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Coal-derived flue gases contain CO2/SO2 and these contaminants preferably have to be captured by cheap sorbents. This remediation approach is from the standpoint of addressing issues such as global warming, acid rain and development of Advanced Power Generation Systems and to realize the economic gain as well. Conventional and existing dry scrubbing technologies use regenerable sorbents which are pollutant specific and require expensive stabilizers in order to attain versatility. This paper discusses the use a novel class of sorbents prepared from the heavy metal contaminated Berkeley Pit water (Butte, Montana) by a proprietary process developed at The University of Nevada, Reno. These sorbents are activated mixed spinel ferrite (MxFe,_X04)' Preliminary experimental results show that the sorbents have good desulfurization and CO2 decomposition capacities. The decomposition effectiveness of these mixed spinel ferrites was studied at 300°C and compared against the synthetic magnetite obtained from ferrous sulfate solution in our laboratory. The results indicated that the mixed spinel ferrite had good affinity for the adsorption and decomposition. The CO2 decomposition data of both sorbents fitted the first order reaction kinetics. Even though the surface area of the magnetite was higher than that of mixed spinel ferrite, the CO2 decomposition rate of the mixed spinel ferrite was estimated to be 2.5 times higher than that of magnetite under identical conditions. The carbon analysis deposited on the sample indicated that the CO2 was 100% decomposed into carbon and other carbon! hydrogen compounds by the mixed spinel ferrite whereas the conversion was 43% by the magnetite. In terms of specific adsorption of carbon, ferrite was 3-5 times more efficient than magnetite.

Jan 1, 1996

By Zia Zafir

Design of the deep foundations for the loads imposed by lateral spread include the estimate of the pressure applied by the liquefied material as well as amount of anticipated displacement. In the absence of a non-liquefiable cover over a liquefiable layer, it is possible to design the foundation system just for the additional pressure applied by the flow slides. On the other hand, if a non-liquefiable layer exists above the liquefied zone, the foundation should be designed for anticipated movements. To completely account for liquefaction and/or lateral spread and their interaction with the deep foundation system, a coupled soil-structure interaction (SSI) analysis should be performed. However, a complete SSI analysis may not be feasible for most of the projects. This paper will present recent advances in analysis techniques and simplified methods to design deep foundations for liquefaction and lateral spreading. In addition, a case history of the Rancho California Bridge in southern California located within 1 km of the active Elsinore fault will be presented. One of the bridge abutments is underlain by potentially liquefiable layers. The pressure applied by the liquefiable layer was estimated to be greater than the shear capacity of the 36-inch CIDH piles designed for the abutment. However, with limited ground improvement and more careful analyses incorporating structural effects of CIDH piles, resulting design and construction resulted in a factor of safety greater than 1 against slope failure. The recommended approach was generally consistent with the recently published, and AASHTO sponsored, NCHRP 12-49 project regarding seismic design guidelines for new bridges and the effects of seismic displacements against bridge foundations.

Jan 1, 2006

By G I. Lumley

‘Every mine is a pilot’ is an attitude which encourages the mining paradox of optimistic mine plans and equipment under performance; propped up by an environment lacking accountability. The premise that ‘every mine is a pilot’, appears to underlie the development and operating approach to most mines. It is the hypothesis of this paper that many mining companies, development teams and their managers largely ignore what is done elsewhere. Anecdotally, most planners don’t know whether the selected rates are high or low (rates based on theoretical models tend to be high – certainly higher than what most companies can achieve). Mines then consistently operate the equipment at rates well below targets; often more than 20 per cent below. Further to this paradox, mine performance data demonstrates the average mine is currently operating their equipment at levels of output not much more than half the output of those in the top ten per cent. On the whole mines don’t know the potential of their equipment and therefore don’t put appropriate plans in place to do better. After all, when ‘every mine is a pilot’ there is little reason to look to one’s peers for an indication of potential. This paper will outline why every mine is not a pilot and how mines do value some knowledge, but not as much as they should. This paper proposes a two-pronged approach to address this issue in the area of equipment performance. This approach is to:1. engage in better forecasting of equipment rates and better subsequent performance through benchmarking against industry standards2. provide conditions for more accountability.These parameters are linked and proper implementation of them will address the losses which many shareholders and financiers have incurred when investing in companies with unrealistic mining plans.CITATION:Lumley, G I, 2016. Is every mine a pilot? In Proceedings International Mine Management Conference, pp 75-88 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By R. G. Davies

Isothermal annealing of quenched Fe3Al reveals that the superlattice forms by the nucleation and growth of ordered domains. The activation energy for isothermal ordering and initial domain growth is -29 keal per mole, which is thought to he the activation energy for vacancy migration. Domain growth, in the absence of excess vacancies, has an activation energy of -100 keal per mole. A maximum in the hardness is observed when the structure consists Of ordered domains, -35-4 in size, growing into a short-range ordered matrix and, also as a function of degree of order, S, with an infinite domain size at S = 0.4 to 0.5. It is proposed that both maxima are due to a transition from deformation by unit dislocations to deformation by superdislocntions. FE-AL alloys containing more than -23 at. pet Al, when quenched from above the critical temperature for the Fe3A1 type of order, always contain the maximum possible amount of FeAl (B2) type of order' (see Fig. 1). Thus when the Fe3A1 superlattice forms, in a 25 at, pet A1 alloy, it does so from an imperfect FeAl structure. The formation of the Fe3Al superlattice has been the subject of several recent X-ray,1, 2 electrical-resistivity,3"6 and dilatometric3 investigations. McQueen and Kuczynski3 concluded that the isotherma1 ordering of Fe3Al, after quenching from 800°C (T,, the critical temperature for order, is 55O°C), takes place by the nucleation and growth of ordered domains. However, Feder and Cahn4 found that the isothermal ordering was complex but more like a homogeneous nucleation process than a nucleation and growth process. Lawley and Cahn2 reported that the degree of order is a continuous function of temperature which is a characteristic of a homogeneous nucleation process. Thus, the evidence is conflicting as to the nature of the Fe3Al ordering reaction. Lipson7 was the first to suggest that ordered domains should exist in the Fe3A1 structure since, as

Jan 1, 1964

By Humphrey Dean

"Canadian mining companies now operate numerous Koepe-type friction hoists in a variety of different shafts, most of which have a depth in excess of 3,000 feet. Rope performance reliability is an absolutely essential ingredient of most installations and, for this to be provided, a more comprehensive understanding of rope reactions to applied stresses is required.It is the intent of this paper to illustrate for the operators the importance of the critical stresses encountered and to provide a maintenance program designed to circumvent potential difficulties."

Jan 1, 1970

By J. O. Stephens

During the late 1940's and early 1950?s, the Westinghouse Combustion Turbine Division built and demonstrated a residual oil-burning locomotive on six eastern railroads. Plans were made to convert to burning pulverized coal, and a single combustor was operated at a full-pressure condition in the laboratory for about two years. During the mid-1960's to mid-1970's, there was considerable interest in coal-burning MHD and a combustor was developed which would also be applicable to combustion turbines. In the early 19801s, the BCR National Laboratory (BCRNL) became affiliated with the University of Pittsburgh, and a program was begun, supported by the Stare of Pennsylvania, to develop an all-purpose combustor for use with industrial and utility boilers and eventually with combustion turbines. In this paper, we review the work of almost 40 years, indicate our present position, and propose steps to be taken leading to efficient and environmentally acceptable power generation from coal, and specifically to coal-burning locomotives.

Jan 1, 1986

By C. H. Schack

Extractive metallurgy techniques currently employed to recover silver from primary ores and secondary scrap were reviewed and evaluated to identify and delineate metallurgical problems whose resolution would increase the supply of silver from domestic materials. The survey revealed that practically all primary silver is recovered by froth flotation concentration of various types of ores, followed by smelting and refining of the separate lead, copper, and zinc concentrates. Silver losses during the complex processing are, with rare exception, inconsequential. Furthermore, any silver production gain from base metal ores, which contribute about two-thirds of the total primary silver, is directly dependent in improvement in the market for the base metals. Statistical data on new and old silver scrap are wholly inadequate to make reliable conclusions about scrap processing problems and the possibility of increasing the recovery of silver from the many forms of secondary silver- bearing materials. The available information indicates (1) that efficient silver reclamation practices are employed by the larger users of silver, and (2) that recovery of additional secondary silver involves solution of problems of collection rather than of processing. Several possibilities exist for limited increases in silver production from primary ores by improvement in metallurgical practices. Specifically, research is needed to (1) solve the problem of recovering silver from the copper ores of the Copper Range district, Michigan; and (2) devise economically feasible methods for recovery of silver from presently marginal or submarginal ores that because of grade, location, and frequently complex nature cannot presently be exploited by conventional techniques.

Jan 1, 1965

By Mehih Demirkan, Kevin Tehansky

Located about an hour drive south from Washington, D.C., the Maryland Transportation Authority (MDTA) contracted with Skanska-Corman-McLean (SCM) to deliver a new Governor Harry W. Nice Memorial/Senator Thomas "Mac" Middleton Bridge, which takes U.S. 301 over the Potomac River, spanning 1.9 mi (3 km) from Maryland to Virginia. The new bridge aimed to improve capacity, safety and access of the roadway and was planned as a four-lane span with deep foundations that would be constructed fewer than 150 ft (45 m) north of the existing alignment of the more than 80-year-old bridge. The new Harry Nice Bridge opened in the fall of 2022 with a design life of more than 100 years, servicing 12 ft (4 m) wide lanes with 2 ft (0.6m) shoulders, doubling capacity, enhancing emergency response, upgrading maintenance and inspection activity access, and featuring lane sharing for cyclists.

Apr 1, 2023

By Robert Glass Cleland

THE BEGINNING of a large enterprise is often as in- significant as a lump of leaven hidden in a bowl of meal or a handful of mustard seed that the wind blows across a field. In 1950 the company known today as the Phelps Dodge Corporation had nearly thirty-two thousand stockholders, paid salaries and wages of about fifty million dollars to some thirteen thousand persons, produced nearly four hundred and ninety million pounds of copper, and possessed net current assets of approximately one hundred and six million dollars. For the origin of this great business, one must go back approximately a hundred and fifty years to an obscure saddle-making shop in the small town of Hart- ford, Connecticut. Anson Greene Phelps, proprietor of the shop and master saddler in his own right, was born in 1781-the year of the Battle of Yorktown, the surrender of Cornwallis, and the close of the Revolutionary War Anson's forebears had come to America in the great Puritan migration that left fields, shops, pulpits, and hearthstones in the reign of Charles the First to transplant the strong, tough roots of their race, culture, and institutions in the New World.

Jan 1, 1952

By J. Budac, R. Kofluk, S. Mankasingh

Stainless steels such as 316L or 304 are normally relatively resistant to attack by nitric acid. However research at Sherritt International’s Fort Saskatchewan Operation reveals that when the stainless steel is immersed in an aqueous system in which nitric acid is used to dissolve metals such as cobalt or nickel, the steel can be seriously corroded. Sherritt is patenting a simple process for arresting the corrosion via the use of copper. This process is expected to substantially eliminate corrosion in processes where nitric acid is used to dissolve metals attached to a stainless steel substrate.

Jan 1, 2014

By Charles H. Dowding

Whenever piling vibrations are significant, construction activities associated with pile driving and/or excavation can produce permanent displacement. These permanent displacements are more detrimental to structural performance than the hair sized, cosmetic, plaster cracks that might be produced by slightly exceeding reasonable vibration controls. Case studies are presented which demonstrate the relative importance of permanent displacements compared to directly produced transient vibration displacement within a horizontal distance of one pile length. Special attention is paid to settlements produced by densification of liquefiable sands. SOURCES OF TRANSIENT AND PERMANENT DEFORMATION DURING CONSTRUCTION Confusion over multiple sources of facility deformation caused by adjacent construction complicates the discussion of the relative importance of vibration induced cracking. None of the recent scientific investigations of vibration induced cracking (Siskind et el, 1980), involved deformation other than that produced by ground vibration from rock blasting. Thus these studies carry the implicit assumption that no ground deformation occurred other than that produced by the transient vibration. In other words there is no permanent deformation other than that which is typical of the older residential structures investigated.

Jan 1, 1991

By Michael B. Cortie

Mesoporous gold sponge has the unique property of being both metallic and highly resistant to oxidation. It has potential application in catalysis, in bio-sensors, in optical coatings, in analytical chemistry and, as we show here, as the basis for a new kind of ultra-capacitor. Due to the cost of gold, the most probable niche for a gold-based ultra-capacitor would be in the high-power/high-energy regime, a region where gold would compete with devices based on RuO2. A high internal resistance limits the power that can be usefully drawn from existing carbon-based ultra-capacitors, and that this problem can potentially be overcome by gold-based devices. A simple proof-of-concept ultra-capacitor based on mesoporous gold is described and its behaviour during charge and discharge cycles examined. In this work a step change in the input or output voltage of the device was used as the controlling parameter. There was also a residual faradaic current resulting from traces of undissolved aluminium left over from the AuAl2 precursor used to make the sponge, and some charge storage due to polarization of the solution. Deconvolution of these three effects was not entirely accomplished, but an ostensible capacitance of about 7 to 14 mF/g Au was demonstrated. Further improvement from these early results seems likely.

Oct 1, 2003

By G. W. Jones

In a previous report results were given and a method outlined whereby from a knowledge of the composition of the natural gas and of the inflammability limits of the individual constituents composing the natural gas, the limits of inflammability of natural gas and air mixtures could be closely calculated. This method is based on the application of Le Chatelier's law as modified by Coward, Carpenter and Payman, to apply to a mixture of any number of combustible gases. This law must not be used indiscriminately, because many exceptions have been found. For example, when ethylene, acetylene, hydrogen sulphide, or chlorinated hydrocarbons are present the law may not hold. For a discussion of the rally exceptions which have been found, reference should be made to a report by Coward and Jones. Before this method can be used the inflammable limits of the individual constituents must be known. Also, the composition of the complex combustible mixture, and representative mixtures besides, must be tested both experimentally and by calculation to prove whether Le Chatelier's law may be applied.

Jan 1, 1933

By Lee W. Saperstein

In surface mining for coal, common practice for the disposal of preparation plant refuse is to bury it. As with surface refuse piles, these buried wastes can ignite and can also lead to ground and surface water pollution. Steps to ameliorate these problems have been devised over the years. C and K Coal Company, of Clarion, Pa., the largest Pennsylvania surface mining company, has incorporated all of these steps and added of few, of their own in their latest disposal practice. In addition to layering and compacting, C and K practices selective placement and dilution to minimize longterm problems.

Jan 1, 1977

By R. H. King

Underground coal mining machinery utilizes portable electric sables, "trailing cables." to obtain power from load centers or distribution boxes. Cables are frequently damaged since mobile equipment, poor lighting, and restricted space are inherent to coal mining operations. Normally, the damage is repaired by splicing--the joining of one or more severed conductors and replacing insulation and jacket. Figure 1 illustrates a typical single conductor splice. Although the repair seems simple, difficulty of the splicing process is exemplified by the many safety hazards and frequent production delays that result from defective splices. Forty-two cable splice related injuries were reported to the U.S. Bureau of Mines in 1972 and 1973. Additionally, 17 splices related fires were reported in the three year period prior to December 1972. Assuming the damaged area is quickly located, an average splice time for a two conductor cable is twenty minutes. Some operators estimate this delay is incurred once per day per operating section. If one ton per minute is averaged throughout the shift, each unit could loose 4800 tons per year from splice delays. An estimated cost for materials and labor to make a splice is $20. The expenditure could result in a $4800 annual cost per section. The estimated expense does not include wages of other personnel waiting for the repair to be completed. Nevertheless, labor and materials cost is minor compared to the income lost from decreased production.

Jan 1, 1975

By H. Preßlinger, H. Hiebler, K. Klepp, W. Posch, M. Mayr

It was investigated in which form sulphur is bonded in ladle slags. For this purpose, the mineralogical phases of the ladle slags were qualitatively and quantitatively evaluated by means of a microprobe. This slag characterization allowed reconstructing the bonding of sulphur into the phases of the ladle slag. Moreover, the reaction process with regard to the ionic theory as well as the structural formula for the mechanism of sulphur bonding were discussed. The bonding of sulphur into calcium aluminate slags is determined by the sulphide ion content in the slag as well as by the ratio of (CaO)/(Al2O3). Calcium sulphide separates only if the slag contains a large number of sulphide ions. When Ca12Al14O33is separated, the sulphide ion is successively integrated into the lattice. The crystal lattice of Ca12Al14O33is characterized by an open, three-dimensional anionic network composed of aluminium-oxygen tetrahedrons linking the edges. In this network, large interstitial spaces are formed, which may be filled with calcium ions on the one hand and statistically with a free oxygen or sulphide ion on the other hand. Key Words: ladle slag, structure, phases, calcium sulphide, calcium aluminate, desulphurization

Jan 1, 2004

By Yoon T. Auck, Milton E. Wadsworth

Column leach studies of two low grade prophyry copper ores were made with variables of size, flow rate, pH, drainage rate and tempature. Evidence is presented to show that, in some types of ores, sulfide minerals block leaching channels and regulate the rate of dissolution of gangue constituents. Basic iron sulfates, dissolved by introducing acid, provide oxidizing agent in the form of ferric ion in the absence of oxygen. Ferric ion then acts to release copper from the ore. Oxygen up-take was found to increase with the lowering of the pH and to follow parabolic kinetics attributable to the precipitation of basic iron salts within the pore channels. Slow drainage of residual gravitational water can seriously retard oxygen up-take during oxidation for particles in the coarse sand range. A model is presented for dump leaching in which a reaction zone connected by channels to the surface of the ore particle moves topo-chemically during the course of the reaction.

Jan 1, 1973

By G. W. Hodges

The Basic Oxygen Process shop at Gary Works is a three vessel shop tapping 220 ton heats. The larger portion of the heats are teemed into ingot molds with the remaining heats being continuously cast in a single strand continuous slab caster. Ingot production includes a wide range of carbon, alloy, and high-strength steels in many ingot sizes for bar, structural, plate and sheet and tin products. Individual ingot weights vary with the number of ingots per heat ranging from a high of 48 to a low of five. Caster production is primarily Riband, a proprietary low carbon grade for sheet and tin applications developed by United States Steel for continuous casting; some Riband steel is vacuum degassed prior to casting. Maintaining a satisfactory level of ladle performance on both ingot and caster heats with a high production rate and widely varied product mix is a demanding and exacting job requiring the best of equipment, materials, and, most importantly, personnel. The improving trend in ladle performance in the No. 1 BOP shop at Gary is due to a combination of factors, which will be described in the following presentation.

Jan 1, 1972

By Shibu John

The COREX® process is beside the FINEX® technology the only industrially realized alternative to the blast furnace route for the production of hot metal. Changes in the raw material sector in respect of decrease in quality, strictly enforced environmental laws and positive operation results of COREX® reference plants make it worth to carefully re-evaluate the COREX® technology in comparison with the traditional blast furnace technology. Integrated Plant concepts based on COREX® offer solutions for future challenges of the iron- and steelmaking industry, which include: economical hot metal production; efficient and highly economic export gas utilization (power generation, DRI production, syngas production for chemical products); lower raw material cost, higher raw material availability; environmental friendly high grade steel production. The economic evaluation of different COREX® gas based plant concepts in comparison with the traditional blast furnace route shows that the COREX® technology is highly competitive in the challenging iron and steel producing environment.

Aug 17, 2017

By C. Lottering

Copper sulphate solutions are produced during the pressure leaching of first-stage leach residue in a typical base metal refinery process. Apart from impurities such as selenium and tellurium, this leach solution also contains other precious metals (Rh, Ru, and it) due to dissolution in the pressure leaching stage. Selenium and tellurium are removed from the leach solution by precipitation with sulphurous acid, since these elements negatively affect electrowinning. This study investigates the feasibility of modifying the Se/Te precipitation process step to achieve significant rhodium precipitation in addition to selenium and tellurium precipitation, in order to reduce the rhodium inventory of the process. Thiourea, S02, formaldehyde, formic acid, and sodium thiosulphate were evaluated to determine which of these reagents would achieve the highest Rh precipitation. Based on these screening tests, SO2 and thiourea were selected to be used as precipitation reagents in optimization tests. During these optimization tests, the operating temperature (80 to 150°C) and the amount of reagent added (80 to 140 per cent excess) were varied to evaluate the effects that these operating conditions have on the precipitation behaviour of Rh as well as Se, Te, Cu, and Ni, and to propose appropriate operating conditions. It was found that thiourea resulted in good Rh and Se precipitation (typically in excess of 90 per cent), but precipitated noticeably more copper and nickel from the solution than when SO2 was used. In addition, thiourea had poor Te removal characteristics. SO2 achieved a maximum of 70 per cent precipitation of the rhodium. Faster kinetics and a larger extent of Te precipitation were, however, observed when using SO2 compared to thiourea.

Jan 1, 2012