Search Documents

By Enid C. Plante

To extend our knowledge of the flotation behavior of sulphide minerals, the response of the following minerals to ethyl xanthate as collector was studied by captive bubble and cylinder flotation tests: antimonite (Sb2S3), arsenopyrite (FeAsS), covellite (CuS), rnarcasite (FeS2), orpiment (As&.), pyrrhotite (FeS) and tetrahedrite (4CU2S, Sb2S3). Lollingite (FeAs2) was also exarnined to determine if its behavior could be correlated with that of pyrite or rnarcasite (FeS2. Experimental Method Mineral for Flolation and Contact Tests Mineral was prepared in the manner a1ready described1 and its behavior both freshly ground and "oxidized" was studied. Tests in which the mineral was allowed to oxidize for various periods showed that a uniform response to xanthate was reached in two days or less. Oxidation Products The soluble oxidation products from most of the above minerals were measured and their effect on the flotation of the mineral studied. The mineral samples were wet ground to minus-52 mesh and deslimed, and 20 g of this material placed in 200 ml of distilled water of a measured pH value, and CO2-free air bubbled through each suspension at a constant rate (about I bubble/sec) for 5 days. It has been shown1 that the size of the mineral is unimportant in the rate of formation , oxidation products and that probably the supply of oxygen to the mineral is the rate-determining step. At the end of 5 days the pH value of the 'supernatant liquid was measured again, the mineral filtered off and the soluble products determined. Methods for estimation of sulphur acids, ferrous and ferric iron and copper have already been described.l No satisfactory method was found for antimony. Arsenic was estimated as the arsenate.2 Flotation of "Unoxidized" Minerals with Ethyl Xanthate as Collector Fig I to 3, 4. 6, show the effect of alkali and cyanide as depressants for the minerals with 25 mg potassium ethyl xanthate per liter as collector at 35°C. Wark and Cox8 have shown that with ethyl xanthate as collector, galena, pyrite and chalcopyrite show a greater tolerance to cyanide and hydroxyl ions at room temperature than at 35°C Covellite (Fig I), marcasite (Fig 2) and pyrrhotite (Fig 3) behave similarly. The independence of the curves for pyrrhotite at 35°C with respect to cyanide

Jan 1, 1949

By R. Blickensderfer

Several thin film absorber stacks with spectrally selective characteristics were developed by the Bureau of Mines. The stacks consisted of a silicon thick film or a zirconium compound thin film on a reflective thin film of silver. The zirconium absorber films, with the general formula ZrCxOyNz, were prepared by reactively sputtering zirconium or zirconium carbide in argon with small amounts of oxygen, nitrogen, or both, or by oxidizing zirconium films in air. A few similar types of films were prepared from titanium. The short-wave absorptance over the solar spectrum, a(s), and thermal emittance at 600 K, e(600 K), of the solar absorber stacks were calculated from room-temperature reflectance data. The values of a(s) ranged from 0.47 to 0.93, e(600 K) from 0.49 to 0.034, and the ratio a(s)/e(600 K) from 1.7 to 34. The specimen with the best combination of properties, a ZrNx-Ag stack, had a solar absorptance a(s) of 0.85 and a ratio, a(s)/e(600 K), of 24. The effect of film thickness and composition on spectral selectivity was determined. An emissometer for measuring normal total emittance up to 800 K and a method for determining a (s), e(T) (hemispherical), and a(s)/e(T) using simulated solar radiation are described. A calorimetric method for measuring a(s) and e(T) (hemispherical) at elevated temperature is also described. Measurements made on several specimens agreed favorably with calculated values.

Jan 1, 1976

By David Arana

The use of gas-water dispersion of a molten material flow onto a vibrating surface is developed as a process to minimize water pumping requirements, minimize the risks of explosions, and minimize the post solidification dewatering and fines handling equipment requirements. The process uses existing vibration transport technologies and common plant utilities. Plant trials using the smaller footprint and the progressive molten particle cooling time have yielded encouraging results. The results are analyzed and reported.

Jan 1, 2006

By G. Delagrammatikas, M. Karmis, J. Mastoris

The evaluation of raw materials in terms of quality profile, mineralogical character and mechanical properties is of great importance to the cement industry. The variability of their chemistry and structure is among the decisive design parameters in the choice of any mining, handling and preblending systems. Furthermore, clinker and cement production require sound estimates of the above parameters, to help produce some appropriate and realistic raw mix configurations and achieve minimum standard deviation of the major components. This paper addresses this subject from the perspective of a cement producer and presents the principles of a methodology aimed at optimizing mine planning and process design. Finally, results from case studies on actual sedimentary deposits currently in operation are discussed.

Jan 1, 2002

By Ivan José de Santana

Neste trabalho, as diferentes microestruturas, as propriedades mecânicas e a soldabilidade do ferro fundido submetido aos processos de soldagem SMAW, com a utilização de eletrodos de Fe-Ni, e GMAW mecanizado, com a aplicação de arame de Fe-Ni e proteção de Ar-25%CO2, foram investigadas e comparadas. Dentro deste contexto, após a realização de testes de soldagem, com e sem a aplicação de pré-aquecimento, utilizando diferentes parâmetros de soldagem, os cordões de solda foram avaliados por meio de microscopia óptica e microscopia eletrônica de varredura, assim como pela análise dos perfis de micro-dureza e da composição química do arame e do material depositado. Foi possível avaliar a influência da aplicação de diferentes parâmetros elétricos de soldagem, a utilização ou não de pré-aquecimento nas microestruturas geradas nas zonas fundidas, parcialmente fundidas e termicamente afetadas dos cordões obtidos, assim como as propriedades mecânicas.

Aug 8, 2018

By Jae-Chun Lee, Sadia Ilyas

We investigate the technical feasibility of bioleaching of metals from low grade sulphidic ore. Experiments were conducted with an adapted consortium of Sulfobacillus thermosulfidooxidans and Thermoplasm acidophilum in batch bioreactors (1.5 L), small columns (10 kg ore load, 8 % S0 sludge) and large columns (80 kg ore load, 12 % S0 sludge). Approximately 83 % Ni, 85 % Cu, 55 % Fe and 81 % Zn was leached out in batch mode while 93 % Ni, 89 % Zn, 81 % Cu and 65 % Fe was leached out in column reactors. Bioleaching potential improved by acid pre-leaching, adaptation of microbial consortium and periodic bleeding of effluents.

Jan 1, 2014

By Chuanlin Fan

The process of flotation separation and recycling of spent potlining (SPL) was described. On the basis of the laboratory investigations, the effects of influencing factors in froth flotation process, such as grain size, flotation agent dosage, pH value, pulp density, and dissolved components concentration, etc, were carefully studied. And the influence on environment of the process was also discussed. It was found that flotation separation can be used as an environment-friendly method for treatment of SPL residue. Carbon and other compounds (include cryolite, sodium fluoride, calcium fluoride and diaoyudaonite, etc.) from SPL were separated and recycled as flotation products respectively.

Jan 1, 2009

By G. Deissman, S. Kistinger

For the last 15 years environmental Life-Cycle Assessments (LCA) have increasingly been used to evaluate the environmental performance of industrial processes and products and have been employed as a basis in decision making processes in the public and industrial sector. However, assessment methodologies for environmental protection measures and reclamation/remediation measures with respect to their consumption of natural resources are generally poorly developed. In this presentation a methodology for LCA of environmental protection measures and remedial actions, respectively is suggested, using the remediation/reclamation of mining sites as an example. Key aspect of this approach is the development of an evaluation method appropriate for environmental protection measures, which links the various impact indicators recognised in the impact assessments and allows their integrated assessment.

Jan 1, 2005

By Wayne A. Charlie

An experimental test program being conducted at Colorado State University and involves the study of the behavior of water saturated sands under shock and explosive loadings. The study is being conducted to evaluate potential blast induced changes in dynamic soil properties, soil shear strength loss (liquefaction) and densification of water saturated sands under single and multishock loadings. This paper presents testing and measurement objectives, and the equipment and instrumentation developed to load, measure, record and analyze the transient and long term soil behavior. The laboratory shock facility is capable of generating multi-shock pulses with milli-second rise time, peak stress amplitudes of up to 35,000 KPa (5000 psi), peak particle velocity of 5000 cm/set and peak acceleration of 10,000 g. The field explosive facility subjects saturated soil to controlled explosive loadings. Of major interest is the soil strain and water pressure, both during and after the passage of the stress wave, as a function of peak particle velocity, peak strain, loading rate, soil density, initial confining stress and the number of loadings. Based on data obtained to date, soil densification is due to consolidation following liquefaction.

Jan 1, 1991

"The 33rd annual American Mining Hall of Fame Awards Banquet and Fundraiser sponsored by the Mining Foundation of the Southwest (MFSW) will be held at the JW Marriott Tucson Starr Pass Resort & Spa on Saturday, Dec. 5, 2015. Each year, one living Hall of Fame inductee, two Medal of Merit recipients, several honorees from Mining’s Past, an Industry Partnership Award and a Special Citation are recognized for their respective contributions to the mining industry.Conrad E. Huss, cofounder of M3 Engineering & Technology Corp. located in Tucson, AZ, will be honored as the 2015 Hall of Fame Inductee and will serve as the keynote speaker at the awards banquet. Huss has served his company as chairman of the board for its entire 30 years and guided M3 to become a full discipline firm. Now M3 offers complete project execution through engineering, procurement and construction management procedure and has become a major engineer of large observatories around the world. The company now has more than 1,000 employees with offices in Arizona, North Carolina, Mexico, Argentina and is incorporated in Guatemala, Peru and Canada.The Medal of Merit will be awarded to Charles Michael (Mick) Lownds, founder of his eponymous consulting firm in Salt Lake City, UT, for his 42 years in commercial explosives following tenure at Sasol and at Orica. Originally from South Africa, Lownds immigrated to the United States in 1998 and has made significant advancement on electronic initiation systems. Lownds has published numerous technical papers, is an inventor with 12 awarded United States patents and was also the recipient of the President’s Award from the International Society of Explosives Engineers in 2000.Medal of Merit for young professionals will be awarded to Fiorella Giana, Freeport- McMoRan Inc.’s (FCX) mine manager at Bagdad. Born in Buenos Aires, Argentina, Giana left the small cattle farm where she was raised in 2001 to pursue higher education in the United States. For the past decade at FCX, as a result of her extraordinary combination of technical skill, leadership and commitment to excellence, she has been given positions of progressively greater responsibility from an entry level engineer to senior mine engineer, to chief engineer and now as mine manager, a position rarely held by woman."

Jan 1, 2015

By Ralph H. Espach

In the spring of 1943, when it was evident that the Tensleep sandstone in the Elk Basin field, Wyoming and Montana, held a large reserve of petroleum, Bureau of Mines engineers obtained samples of oil from the bottom of nine wells and analyzed them for such physical characteristics as the volumes of gas in solution, saturation pressures or bubble points, shrinkage in volume caused by the release of gas from solution, expansion of the oil with decrease in pressure, and other related properties. The composition of the gas in solution in the oil was studied. The pressures and temperatures existing in the reservoir and the productivity characteristics of the oil wells were determined. The data obtained indicate that the oil in the Tensleep reservoir of the Elk Basin field has unusually varying physical characteristics, such as a saturation pressure of 1,250 pounds per square inch absolute and 490 cubic feet of gas in solution in a barrel of oil at the crest of the structure, and a saturation pressure of 530 pounds per square inch absolute and 134 cubic feet of gas in solution in a barrel of oil low on the flanks. The hydrogen sulfide content of the 6a r; in solution in the oil varies from 18 percent for oil on the crest to 5 percent for oil low on the flanks of the structure. Of even greater significance is the fact that these and other variable characteristics of the reservoir oil are related to the position of oil in the structure. Many geologists and petroleum engineers have considered all the oil in a petroleum reservoir to have uniform physical characteristics and that equilibrium conditions prevailed in all underground accumulations of oil and gas. That such is not always so is borne out by the results of the study made by the writers.

Jan 1, 1951

By P. Linzer, L. M. Linzer

The gravity method is often applied in mining-related scenarios such as geological and mineral exploration, detecting subsurface cavities and voids (“receptacles”) that may become sinkholes, siting of surface structures, fault-mapping, and more. It is also widely applied in geotechnical engineering to map subsurface karst profiles and to detect subsurface cavities, such as can occur in open pit mines. While it is widely acknowledged that, compared with other available geophysical methods, this method is the most applicable to the karst profiling problem, survey geometries applied in the field are often far from optimal. The gravity surveying specifications prescribed in SANS 1936 omit some key requirements for optimal survey outcomes, and this paper is intended to fill those gaps. The authors have seen scopes of work that require only a few measurements over the footprint of a proposed structure, indicating a lack of understanding of the nature of the gravitational field. A single gravity measurement is subject to the camouflaging effects of several influences, many of which can be larger than the anomaly caused by the subsurface density variation itself. Papers in the body of literature show an awareness of the need to map the regional field so that it can be subtracted to unmask the residual gravity anomaly, but rarely do they examine how instrument sensitivity governs the size of detectable anomalies or discuss how a detailed terrain correction can be instrumental for isolating faint targets. This paper aims to explain how to apply the gravity method correctly to mining and geotechnical problems, specifically in the detection of subsurface cavities. It discusses various factors to assist with optimising the acquisition of gravity data and its processing so as to maximise the practical value of gravity surveys.

Sep 1, 2025

By Saieb Haddad, Henry Pate

"Building retaining walls in an urban area is becoming more difficult due to right-of-way restraints. Using standard concrete cantilever walls requires a construction easement behind the walls for installation, which for the most part is unavailable. To install these types of walls in a limited right-of-way requires extensive temporary walls to minimize the construction easement. Top-down construction walls utilizingtie-back anchors for support require either the purchase of the right-of-way or underground easements in the area of the anchors.These problems faced the Department on Interstate 75 widening in Knoxville, TN in an area of a large cut. A multi-story Insurance Building and a large commercial Retail Center were located at the top of the cut. To prevent any impact on the buildings, the walls had to be placed within a limited area. The option of buying the properties was prohibitively expensive. Due to the height of the two walls and the variability of the underling rock line, contiguous caisson pile cantilever walls were contemplated as the only wall type that would be appropriate. The cost of the two walls was estimated to be very close or even higher than the cost of purchasing the two buildings. The Department believed that there must be a better way to deal with the problem. A vertically tied-down pile frame wall constructed from the top-down with a concrete facing was developed. This allowed the construction of the walls to be restricted to the available limited area and provided substantial savings for the State.INTRODUCTIONThe widening of I-40/75 has been a major transportation project in the Knoxville area which is being constructed by the Tennessee Department of Transportation. The project includes 18 Retaining Walls and 13 Bridges.Two of the 18 Retaining Walls, refer to Figure 1, are to support two valuable properties, one being an insurance company housed in a multi-story office building and the other a suburban shopping center which were appraised at $13.0 million and $5.0 million respectively. Due to the 31 ft. (9.5m) maximum height of each of the two Retaining Walls and the limited Right-of- Way of 15.0 feet (4.6m), a contiguous caisson pile cantilever wall was proposed for each of the two retaining wall sites with an estimated cost of $12.0 million each. The contiguous pile cantilever Wall is comprised of a line of caisson piles socketed into underlying competent bedrock. The design required that 4 ft. (1219mm) dia. piles be installed at 6 ft. (1.83m) centers, socketed into rock in order to provide lateral stability and restrict lateral wall movement to acceptable limits. The line of caissons would be fronted with a cast-in-place concrete face wall"

Jan 1, 2007

The mining industry continues to faces significant challenges due to increasing resource constraints (quality of ore bodies, water, energy, human resources) and increasing license to operate requirements (safety, health, environment, location) from society, employees and shareholders. Technology advancements and hence research are necessary to ensure that the industry remains viable in this changing environment. Collaborative research is an important part of a company's research portfolio and offers the opportunity for the industry to work on generic issues that it is facing. Obvious benefits include the reduced cost to individual companies by sharing the costs, the opportunity to leverage government funding and the opportunity to conduct longer term projects resulting in skills development (PhD and MSc). Limitations of collaborative research include the reduced focus on company specific issues and the loss of competitive advantage from owning the outcomes of the research. The challenge for researchers and research managers is for them to demonstrate the value derived from longer term, pre-competitive collaborative research. The competitive advantage is not necessarily derived only from the outcomes of the research but rather from the company's ability to direct the research, translate the generic research outcomes to address company specific issues and to implement improvements at its operations. Implementation remains the greatest challenge. In this paper, case studies of selected collaborative research projects are presented to demonstrate key success factors required for implementation of research outcomes. This is an ABSTRACT ONLY. A full-length paper was not prepared for this presentation.

Sep 13, 2010

The Kaiser Aluminum and Chemical Corp. announced plans to raise June ingot prices by 4 cents to 57 cents per pound. Producers? April value for 99.5 percent unalloyed aluminum ingot was at 53 cents per pound. Domestic merchants last month were quoting the metal at 48-49 cents per pound. Primary aluminum producers began restarting production facilities following the settlement of the coal strike. Noranda Aluminum Inc. recalled workers to prepare potlines for production at its plant at New Madrid, Mo., which had closed February 14, 1978 due to the shortage of coal. Eastalco Aluminum Co. resumed full capacity production at its Frederick, Md. smelter where production had been cut by 30 percent. Anaconda Aluminum Co. resumed full capacity production at its Sebree, Ky. smelter.

Jan 1, 1978

By Gustavo Henrique Bolognesi Donato

Ensaios de curva R (J vs. ?a – crescimento dúctil de defeitos) e de propagação de trincas por fadiga (da/dN vs. ?K) são balizados por normas como a ASTM E1820, ISO 12135 e E647, as quais exigem dimensões mínimas para as amostras C(T) ou SE(B) a fim de garantir condições SSY e portanto a validade de K e J. Entretanto, tais exigências usualmente conduzem a dimensões expressivas que dificultam a retirada de amostras de chapas finas ou mesmo de muitas estruturas reais. Como alternativa, estudos de Koppenhoefer e Dodds (1998) e mais recentemente de Shin e Lin (2012) indicaram a possibilidade de uso de amostras em miniatura (inclusive Charpy contendo pré-trinca) para determinação de curvas R e da/dN vs. ?K. As grandes questões são a viabilidade de ensaio de amostras pequenas com repetibilidade e a adequada avaliação dos limites de validade das forças motrizes nestas geometrias, a fim de garantir condições de similitude. Como um passo nesta direção, este trabalho investiga o potencial de amostras Charpy pré-trincadas (10x10x70mm) na determinação de curvas R e da/dN vs. ?K. Inicialmente, ensaios de ambos os tipos foram realizados em amostras de um aço estrutural ferrítico empregando uma máquina universal MTS 810. Apesar das dimensões reduzidas dos espécimes, os ensaios se mostraram viáveis e apresentaram boa repetibilidade e estabilidade dos resultados experimentais. Ainda, boas práticas de ensaio puderam ser estabelecidas para suportar os trabalhos futuros com tais geometrias.

Aug 8, 2018

By Gilmar Zacca Batista

The present work is a part of a comprehensive program that aims to evaluate the girth welding procedures for heavy wall API 5L X65 pipes produced for sour service applications. This article describes the results of toughness, strength and sour resistance of girth welds produced with different welding consumables. The methodology applied included girth welds production with GTAW process for root pass using ER70S-6 consumable and FCAW process for filling passes using E71T- 1CJ and E91T1-GM-H4 consumables. Mechanical tests of Charpy, CTOD, tensile, hardness and stress corrosion cracking were also performed. The E71T-1CJ resulted in a girth weld with tensile and yield strength around 7% lower than the pipe. However, according to the papers analyzed at this study, a value up to 10% of undermatching could be acceptable. The CTOD and Charpy tests showed good toughness and weld metal embrittlement was not observed. The hardness and the stress corrosion cracking tests demonstrated that the consumable ER70S-6 is suitable for sour service. All properties evaluated met the requirements specified by the onshore pipeline standards, showing that the consumables ER70S-6, E71T-1CJ and E91T1-GM-H4 are suitable for the welding of heavy wall X65 pipe with sour service and toughness requirements. If an overmatching is required, the E91T1-GMH4 shall be used to assure a strength overmatching and prevent plastic strain concentration at the weld metal. The results provided by this paper can be used for consumable selection and for welding procedure qualification of pipelines construction when heavy wall API 5L X65 are used for sour gas transportation.

Aug 16, 2017

The purpose of this study was to investigate the immobilization as a host for metallic pollutants (Cr, Cu, Pb, and Zn) by ettringite phase. Ettringite phase is produced through hydration reaction of calcium aluminate with gypsum. From the XRD patterns, it is known that the distance between spaces in 010 planes in ettringite crystal increase with an increase of ionic radius of heavy metal except Pb; no big difference is shown. For this reason, the d-value of 010 planes in ettringite crystal increased with the substitution of Cr, Cu and Zn having a big Al ironic radius. But in case of Pb, because the substitution occurred at calcium site, it does not influence to increase d-value of 010 planes.

Jan 1, 2006

By R. Hogg, Y. Lee, D. E. Rannels

"Lee, Yu-Chen, Richard Hogg, and D. Eugene Rannels. Extracellular matrix synthesis by coal dust-exposed type II epithelial cells. Am. J. Physiol. 267 (Lung Cell. Mol. Physiol. 11): L365–L374, 1994.—Although integrity of the alveolar basement membrane may influence progression of lung injury induced by inhaled particulates, little is known about direct effects of coal dusts on the alveolar epithelium or its extracellu¬lar matrix (ECM). Effects of dust on synthesis of cell and ECM proteins by type II cells (T2P) was thus investigated. Three coal dusts (anthracite no. 867; bituminous no. 1451 and no. 1361) and mine dust MIT-3, of respirable size, were studied as a function of dose and time over 3 days of primary T2P culture. On day 1, 750 µg/ml of 867 were required to increase relative synthesis of ECM proteins (ECM/cell). MIT-3, 1451, and 1361 were without effect. By day 3, 867 or MIT-3 increased ECM/ cell 60-100% at 300 µg/ml; 1451 produced modest, dose-dependent stimulation, whereas 1361 remained without effect. None of the dusts caused significant cytotoxicity. The results show dose- and time-dependent effects of well-characterized coal and mine dusts to modify partitioning of newly synthesized proteins into the ECM and suggest that coal dust exposure may modulate structure or function of the subepithelial basement membrane.basement membrane; cell culture; inorganic dust; lung injury; extracellular matrix deposition; pulmonary epitheliumCHRONIC EXPOSURE to coal dust may be associated with development of pulmonary fibrosis and consequent loss of normal lung function (see Ref. 26 for review). Al¬though the pathways of inorganic dust-induced lung injury are recognized to involve an inflammatory re¬sponse, the underlying pathogenic mechanisms are not understood in detail. Acute and chronic responses to dust exposure involve a variety of interacting cells of the immune system, including macrophages, T cells, and B cells, along with pulmonary fibroblasts. These responses reflect direct effects of the dust particles, as well as indirect effects mediated by soluble factors, including cytokines and eicosanoids (see Ref. 41 for review).Studies of pulmonary macrophages and fibroblasts following silica exposure suggest that dust-induced damage at the airway surface may involve cellular injury through oxidant-mediated pathways. Coal dusts and related inorganic particulates can activate the alveolar macrophage (42) to produce fibronectin (15) and cytokines, such as interleukin-1 or tumor necrosis factor (4) and/or other soluble products which act locally (29) to cause acute cellular injury and to initiate the progression of fibrotic lung damage (16). Type I epithelial cells are typically more susceptible than type II cells to oxidant injury. Type I cell damage and subsequent death leads to denudation of the subepithelial basement membrane (2, 21) and can be associated with leakage of plasma constituents from the pulmonary vasculature into the alveolar compartment (13)."

Dec 1, 1995

By Kevin Phelan, Gary Johnson, Peter Sperring

The vast majority of tailings in the Western Australian Goldfields are deposited in purpose-built storage facilities. At mine-sites with open-pit mining operations there is also the requirement to mine and stack large volumes of waste rock, usually into surface waste dumps. As these dumps have typically 30% of their gross volume present as voids, there is the potential to use this void space for the storage of tailings. The concept of co-disposal is to store the tailings material in the void space of the waste dumps, eliminating the need for a separate tailings storage facility. Dominion Mining Limited have been investigating the possibility of using co-disposal as a means of tailings storage. Laboratory testwork has been used to understand some of the issues associated with the concept, and assist in the design of an on-site demonstration of the concept. Co-disposal offers a number of potential advantages, and despite a number of practical hurdles to overcome, considerable economic and environmental benefits could be realised if this concept can be demonstrated on a commercial scale. The major advantage of such a system is to remove the need to build, operate and rehabilitate a separate tailings storage facility. Rehabilitation can be incremental throughout the mine life as the co-disposal site will be virtually indistinguishable from a current waste dump in both size and form. Other potential advantages include more stable waste dumps, less land area disturbed on the project site, and better water recovery from the tailings.

Jan 1, 1995