. The fact that this reagents is more selective than xanthate is demonstrated by comparative flotation tests on actual ores.

Jan 1, 1994

By J. A. Frew, R. M. Glen

Recovery of galena and sphalerite from fine grained lead-zinc ores by flotation normally requires re-grinding to achieve economic recoveries at acceptable concentrate grades. Re-grinding aims to reduce the coarse valuable mineral particles to a size where they float more readily and to liberate the composite valuable particles so that the gangue in these composites does not dilute the concentrate. Besides changing particle size and liberation, re-grinding changes the surfaces of the minerals and thus may alter the rate that mineral particles of a given size and liberation float. A method was developed to apportion the total change in recovery after re-grinding between changes in size and liberation and changes in flotation rates. The flotation behaviour of minerals, before and after re-grinding, was measured by floating samples of plant streams under controlled conditions in a laboratory cell. Results from several industrial lead-zinc circuits indicated that the change in behaviour observed fell into three different categories. It is concluded that the method will indicate whether the focus for optimization of existing plant should be on comminution or flotation, and it will help determine the path for laboratory testing in designing new regrind circuits.

Jan 1, 1995

By Alain Broussaud, Guy Fourniguet, Jacques Franck, Pierre Conil

Steady-state simulation is now in current use to assist mineral processing plant design and optimization. However, the reliability of results generated by simulators has not until now been seriously investigated. A simulator supervision algorithm was designed and programmed to study both the influence of the reliability of experimental data on the accuracy of unit operation model calibration, and the influence of unit operation model accuracy on the results of direct plant simulations. An application to a grinding flotation plant is described and discussed. The approach may open the way to the quantitative analysis of the risks taken in mineral processing projects, which would be similar to the application of geostatistics to mining projects.

Jan 1, 1990

By O. A. Bascur

The problem of setting the proper control objectives and/or having several objectives to be met in the implementation of grinding control strategies can be resolved. The design and implementation of a distributed control system for safe operation of a grinding circuit while maximizing profit is presented. An optimal recovery through- put target for a desired grind is accomplished by advanced control strategies at the DCS level. A mill load constraint control technique provides stable operation with a substantial increase in throughput, while the desired grind index is maintained by an inferential grind control technique without using a particle size analyzer. The integration of crushing/grinding and flotation in the overall design was the key to the success of the project. This synergistic effect was obtained by implementing a computer plant management system in the concentrator. The overall/philosophy was to keep the implementation simple while using new technology creatively.

Jan 1, 1991