Search Documents

By Munro P. D

Eh-pH measurements were taken on an industrial zinc reverse flotation process at Brunswick Mining and Smelting Corporation Limited. Laboratory zinc reverse flotation testwork on samples of the feed to the industrial process produced Eh-pH data which were similar to the data from the industrial process.Later, the Eh-pH data from the industrial process were compared with data from a pilot plant scale zinc reverse flotation process at Mount Isa Mines Limited. After comparison with the data from Brunswick Mining and Smelting Corporation, deficiencies in the pilot plant Eh-pH data could be recognised and corrective actions were taken for the pilot plant. A robust pilot plant zinc reverse flotation process was obtained with consistent performance at the expected level.The implications of these findings for a range of processes are also discussed.

Jan 1, 1988

By A. Konya

"INTRODUCTION Underground Mining and Construction projects face several challenges unique to the underground environment compared to the surface environment. The goals of an effective blasting program are the development of a blast pattern that minimizes cost, maximizes face advance, and provides the desired fragmentation and face profile. In addition to these , mines must consider the very real operational problems that occur such as drill deviation, ground vibration, and deadpressing or sympathetic detonation of explosives. These operation problems lead to increased costs and decreased production in the mine, hurting the bottom line. Combined with these problems, underground blasts can be difficult to monitor and evaluate due to tight spaces, dust during the blast obscuring video, and the need to evacuate the immediate area with no clear line of sight to observe performance. This creates an environment which most mines know that blasting can be improved in their underground operations, yet most are hesitant to change due to fears of the shot freezing, misfires occurring, and questions about how to achieve a proper design. The explosive companies and shot service providers also offer limited assistance or knowledge in the underground blasting realm, unlike with surface blasting, leaving many underground operations in the dark. It is for these reasons that most underground operations are operating decades behind the current technologies and incurring significant costs, both real and hidden, from there blasting operations. This paper discusses philosophical changes to designs that need to be made for effective design and modifications of underground blast patterns to prevent deadpressing and precompression of modern explosive products (Konya, Konya, & Worsey, Modern Blasting Method Selection, 2017). While numerous different methods of underground heading development exist, there are two types that are used in a majority of mines around the world, these are the burn cut and the V-cut. The burn cut is a parallel cut that has holes that go straight into the face and are primarily used in smaller opening (due to ability to pull deep rounds with smaller room widths) and metal mines (helps in ore dilution and greater fragmentation). The V-Cut is a cut that uses angled drilling towards the center of the face (in the traditional method) and is primarily used in underground aggregate operations due to its cheap cost but larger fragmentation sizes and greater throw of the muckpile. This paper will discuss these two forms of cuts specifically with the understanding that modifications to these can be applied to other parallel and angled underground heading techniques. BURN CUT The burn cut is one of the older forms of underground blasting, where a part of the blast (burn) of a shot is heavily loaded with additional empty (relief) holes with the goal of smashing (aka burn) and pushing/blowing all the material in the burn out to provide relief for subsequent blastholes. The relief holes in the burn cut provide a parallel relief for the holes that are firing to break too creating a second plane of relief, however these are extremely small and can cause many problems if a design is improper."

Jan 1, 2018

By Kenric C. Owen

INTRODUCTION Situated 23 miles east of Pretoria the Premier Mine started diamond production in 1903. Two years later it produced the largest diamond yet discovered, the 3 106 carat Cullinan stone. For the period to 1932 when the mine was closed down due to economic circumstances, open cast mining was practised using inclined rope haulage traction and by this time had produced 48.5 million carats of predominantly industrial quality diamonds from 148 million tons of ore. In 1945 it was decided to re-open the mine using underground mining methods. A system using long hole benching was devised (Hodgson and Sewel 1960). This system was later modified but still forms the basis for approximately fifty percent of production. Following the successful introduction of block caving on associated diamond mines in the Kimberley area (Gallagher and Loftus 1960) this mining method was introduced to the Premier Mine in the late 60's and now accounts for nearly 50% of production. This paper will discuss block caving at Premier Mine in the light of our experience and discussion will be directed to the main geological and structural features of the orebody and host rocks and the related constraints imposed on the mining methods. Reference is made to the long hole benching mining method for comparative purposes. GENERAL DESCRIPTION OF OPERATIONS The ore from the block caving and bench mining areas gravitates via ore passes to a twin haulage, 500m below surface. Electric 13 tonne locomotives, each hauling a train of 10 Granby type cars, deliver the ore to two 42" x 48" (1.06m x 1.22m) jaw crushers. The ore is reduced in size to minus 0.15m before being hoisted to the treatment plant on surface. Hoisting is done with 12.5 tonne bottom discharge skips in a five compartment rectangular shaft using two 3 240 H.P. semi automatic Ward Leonard winders. A small single drum service winder operates in the other compartment. Men and materials travel in a separate shaft in a 5,4m x 2,8m cage operated by a Koepi winder. These two shafts are also the main intake airways to the mine. The two main extraction fans capable of 250 m3/s at 3,2 kPa are situated on surface and are connected to the underground workings by an incline and a network of air passes and return airways. GEOLOGY Although there are numerous occurrences of kimberlite bodies in the district, the Premier Mine kimberlite pipe is the only economic orebody. It is roughly oval in shape with surface dimensions of 900m on the long axis and 450monthe short axis. The surface area is 320 000 m2. The kimberlite has intruded a massive body of felsite and norite which is intersected by a number of faults. The contact between the kimberlite and host rock is clear cut and dips inward at an average angle of 80°. Cutting across the pipe and the country rock is a 75 metre thick gabbro sill, the top of which intersects the pipe below the 347m level and dips at 15' to the north west. The kimberlite has been metamorphosed a distance of some 20m both above and below the sill contacts. Age measurements on biotite from the gabbro date the sill as 1 115 million years, thereby providing a minimum age of the pipe. (Pre Cambrian). All other pipes in South Africa are of Cretaceous age (60 million years). A simplified geological plan and section of the Premier Mine orebody is shown in Figure 1. It is thought that the kimberlite intruded in at least three distinct phases. The kimberlites of these different phases can be distinguished most easily by their characteristic colour. BROWN KIMBERLITE. This is the oldest kimberlite and forms a crescent shape in plan on the south eastern side of the pipe. In depth it increases in relative area. Although the brown kimberlite carries the highest diamond grade in terms of carats per ton all the various kimberlites in the Premier pipe are economic to mine.

Jan 1, 1981

By S. Koca

Vast amount of fly ash, bottom ash and slags, are produced each year due to coal combustion in thermal power plants. These products consist of mainly unburned carbon and inorganic compound (such as: silica, alumina, iron oxides, magnesium oxide, phosphorus oxide etc.). These are valuable minerals and can be recycled or recovered if properly processed. One third of the material find application as an ingredient in cement and other construction products, the rest is held in dams or similar dumps, which results in a hazardous impact on the environment, polluting soil and ground water. The unproductive use of land, the associated long term financial burden maintenance and negative environmental impacts have led to realization that alternative uses for combustion by-products as a value added product beyond incorporation in construction materials are needed. At present, there is an intensive search to increase their uses. Other uses of coal combustion residues include as raw material in brick and ceramic tile fabrication, as filler in plastics and paints, extraction of valuable mineral materials, production of zeolites and soil and mine waste treatments. Separation of unburned carbon from bottom ashes by means of flotation was conducted in order to increase the possibility of the recycling of coal combustion wastes. In the flotation experiments collector, dispersant and frother amount, pulp density and pH were tested as variables. After first stage flotation experiments, at optimum conditions, the carbon content was reduced down to 5.58 % in the tailings fraction. This fraction meets the industrial specifications and can be utilized as a cement additive. At the same conditions the carbon content of the concentrate increased to 44.72 % at a carbon recovery of 65.81 %. After the cleaner stage flotation experiment the carbon content of the product is enhanced to 62.53 %. This fraction can be blended back into the coal feed to the power plant boilers.

Jan 1, 2014

By Mario Mauro, Jeff Taylor, Carlos Morales

"In 2007 the US Army Corps of Engineers classified the Herbert Hoover Dike in Florida as a Dam Safety Action Classification (DSAC) 1 dam, and started the implementation of one of the largest dam rehabilitation projects in the nation. The construction of the cutoff wall is a key feature of this rehabilitation work to upgrade the dike to current dam safety criteria. The cutoff wall installation is currently being completed on Reach 1, which extends from Port Mayaca to Belle Glade, under a Multiple Task Order Contract based on performance specifications and stringent verification criteria.For the construction of the cutoff wall TREVIICOS selected the self-hardening slurry method. Since the cutoff wall is installed through a layer of highly variable limestone with Unconfined Compressive Strength (UCS) up to 14,000 psi, the excavation requires the use of the hydromill equipment. This is the first successful application of the hydromill technology with self-hardening slurry in a large scale project in the US. This paper presents the details of the method utilized, the quality control procedures, and the experience gained over seven miles of cutoff wall installed.INTRODUCTIONProject LocationThe Herbert Hoover Dike (HHD) system, around Lake Okeechobee in South Florida, consists of a series of levees, culverts and locks and is approximately 143 miles long (Figure 1).Lake Okeechobee is the second largest freshwater lake in the lower 48 states of the United States. The lake is the primary drinking water source for numerous communities around the lake and to millions of people living along the lower east coast. The lake is also a vital source of irrigation for the agricultural industry in the South Florida region.Lake Okeechobee is 33 miles wide from north to south and 30 miles wide from east to west and has a surface area of 730 square miles. The average water depth of the lake is 9 ft."

Jan 1, 2017

By Kerina Taylor

Due to their high amount of stored energy, explosives have been the cause of many serious injuries and fatalities over the last centuries. Despite safety advances and awareness in the last decades, injuries and fatalities continue to occur at mining operations due to blasting. According to the National Institute for Occupational Safety and Health, from 1978 to 2001, blasting incidents claimed 106 lives and were responsible for over 1000 injuries in mines in the US. The main causes of incidents found today are flyrock, blast area security and premature detonations. The concerted efforts of the mining and explosives industries and labour and government agencies have greatly improved the safety record of blasting in mines.

Jan 1, 2011

By T Walton, C Perring, M Pepper, G Gerber

The Yandicoogina Channel Iron Deposit (CID) is an accumulation of iron pisolites cemented by a goethite-rich matrix. The Yandicoogina CID’s are found in a palaeochannel that meanders within a broad structural basin of the Yandicoogina Syncline in Pilbara region of Western Australia. RTIO Yandicoogina Mine Geology team contributed to a number of strategies maximising the iron ore reserves mined by Rio Tinto. Two strategies are discussed: the replacement of the Batter-Berm final pit walls by contour dozing; and upgrading the lower grade material to crusher feed. 1. Contour dozing – traditional Batter-Berm pit final wall configuration left kilometre long wedges of ore sterilised around bench margins. Contour dozing final walls (ie dozing of ore down the ore-waste contact) as internally defined by RTIO Yandicoogina Mine Geology (Mine Geology), enabled recovery of additional crusher feed. 2. Upgrade of lower grade material – the lower ore domain (GVL) within the Yandicoogina orebody contains numerous clay pods. Contaminant Al2O3 inherent within clay pods can result in CID material outside of crusher feed grade specifications, causing it to be flagged as ‘internal waste’ in mining models and permanently lost to waste dumps. In 2011, after multiple tests, Mine Geology demonstrated that this material could be upgraded to crusher feed via wet processing. With the support of the RTIO Metallurgical Development team new grade specifications were defined. The resulting material has been used to supplement higher grade ore. While increasing the mining ore output, these ongoing value-adding strategies also promote more sustainable mining via better use of the non-renewable iron ore commodity. The initiatives extend mine life, reduce waste movement, improve strip ratio and increase productivity

Mar 22, 2022

By J. M. Whatley

"IntroductionIN UNDERGROUND mining operations, the mine hoist has become one of the most important and one of the most expensive single pieces of equipment. As the means of transporting men and materials to the face, broken ore to the mill, and waste to the dump, it is often the very lifeline of a mine and must operate with dependability and efficiency or the whole operation will suffer. The mine hoist has become synonymous with safety. In few other types of mechanical equipment do so many men so frequently and completely place their lives. In Canada, more has probably been done to assure safe hoisting than in most other countries, but, unfortunately, this has resulted, in many cases, in the mines having to pay a high price for equipment. Hoist manufacturers have carried out much research in recent years in the endeavour to keep down these costs and at the same time maintain or improve the efficiency and safety of their products. Broadly classified, the bases for design research are dependability, efficiency, safety, and first cost.Probably the greatest single factor influencing the design of mine hoists was the introduction of electric motor drives. It was not until about 1905 that an effective start was made in the development of electric mine hoists, and then only with machines of small size. From that time on, however, progress was rapid, as may be gauged from the fact that by 1910 one large group of mines in Johannesburg had in use, or on order, fifty-four three-phase hoists and four Ward-Leonard. type hoists."

Jan 1, 1953

By O. C. Ralston

The Bureau of Mines has under development on a technical scale an electrolytic process for treating oxidized ores of zinc , using caustic soda as an electrolyte . Whereas the Bureau process can alternately make either solid zinc or zinc dust , the following paper , from the Ludwigshafen research laboratory of the well -known I. G. Farbenindustrie , A. G. , of Germany, deals only with production of zinc dust from sodium zincate solutions and may well serve as introduction to the subject for American metallurgists . The Bureau of Mines pioneered in the idea ; a study on laboratory scale by H. J. Morgan and 0. C. Ralston was made early in the First World War, and published in Transactions of the American Electrochemical Society . The Eckardt paper , translation of which follows , goes more thoroughly into the preparation of electrolytic zinc dust , and later publications of the Bureau of Mines will deal with broader details and application of the idea to treatment of lowgrade ores and metallurgical intermediates , which is the point where Eckardt left off . 4 The Eckardt report became available through operations of Field Information Agency , Technical ( FIAT ) of the Office of Military Government for Germany (US ) , which made bibliofilm copies of the files of internal technical reports of many of the German industrial establishments , Eckardt's report is dated April 1939 and was taken on FIAT Microfilm Reel MM 106 , frames 82-101 , which is on file as Publication Board Document 41411 in Office of Technical Services of the U. S. Department of Commerce , Washington , D, C , Eckardt points out that the normal source of zinc dust is the blue powder of the zinc retorts , which decreases in volume every year owing to technologic improvements in zinc smelting. I. G. saw the importance of making a

May 1, 1948

By Anthony J. Deevy

"Abstract -The Magino gold mine is located 45 km northeast of Wawa, Ontario. There was limit­ ed gold production in the Iate thirties. The present operation was officially opened in October 1988 and produced gold until September 1992. It was a 635 tonnes per day, decline-accessed mine, with ore coming from several small blast hole and shrinkage stopes.The host for the gold is the Webb Lake granodiorite stock which was intruded into the Goudreau Lake Deformation Zone. This east-northeast-striking deformation zone overprints the generally east­ west-striking isoclinally folded metavolcanic and metasedimentary rocks, which make up the east end of the Michipicoten greenstone belt. The ore-shoots are controlled by dextral delatancy associated with the Goudreau Lake Deformation Zone. Shearing, bleaching and silicification accompanied the gold emplacement."

Jan 1, 1994

By Mario Mauro

In 2007 the US Army Corps of Engineers classified the Herbert Hoover Dike in Florida as a Dam Safety Action Classification (DSAC) 1 dam, and started the implementation of one of the largest dam rehabilitation projects in the nation. The construction of the cutoff wall is a key feature of this rehabilitation work to upgrade the dike to current dam safety criteria. The cutoff wall installation is currently being completed on Reach 1, which extends from Port Mayaca to Belle Glade, under a Multiple Task Order Contract based on performance specifications and stringent verification criteria. For the construction of the cutoff wall TREVIICOS selected the self-hardening slurry method. Since the cutoff wall is installed through a layer of highly variable limestone with Unconfined Compressive Strength (UCS) up to 14,000 psi, the excavation requires the use of the hydromill equipment. This is the first successful application of the hydromill technology with self-hardening slurry in a large scale project in the US. This paper presents the details of the method utilized, the quality control procedures, and the experience gained over seven miles of cutoff wall installed.

By Marcus Daubner, Karsten Beckhaus, Florian Bauer

The construction industry can and needs to contribute to a more sustainable world. Accordingly, geotechnical works potentially have a significant share. In this context, Bauer understands “sustainable products for geotechnical works” as those that may cause less emissions and increase the sustainability of construction activities. In order to structure the efforts and systematically pursue sustainable targets in the construction sector, and in the specialist foundation industry, the “17 sustainability goals” presented by the United Nations in their AGENDA 2030, can be used for general guidance and for continuous improvement. Benchmarks for relevant economic and social objectives, mainly with environmental aspects, are inevitable. The key parameter to sustainable products for geotechnical works in the focus of this paper is the optimisation of processes on site needed to fulfill the client’s building task, including the selection of technologies and construction methods with minimum environmental impact and minimum carbon footprint.

May 1, 2022

By P. K. Lucke

ONE of the interesting features connected with the great continental uplift, which formed the table land of Mexico, is the great depth to which oxidation and secondary enrichment of orebOdies occurred. This table land lies at altitudes ranging from 4000 to. 7000 ft. (1219 to 2133 m.) above sea level. Several cases could be cited of oxidized zones in copper and lead mines which reached depths of upward of 1500 ft. (457 m.) below the surface, and it is universally admitted that the oxidized zone in a mine is limited by the permanent water level. FIG. 1. Mexico, however, like many other countries in which deserts occur, is visited at rare intervals by tremendous floods, which sometimes cause variable water levels over long periods. The following cases bear out the idea, and lead to interesting conclusions of commercial value. My paper demonstrates that carbonates of ores may occur below water level and sulphides above, and I will endeavor to explain the causes of the phenomena in certain specific instances.

Jan 6, 1918

By Lyman H. Hart

Some of the significant facts that will affect the supply and demand for metals during the next few decades are given in this presentation. This is important because the only hope for intelligent guidance of the national destiny depends upon presenting a consistent and accurate picture of basic problems. The metals problems now fomenting are only slightly less important than those precipitating the energy crisis. Admittedly, it is difficult to generate serious thinking on this subject when the world is enjoying easy access to all metals at modest prices. This is possible because of the current world capacity to over-produce, and United States credit standing, at least up to now, has permitted buying freely on world markets. Although both these vital conditions are subject to change, there is little doubt that if the U.S. financial house is kept in order, we can muddle along for a while on a generally expanding, metal-based economy. But should our credit standing be permitted to collapse, or should there be a tightening of world supplies of metals, the nation would immediately find itself in trouble. Unfortunately, clear signals indicate that both of these conditions are threatening. The metal age started many centuries ago, and with the exception of the noble metals, barely a dent was made in world reserves until the present century. Then, as a result of the pioneering ideas of D. C. Jackling and Paul Gemmel, and the willingness of the McNeals, Penroses and Guggenheims to back ideas with money, a virtual explosion of metal production was propagated throughout the world. It is important to examine the causes of this expansion to determine whether it is a trend that may be sustained or whether it is anomalous and therefore attributable to circumstances not likely to be repeated or continued. This period of plenty is a once only phenomenon. Vast metal resources have been sitting around here for eons, while the world was unaware of or unconcerned with their existence. But when population began to grow exponentially, and ways were discovered to use metals to develop machines to do the work of men and animals, the exploitation of raw materials increased at a staggering rate. And now the realization is dawning that minerals are a wasting asset and are beginning to present supply problems that should begin to be of concern. Two main factors have caused this condition; One is the population growth, and the other is the expanding demand for irreplaceable raw materials as nations become more developed. A group of systems analysts, at Massachusetts Institute of Technology in a book Limits of Growth, has warned that at present rates of population growth and resource consumption together with environmental constraints, a point will be reached within 100 years when the world population will become totally incapable of supporting itself. The authors conclude that this end result could be avoided if a planned equilibrium could be established at a lower rate of population growth and resource consumption. Fortunately, there is evidence that the population problem is moderating. The growth rate in the U.S. has decreased from 2.3% per year in 1900 to 1.1% in 1970. But, even at the lower rate, population will double in 70 years. The world rate is greater, and if it continues, world population will rise from 3.5 billion to nearly 10 billion in 50 years. All of these projections are questionable because the dangers of growing population are now being recognized. A marked decrease in growth rate has been noted in the more developed countries-in fact, it was zero in the U.S. in 1972. The other factor affecting consumption of raw materials is the increase in per capita use of most items as individuals become more affluent. Many economists believe that developing countries such as China and India represent a vast future potential market; but there are others, with whom the author agrees, who believe over-population tends to stagnate development. Nevertheless, it is a fact that vigorously developing societies increase consumption at a rate far above their population growth rate.

Jan 1, 1974

By D. A. Pirttinen

The promotion of improved coal quality for thermal generation can benefit our national economy. The construction of electric generating facilities in Canada is expanding at a rapid rate to satisfy the demands of a rising population and new uses for electrical energy. With remaining economic water power resources in the process of development, generation from thermal sources continues to grow. The increase in thermal capability has been somewhat arrested by a de-pressed economy, widening of inter-provincial and state transmission networks and decisions to exploit certain water resources before high capital investment is further in-creased by rising construction costs. The introduction of extra high volt-age transmission lines will further delay thermal generation planning, but in due course, when the effects of restrictive factors have been dissipated, steam-electric generation from fossil fuels will rise to considerable proportions. In time, nuclear sources will contribute a growing share to thermal power, but, it is doubtful if nuclear participation will ever displace conventional fuels for steam rising, unless it can be adapted to operate efficiently for variable outputs in peaking service. It appears certain that fossil fueled

Jan 1, 1961

By A. Monballiu, J. A. Martens, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, B. Meesschaert

In this work, bioleaching of non-sulphidic materials by applying chemoheterotrophic bacteria and fungi is studied. It was found that the tested fungus, Aspergillus niger, leached substantially more nickel from olivine than the tested bacterium, Bacillus mucilaginosus. A. niger also outperformed fungal species Humicola grisae and Penicillium chrysogenum in the leaching of olivine. Contrary to traditional acid leaching, the microorganisms leached nickel preferentially over magnesium and iron. On average, a selectivity factor of 2.2 was achieved for nickel compared to iron. This can potentially facilitate postprocessing of the leach liquor and reduce the cost. The impact of ultrasonic conditioning on bioleaching was also tested, and substantial increase in nickel extraction with A. niger was observed. This was credited to an increase in the fungal growth rate, the promotion of particle degradation, and the detachment of the stagnant biofilm around the particles. Furthermore, ultrasonic conditioning enhanced the selectivity of A. niger for nickel, resulting in a selectivity ratio for Ni/Fe equal to 3.5. The chemical resistance of the selected microorganisms to several heavy metal and metalloid (As(III,V), Cd, Cr(III,V), Ni, Pb, Zn) was evaluated. It was found that, with the exception of As(v) and Cd, A. niger has high tolerance to these components. Therefore, this biohydrometallurgical route can potentially be applied to non-sulphidic wastederived materials, such as industrial slags, ashes and sludges.

Jan 1, 2014

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1954 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 101 samples of aviation gasoline. Data also are given for 30 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers I 1954 production in their laboratories and the results submitted to the Bureau of Mines for compilation. The products of 19 manufacturers of aviation gasolines and of 15 producers of aviation jet fuels are represented.

Jan 1, 1955

By Mauricio Guimarães Bergerman

At the regrind or secondary grinding stages of base metal ores, the concern about energy efficiency is usually extremely important. In general, the specific energy consumption at this stage is higher than during the primary grinding stages. In addition, a tendency of finer grinding has been observed in the new projects of metallic minerals, due to the finer mineral liberation, which leads to increasing capital and operational costs. At Vale?s new copper projects in Brazil, regrind sizes with a P80 of approximately 40 to 20 µm have been necessary. Conventional ball mills, adequate for primary grinding, usually bring about low energy efficiency with products bellow 50 µm. Vale is using the vertical mill on its copper projects ? Sossego and Salobo, in order to optimize the regrind of rougher concentrates and reduce energy consumption. This paper presents the results of industrial surveys carried out on the Vertical mill circuits of Sossego plant during its initial years of operation, and compares these results with the design criteria and laboratory regrind tests used for the mill scale up. Keywords: grinding, regrinding, copper, vertical mill, stirred mill

Sep 1, 2012

By William Hall

THE product obtained by roasting stibnite is likely to contain some unoxidized antimony trisulphide and a mixture of antimony trioxide and antimony tetroxide. It was desired to determine, as accurately as possible, the condition of the antimony as well as the total quantity present. Attempts were made to separate the trisulphide and the two oxides by methods based upon their varying solubilities in different solvents, but no satisfactory results were obtained in this way. It was found, however, that by determining the total antimony content, the antimony present as trioxide, and the antimony present as trisulphide, a good idea of the chemical composition of the roasted product could be obtained. The total antimony was determined by dissolving the sample in concentrated hydrochloric acid, reducing the antimony entirely to the trivalent condition by means of hydriodic acid and eventually titrating the antimony back to the pentavalent condition by means of iodine in the presence of sodium bicarbonate.' The details of the procedure are as follows: Weigh out 0.25 gram of the roasted product into a trapped flask (Fig. 1), add 4 grams of powdered tartaric acid, 2 grams of potassium iodide and 40 c.c. of concentrated hydrochloric acid. Boil the solution gently for 5 min. and then cool to room temperature by shaking the flask while holding it under running water. Then, very carefully discharge the iodine color by the cautious addition of 0.05-normal sodium thiosulphate solution, adding a little starch toward the last. Nearly neutralize the acid with ammonia solution, but leave the solution distinctly acid. Pour the slightly acid solution into 200 c.c. of water con-

Jan 1, 1916

By William Rachunis

This publication describes the construction of 43.64 miles of underground tunnel to be used as an aqueduct, known as the West Delaware aqueduct. In the past, the accident history of tunnel operations has not been favorable, the "rule of thumb" being a death for each mile of progress, according to the meager accident statistics available for the tunnel-driving industry. The accident experience at this project and the use of modern equipment established safety and progress records that were accepted by tunnel people as a record at the time. The city of New York comprises 5 boroughs, with a total population of approximately 8 million people, and uses about 1,210 million gallons of water each day. The water supply for the city is the responsibility of the New York City Board of Water Supply. This organization has constructed an extensive aqueduct system, the Delaware aqueduct, to convey water to the city from the distant mountain and river sources in the Catskill Mountains in the Southern Tier areas of New York State (figs. 1 and 2).

Jan 1, 1962