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By Yury V. Kulikov, Rakan Rahbani, Arkady Y. Senchenko

"The relevancy of complex minerals treatment is constantly increasing taking into account mineral resources depletion. Different refractory ores and concentrates, oxidized and polymetallic ores, as well as metallurgical products (slags) can be assigned to such mineral type. The treatment of such products via conventional flowsheets requires considerable capital and operational costs and does not always provide high recovery level of valuable components into a saleable product. Therefore, considerable amount of ores and metallurgical products are not treated, or treated inefficiently. One of the most promising approaches that allows economic treatment of refractory products is their ultrafine grinding down to 5-20 µm with subsequent processing or hydrometallurgy. Horizontal bead mills - the IsaMillTM, developed by Xstrata Technology, received their wide application in mining industry. Standard testing is performed under laboratory conditions in an M4 IsaMillTM (volume - 4 liters) to define the parameters of fine grinding. This mill completely simulates the operation of full scale industrial mills up to 50 m3 in volume (up to 8000 kW motor). The paper describes fine grinding technology performed in bead mills, and the importance of testing according to a certified method for industrial equipment selection. The paper contains description of promising directions of fine grinding technology application for several projects in Russia and Kazakhstan."

Jan 1, 2014

By David M. Rempe

The purpose of this standard is to provide a method for testing of cushion materials that leads to uniform results when employed by various organizations and laboratories. The load-deflection characteristics measured using this method are intended to provide input data for analysis of pile driving, as in wave equation analysis of pile driving. It should be recognized, however, that there are several factors which may cause a difference in performance between the test samples under laboratory conditions and actual cushion materials under pile driving conditions. These factors include variations in material properties from sample to sample, compaction and/or deterioration of the materials with use, eccentric loading due to misalignment, confinement effects or the cushion container or inter layered materials, head buildup, rate of loading, etc. In order to obtain representative load-deflection characteristics, therefore, testing of cushion specimens which have been subjected to actual pile driving conditions is encouraged 1 such specimen should be tested at various stages of the useful life of the cushion. The users of the data are cautioned to determine if the particular wave equation program they are using requires either the secant or tangent definition of the stiffness and modulus of elasticity.

Dec 1, 1984

By W. Fletcher

Startup of a new plant is a very interesting time. It generally is also a very demanding and often frustrating period. Startup problems can become serious ii they impede the early achievement of full plant production. Raw materials are wasted, manpower is unproductive, field modifications can be extremely expensive and market commitments may not be met. This paper outlines a well proven and highly successful approach to eliminating many of the problems and frustrations often experienced in plant startup. The procedures and methods summarized in the following paragraphs have been developed over a period of 25 years during which some 90 plants were started up.

Jan 1, 1981

By Houston Kempton, David Atkins

Mining in semi-arid climates can produce environmental impacts that will not begin for hundreds of years, but once started, may continue for thousands of years. Pit lakes may eventually exceed toxicity thresholds as metals are evaporatively concentrated, and slow unsaturated flow through acid-generating waste can eventually load several kg-SO4/m2-yr to underlying water tables. U.S. regulations are poorly equipped to respond to delayed and long-term environmental impacts, delaying permits as operators and regulators grapple with uncertainty. Improved uncertainty analysis, additional long-term mitigation options, and explicit regulatory guidance offer solutions to this dilemma.

Jan 1, 2000

By W. D. Striffler

Land disturbed by surface mining in Colorado and other western states has increased substantially over the past several years and is likely to increase even more in the future. This study was initiated to provide basic information on hydrologic and erosional characteristics of regraded coal spoils in Colorado as an aid for planning future reclamation activities. Eleven of twenty-one surface mines licensed in Colorado were sampled during the summer of 1980 and 1981. Mines not sampled included mines which had not progressed to the point that reclamation had begun, and mines where operators denied permission to sample. All coal regions were sampled with the exception of the San Juan Coal Field. Physical and hydrologic characteristics of regraded coal spoils in Colorado were determined using standard field and laboratory procedures. Field sampling included characterization of sites (slope, vegetation density, proportion of surface rock, bare soil, etc.) and infiltration measurements using a l-meter square drop former raining on a 1/2 square meter rectangular plot frame. Core samples collected in the field were analyzed for saturated hydraulic conductivity, bulk density, organic matter, moisture retention and texture. The erosion potential of each site was determined using the Universal Soil Loss Equation (USLE). Results of the sampling indicate that infiltration rates vary widely both within and between sites. However, definite trends with respect to coal fields are apparent. For example, the Green River (Yampa) coal region had a wide range of sampled infiltration rates (1.2 to 5.1 cm/hr). However, most of the sites clustered towards the low end of the range. The North Park (Marr Strip) also was rated at the low end of the infiltration range (2.0 to 3.0 cm/hr). Average infiltration rates for the Canon City and Uinta Coal Regions were at the high end of the range (4.9 to 5.5 cm/hr). Multiple correlation analysis of infiltration rates vs. site characteristics showed that infiltration rates were most closely correlated with the depth of wetting, the amount of mulch cover, and site slope. The depth of wetting was highly correlated with the depth of the topsoil and the bulk density of the spoil. In general, the topsoil at all sites appeared to be highly permeable to water intake but once saturated, subsequent infiltration depended upon characteristics of the underlying spoil. Vegetation cover affected infiltration on individual mine sites but was not as pronounced as topsoil characteristics or mulch. Erodibility of topsoil and spoils, as determined by Wischmeier's "K" factor, ranged from 1.34 to 0.56 tonnes/ha. (topsoil) and 1.25 to 0.66 tonnes/ha. (spoils). Definite trends in erodibility are evident. The Green River (Yampa) Coal Region displayed consistently higher erodibilities (1.34 to 0.75 tonnes/ha.) than other coal fields (0.72 to 0.56 tonnes/ha). Lowest erodibilities were observed in the Uinta, North Park, and Raton Mesa Coal Regions (0.56 to 0.62 tonnes/ha). Erodibilities of underlying spoils showed similar trends as the topsoils. Erosion potential (the product of soil erodibility and rainfall erosivity) was detennined using calculated ?K? factors and rainfall erosivities (R) taken from Clyde (1976). Results show that the Delagua coal field, Raton Mesa Coal Region had the greatest erosion potential due to the high rainfall energies in the region, while the North Park and Uinta Coal Regions had the lowest potential erosion.

Jan 1, 1981

By J Sigda, T Jones, D Staggs, J Ewing, C Cheng, J Pickens, S Paulka

Mine-derived solutes from Energy Resources of Australia’s (ERA’s) Ranger uranium mine have been closely monitored for decades. Ranger is surrounded by the Northern Territory’s Kakadu National Park and is upstream of Ramsar convention wetlands. Modelling of groundwater flow and solute egress from mine wastes to surface waters has helped ERA successfully assess closure options and secure intermediate regulatory approvals during the site closure process. Potential environmental impacts were assessed using groundwater modelling in support of three ERA applications involving disposal of tailings-derived mine waste. Model results were an important part of the basis for obtaining regulatory approval. Three case studies are presented describing the three applications and how the groundwater modelling supported approval of the applications. For case study #1, INTERA supported ERA in addressing stakeholder concerns in 2017 regarding two aspects of tailings deposition in Pit 3. The first was the potential for flow of tailings fluid into the surrounding formations during tailings deposition. The second was the difference in post-closure magnesium (Mg) loading to surface water for two tailings deposition scenarios. INTERA developed a two-dimensional (2D) model that showed excess tailings pore pressures would not cause outflow and solute egress from the pit during deposition. INTERA’s three-dimensional (3D) models demonstrated that post-closure Mg loading to creeks for both tailings scenarios differed marginally and would be a small fraction of natural creek Mg loads. The modelling results helped avoid delays in completing tailings deposition driven by stakeholders’ environmental concerns. Case study #2 consisted of supporting ERA’s 2019 request for approval to change the tailings deposition method and final tailings level in Pit 3. INTERA’s model results for the permitted and proposed deposition methods showed minimal differences in post-closure Mg loading to creeks. The model results helped ERA obtain the needed approval for the tailings deposition method and water and tailings levels in Pit 3. For case study #3, INTERA modelled the comparative impacts from leaving the entire contaminant plume from the temporary tailings storage facility (TSF) in situ or excavating a portion of the contaminated material from beneath the TSF floor and placing it in Pit 3. The modelling results supported an approved TSF contaminated material application important for ERA to stay on schedule and minimise both closure costs and environmental impacts.

Jul 1, 2021

By D. Limpitlaw

Industrial mining in Zambia started in the 1930s when the world class copper deposits near the border with Katanga were developed. The discovery of these deposits began at the turn of the century when the first claims in the Copperbelt were pegged at Chambishi, north of what became the town of Kitwe1. World War I and the difficulties of raising sufficient capital for such large scale undertakings delayed the exploitation of these deposits. Following this hesitant start, a large copper mining complex was built, resulting in the development of five major towns, all highly dependent on the mining and beneficiation of copper and cobalt. Copper became so important to the country that, on independence, the only non-mining town to make it onto a list of the top six was the capital, Lusaka. From commissioning of the mines to the end of the colonial period in 1964, copper production increased to just over 640 000 t annually2 (see Figure 1). After the establishment of the new Zambian state, production continued to increase, supported by a benign legislative environment and strong international copper prices. The government of Kenneth Kaunda was intent on improving the conditions of the rural poor and reducing unemployment in urban areas. To this end, the government embarked on an ambitious project of refocusing Zambia's economy away from the colonial role of commodity supply to one of decentralized mass employment. The Copperbelt industrial complex was key to the success of this approach, and in 1969 the Zambian State acquired a 51 per cent stake in Zambia's two main copper producing companies: Roan Selection Trust and Rhodesian Anglo American Corporation. The former became Roan Consolidated Mines Ltd (RCM) and the latter became Nchanga Consolidated Copper Mines Ltd (NCCM). In the year they were nationalized, the mines produced at least 720 000 t of copper? and employed approximately 48,000 workers (see Figure 2)2-4. The subsequent economic policies of the Zambian Government depended heavily on the state's ability to monopolize the proceeds of copper mining.

Jan 1, 2011

By A. J. Partos

Table 4, Page 311 Table 4 Experimental Parameters from Straight Line Interpretation of Mohr Failure Envelope [ ]

Jan 1, 1991

EXECUTIVE COMMITTEES OF LOCAL SECTIONS New York L. W. FRANCIS, Chairman. WILLARD S. MORSE, Vice-Chairman. . THOMAS T. READ, Secretary, Woolworth Bldg., New York, N. Y. P. A. MOSMAN, Treasurer. LOUIS D. HUNTOON, Boston HENRY L. SMYTH, Chairman. ALFRED C. LANE, Vice-Chairman. AUGUSTUS H. EUSTIS, Secretary-Treasurer, 131 State St., Boston, Mass. TIMOTHY W. SPRAGUE, HENRY A. WENTWORTH. Columbia F. A. THOMSON, Chairman. GEORGE W. RODDEWIG, Vice-Chairman. LYNDON K. ARMSTRONG, Secretary-Treasurer, P. O. Drawer 2154, Spokane, Wash. R. S. McCAFFERY, S. H. RICHARDSON.

Jan 6, 1914

By Essie Esterhuizen, John Ellenberger, Dennis Dolinar

"Underground stone mines in the United States use the room-and- pillar method of mining. The stability of the roof between pillars determines the mining dimensions and size of equipment that can be used. The findings of a survey of roof span stability issues and design practices are presented, and the observed factors contributing to roof instability are discussed. Identified stability issues are evaluated, such as maximum roof span, horizontal stress, and roof beam stability. The results of field observations, roof monitoring, and numerical analyses are used in the evaluation. The importance of the first roof beam thickness and its impact on roof stability and support requirements is presented. An evaluation of the current experience with stone mine roof spans relative to international experience is presented. A step-by-step design procedure is suggested which emphazises the need to collect adequate geotechnical data, understand the immediate roof stability, select a mining direction, and meet support requirements.INTRODUCTIONIn room-and-pillar mines, the roof between the pillars is required to remain stable during mining operations for haulage as well as access to the working areas. Roof and rib falls account for about 15% of all reportable injuries in underground stone mines (Mine Safety and Health Administration, 2009). Therefore, the stability of the roof is an important safety consideration. The size of the rooms in underground stone mines is largely dictated by the size of the mining equipment. Large mining equipment is used, requiring openings that are on average 13.5 m (44 ft) wide by approximately 7.5 m (25 ft) high to operate effectively (Esterhuizen et al., 2007). The dimensions of the roof spans are largely predetermined by the equipment requirements, and design is focused on optimizing stability under the prevailing rock conditions. If the rock mass conditions are such that the desired stable spans cannot be achieved cost effectively, it is unlikely that underground mining will proceed. In addition, large roof falls can extend across the full width of a room and may extend more than 5 m (16 ft) above the roof line. These large falls are a safety hazard and can have a significant impact on mine access and production. The National Institute for Occupational Safety and Health (NIOSH) research into stone mine roof stability has focused on identifying both the causes of roof instability and techniques to optimize stability through design."

Jan 1, 2010

By Wolfgang Hermann

The ancit-process of the Eschweiler Bergwerks-Verein, an affiliate Company of ARBED S.A., Luxembourg, was developed in its principles by the Dutch State Mines, Limburg, in the mid-50's with the aim of producing a smokeless domestic fuel on the basis of low volatile hard coal. In 1967, the EBV erected a 10 t/h large- size pilot plant along these principles in the Aachen mining district and further developed the acquired know-how. In hardly 10 years more than 650 000 t of ancit briquettes with unit weights between 17 and 100 grams were produced and in the meantime stream rates of over 85 % of the yearly utilization hours have been reached. In more than 10 blast furnace trial runs involving substitution rates up to 100 p. c. ancit have proved the suitability of ancit as a metallurgical fuel both for a burden with a high and a poor iron content. Construction work for a minor process-step to enable processing of coal with a higher content of volatile matters is finished and first results are expected by summer this year. A pilot plant with a 30 t/h capacity working on a low-volatile coal basis is being planned. Engineering and construction are supervised by MecanARBED. Luxembourg, as responsible contractors.

Jan 1, 1977

By N. A. Gokcen, M. Ohtani

Thermodynamic intevaction pararnetevs of elements E2(2), for dilute binary solutions of a component "2" in liquid iron, i.e., E(22) = 9 In f2/?N2 where f2 is the activity coefficient and N2 the mole fraction, and E(3) 2 = In f2/ N3 dilute ternary solutions of "2" and "3," and the carbon saturation parameter sc(3) (In f c/ N3) N c/N Fe for N3 - 0, are critically examined and correlated. It has been found that the interaction parameters and the atomic numbers of alloying elements follow regular periodic putterns. PHYSICO-chemical behavior of alloying elements in molten iron have become the subject of numerous investigations during the past 25 years. Consequently, the mutual effects of elements in the iron-rich solutions Fe-C-X, Fe-N-X, Fe-H-X, Fe-O-X, and Fe-S-X where X represents an alloying element, have gradually become better understood. These effects for a given temperature and pressure may be expressed by the interaction parameter of Wagner1, 2 derived briefly in the following manner. The complete differential of the Gibbs free-energy equation at constant temperature and pressure is dF = Fl dn, + F2 dn, + F3 dn3+ . . . [ 1] where F is the free energy; F 1, the partial molar free energy of "I"; and n,, the number of moles of "i." Cross-differentiation of this expression* *Cross-differentials are obtained as follows: Since the order of differentiation of F with n2 and n3 is immaterial, the left sides of the second differentials are equal, hence the derivation of Eq. [2] is obtained. For a dilute solution of components 2 and 3 in solvent 1, with the substitution of RT In f i = Fi xs for Fi where fi is the activity coefficient, and Fixs is the excess partial molar free energy, Eq. [2] becomes O) [3] where N2 and N, are the mole fractions. The interaction parameters are defined by

Jan 1, 1961

By Herbert Clark Hoover, Lou Henry Hoover

DIGGING of veins I have written of, and the timbering of shafts, tunnels, drifts, and other excavations, and the art of surveying. I will now speak first of all, of the iron tools with which veins and rocks are broken, then of the buckets into which the lumps of earth, rock, metal, and other excavated materials are thrown, in order that they may be drawn, conveyed, or carried out. Also, I will speak of the water vessels and drains, then of the machines of different kinds,1 and lastly of the maladies of miners. And while all these matters are being described accurately, many methods of work will be explained. There are certain iron tools which the miners designate by names of their own, and besides these, there are wedges, iron blocks, iron plates, hammers, crowbars, pikes, picks, hoes, and shovels. Of those which are especially referred to as " iron tools " there are four varieties, which are different from one another in length or thickness, but not in shape, for the upper end of all of them is broad and square, so that it can be struck by the

Jan 1, 1950

By R. J. Andreini

Solvent extraction is widely used in hydrometallurgical processing of uranium for purification and upgrading leach solutions prior to recovery of metal values. Conventional solvent extraction processing utilizes mixer-settler units to achieve mixing of the aqueous and organic phases. Use of mixer-settlers permits continuous treatment of feed, but the processing rate is restricted by the time required for phase separation after mixing. Because of the high-shear type mixing used in a mixer settler a portion of the organic phase becomes mechanically entrained in the aqueous resulting in loss of extractant. For this reason application of mixer-settler units is often limited by the settling area required for phase separation, especially for systems where high volume throughputs are desirable or necessary. Several alternatives to mixer-settler operations involving the use of column extractors have been proposed. Packed columns (1-2), in which organic and aqueous phases are fed countercurrently, utilize packing materials similar to those used in gas absorption or distillation columns. Extraction columns utilizing rotating(3-5) or reciprocating elements(6-7) to achieve mixing have also been developed. Van Dijek(8) originated pulsed columns, in which mechanical or air pulsing of the phases enhances the mixing in the vessel. Each of the above column processes involve varying degrees of mechanical complexity which may lead to operational difficulties.

Jan 1, 1975

By BION J. ARNOLD

WE can, I think, rightfully claim, irrespective of our faults, that engineers must, in order to last as engineers, possess the qualifications of integrity, stead- fastness of purpose, ability to think straight, and to apply these qualities consistently and continually in their everyday work. All engineers know this, most of them conform, and in order to drive it home I might, if 'clothed with proper authority, preach to you at length, but I shall not take the chance. So I only want to make a suggestion or two to the young engineers. Have an ideal and work toward it. You will have your disappointments and your temptations but keep your record clean, and if anyone says you are foolish or ugly, or homely, or that you need a guardian, take the criticism with a smile, for he may be able to prove his contention; but if he attacks your integrity, strike at once and fight hard, for he has assailed not only your character but your principal asset as an engineer.

Jan 1, 1929

By C. J. Greet

Grinding with an electrochemically inert grinding media (i.e., high chrome white iron) shifts the pulp potentials to more oxidising conditions, increases the dissolved oxygen content and reduces the EDTA extractable iron concentration when compared with milling with electrochemically active grinding media (forged steel). These changes in pulp chemistry produce cleaner particle surfaces, reduce reagent consumption, and increase concentrate grades and recoveries. This paper presents a robust laboratory test program that not only demonstrates the changes in the pulp chemistry, but also provide an indication of the magnitude of the metallurgical improvements that are possible. While laboratory studies are interesting, the proof is in the pudding! So, the paper provides an overview of plant trials conducted at several porphyry copper operations around the world: Newmont’s Cadia and Red Chris Operations, as well as Evolution Mining’s Northparkes Operation. These successful plant trials clearly demonstrate that selection of the right grinding media alloy will yield savings in grinding media consumption and reagent consumption as well as increases in revenue through improved copper and gold recoveries. However, many of the porphyry copper mines on the Eastern Pacific are copper-molybdenum deposits. The paper presents laboratory test results for typical copper-molybdenum operations and extrapolate these numbers to what might be expected should a plant trial occur.

Feb 1, 2025

By Robert Stefanko

Transients are results of sudden changes which take place in power systems and can be created by the opening and closing of switches and circuit breakers or the occurrence of a fault anywhere in the complex. Transients are of short duration, and the time during which they occur is an extremely small percentage of the total operating time. However, it is during these short periods that the greatest electrical stresses occur, mainly due to excessive currents or voltages. In extreme cases, system parts are damaged, and equipment failure follows. Safety can be further compromised because anomalous voltages can exist at machine frames. For several years, the electric utilities have been well aware of the serious nature of transients on their systems, but problems firmly believed to directly result from these phenomena are just now becoming apparent to the coal mining industry. The situation became discernible after the underground introduction of high voltage distribution systems (along with vacuum circuit breakers) and sensitive solid state electronic apparatus. In order to protect against such transients, knowledge about their characteristics and origin must be obtained.

Jan 1, 1974

By Sergei A. Degterov

A thermodynamic database for the slag, matte and liquid copper phases in the Cu-Ca-Fe-Pb-Zn-Si-O-S system has been developed for the ranges of compositions of importance to the production of copper. When used with the Gibbs energy minimization software and other databases of the F*A*C*T thermodynamic computing system, this database will permit the calculation of matte-slag-copper-gas phase equilibria that take place during copper smelting and converting. The calculations reproduce within experimental error limits all available experimental data on phase diagrams, activities of components, enthalpies of mixing, matte - alloy miscibility gap and tie-lines. The calculated solubilities of Cu in both S-free slag and slag equilibrated with matte are also in good agreement with experiment under all studied conditions, such as at SiO2 saturation, in equilibrium with Fe, Cu or Cu-Au alloys, at fixed oxygen or SO2 partial pressures and at different contents of Pb, Zn and CaO in the slag. Sulfide contents (sulfide capacities) of the slags are predicted within experimental error limits. The distribution of Pb and Zn among matte, slag, copper and gas has been calculated. The calculations are in good agreement with experimental data and predict the distributions under conditions which are difficult to study experimentally, such as at magnetite saturation or under various oxygen partial pressures and iron to silica ratios in the slag.

Jan 1, 1999

By J. E. Nesset, E. R. Bobicki, K. L. Bilaniuk

The introduction of froth flotation technology in Canada, and in particular, in British Columbia, began not long after it was successfully applied in the Broken Hill mining area of Australia which began around 1905. It proved to be a revolutionary and transformative technology that resulted in marginal operations in copper, lead and zinc becoming profitable in spectacular fashion. The paper presents the technology of both oil flotation and froth flotation in the context of the challenges of the time and its early application in British Columbia at the Le Roi No.2 mine (1903), the Britannia Copper mine (1912), and at the Allenby concentrator of the Copper Mountain mine (1918-19). New-found archival documents indicate the Britannia application to be the first production application of froth flotation for copper ore outside Australia, a claim that is currently made by the Braden mine (now El Teniente) in Chile. Flotation was initially an add-on process following gravity methods but was rapidly shown to be far superior method for the bulk and selective recovery of metal sulphides. Flotation proved particularly successful for the recovery of zinc sulphide (the so-called ‘zinc problem’) which was considered a contaminant at the time. The ‘copper problem’ related to the poor recovery of fine copper sulphide particles that were not amenable to gravity methods. The success of flotation led to changes in both the scale and methods of mining, concentration and smelting in a manner that allowed integrated mining companies to flourish. Many are still with us today. INTRODUCTION The advent of froth flotation in the early 20th century was truly a revolutionary technological development, not only for the mining and metallurgical industries, but arguably more so for business and society overall. The Canadian technology historian Jeremy Mouat stated (1996) “The development of flotation was the greatest single metallurgical improvement of the modern era...it is not overstating the case to claim that flotation was of central importance to the smooth functioning of the global economy”. It should, therefore, be a story of interest to us all. The aim of this paper is not to retell the full story, that has been well covered by others (Hoover, 1912; Rickard, 1916a; Hines & Vincent, 1961; Lynch et al., 2010) but rather to add some Canadian perspective and the key role played by companies and individuals in those early days, focusing on events in British Columbia’s copper industry. EARLY DEVELOPMENTS During the later half of the 19th century, a number of flotation-related patents were issued. These include the 1860 patent (Britain) granted to William Haynes for a process to separate sulphides from ground ore by mixing it with oil (1-10% wt) followed by a separation process in a water-filled vessel; the 1877 patent granted to Georg and Adolph Bessel (Germany) for a process involving the mixing of oil and graphite ore followed by boiling in water to produce a high grade graphite froth (>90% carbon); and the 1885 patent granted to Rebecca ‘Carrie’ Everson for the separation of sulphides by mixing sulphide ore with small quantities of oil, and adding water followed by sulphuric acid. These processes are more properly referred to as bulk oil flotation due to the relatively large quantity of hydrocarbon used.

Jan 1, 2019

By Yingchang Tsenshan Wang

UUIN L&SS 1» Paqb I. Introduction........................................................658 1. Subject and Scope...............................................658 2. Acknowledgments...............................................659 3. Review of Previous Work........................................659 Field Data...................................................659 Experiment.a1 Data............................................662 4. Plan of Present Investigation.....................................662 Method of General Procedure...................................663 I1. Experimental Work..................................................663 A. The Solution of Sphalerite..............................:........663 1. The Solvent Effect of Iron Sulphates upon Sphalerite...........663 2. The Solubility of Sphalerite in Salt Solutions of Silver, Copper and Lead...............................................668 B. Formation of Zinc Carbonates....................................674 3. The Reactions of Carbonates and Bicarbonates With Solutions of Zinc Salts............................................674 4. The Reaction of Zinc.Sulphate Solution With Limestones.......684 C. Peculiar Conditions Affectitig the Formation of Zinc Silicate (calamine) and Zinc Carbonate (smithsonite)..........................686 5a. The Effect of Carbon Dioxide Upon the Basic Silicate and the Carbonates of Zinc in Water, and Its Bearing Upon the Conditions of Theii Precipitation..............................686 5b. The Reactions of Solutions of Soluble Silicate With calamine and Smithsonite in Solution in Presence of Carbon Dioxide..689 6. The Reactions of a Mixture of Hydroxide and Silicate of Sodium with a Dilute Solution of Zinc Sulphate...................691 D. High-Temperature Methods.....................................692 7a. The Influence of Temperature on the Formation of Calamine..692 7b. Possible Effect of Heat on Calamine and Srnithsonite.........697 E. Summary of the Experimental Work..............................698 III. Petrographic Work....................................................700 1. The Occurrence of Sphalerite in Limestones or in Cherts............701 Summary of the Blende in Limestones and in Cherts.............7432 2. The Partially Altered Sphalerite and the Oxidation Products........702 a. Smithsonite with Blende....................................702 b. Calamine with Blende......................................703 c. Smithsonite and Calamine..................................703 d. Summary on the Partially Altered Sphalerite and Its Oxidation Products..............................................704 IV. Concl~~siom ........................................................-705 V. Microphotographs and Photographs with Their Explanations.............705

Jan 1, 1916