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By Doerner H. A.

From thermodynamic calculations Maier predicted that zinc oxide and methane would react at specified temperatures substantially according to equation (1). (1.) ZnO + CH4 = Zn (gas) + CO + 2H2. Other reactions that may take place are (2.) CH4 = C + 2H2. (3.) ZnO + CO = Zn (gas) + CO2. (4.) ZnO + H2 = Zn (gas) + H2O. Maier predicted that 870°C would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1), at equilibrium, would be substantially complete at or above 927°C. Theoretical considerations indicate that reaction (1) is reversible: this is supported, but not proved, by experimental data. The other reactions are known to be reversible. At low temperatures reaction (2) requires a catalyst and it is slow below 1000°C. Reactions (3) and (4) are rapid, but the equilibrium constants are such that only small concentrations of CO2 or H2O can be produced below 1000°C. Maier calculated that CO2 should not exceed 0.5 per cent at 870°C., and the calculation for water vapor gives a still smaller order of magnitude.

Jan 1, 1931

By Lauri Holappa

Copper converting is mostly performed in Peirce-Smith converters. The process is still very similar to the original one developed in the early 20th century. It is a batch process in a horizontal cylindrical reactor with air blowing via tuyeres along the length of the reactor side. The Peirce-Smith converter has its roots in Bessemer's inventions in the 1850's as he tested both horizontal and vertical vessels for steel converting. However, for steel making a vertical pear-shaped converter with air bottom-blowing was established. In the course of time, there was a distinct necessity for oxygen usage instead of air due to harmful effects of nitrogen to steel properties and its cooling effect. In-bath blowing of oxygen did not succeed, however, and top-blown oxygen converter with oxygen lance (LD or BOF) was first developed in he 1950's and emerged rapidly to a dominating position. Somewhat later oxygen bottom-blowing via special shrouded tuyeres was developed (OBM or Q-BOP) but has attained only fractional share. Bottom-blowing technique had, however, impact on the current combined blown converters which adopted the benefits of both top and bottom blowing. In copper converting Peirce-Smith type converters have kept their position until today although new processes have been introduced and at least few of them seem to be emerging. In one respect copper converting has a clear leading position i.e. in the progress of continuous converting processes (Mitsubishi, Ausmelt). These processes utilise top-blowing lances instead of in-bath blowing tuyeres. A different principle for continuous converting is flash converting by Kennecott Outokumpu, which makes smelting and converting independent of each others. Solid ground matte is used as a feed for flash converting in a reactor shaft similar to Outokumpu matte flash smelting. A comparable process has been presented by Inco too. The paper discusses principal physico-chemical and process technical similarities and differences in copper and steel converting. Although these processes are metallurgically quite different it seems that during the modem history of ferrous and non-ferrous metallurgy, starting from the 1850's, the exchange of knowledge between these disciplines has been quite intensive. In long-term perspective, many similarities in the development can be found but also divergences due to different ambient circumstances.

Jan 1, 2003

By P. A. Richardson

The current Bureau of Mines active list of permissible explosives includes 76 brands. Eleven are gelatinous and the rest are the granular type. The list of permissible blasting devices comprises five Cardox models.

Jan 1, 1970

(Members are urged to send in for this column any notes of interest; concerning themselves or their fellow-members.) Members and guests who called at Institute headquarters during the period Nov. .10, 19 16 to Dec. 1.0, 1916: Chester Atkinson, La Fundicion, Peru. , Paul Llewellyn, East Chicago, Ind. F. J. Brule, Toronto, Ont., Canada. Harry March, London, England. Sterling H. Bunnell, New York, N. Y. E. P. Mathewson, Toronto, Ont., Canada. G. H. Cunningham, Hobart, Tasmania.' E. W. Moore, Budapest, Rumania. Courtenay DeKalb, Tucson, Ariz. W. J. Pentland, Guadalajara, Mex., E. H. Dickenson, New Y.. Heinrich Ries, Ithaca, N. Y. E. B. Durham, Mount Kisco, N. Y. W. E. Saunders, Philadelphia, Pa. L. B. Eames, Pueblo. Colo. J. G. Scrugham, Reno, Nev. N: H. Emmons, 2d, Copperhill, Tens. - W. H, Seagrave, Kennecott, .Alaska. R. E. Hoffman, Hannibal Mo.'s H. B. Small, Magangue, Colombia. B. B. Hood, Chronic, N. J. W. H. Staver, Washington, D. C. H. E. Jackman, Rochester, N. Y. R. K. Stockwell, Santiago, Chile. F. H. Jackson, Joplin, Mo. Warren D. Thompson, Boston, Mass. Knight S. Jordan, Provo. Utah. Thor Warner, Kingman, Ariz. William Kelly, Vulcan, Mich. S. T. Wellman, Cleveland, Ohio. W. H. Lanagan, San Francisco. Cal. F. H. Willcox, Pittsburgh, Pa. H. H. Lauer, Northampton, Pa. Arthur K. Adams has been appointed geologist to the Andes Copper Co.

Jan 1, 1917

By Anna Carolina Cerqueira Neves

As fibras sintéticas vêm sendo gradualmente substituídas por fibras naturais. Em comparação com a fibra sintética, fibra natural demonstrou vantagens econômicas e ambientais. Visto que apresenta características interfaciais com matrizes poliméricas que favorecem a absorção de energia de alto impacto pela estrutura. No entanto, até agora pouco foi avaliado sobre a fibra de cânhamo incorporada em matrizes poliméricas. Este estudo tem o objetivo de avaliar a resistência ao impacto deste tipo de compósito com matriz de poliéster reforçada com diferentes porcentagens de fibras de cânhamo. A resistência ao impacto aumenta proporcionalmente com a quantidade relativa de fibras incorporadas como reforço na matriz polimérica. Este desempenho foi relacionado com a dificuldade de ruptura imposta pelas fibras, resultante da interação da matriz de fibra de cânhamo / poliéster de forma a ajudar a absorção da energia de impacto.

Aug 17, 2017

[JOHN B. MARKS President Boston Bldg., Denver, Colorado BENEDICT SHUBART Secretary-Treasurer 521 Boston Bldg., Denver, Colorado H. H. BUBB Vice-President for Colorado Cokedale, Colorado W. J. REID Vice-President for Utah Wattis, Utah WM. MOORHEAD Vice-President for New Mexico Dawson, N. M. GOMER REESE Vice-President for Wyoming Frontier, Wyoming EXECUTIVE BOARD COLORADO: E. H. McCLEARY Alamo SAMUEL TESCHER Denver UTAH: DAVE BROWN :Storrs JOHN JENNINGS Hiawatha NEW MEXICO: JAS. McDOUGALL Van Houten GEO. MIKSCH Gallup WYOMING: T. H. BUTLER Hanna L. A. NORMAN Sheridan]

Jan 1, 1925

Ten years ago we surveyed in "Uspekhi Khimii" the mechanism of the synthesis of hydrocarbons from CO and H2 (1).5 With new data obtained since then, mostly by Soviet researchers, our previous work (2), dealing with new forms and catalysts of the synthesis, is brought up to elate by reviewing research in this field. FORMATION OF CARBIDES The hypothesis that carbides are intermecliates in the synthesis assumes that carbon monoxide reacts with the metals of the eighth group and that this reaction is connected with the reversible reaction 2CO[=]C +CO2 (1) in a certain range of temperatures (3).

Jan 1, 1958

By Liu Fan, Shang Yanbo, Wang Zhongming

"Besides valuable metals of Cu, Sn, WO3, Zn, there are S, Ag, CaF2, In and so on in a complex ore deposit in south China (which belongs to Hu Nan Shizhuyuan Non-ferrous Metal Limited Liability). Although it proved reserve amounts to 3.5×107 ton, its crystal character limits its utilization in large-scale. It features complex relationships between valuable minerals, finest crystallized particle size, low-graded valuable metals (Cu 0.30%, Zn 0.5-0.7%, Sn 0.2%, W<0.1%). If only tungsten minerals are considered, it means WO3 grade is too low (the cut-off grade of WO3 is 0.1% in China). Only Cu and Sn minerals are recovered from 2006 and Cu recovery is less than 70%, Sn 15-20%. Other valuable metals of W, Zn, S and CaF2 were lost in the tailings. To make good use of the ore, the technology of fully recovering Cu, Sn, W, Zn, CaF2 and rare metals are in urgent need. After systematic researches, the flow sheet of "bulk flotation of Cu-Zn minerals at first, then Cu-Zn separation, then recovering sulphide by flotation, then recovering iron minerals by magnetic separation, then bulk flotation of Sn-W minerals after desliming" is developed. Furthermore, specific Sn-W collectors of BK411 and BK412 are applied into the processes and better indexes are obtained. The industrial indexes are listed as followings: the content of Cu, Zn, Sn, WO3 of ROM ore is 0.31%, 0.65%, 0.13%, 0.03%; Cu and Zn recovery are 82.23% and 37.79% respectively; 63.76% of Sn and 34.34% of WO3 go into the Sn-W bulk concentrates. Economic benefits are remarkable."

Jan 1, 2014

By T. R. Rehak

Blasting operations are an essential element in the recovery of our Nation?s mineral resources. The mining industry uses billions of pounds of explosives annually. The majority of blasting occurs in surface mining operations. Blasting results in the fragmentation and often the projection of rocks. Frequently, the rocks are thrown beyond the expected limits. Flyrock and failure to secure the blasting area dominate blasting-related accidents in mining, especially in surface mining. Blasting accidents in the mining industry tend to result in critical injuries or fatalities. Accident reports and information collected from the Mine Safety and Health Administration (MSHA) and other government agencies provide supporting evidence. According to the data collected, blasting-related accidents (in mining) were 11 times more severe than all other types of mining accidents. Blasting accidents are not unique to mining operations - the same situation exists in the construction field. In this paper the authors have compiled a list of the primary causes of flyrock and the failure to secure the blast area. In the next phase of this project, typical blasting scenarios will be reviewed which will highlight the main reasons flyrock and/or lack of blast area security occur. This will alert miners and construction workers to the current problems/hazards associated with blasting and to identify other safety measures to protect personnel.

Jan 1, 2000

By T. T. Read

JAPAN&apos;S iron and steel industry has always been closely connected with military strategy. Many years ago it became evident that the country&apos;s iron-ore resources were too small to support any extensive industry. As a result a belief in the imperative necessity of securing such resources has influenced Japan&apos;s political and economic policy in the Far East. Iron-ore developments in China are too well known to need repeating except to note that they have been rather unsatisfactory to both China and Japan. The ore deposit at Tayeh, in China, is not as large as was first believed and, though that and other sources of supply in China proper are now furnishing Japan a little more than a million tons of ore yearly, it cannot be counted upon as a large permanent source of supply. The deposit in Shantung proved so disappointing on further exploration that operations there have, so far as I know, long since ended. The operations at Pen-bsi-hu, in South Manchuria, which C. F. Wang de¬scribed in the A.I.M.E. TRANSACTIONS for 1918, Vol. 59, were reported to have yielded 84,000 tons of pig iron in 1928 and about 50,000 in 1935, so they seem to be going back.

Jan 1, 1937

By Ivan F. Avery

DOMESTIC production of carbon black increased 4 percent in 1962 to 2,056 million pounds. Furnace black output was 8 percent, or 132 million pounds, above that in 1961 and accounted for 90 percent of total carbon black production. Channel black output continued to decline and was 55 million pounds less than in 1961. Carbon black shipments during the year totaled 2,082 million pounds and were 5 percent above those of 1961. About one-fifth of these shipments were exported; the balance were sold domestically. An increase of 180 million pounds in domestic sales was partially offset by a decline of 80 million pounds in exports. Total value of carbon black production in 1962 was $145 million. The average value per pound of 7.06 cents was 0.24 cent per pound less than in 1961. Producers&apos; stocks declined 26 million pounds during the year.

Jan 1, 1963

By H. Craig Boyle, Craig H. B. Leitch

"The Trout Lake stockwork molybdenum deposit is located in the Selkirk Mountains of British Columbia, 50 km southeast of Revelstoke. The property is being explored by a joint venture between Newmont Exploration of Canada and Esso Minerals Canada.The deposit is associated with a small granodiorite stock of Upper Cretaceous age (76 Ma) which has variably altered the surrounding schists, argillites and marbles of the lower Paleozoic Lardeau Group to hornjelsic biotite schists and skarn. The intrusive is composed of a small stock and an intersecting network of northeast- and northwest-trending dykes at surface that coalesce downward into a larger stock. There are two main phases of intrusion, with an earlier quartz porphyritic granodiorite cut by an intra-mineral ""quartz diorite"" porphyry. A strong sub-vertical north-trending fault controls the distribution of the mineralized stock work and displays post-mineral movement.Molybdenite, accompanied by pyrite and pyrrhotite, is mainly present along the margins of veins in a well-developed quartz stock work, but occasionally is strongly disseminated in microfractured intrusives. The stock work is strongest in and around the contacts of the intrusive and its apophyses, and occurs over a vertical range of more than 1,000 m. As defined by the 0.10% MoS] contour, the main mineralized zone is up to 300 m long by 200m wide. Preliminary drill-indicated reserves, currently being revised, are approximately 50 million tonnes of 0.23% MoS2, within which are several zones of higher-grade material. Hydrothermal alteration, as defined by quantitative X-ray diffraction studies on composite core sections, is composed of a central quartz/K-feldspar/albite/minor biotite zone coincident with molybdenum mineralization, which is overlapped by a slightly later, antipathetic quartz/ sericite/pyrite zone. Ankeritic carbonate is also a common alteration mineral, but only traces of fluorite, and no topaz or sulfosalts, have been observed. Analysis for trace elements such as Sn, W, Bi, Sb, As, Hg, U, Ag, Au, Mn, Cu, Pb, Zn and F has been limited except for Sn and W, which appear to be zoned inside and outside the Mo zone respectively; the other elements do not show detectable patterns thus far."

Jan 1, 1983

By D. W. H. Su

This paper describes geomechanical criteria employed by Consol Energy for selecting mine-specific longwall face supports in the past decade. The criteria include immediate and main roof rock characteristics, floor rock characteristics, critical tip-to-face distance and shield operating range. Detailed roof rock properties from high-density core holes as well as in-mine scope holes are used to evaluate the set load density and shield stiffness required to control the immediate roof and the yield load density required to absorb the load density developed from main roof weighting. Detailed floor rock properties from core holes and in-mine floor bearing capacity tests are used to specify the maximum peak toe pressure as calculated by the Jackson method. The critical tip-to-face distance is evaluated based on the immediate roof rock strength, layering and thickness. The shield operating range is evaluated based on main bench thickness, the presence of thick draw slate, the potential of minor roof falls at the face and transportation restriction. Three case examples representing three different geologic conditions are presented to illustrate the successful application of these geomechanical criteria for selecting longwall face supports within Consol Energy in the past decade.

Jan 1, 2004

By W. K. Muwais, R. G. Cuddy

"The Lower Cretaceous McMurray Formation contains the bitumen reserves of the Syncrude Mine in northeastern Alberta. This formation comprises sediments deposited sequentially in fluvial, estuarine and marine depositional environments. The Syncrude Base Mine area consists mostly of estuarine sediments, as much of the original marine sediments have been eroded away. These estuarine deposits consist of channel-fill sediments and interchannel tidal flat sediments with the channel-fills comprising most of the orebody.Channel-fills contain, among other lithologies, interbedded sand, silt and clay rich layers that often occur as sequences of inclined beds with dips up to 25 degrees or more. A detailed knowledge of the distribution of these inclined beds, their lithological characteristics and their continuity is very important in assessing the risk of mine highwall instability . Techniques used to identify and characterize adverse structures are reviewed. INTRODUCTIONGeneralThe Syncrude Canada Ltd. oil sand mine is located within the surface mineable portion of the Athabasca Oil Sands area about 40 kilometres north of Fort McMurray in northeastern Alberta, Canada (Fig. I). The company commenced large-scale strip mining of oil sands in June 1977in the area, referred to as the Base Mine, situated in the southeast corner of the company&apos;s two lease areas (Fig. 2).The mining method (Fig. 3) utilizes large electric drag lines operating on a single bench with highwall depths up to 60 metres. Feed grade oil sand (= 6 wt.% bitumen) is mined by draglines and windrowed parallel to the highwall crest. Lower grade oil sand « 6 wt. 0J0 bitumen) occurring as waste bands is selectively mined by the draglines and cast back into the mined out pit or placed on the bench and hauled by truck. The windrowed feed is delivered to the extraction plant by a bucket wheel reclaimer and conveyor system. Stripping of Recent, Pleistocene and Cretaceous overburden units is done outside the conveyor systems by mobile equipment. The 4.5 kilometre long mine is split into four quadrants for planning and scheduling purposes, with each quadrant having an individual dragline-bucketwheel-conveyor system.Surface mining of oil sand at Syncrude requires the removal of vast quantites of material. The design of the open pit mine relies heavily on knowledge of the distribution of ore and waste materials, and on the physical characteristics of these materials.The geology of the oil sand below the dragline bench at the Syncrude Mine is complex. Geological, geotechnical and hydrogeological factors play an important role in the design and operation of the mine. This paper describes aspects of the geology that impact on the design and operation of the mine. Some of the methods and procedures adopted by Syncrude to successfully overcome difficulties that the complex geology creates are discussed."

Jan 1, 1989

By L. G. Marsh

The manufacture of lubricating oils from wax-bearing crude petroleums involves the removal and recovery of the paraffin wax contained in the lubricating distillates. During this process several intermediate products are formed, among them the mixture of waxes and oils known to the refiners as "foots oil." Because of its complex character, foots oil is little understood, and therefore methods of handling it in refineries are often inefficient. The Bureau of Mines is studying the manufacture of lubricating oils, and during the work has investigated the redistillation of foots oil. This report gives in brief the results of the investigation, and recommendations based upon it.

Jan 1, 1926

By Gordon B. Brox, Joseph F. Mcaleer, Charles C. Goddard, Edward P. Shea, Robert G. Ingersoll, Lester G. Zeihen, George J. Burns, John M. Guilbert, Richard N. Miller, Charles Meyer

The Boulder batholith is a composite intrusive in which the Butte quartz monzonite is the dominant rock type. Quartz porphyry dikes intruded the quartz monzonite in directions which were subsequently followed by the eastwest- striking Anaconda system of veins, the earliest major veins in the district. Anaconda veins are faulted by northwest-striking veins of the Blue system, which are most prominent in the central third of the district. Anaconda veins are the major producers in the western third of the district and also in the eastern third, where the "horsetail" zones break off from them. Individual oreshoots are thousands of feet long as well as deep on both systems of veins, but they are generally more persistent and thicker on the Anaconda veins. Viewed broadly, the mineralization in the big veins is arranged in crudely concentric zones of zinc and manganese around a central zone of copper. Only slightly offset from these zones, but earlier structurally, is a zone in which quartz-molybdenite veinlets are prominent. This zone tops at about the 2800 level and widens downward. The pattern of distribution of Cu-Fe-S series minerals in the large veins of the copper zone is not symmetrical with respect to the metal zones. There is a fringe of chalcopyrite-bornite all around the copper front. However, within the copper zone, pyrite-chalcocite-enargitecovellite- digenite assemblages are prevalent near its eastern edge from the 3800 level to the surface, whereas deep on the large Anaconda veins in the western part of the copper zone, chalcopyrite is dominant. Here the chalcopyrite grades upward into bornite-chalcocite ores and eastward into the high-sulfur assemblages of the Leonard mine. Sericite-biotite-K-feldspar alteration envelopes, containing up to about 2 per cent copper as chalcopyrite, are present on some of the quartz-molybdenite veinlets at deep mine levels in the molybdenite zone. These envelopes contrast sharply mineralogically and chemically with the later sericitic and argillic alteration envelopes around Main Stage veins. K'0-Ar'0 ratios indicate that they may be older by about 4 m.y. Secondarily enriched copper ores are mined in the Berkeley pit in the southeastern part of the district. At the present time they account for about half of Butte's production of copper.

Jan 1, 1968

By P. N. Calder, D. B. Apel, S. D. Butt

Mine-wide (MW) microseismic systems use widely spaced transducers to determine the source location and parameters of stronger microseismic events, while high frequency (HF) systems use fewer transducers to monitor local areas for the weaker events that can precede stronger events. Previous monitoring at the Creighton Mine indicated that an HF transducer located 120 m away from an active stope recorded two types of activity in response to production blasting: the first occurring at the same time as the production blasts and associated with the passage of the direct seismic waves from the blast through the local area, and the second occurring several hours later and associated with the arrival of a slower moving stress change through the rock mass (which was identified by the mine’s MW system). Interpretations of locally increased stress levels, based on analysis of the recorded HF events, correlated with the nearby occurrence of two strong seismic events. These results were applied to a similar monitoring trail at the Kidd Creek Mine where the transient stress changes induced by several development blasts were monitored. It was observed that increases in HF activity corresponded with the occurrence of MW events near the transducer location, and that fewer HF events were recorded the longer this occurred after the blast. Local geological features appeared to influence the number and occurrence of both HF and MW events.

Jan 1, 2000

THE QUARTETTE Mine near Searchlight, NV, a mine that first operated in the 1890s, could begin processing ore again by September. Jetco Enterprises Inc. plans to work through the tailings and ore close to the surface followed by plans for an openpit mine. It is one of at least three new mining efforts in the region, the Associated Press reported. Another is north of Searchlight, with yet another across the Colorado River in Arizona, east of Bullhead City. Gold mining is rare in southern Nevada. The area generally lacks the rock type that contains gold deposits. Restrictions on federal wilderness areas and protections for the desert tortoise also play a role. Gold veins in the region are generally small and erratic in length and height, Bill Durbin, a geologist and chief of southern Nevada operations for the Nevada Division of Minerals told the Associated Press. L.R. Tad Tinnell, president of Jetco Enterprises, has long eyed the mine. From 1993 to 1995, he explored and drilled on the property, which was still owned by Searchlight Mercantile.

Sep 1, 2013

By Gene Asai

Properties obtained for columbium carbide-carbon castings ranging in car-bon content from 12 to 17 weight-percent were compared with those of hot-pressed composites of similar composition. The properties were oxidation resistance in static air between 500° and 700° C, linear thermal expansion between 20° and 2,400° C, electrical resistivity between 20° and 1,500° C; microhardness between 20° and 1,500° C, and modulus of rupture between 1,300° and 1,800° C. CbC-C castings differed markedly from hot-pressed material with respect to microstructure, electrical resistivity, and modulus of rupture, but behaved quite similarly with respect to oxidation resistance, thermal expansion, and hot hardness. In oxidation resistance, thermal expansion, and hot hardness both materials were independent of carbon content. Both castings and hot-pressed composites oxidize rapidly in air above 600° C, have thermal expansion coefficients very similar to columbium metal, and the logarithm of the hardness decreases linearly with increasing temperature. The microstructures of hot-pressed composites contained varying amounts of graphite in a CbC matrix but did not contain significant amounts of a eutectic structure present in all castings, nor did they contain graphite needles which were present in the hypereutectic castings. The higher electrical resistivity of hypereutectic castings over hypereutectic hot pressings was attributed to the presence of highly oriented graphite needles in the castings. The modulus of rupture of castings was 1-1/2 to 2 times that of hot-pressed composites. Both materials displayed bend ductility above 1,800° C.

Jan 1, 1971

Under the Bureau of Mines Research Contract Number H0252071, Foundation Sciences, Inc. has compared the relative effectiveness of roof bolts installed at an angle over the rib with that of bolts installed vertically at the rib side, The information gathered during this investigation was sufficient to supply supplementary information on the mechanics of roof support systems and the general acceptability of field instrumentation methods. During the 140 days of field investigation, 235 bolts were installed, 45 inclined and 190 vertical, in two adjacent intersections. Of these 235 bolts, 30 were in-stalled with load cells and 38 were tested for anchor capabilities. In addition to this instrumentation, the deformation of the opening was measured by convergence meter on 9 lines throughout the two testing areas, and a borescope and photo-elastic gauges were utilized to obtain information on the roof action beyond the surface.

Jan 1, 1977