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By R. C. Bunge

Many minerals float best with fatty acids in the intermediate pH range. For example, fluorite, a semi soluble salt mineral, exhibits a maximum contact angle and a maximum flotation recovery in the pH range of 6-8 after conditioning in a palmitate solution (fig. 1). The maximum in flotation coincides roughly, as many researchers have observed, with the boundary of bulk precipitation of the fatty acid. According to fig. Z this boundary is in the above case of 5xl0-7 M palmitate approximately at pH 6.3. For assessing the phenomena occurring at the bulk precipitation boundary of fatty acids, the surface tensions of carboxylate solutions have been measured under various conditions. Fig. 3 shows the surface tension development of palmitate and myristate solutions of increasing concentration at pH 12. Also shown are the bulk precipitation edges (BPE) of the respective solid species that is stable under these conditions, that is the potassium acid soap, HKAZ. Both curves display a similar behavior. As the concentration of carboxylat,e increases, the surface tension decreases, until a minimum is reached at which the curves level off. The decrease of surface tension with increasing carboxylate concentration is generally taken to indicate the surface excess of the carboxylate ion. The point where the curve suddenly levels off has not yet been explained. While it is well known that the onset of micellization (CMC) may cause such an inflexion of the surface tension curve, this cannot be the case here because the position of this point depends, as shown in fig. 4 for palmitate, on pH (the CMC is generally independent of pH). We believe that this point indicates the precipitation of a colloidal acid soap (colloidal precipitation edge, CPE) before the bulk precipitation of this species sets in (BPE).

Jan 1, 1994

By M. Misra

A sample of thorium-contaminated soil from Kirtland Air Force Base (AFB) was subjected to froth flotation for removing thorium contaminants. A series of flotation tests were conducted to screen and evaluate the reagents. Among the collectors used, sodium oleate exhibited to show the promising results. Preliminary tests showed that a concentrate having activity as high as 5300 pCi/g can be obtained from the contaminated feed soil having activity 800 pCi/g. The volume reduction obtained was 89% and the activity recovery in the concentrate was 68%. The paper discusses the physico-chemical characterization data and the potential physical separation decontamination schemes for the thorium contaminated soils.

Jan 1, 1996

By M. G. Rylatt

The Ekati process plant flowsheet features the common steps in diamond recovery plant design. Primary treatment and concentration is by crushing, scrubbing, high-pressure grinding rolls and heavy medium separation (Fig. 1). Secondary concentration is by an attrition mill; wet, high-intensity magnetic separation and X-ray sorting (Fig. 2). All of these are performed on site, although final sorting of the diamonds into commercial categories will be carried out elsewhere. The initial throughput rate is 9 kt/d (9,900 stpd), increasing to 18 kt/d (20,000 stpd) during the first 10 years of operation. A range of ore characteristics will be encountered that will effect the plant operating conditions during the life of the mine. The adopted design envelope is based on these expected variations. The design is based on the use of large-scale equipment, incorporating the latest and most efficient technology available. Where proven technology exists, no attempt was made to reinvent the wheel. However, where recently developed technology offers a significant advantage, this has been incorporated into the design. The Ekati run-of-mine (ROM) and coarse ore handling facilities are unheated, to take advantage of the better handling characteristics of the frozen ore in winter. The stockpile reclaim features an MMD mineral sizer (a toothed roll crusher) to minimize the problems of handling thawed, sticky kimberlite in the summer and break frozen lumps in the winter. All processing downstream from primary crushing and the coarse ore stockpile is carried out in a temperature-controlled environment in the main process plant building. Personnel involvement in the process is mini¬mized by using a Modicon Quantum series PLC with human-machine-interfaces (HMI) running Wonder-ware software on dedicated personal computers.

Jan 1, 1999

By H. K. Lin

Elemental sulfur is founded to be the predominant sulfur-containing species in a leaching residue resulting from ferric chloride leaching, under given conditions, of a chalcopyrite concentrate. The mineralogical study of the leaching residue which consists of 52% elemental sulfur reveals that the sulfur formed at the end of leaching process is in the form of discrete crystal rather than coating film. Flotation has been applied to recover the sulfur successfully using xanthate as a collector. Dispersants arc needed to prevent the mechanical entrapment of silicate and quartz by sulfur. Very high recovery of sulfur with satisfactory grades can be achieved with a relatively simple notation scheme.

Jan 1, 1991

By Michael J. Hannan, Thomas F. Torries

The nature of industry structure is examined and the structure of the aluminum, copper, lead and zinc industries are described by the use of factor analysis. Capacity is defined and the relationship between industry structure and capacity utilization is examined. It is demonstrated that excess capacity is possible in industries with competitive or monopolistic characteristics, but the effects of the overcapacity are vastly different in the two cases. In a competitive industry, cycles of overcapacity with attendant fluctuating prices are expected. A change in industry structure from monopolistic to competitive characteristics over time causes profits and economic rents to be transferred from the producer to consumers of the mineral.

Jan 1, 1989

By M. J. Laurila

On-line analyzers have made possible the use of Fuzzy Logic Control (FLC) for local control applications in coal preparation plants. This includes FLC control of complete circuits such as heavy media vessels, cyclones and froth flotation. These circuits can be controlled in real time in a feedback control loop with an on-line analyzer. Control strategies can be readily developed using Statistical Process Control (SPC) techniques which are first applied off-line in manual mode through the use of control charts and then this process is brought on-line using FLC in conjunction with an on-line analyzer to fully automate the circuit. This paper outlines the types of control strategies employed and presents examples of automatic verses manual control.

Jan 1, 1997

By Levent Ozdemir

An extensive study involving laboratory testing and computer modeling has been performed to assess the technical and economic feasibility of utilizing the recently developed minidisc cutters on roadheaders for hard rock mining. The results show that heavy duty roadheaders fitted with minidiscs can excavate hard rock formations at acceptable production rates and cutter costs. This paper presents and discusses the results of this study together with the ongoing developmental efforts of this technology, which include laboratory testing of a roadheader cutting drum with minidiscs and full scale field testing of a machine in hard rock

Jan 1, 1995

By Morgan M. Sears

In recent years, one large mine collapse and numerous smaller bump events have resulted in a renewed interest in coal bump research. With numerical modeling, the Energy Release Rate (ERR) calculation quantifies the ?release? of the gravitational potential energy of the rock mass into the environment as mining progresses. This release of energy can occur passively in the form of heat and sound or dynamically in the form of pillar bumps or rock bursts. From the initial application of a calculated energy release rate in the deep hard-rock mines of South Africa, the ERR was found to have a significant correlation with the risk or potential of damaging coal bumps or rock bursts. In this research, an ERR calculation is incorporated into the modern LaModel program to facilitate the analysis for potential coal bumps. Initially the ERR calculations in LaModel are verified using a case study of cut sequences originally modeled using the MULSIM/NL program. Then, the ERR calculations are applied to a bump-prone mine in Southern Appalachia were a number of different pillar recovery cut sequences were used in order to minimize the risk of bumps.

Jan 1, 2009

By Slavko Ostojic, V. G. Hill

This paper reviews various bauxite classification schemes with respect to the differences in texture, composition and geological associations of the deposits. It demonstrates that a techno-economic classification, based on: a) associated rock type - lateritic versus karstic, b) content of aluminum ore minerals - gibbsite, boehmite and diaspore, and c) gangue minerals (iron oxides etc.) has a geological basis with natural cut-off points for the bauxite types identified. Thus, this scheme is seen as applicable to bauxite resources. It also provides a basis for their rational exploitation taking into consideration the long-term interests of both the bauxite producing and consuming countries. Against this background, the industrial mineral or non-metallurgical grades of bauxite are seen as localised and relatively rare occurrences. Their consumption should, therefore, be aimed toward the specific (hence more remunerative) products as indicated by the bauxite characteristics.

Jan 1, 1984

By M. Karmis

The determination of the surface area which may be impacted by underground mining is an important consideration in subsidence engineering. A number of parameters have been utilized to identify this influence area, most notably the angles of draw and break. This paper discusses the implications of selecting an appropriate "damage angle" for defining a potential damage area due to mining, within which surface structures may be impacted Furthermore, the influence of both mining and geological factors, such as mining width and depth and overburden lithology, on this angle is examined, using the Surface Deformation Prediction System (S.D.P.S) software. Finally, recommendations are given for applying these concepts in subsidence control.

Jan 1, 1994

By Pedro E. Rengifo

Splicing methods have undergone considerable developments over the last 2Oyears. Continuous conveyor belt service is dependent entirely on the strength and life of the splice to hold the two ends together. Ultimately, belting performance is dependent on the quality, efficiency, and technique of the splicer. As customers demand better belting performance and running tensions increase, the need for splices that perform as efficiently as the belting has increased also. Higher dynamic belt constructions have also dictated the need for "new"sp1icing techniques. Regardless of the belt type used or spliced, one item that is most necessary with all belt types is the quality of the workmanship and standardized splicing methods that employ all of the necessary elements required to ensure reliable field service. This paper will explore the use of Goodyear-issued internal standards for field splicing following the constraints of quality and efficiency for fabric and steel cord reinforced belting. Also included are the 10 most common mistakes made by splicers, Goodyear-issued Field Quality Assurance Standards, and check lists for end users to adhere to the manufacturers' requirements for splicing including materials and specifications for conveyor belt splicing and repairs.

Jan 1, 2004

By J. H. LaVerne Palmer, W. (Bill) C. Cox, Lorant B. Geller

An erector transporter (ET) has been designed and built to lift, carry and erect heavy machinery components, in particular the components of a 7.6 m diameter tunnel boring machine (TBM), within the access tunnels of a submarine coal mine in Eastern Canada. The ET is capable of manoeuvring within a 7.6 m tunnel while precisely positioning components as large as 6 m in diameter and weighing up to 27 tonnes each. The unit can negotiate 20% grades while carrying loads of 30 tonnes. The major design features, verification tests and performance trial results are presented. The versatility of the ET is such that many other applications are possible.

Jan 1, 1985

By J. A. Hartlage

Four years ago, Ashland Chemical Company introduced a new copper solvent extraction reagent for hydrometallurgical utilization. The reagent, an alkylated 8-hydroxyquinoline, is called Kelex 100 ®(1). Since the time of introduction, the reagent has been investigated by several workers for its solvent extraction utility in the separation and purification of transition metals (2-7). In the following text, those factors which are essential to the optimum performance of Kelex 100 on concentrated copper solutions will be discussed. To date, the reagent has been found useful in active concentrations of from 1 to 20% Kelex 100. In order to achieve the best performance for Kelex 100, it has been found that a phase modifier is essential. Various alcohols and phenols have been evaluated in order to improve phase performance and stripping characteristics of the solvent system. Modifiers and diluents are especially important when solvent activities between 3 and 20% Kelex 100 are employed. A 15% Kelex 100 solvent, for example, containing 15% nonyl phenol in Escaid 100 (Exxon) can be utilized to remove greater than 33 grams per liter of copper from an aqueous feed without interstage neutralization, and in the same process scheme the reagent can be stripped to less than 1 gram per liter barren organic producing a pregnant electrolyte containing greater than 40 grams per liter copper and less than 120 grams per liter sulphuric acid. The unusually efficient stripping of Kelex is accomplished by protenation of the extractive molecule during the stripping process.

Jan 1, 1974

By V. Price

Abstract: Action of certain strains of bacteria has been implicated as a significant factor in the oxidation of ore deposits. Other bacteria are thought to be significant in the formation of syngenetic sedimentary ores and in supergene enrichment processes. A normal soil/ground-water regime provides all of the necessary pH and Eh conditions for several groups of bacteria which influence the sulfur cycle in nature. Limiting concentrations of nutrients such as sulfate ions can determine whether a particular microbial species is active at a given place. In the present study, ground water was analyzed from a mineralized area and from a presumed barren area. Trace metal content of the ground water gave no well defined clue as to the presence of a sulfide ore deposit. Sulfide producing bacteria (presumably sulfate users) were found in water from about 50% of wells sampled in the mineralized area and in about 30% of samples from the barren area. These bacteria are readily detected and may provide a useful tool for regional geochemical recon-naissance. Bacterially produced sulfide ions can remove metals such as copper and zinc from solution thus complicating the interpretation of hydrogeochemical prospecting.

Jan 1, 1972

By D. R. Spears

The Bureau of Mines has investigated the fundamental aspects of shear-flocculation using a rapid, in-situ particle size analyzer. Silica was stirred in the presence of an aliphatic amine to determine the effects of collector coverage, stirring speed, and solids concentration on the kinetics of shear-flocculation. The results showed that shear-flocculation is a two-stage process. In the first stage, mean particle size increased rapidly in the first 1-2 min of reaction; in the second stage, an equilibrium was set up between the rate of floc growth and floc decay. Collector dosage affected the position of the equilibrium by altering the number of surface sites for particle-particle attachment. A minimum stirring speed was necessary for shear-flocculation to occur and was dependent on solids concentration and collector dosage. This speed was the minimum necessary for particles to overcome the electrostatic energy barrier which kept conditioned particles dispersed. Larger particles flocculated more rapidly. At very high stirring speeds, large flocs became unstable, resulting in a narrowed particle size distribution in the slurry.

Jan 1, 1993

By Kanaan Hanna

A joint research program between the U.S. Department of the Interior's Bureau of Mines and Cyprus-Yampa Valley Coal Company is being conducted at the Foidel Creek Mine, Oak Creek, Colorado. This program goal is to study the effects of state-of-the-art, high-speed, automated longwall mining on health and safety, and primarily, ground stability under various geological conditions. The Bureau installed an automated data monitoring system, known as the Ground Control Management System (GCMS), to monitor in real-time the effect of rapid mining on pillar and face loading, stress redistribution in and around the longwall panel, and caving characteristics of the roof. The Bureau's GCMS, combined with the company's existing monitoring systems, which include environmental monitoring, a computer programmable conveyor belt system, and gamma ray roof control thickness indicators, has been effectively used to improve safety at the face, increase productivity, and reduce production costs.

Jan 1, 1991

By Y. J. Wang

In the mathematical analysis of electrical networks, the electrical devices are often modeled using idealized network elements such as current sources, voltage sources, and resistors. An analogous approach is outlined here for the modeling of mine ventilation networks, which can be considered nonlinear resistive networks. The modeling technique proposed uses five basic (non-reducible) elements: the H element, the Q element, the D element, the R element, and the N element. These elements are characterized by their (a) pressure gain or loss, (b) air quantity, and (c) pressure-versus-quantity relationship, each of which may be known or unknown. In addition to the definition of the basic elements, the necessary conditions for which there exists a unique solution are discussed. This is performed using theoretical developments derived from electrical circuit theory and illustrated in example networks. The proposed procedures are useful in the solution and characterization of mine ventilation networks.

Jan 1, 1996

By David D. Eyer

In today's world coal market, coal quality is becoming increasingly important. Often the coal quality parameters are one of the crucial considerations in the development of a coal mine. Because of the user's tighter specifications and because of strict environmental regulations, coal producers are being called on to predict with increasing accuracy, not only the quality of their product but also the variability of that quality. This area of reserve evaluation is naturally receiving a great deal of scrutiny. Consolidation Coal Company has developed reliable and sophisticated methods for predicting coal quality, but the company's efforts continue to search for even better techniques. The following is a step-wise summary of The methods currently used by consolidation coal company, with A recent project used as an example. Two of the newer, and as yet experimental techniques will be briefly discussed.

Jan 1, 1980

By I. E. Odom

An electron optical and microprobe study was made to determine the physical and chemical nature of the silica minerals that occur as natural impurities in bentonite and montmorillonitic fuller&apos;s earth clay products (both granular and powder) and that occur in <10-µm dusts from plants that process these products. The purpose of the study was to determine if discrete "free" silica minerals, such as quartz, could be observed using SEM and EDS methods. No “free" silica minerals could be observed in the SEM images of the granular and powdered products, either among or on the surfaces of the particles. Also, no “free" silica could be identified by either SEM or EDS analyses of the dusts, even though quantitative X-ray diffraction analysis indicated that trace amounts of quartz occurred in all samples. It was determined that these quartz and other silica minerals were encapsulated or coated by montmorillonite. Vigorous washing, however, removed some of the clay coatings, so that small amounts of silica minerals could be seen by SEM and EDS analysis. It was found that all primary crystalline quartz grains in the bentonites have diagenetic overgrowths consisting of a mixture of montmorillonite, opaline silica and possibly microcrystalline quartz. Detrital quartz grains in the fuller&apos;s earth have thin diagenetic overgrowths of opaline silica, also containing montmorillonite. The clay encapsulation of the silica minerals in the products studied, as well as in the potentially respirable (<10-µm) dust produced during manufacturing of bentonite and montmorillonitic fuller&apos;s earth clay products, is considered to be an important factor influencing the potential health effects (e.g.. silicosis) of the contained silica. Even if clay dust containing silica should be inhaled, the montmorillonite encapsulating the quartz and other silica minerals would prevent direct contact of the silica with lung tissue. The clay encapsulation of quartz, as well as the highly hydroscopic nature of montmorillonite, may explain why not a single confirmed case of silicosis has ever been reported among plant workers in more than 65 years of production.

Jan 1, 1998

By R. G. Reddy

Solid state reduction of roast movat chromite ore with carbon was carried out as a function of C/FeO ratio and temperature in the range 800°C to 900°C by thermogravimetry analysis (TGA). A two stage mechanism, (1) the reduction of FeO present in Roast Movat with carbon monoxide; and (2) the regeneration of CO by the oxidation of carbon with CO2 was proposed. The rate controlling step is the carbon oxidation reaction. A kinetic equation, that of random nucleation, was proposed. The activation energy for the reduction was determined to be 55800 J/mole and is compared to those activation energies determined for other chromite ores.

Jan 1, 1998