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By R. L. Miller

The potential for recovery of enriched uranium from spent nuclear fuel which has been consolidated into a nuclear waste form was explored in the studies reported here. The waste form of interest is iron-enriched basalt (IEB)--a silicate-based, fused-cast ceramic. IEB samples were prepared containing fuel assembly materials that simulate the core debris of Three Mile Island Unit II;1,2 the nominal composition of the consolidated waste form is given in Table 1. Ore Types The IEB samples, or man-made uranium ores (MMUO), are in two different mineralogical forms. Each MU0 was made by melting the constituent materials and holding at about 1500°C for 1 h. The MMUOs were then heat treated to control crystallization and crystal growth and then cooled to room temperature.

Jan 1, 1983

By William M. Kester

Finely sized Upper Freeport coals are beneficiated to reduce ash and sulfur using high-intensity magnetic separation to process both (1) raw, untreated coal as well as (2) raw coal which was pre-treated thermally with steam and air. Substantial, sulfur and ash reduction can be obtained using both approaches to magnetic beneficiation of coal fines, but evidence indicates that pre-treatment which would constitute a costly supplementary step is technically inferior to the direct beneficiation of raw, untreated coal. These bench-scale studies demonstrate that if high-intensity,; high capacity, dry, magnetic beneficiation equipment can be developed and' installed at coal burning power plants or at appropriate points in coal preparation plants substantial quantities of sulfur may be removable from coal after pulverization as a means' to reduce air pollution.

Jan 1, 1965

By C. D. Harrison

This paper presents the results of 18 high-G centrifuge tests performed at the Electric Power Research Institute's Coal Cleaning Test Facility in January 1985. These tests, using -28 mesh (0.6mm) froth flotation product, show that the high-G, solid-bowl centrifuge can produce clean-coal moistures of less than 12 percent at solids recovery rates exceeding 98 percent. The high-G centrifuge achieved these low moistures by applying centrifugal forces up to 2,000 times gravity. Because these forces are two to three times the forces used in a screen-bowl centrifuge, the high-G centrifuge can use a solid bowl and still produce a low-moisture product. The solid bowl captures ultrafines that would pass through a screen bowl, and thus obtains higher recovery rates than a screen-bowl centrifuge.

Jan 1, 1985

By J. Diao

In order to understand the flotation kinetic behavior of coal and associated mineral matter, a detailed investigation was conducted in a 2-liter Denver flotation cell using three high sulfur coals at three feed sizes, minus 28. 100 and 200 mesh. Subsequently. the flotation products were sieved into different size fractions and analyzed for their ash and pyritic sulfur content in order to delineate the effect of particle size on the rate at which each constituent floats. The results were tested with several different flotation kinetic models and the best model for coal was then chosen. The flotation rate constant and the ultimate recovery calculated from a kinetic model were used to delineate the effect of particle size, collector (dodecane) and frother (MIBC) dosages on the flotation kinetics of coal, ash and pyrite.

Jan 1, 1992

By E. Martinez

A heavy mineral sand sample was tested containing 13% heavy mineral consisting of rutile, zircon, and ilmenite. Eleven tests were run at a mill site with a Mineral Deposit Limited MG 4 spiral to determine the effect of the addition 0; magnets to the spiral compared to conventional gravity separation. Different magnet configurations and field strengths were tested. Optimum results were obtained with the spiral retrofitted with magnets. The heavy mineral content of the concentrate was increased from 55.5% in the control to 64.2% with the magnets. The 8.7% improvement in heavy mineral recovery was due not only to the weakly-magnetic ilmenite, but also to increased recoveries if the non-magnetic zircon and rutile. The increased recoveries were achieved with no loss of concentrate grade.

Jan 1, 1992

By L. G. Austin

A program has been written to combine the Klimpel-Austin approximate model for liberation in a binary system with a mill model applicable to ball milling. The model applies for a system where the volume fraction of valuable B in host matrix A is small. The mill model is treated as an equivalent series of fully-mixed reactors. Twenty-three classes of material are considered: pure A; pure B; unchanged AB; 0-10.2 B in AB either as surfac- exposed B or as wholly-contained grains of B; 10-20% B in AB, surface-exposed or wholly- contained;etc.. to 90-100% /b ub /ABm syrface-exposed or wholly-contained. Illustrative cases are given making reasonable assumptions concerning relative rates of breakage and primary breakage distribution functions for each class of material.

Jan 1, 1986

By D. Kang

The adsorption behavior of silver in ammoniacal solutions on to activated carbon has been studied. The parameters affecting the adsorption of silver on to activated carbon included temperature, agitation speed, concentration of cations and anions as well as that of ammonia. It was found that the adsorption of silver from ammoniacal solutions was dependent upon the initial silver concentration in the solution and other factors. The recovery of silver from ammoniacal solutions was found to be not so effective as the case with gold reported earlier. The adsorption rate was relatively slow overall, despite a rather fast initial adsorption. The apparent activation energy for the adsorption was measured to be 30.2 kJ/mol. It was believed that the kinetics of the silver adsorption on activated carbon was limited by a mixed control mechanism.

Jan 1, 1998

By M. G. Ayat, J. Dasher

Having an interest in coal slurry pipelines from a decade of arguments with Ed Wasp and crew at Bechtel about pumping thicker slurries slower, I immediately read this article and found nothing in it pertinant to the title. Ayat and Scott pumped five unidentified coals at 9% solids (50%-60% is the area of interest) in a 25-mm (1-in.) pipe around two square elbows through a 76-mm (3-in.) cyclone for up to 60 minutes and sized a large number of samples of unstated size on an unidentified wet screening device. They did not measure power consumption, discharge pressure, flow rate, or give pump tip speed or impeller diameter. They siad the cyclone had a "high" pressure drop (unmeasured) and did much of the degradation (measured) but more or less per unit of energy expended? Hargrove was not measured, so there are no data as to whether it would correlate with degradation. The authors conclude, with no attempt, correlation is "hard to establish." Please experiment before concluding. I am at a loss to know what "increasingly smaller size" means, much less what theory says such particles take "exponentially larger quantities of energy," which the authors neglected to measure. If such experiments without pertinent data or justified conclusions must be published, please attach a pertinant title.

Jan 1, 1990

By E. Taskin

Diasporic bauxite from the Mugla-Milas region was mechanically activated in a planetary mill for different activation times and the structural changes were examined by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and specific surface area analysis (BET ? Burnauer, Emmett and Teller). Non-activated and activated bauxite samples were leached directly in alkaline (Na2O) solution at atmospheric conditions and the activation procedure led to the amorphization and structural disordering of the diasporic bauxite structure, which increased the dissolution efficiency. Effects of milling speed, liquid/bauxite ratio and leaching time on alumina extraction in direct alkaline leaching of diasporic bauxite were also studied. The alumina extraction was ~7% for non-activated bauxite and ~70% for activated (75 minute) bauxite. Key words: Diasporic bauxite, Mechanical activation, Alkaline leaching, Alumina extraction

Jan 1, 2009

By B. R. Satio, P. G. West-Sells, D. B. Dreisinger, B. J. Y. Leong, G. A. Kordosky

Electrolytic techniques have historically been used to remove arsenic, antimony and bismuth from copper refining electrolytes. However, both solvent extraction and ion exchange techniques have been heavily researched and in a number of cases commercially introduced. In this study a large number of solvent extraction reagents and ion exchange resins were screened to determine the selectivity of the reagents for impurity removal. Solvating extractants were found to efficiently remove arsenic from electrolyte. The extent of arsenic extraction increased in the following order: TBP < DBBP < DPPP < Cyanex 925 < Cyanex 923. Antimony and bismuth extraction from electrolyte were demonstrated with the reagent 2EHAP04. The ion exchange resins UR-3300 and Duolite C-467 were found to strongly extract antimony and bismuth from electrolyte. C-467 appeared to be superior to UR-3300.

Jan 1, 1993

By Ahmed Yehia, M. A. Abdel-Khalek, J. D. Miller, M. Fadel

Recently, research efforts have been made to lower the magnesium content of phosphate rock concentrate to be a suitable feed for phosphoric acid production and other related industries. Among these efforts is the bioprocessing technique. However, this study is devoted to study of using an enzyme, extracted from coffee waste, as a surface modifier during the fatty acid flotation of calcareous phosphate rock. A mixture of oleic acid and kerosene was used as collector. Factors, which affect the enzyme activity such as enzyme dosage, solution pH, temperature and conditioning time, were studied. Under the appropriate conditions, a concentrate product containing less than 0.60% MgO was achieved from the Abu Tartur feed (1.80% MgO) with a P2O5 recovery of more than 94%.

Jan 1, 2002

By John A. Herbst

At the last Comminution Symposium a challenge (Meloy and Williams, 1992) was issued to "predict the typical straight-line, self similar" tumbling mill product size distributions using a population balance model (PBM). Implicit in this challenge is the assumption that the PBM is inadequate for predicting real world grinding performance. This response is presented in three parts: I. Theoretical analysis of the general PBM and its appropriateness for comminution system modeling. II. Examination of the accuracy of prediction of real world milling behavior using linear and nonlinear PBMs. III. Evidence from recent microscale comminution research. This paper concludes with recommendations concerning future research which will: 1. further elucidate mechanisms of particle destruction and creation as well as attrition and 2. increase the accuracy of model predictions in highly nonlinear situations

Jan 1, 1997

By R. D. Kelsey

The theory, definition and practical application of cutoff grades have evolved over a long period. This evolution is reflected in the continuing flow of papers on this and other related matters though the rate has varied as new ideas and theories have become understood and applied in practice. Papers by Lane(l) in 1964 and Taylor(-2)- in 1972 provided landmarks in the understanding and general communication of cutoff grade theory and its application. The reasons for the continuing interest in cutoff grades are obvious. Too high a cutoff can reduce the mineral recovered and possibly the life of a deposit. Too low a cutoff would reduce the average grade (and hence profit) below acceptable levels. This paper provides a brief overview of existing cutoff grade theory and some particular aspects of its application.

Jan 1, 1979

By F. F. Peng, Y. Xia

In modeling of hindered-settling bed separators, the published separation mechanisms are based on differences of particle density and size distributions, without the details of complexity of particles-liquid interactions. A fluid dynamic model for the separator is developed using Euler-Lagrange approach of Computational Fluid Dynamics (CFD). Fluid motion is obtained from solving the movement of liquid governing equations. The damping effect on flow pat-terns caused by the movement of particles resulted in liquid-particle coupling is included in the model. Effects of particle size, and particle density compositions, feed rate, feed water flow rate, upward fluidizing water flow rate, etc., are simulated in the 2-D separation model. Flow pattern effects on the separation of fine particles in the separators with center downward-flow and side cross-flow feed systems are investigated.

Jan 1, 2004

By Jaime E. Sepúlveda

Semiautogenous grinding (SAG) operators have been realizing the very significant impact of fresh feed particle size distribution on the mill grinding capacity. In actual practice, this impact may be quite difficult to assess because of the natural process variability that may also involve- concurrently other critical factors such as ore hardness. Recognizing the limitations of the empirical approach, the current publication proposes the use of mathematical models and simulators to explore and assess the net effect of feed particle size only, independent of any other factors. The simulation analysis here reported provides a basis to claim that the size distribution of the particles being ground (simply characterized by a % - 2" or similar measurement) is one of the most relevant controlling variables of the overall mill performance, regardless of the SAG circuit configuration.

Jan 1, 2005

By J. W. C. Wong, S. D. Miller, J. J. Jeffery

Pre-mining identification of acid forming mine and waste materials is of concern to the mining industry because of the potential for the generation of acid mine drainage, acid rock drainage, and soil acidity problems. Accurate identification of acid forming material is essential for developing appropriate waste management strategies to reduce environmental problems related to acid generation from sulphide containing wastes. The acid-base accounting procedure, in its various forms , is commonly used for pre-mining screening of mine and mine waste materials. The procedure is generally effective when used and applied correctly but is prone to incorrect interpretation of results which can have significant financial and environmental implications. This paper examines the acid-base accounting Procedure and the possibility of misuse of this method with special emphasis on the sampling method, the sulphide forms, the acid neutralization capacity, and the interpretation of results. Data from numerous coal, base metal, and gold mining operations are used to illustrate the application of the acid-base account. The data base indicates that overall, approximately 1/3 of all waste generated by mining and mineral processing is potentially acid forming indicating the need for correct identification and management. Problems associated with simple application of 'absolute' acid-base criteria for classifying acid forming material are highlighted and the need for developing site specific or 'relative' criteria is discussed and illustrated by case study.

Jan 1, 1991

By S. Healey, P. Jean, G. Deschenes, M. Fulton

Three years ago, the New Britannia Mine started a project to improve productivity of its cyanidation plant. Results indicated that gold dissolution was strongly influenced by sulphide minerals and that the slower gold dissolution rate had a detrimental effect on overall gold recovery. The leaching strategy had to be modified to address this issue. Changes to the leaching circuit proved to be very successful. The first action was to introduce lead nitrate in the leaching circuit. The strategy of addition of lead nitrate was upgraded in three steps. An on-line free cyanide analyser was installed and the strategy of cyanide addition automated. The enhancement of the leaching kinetics have resulted: an 4% increase of gold recovery, from 87.8% in 1996 to 91.9% in 1999, which represents a reduction of 0.17 git Au in the leach residue; an average of 1330 additional extracted gold ounces per year from 1997 to 1999; a 21 % reduction in the cyanide consumption; the shut down of the cyanide destruction plant; and finally a contribution to the 27% reduction in the overall production cost per tonne of ore.($ 3 per ton). The significant increase of the throughput was instrumental in the reduction of the processing cost. In 1999, the improvement of gold recovery represented an additional gross revenue of $c""l.9 Million. The project is discussed in details in this paper.

Jan 1, 2000

By Wang Dianzuo, Luo Lin, Hu Yuehua, Qiu Guanzhou

This paper introduces a novel classification approach named the flotation classification approach which works by controlling interactions between particles. It differs considerably from the conventional classification processes operating on mechanical forces. In the present test, the micro-bubble flotation technology is grafted onto hydro-classification. Selective aggregation and dispersion of ultrafine particles are achieved through governing the interactions in the classification process. A series of laboratory classification tests for -44 pm kaolin have been conducted on a classification column. As a result, about 92 percent recovery for minus 2 pm size fraction Kaolin in the final product is obtained. In addition, two criteria for the classification are set up. Finally, a principle of classifying and controlling the interactions between particles is discussed in terms of surface thermodynamics and hydrodynamics.

Jan 1, 1995

By G. Atesok, M. Hancer, M. S. Celik, O. F. Emrullahoglu

Multivalent ions are shown to activate the flotation of colemanite in the presence of sodium dodecylsulfate (NaDDS). Floatation recoveries versus barium ion concentrations exhibit three distinct regions of floatability. Adsorption, zeta potential and solubility mesurements under comparable conditions reveal that Region I is characterized by the uptake of Me2+ ions followed by electrostatic attraction of sulfate ions onto the oppositely charged surface. The improvement observed in flotation recoveries in Regions II and III is ascribed to surface and bulk precipitation of metal dodecyl sulfate onto colemanite, respectively. While the most soluble BaDDS ions yield the highest activation, the least soluble MgDDS achieve the lowest activation. It is postulated that metal ions depending on their solubility products with DDS are capable of activating the boron minerals.

Jan 1, 1993

By M. Li, J. D. Miller

Recently water insoluble alcoholic solutions of alkyl hydroxamic acid collectors have been shown to be particularly effective in the flotation of coarse feed material sampled from phosphate operations in Florida, North Carolina and Utah (Miller et al., 2000). The experimental results indicate that high separation efficiencies can be achieved in single stage flotation with these new collectors. In some cases the concentrate grade reached 34% P2O5 with 93% recovery from single stage bench scale flotation experiments. Critical aspects of the composition and structure of these new collectors are discussed with respect to their effectiveness in phosphate flotation. The wetting characteristics at fluorapatite, francolite, dolomite and quartz surfaces are being investigated with the new collector. Finally, other surface chemistry considerations in the development of these new collectors for phosphate flotation are discussed.

Jan 1, 2002