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By J. P. Gouvea, W. Geel

Resin bolting in South Africa has been developed and refined in underground coal mines (i.e., soft rock) since the late 1940s. The extension of resin bolting to hard rock mines started in 2003 and has required significant adaptations, challenging the status quo from both a supplier and applicator perspective. As far as resin bolting is concerned, the most affected aspect in coal mining and hard rock mining environments, is the rock drills or machinery used for installation. Hard rock mines mostly use hand-held airlegs with limited thrust, low torque, and rotation speed, relative to coal mine mechanised bolters. Resin bolt development for hard rock mines was, and still is today, predominantly focussed on compensating for the ‘shortfalls’ of using hand-held airlegs. At face value, hydro-powered rock drills, which are more powerful than traditional handheld equipment, provided hard rock mines with a means to attain more consistent and reliable resin bolt installations. This paper assesses the quality and performance of hydro-powered resin bolting at an intermediate to deep level platinum mine in South Africa and its potential contribution to rock-related instabilities when applied erroneously. The findings of this paper necessitate a revision of current quality control and quality assurance measures related to resin bolting for underground support.

Nov 24, 2025

By H. Ding

Calcium carbonate/Titanium dioxide composite, characterized by coating TiO2 on the surface of CaCO3 particles, is an important substitute for titanium dioxide. This paper studies preparation method of CaCO3/TiO2 ,composites based on mechano-chemical effects, measures its properties as a pigment, analyzes the binding form and interface reaction mechanism between CaCO3 and TiO2. Through single finely grinding of CaCO3, co-grinding of CaCO3 together with TiO2, and mecha-no-chemical effects produced in the course of grinding, CaCO3/TiO2 composites can be prepared successfully. Results indicate that grinding fineness of CaCO3, co-grinding time of CaCO3 and TiO2, the weight ratio of grinding media to mineral feeding, and the amount of TiO2 have much influence on the properties of CaCO3/TiO2 composites. CaCO3/TiO2 composites have the properties same as titanium dioxide pigment, oil adsorption and ultraviolet adsorption same as TiO2, and 90% of hiding power as that of TiO2. Wet grinding of CaCO3 causes the production of mechano-chemical effect and hydroxyl group, through which CaCO3 and TiO2 can be bonded together. Repulsion occurs between the particles of CaCO3 and the particles of TiO2, respectively, they are both in good dispersion. But attraction occurs between CaCO3 and TiO2. TiO2 particles are distributed evenly on the surface of CaCO3. Therefore, coating of TiO2 on the surface of CaCO3 particles and chemical bond between them make CaCO3/TiO2 compo-sites have pigment properties of Titanium.

Jan 1, 2014

By Zhang Libo, Wang Xin, Peng Jin-hui, Ju Shaohua, Guo Sheng-hui, Xu Lei, Huang Meng-yang

"China is lacking high grade titanium ores. This work intends to leach impurities such as Fe, Ca and Mg from a low grade titanium ore, to increase the grade. The original material contained 65% TiO2 , 16.12% Fe, 9.4% CaO + MgO, 4.2% SiO2, 1.25% A12O3, and the particle size is between 0.053-0.045mm. Microwave energy was used to enhance the leaching effect. The results showed that when normal heating was used to leach the mineral, the extraction of impurities Fe, Ca and Mg was very low. However, when microwave energy is introduced, the extraction of Fe, Ca and Mg increased dramatically. The optimized conditions are: relative power 5W/g, the ratio of concentrate to HC1 isl5%, leaching at 160°C for 20 min with a ratio of liquid to solid 12:1 mL/g. The material obtained under these conditions contains 92.73% TiO2, 0.207% Ca + Mg, 0.8% Fe, with 94.6% Ti recovery. The poduct meets with the quality for boiling chlorine.IntroductionThe resources of titanium are very abundant, and are distributed all over the world. There are almost 140 minerals containing TiO2 with a content of more than 1%. However, there are only several minerals which can be used for producing sponge titanium. They are mainly rutile and ilmenite. The grade of nature rutile concentrates is higher than 95% TiO2, and it is a high quality raw material. But the resources of nature rutile are relatively low; after mining for many years, its resources are exhausting gradually. Although ilmenite reserves are great, ilmenite cannot be used as a raw material because of its low content of TiO2, only 45-70%; also it has a high impurity content of Ca, Mg and Fe. In these years, there is a tendency for titanium industry to use high grade concentrate."

Jan 1, 2012

By Jorge Olivari Ortega

El presente texto describe la relación de las enfermedades producidas en la minas auríferas con la biografía del inca Yahuar Huacac. Este inca fue el séptimo gobernante del Tahuantinsuyo, cuyo verdadero nombre deriva de los términos quechua: yahuar "sangre" y huacac, "lloró’; del verbo huacay,"‘llorar", es decir, el que "lloró sangre". Esta anomalía de sus órganos visuales se relaciona con el "sorrompi", o inflación de los párpados que se produce por la reberveración del sol en la nieve que puede ocurrir en zonas alto-andinas (4,500 m.s.n.m.). Otras enfermedades derivadas de la minería son el "usputani", o hemorragia nasal de forma abrupta que se produce por la inadaptación a las zonas altoandninas y el " soroche" o déficit de oxígeno en la sangre. En consecuencia, el inca probablemente desarrolló estas enfermedades por su estancia en la zona altoandina.

Mar 1, 2015

By Jesus Pascual, Jose Sanchidrian, Pablo Segarra

The surface vibration field in the area above an underground mine prior to its development has been investigated, in order to assess the vibration levels expected in existing buildings and in the planned mine facilities from future underground blasts. Shots of 50 and 100 kg of explosive placed in drillholes at depths of 100 to 150 m were fired, and the vibration events were recorded using an array of 40 seismographs in a 400 m square grid, covering a 2×2 km area. Contours of isovelocity were obtained for each shot, showing some directional transmission patterns. Propagation laws were obtained from the results of each shot and also from the bulk of data, both for the whole area and dividing it into four quadrants. The shift of dominant frequency with distance was also analyzed.

Jan 1, 2002

By Masao Miyake, Eiichiro Matsubara, Tetsuji Hirato, Yasuhiro Awakura

"Zn-Cr alloy coating with around 15 wt% Cr has been found to have much higher chemical corrosion-resistance to steel than conventional zinc plating, while· its structure has not been clarified. The Zn-Cr alloy plating is performed at high current densities around 1 A cm-2 and for 10 to 20 sec using acidic aqueous sulfate solutions with some additives in the iron-steel industry. Due to the high current densities, it seems reasonable to consider that the Zn-Cr alloy plating proceeds under an unsteady-state condition and that the resulting coatings have a non-equilibrium phase and have a structure change in the .direction of thickness. In this research, the crystal structure of the Zn-Cr alloy coating electrodeposited at high current densities and change of the structure in the direction of thickness were examined by X-ray diffraction. The coatings containing under 20 and 35-40 wt% Cr had hcp and bee structure, respectively, while the coatings containing 20-35 wt% Cr comprised two phases with the hcp and the bee structure. The structure of the coating varied in the direction of thickness; both the hcp and bcc phases coexisted in the vicinity of the substrate, while the hcp phase became predominant with increasing distance from the substrate.IntroductionRecently it has been reported that Zn-Cr alloy coating containing around 15 wt% Cr has much higher corrosion-resistance to steel than conventional zinc plating.1-3) The corrosion-resistanc·e of Zn-Cr alloy plated steel sheet with a plating amount of 20 g m·2 is, for example, superior to that of Zn plated steel with a plating amount in the range 60 to 90 g m·2 , which is widely used for automotive bodies today.4l The Zn-Cr alloy plating is obtained by electrodeposition at current densities over 0.5 A cm·2 from a sulfate solution containing zinc and trivalent chromium ions and some additives.5•6) The deposition current densities mentioned above are much higher than those for usual electroplating processes, e.g., Zn, Cu and Ni plating, carried out about 0.05 A cm·2 • Therefore, the time required for plating is very short; around 10-20 sec. Due to the high current densities, it seems reasonable to consider that the· Zn-Cr alloy plating proceeds under an unsteady-state condition and that the resulting coatings do not have a phase expected from equilibrium diagrams; no phase diagram of the Zn-Cr system with a full composition range has been available. 7). In other words, the alloy phase plated would be a non-equilibrium phase with unknown structures."

Jan 1, 2000

By L. Roux

This review was initially motivated by the author’s own experience in attempting to reconcile run-of mine production tons with the Coal Resource and Reserve estimation of mineable, in-situ tonnages. The primary scientific measurements and observations that are collected during exploration at the beginning of the value chain will have a profound effect on the future of the mining operation. Due diligence must be exercised during the planning of a new mine and during the life of an existing mine. The comments provided by the technical and economic assessment group of Venmyn Deloitte confirmed the need for this critical review. They found the reporting of Coal Resources in South Africa to be inconsistent. This was particularly problematic in the Waterberg Coalfield in Limpopo Province. In this coalfield there are two types of coal deposit present. The first is comprised of the thick intercalated, cyclic coal and shale/mudstone sequences of the Volksrust Formation. This overlies multiple coal seams within the Vryheid Formation, each of which is thick enough to be extracted as an individual raw coal unit. On the other hand, the interbedded coal and shale seams of the Volksrust Formation require beneficiation to separate the coal from the shale. The review examines practices and methods, investigates alternatives, provides checks and balances, and tests these against actual production reconciliations. In conclusion, the best estimates of the mineable, in-situ tonnage will be obtained from the air-dry raw material density. These estimates should be adjusted afterwards to allow for free moisture content. The adjustments are derived from reconciliation data. The greatest contributing factor to the over-estimation of Reserve tonnages is the moisture content of the raw material. This fluctuates significantly under varying conditions in situ, as well as upon exposure to the natural environment. The air-dried density of the raw material includes inherent (structurally bound) moisture within the matrix. It provides credible tonnage estimations of raw material available while also providing an indication of voids within the volume of material being assessed. The calculated solids percentage can be used to adjust the specific gravity, which is determined via the Archimedes principle. This will supply a representative estimate of the material to be mined.

Nov 1, 2021

By Helmer Heldstrom

Gravity surveying with the torsion balance or the pendulum for ore prospecting purposes has generally not been considered practical or even possible. It is the intention of this paper to show that a fast and sensitive gravimeter can be very useful in ore prospecting, as an auxiliary to the electrical and magnetic instruments. A number of gravimeters have been constructed and put in practical use in the last seven or eight years; for instance, by Ising, Lejay-Holweck, Haalck, Hartley, Thyssen, Noergaard, the Humble Oil and Refining Co. and the Gulf Production Co. Their main application, apart from their use for geodetic surveys, has been for structure mapping in oil prospecting. There is no record that any of them have been used for ore prospecting. About the middle of 1934 the Boliden Mining Co., in Sweden, began experiments in constructing a static gravity meter sensitive enough for ore prospecting. Calculations and considerations that will be discussed later in this paper showed that this would necessitate an accuracy in the measurements of 0.1 milligal—roughly, one ten-millionth part of the total force of gravity. The first successful practical field tests of the instrument were made in January 1936. About the middle of 1937 the Boliden gravimeter was perfected. Ore prospecting with this instrument is now regular practice in Sweden, especially for the testing of indications given by geoelectric and magnetic methods. Gravity Anomalies that May Be Expected from Ore Bodies According to Newton's law, a mass M attracts the unit mass in a distance r with the force , GM where G = the gravitational constant = 6.68 . 10-8 c.g.s units. In the c.g.s., or centimeter-gram-second, system the force of attraction is expressed in the unit "dyne," which has the physical dimension c.g.s.-2 and denotes the force needed to accelerate the unit mass in one second to

Jan 1, 1940

By Helmer Heldstrom

Gravity surveying with the torsion balance or the pendulum for ore prospecting purposes has generally not been considered practical or even possible. It is the intention of this paper to show that a fast and sensitive gravimeter can be very useful in ore prospecting, as an auxiliary to the electrical and magnetic instruments. A number of gravimeters have been constructed and put in practical use in the last seven or eight years; for instance, by Ising, Lejay-Holweck, Haalck, Hartley, Thyssen, Noergaard, the Humble Oil and Refining Co. and the Gulf Production Co. Their main application, apart from their use for geodetic surveys, has been for structure mapping in oil prospecting. There is no record that any of them have been used for ore prospecting. About the middle of 1934 the Boliden Mining Co., in Sweden, began experiments in constructing a static gravity meter sensitive enough for ore prospecting. Calculations and considerations that will be discussed later in this paper showed that this would necessitate an accuracy in the measurements of 0.1 milligal—roughly, one ten-millionth part of the total force of gravity. The first successful practical field tests of the instrument were made in January 1936. About the middle of 1937 the Boliden gravimeter was perfected. Ore prospecting with this instrument is now regular practice in Sweden, especially for the testing of indications given by geoelectric and magnetic methods. Gravity Anomalies that May Be Expected from Ore Bodies According to Newton's law, a mass M attracts the unit mass in a distance r with the force , GM where G = the gravitational constant = 6.68 . 10-8 c.g.s units. In the c.g.s., or centimeter-gram-second, system the force of attraction is expressed in the unit "dyne," which has the physical dimension c.g.s.-2 and denotes the force needed to accelerate the unit mass in one second to

Jan 1, 1940

By Robson Aguiar de Macedo

O estudo de ligas livres de Pb envolvendo o emprego de junções metálicas sob altas temperaturas tem recebido atenção especial, sendo desenvolvidas novas ligas com qualidade e desempenho adequados. Ligas Bi-Ag consistem em alternativas promissoras para a substituição das ligas de solda contendo Pb para tais aplicações, por isso devem ser melhor caracterizadas sob o aspecto de estruturas brutas de fusão. Assim, o presente trabalho objetiva investigar a liga hipoeutética Bi-1,5%Ag (%em peso) solidificada unidirecionalmente sob regime transitório de fluxo de calor. Será analisada a influência dos parâmetros térmicos de solidificação como velocidade de solidificação (VL), taxa de resfriamento (?) gradiente de temperatura (G) na microestrutura e na evolução de dureza da liga citada. Para determinação do perfil de dureza, foram realizados ensaios de dureza Vickers. Para obtenção e caracterização das microestruturas presentes no fundido Bi-1,5%Ag, fez-se o uso da microscopia ótica e da fluorescência de raios-x. Uma estrutura de dendritas facetadas de Bi circundadas pelo eutético Bi-Ag prevaleceu ao longo do lingote Bi-1,5%Ag. Verificou-se um aumento gradativo dos espaçamentos dendríticos primário (?1) e secundário (?2) à medida que a distância da base refrigerada foi aumentada. Em geral, os valores de dureza diminuíram para maiores valores de ?1 e ?2.

Aug 7, 2018

By Alexander Sutulov

El presente texto señala la importancia del beneficio de minerales sulfurados y oxidados de cobre a través de dos apartados: Los aspectos generales y la mineralurgia del cobre. Los primeros comprenden la disminución del contenido fino de las menas, materias primas complejas, aumento de escala, control automático y planta del futuro. Mientras que el segundo, describe la flotación de sulfuros, el proceso de segregación, tratamiento de óxidos, métodos hidrometalúrgicos y la lixiviación bacteriológica.

Nov 20, 1969

By Francis A Thomson

Montana Bureau of Mines and Geology, Montana School of Mines, Butte, Mont Francis A Thomson, President. The Bureau of Mines and Geology was formerly known as the Bureau of Mines and Metallurgy. A list of publications will be sent upon request¬ A series of six Bulletins and five Memoirs liave been issued by tlie Bureau, as well as several miscellaneous contributions Where the price is not indicated in tlie following selected list of those publications which are now available, the publications are presumably distributed gratis: Bulletin 3, Mechanical ore sampling in Montana, by H B Pulsifer (1920); 6, Geology and ore deposits of Bannack and Argenta, Montana, by P. J Slienon, 50 cents, Memoir 1, The Kevin-Sunburst and otlier oil and gas fields of the Sweetgrass Arcli, by E S Perry (1929), 2, Natural gas in Montana, by E S Perry (in preparation), 4, Tlie geologic structures of western Montana, by C H Clapp and others (in preparation), 5, Placer mining possibilities in Montana, by O A Dingman (1932).

Jan 1, 1933

By Jhon Silva-Castro, Russell Lamont

Understanding the behavior of materials subjected to high strain rate conditions is of fundamental importance to the mining industry. Several stages of the mining process involve high speed loading rates including blasting, scraping, comminution, etc. Technical comprehension of how rocks deform, fracture, and fail under these loads is a fundamental first step required prior to any serious attempts at optimization of the energy utilized for pertinent activities in the mining process. A Split-Hopkinson Pressure Bar (SHPB) was designed and constructed at the University of Kentucky to study the dynamic properties of various types of rocks.

Jan 1, 2017

By Milan Yekich, Emanuele Cauda, Justin Patts, Cody Wolfe

A worker’s personal exposure to respirable dust in occupational environments has traditionally been monitored using established methodologies which entail the collection of an 8-hour representative sample that is sent away for laboratory analysis. While these methods are very accurate, they only provide information on the average exposure during a specific time period, generally a worker’s shift. The availability of relatively inexpensive aerosol sensors can allow researchers and practitioners to generate real-time data with unprecedented spatial and temporal granularity. Low-cost dust monitors (LCDM) were developed and marketed for air pollution monitoring and are mostly being used to help communities understand their local and even hyper-local air quality. Most of these integrated sensing packages cost less than $300 per unit, in contrast to wearable or area dust monitors specifically built for mining applications which have been around for decades but still average around $5,000 each. At the National Institute for Occupational Safety and Health (NIOSH), we are leveraging the power of high-volume data collection from networks of LCDM to establish baseline respirable hazard levels and to monitor for changes on a seasonal basis as well as following any application of control technologies. We have seen the effective use and advantages of monitoring live data before, during, and after events like shift changes, operational changes, ventilation upgrades, adverse weather events, and machine maintenance. However, many factors have prevented a systematic adoption of LCDMs for exposure monitoring: concern for their analytical performance, the complexity of use, and lack of understanding of their value are some factors. This contribution outlines a one-year case study at a mine in Wisconsin USA, covering the installation, maintenance, data visualizations, and collaboration between NIOSH researchers and the industrial hygiene professionals at the mine.

Feb 1, 2024

By T. Feldmann

Despite the ubiquity of applications for germanium, there is a lack of practically useful solubility data in acidic solutions. Previous studies were done at ambient temperature and only for commonly used acids (H2SO4, HCl). Hence, an investigation of the solubility of GeO2 in different acids was undertaken. Several inorganic and organic acids were studied in the concentration range of 1–11 mol/L and at 23, 40, and 60 °C. In the case of H2SO4 and HCl previous data was confirmed. Lower acidity resulted in a higher solubility for Ge at all tested temperatures. Tests done at 40 and 60 °C and low to moderate acidity levels, gave slightly increased solubility values at higher temperatures compared to 23 °C. This wasn’t the case at higher acidity levels, i.e., the solubility curves at different temperatures converge at high acidity. Lastly, a relationship of water activity and GeO2 solubility in different acid media was established.

Low-grade ore bodies, increase in rock competency, finely disseminated valuable minerals in the ore bodies, ore variability and water scarcity are among the technical challenges faced by the mining industry. These challenges have increased the business risk, capital investment and operating cost of the mining projects. Since the last 20 years, many large-scale concentrators have been built to cope with the above-mentioned challenges. Comminution, especially the fine grinding is an energy-intensive process. For example, the ball mill has a limitation in the fine grinding regime where the energy consumption increases exponentially when the product size is below 45 µm. The industry has been seeking for solutions that have a minimum risk and total cost of ownership. The stirred milling technology such as the TowerMill is well accepted by the industry as it has demonstrated the attributes required for fine grinding. TowerMill is a matured technology that has been adopted since the 80s for regrinding duty. Recently, this technology was installed in secondary and tertiary grinding duty to prepare a finer feed to rougher flotation. Four units of TowerMills were installed in a magnetite concentrator in Western Australia in tertiary grinding duty. Recently, Nippon Eirich has conducted process performance evaluation on the TowerMill circuit. The outcome of the exercise had indicated that the circuit is consuming 3.4 kWh/t to reduce from 55 µm to 35 µm with a narrow product size distribution. The effect of operating variables such as the specific energy, grinding media size, mill content % solids and mill feed configuration on the grinding efficiency were evaluated at the plant scale. Furthermore, the scale-up methodology was validated. The scope of this paper includes the performances of TowerMill and the validation of scale-up methodology.

Jan 1, 2018

By P. E. Weidmark

"PART I - Published PapersBallivy, G., and Dupuis, M., ""Laboratory testing for the design of grouted rock anchors""; Proc 6th Pan Am Conf Soil Mech Found Eng; Lima; 1:277-291; 1979.Ballivy, G., Ladanyi, B., and Gill, D., ""The effects of moisture content on the strength of fissured rocks""; Proc 1// 1ntnl Congr 1.A.E.G.; Madrid; //:2:7-16; 1978.Baumgartner, P., and Stimpson, B., ""Development of a tiltable base friction frame for kinematic studies of caving at various depths""; Int J Rock Mech Min Sci Geomech Abstr; 16:4:265-267; 1979.Bawden, W.F., and Roegiers, J.-c., ""Discussion and interpretation of the mathematics governing radial flow in a single horizontal rock fracture""; ISBN 07727-7002-6; Dept Civil Engng publication 79-11; Univ Toronto: 134p;1979.Chatterji, P.K., Smith, L.B., and Insley, A.E., ""Construction of Saline Creek Tunnel in Athabasca oil sand""; Can Geotech J; 16:1:90-107: 1979.Coates, D.F., and Gyenge, M., ""A case history of pit slope design""; Proc 4th ISRM Congr; Montreux, Switzerland; Sept 1979; 1:Theme IV:591-596; 1979.Crawford, A.M., and Curran, J.H., ""A dynamic direct shear machine for determining the time-dependent behaviour of rock joints"": Dept Civil Engng publication 79-08; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A displacement discontinuity approach to modelling the creep behavior of rock and its discontinuities""; Dept Civil Engng publication 79-09; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A higher-order displacement discontinuity element""; Dept Civil Engng publication 79-10; Univ Toronto; 1979.Cruden, D.M., ""A computer-based system for rock mass description""; Proc 1// Intnl Congr I.A.E.G.; Madrid; //:2:155-159; 1978.Cruikshank, D.J., and Curran, J.H., ""A.B.LE. approach to modelling of fluid flow in fractured rock masses""; Proc 7th Cdn Congr Appl Mech; May 1979; Sherbrooke, Que; 887-888; 1979."

Jan 1, 1980

By Sepulvedam Jaime E., Levi Guzmán Rivera

"Grinding media consumption rates and their dependence on key operating conditions in semiautogenous grinding mills is analyzed on the basis of a detailed mathematical model recently developed by Moly-Cop´s specialists which describes and takes into account the three primary media consumption mechanisms, namely: abrasion/corrosion, surface spalling and impact ball breakage. The influence of key mill operating conditions – such as ball filling, discharge grate opening, mill speed, lifter profile, and ball quality – on their corresponding grinding media consumption rates is explored via a variety of model simulations, discussing in every case the independent contribution of each of the indicated consumption mechanisms to the estimated total ball consumption rate.INTRODUCTIONA thorough understanding of the independent contribution of each grinding media wear mechanism is extremely important, especially in semi-autogenous grinding (SAG) operations where macrowear (spalling) and ball breakage cannot be ignored or neglected. The high impact conditions imposed in modern SAG milling environments has created serious challenges for grinding media manufacturers since their products must be able to perform with minimal breakage and surface spalling.GRINDING MEDIA WEAR MECHANISMFor SAG milling operations, at least 3 different mechanisms have been identified as the main contributors to the observed overall grinding media consumption, here referred to as: abrasion / corrosion, ball breakage and surface spalling.Wear by Abrasion/CorrosionThe abrasive/corrosive wear mechanism has been discussed in depth in previous publications (Benavente Hector, 2007; Guzman Levi, 2014; Sepulveda and Morrow, 2014). The most widely accepted approach to mathematically characterize the consumption (wear) kinetics of grinding media in rotary tumbling mills is known as the Linear Wear Theory (Prentice, 1943; Norquist, 1950; Sepulveda, 2004) which claims that—at each instant 't' after a grinding body enters the mill load—the rate at which the body loses weight is directly proportional to its surface area exposed."

Jan 1, 2016

By J. W. Spretnak, J. N. Cordea

The gain boundary relaxation in high-purity aluminum, nickel, copper, and silver was studied by means of a low-frequency torsion pendulum. Both internal friction and creep at constant stress tests were conducted. A lognormal distribution in relaxation times was found to account for the relatively wide experimental internal friction peaks and the gradual relaxation behavior during the creep tests. This distribution was separated further into a lognormal distribution of relaxation time constants and a normal distribution in activation energies. A spread of up to ±6 kcal per mole in the activation energies accounted for the major part of the distribution. A "double-peak" internal friction phenomenon was observed in silver. The activation energies in kcal per mole derived from the grain boundary relaxation phenomena are 34.5 for aluminum, 73.5 for nickel, 31.5 for copper, and 41.5 for silver. It was found that the rain boundary relaxation strength in these metals increases with the reported stacking-fault energy. GRAIN boundary relaxation phenomena have been observed in a large number of polycrystalline metals and alloys. Numerous investigations have been conducted to study the structure of the grain boundary through this relaxation process. One of the first investigators was Ke1-4 who observed that the activation energy for grain boundary relaxation in aluminum, a brass, and a iron was about the same as that for volume diffusion. He concluded that the grain boundary behaved as if it were a thin liquid layer with neighboring grains sliding over one another. Leak5 conducted experiments on iron of a higher purity and observed that the grain boundary activation energy is comparable with that of grain boundary diffusion. He suggested that, in metals where this relationship holds, the damping may be caused by a reversible migration of grain boundaries into adjoining grains. Nowick6 has presented an interesting view of inter-facial relaxation with his "sphere of relaxation" model. A relaxed interface is represented as one where the shear stress is greater than the normal value along the edges and zero in the interior of the interface. The region of the stress relaxation is pictured as a sphere surrounding the interface. From his calculations Nowick concluded that the slip along an interface is directly proportional to its length. Therefore, the time of relaxation, T, depends on the size of the relaxation interface. This means that in the Arrhenius relationship, t = TO exp[H/RT], valid for atom movements, the relaxation time T is predicted to be proportional to the grain diameter through the pre-exponential term, TO. Since the internal friction can be given as Q-1 = ?j wt/(1 + w2r2), where ?J is the relaxation strength and w is the angular frequency, an increase in grain size at a constant frequency will shift the peak to a higher temperature. A great deal of work has been done to determine the exact relationship between the internal friction and grain size.1,5,7,8 In metals, the grain boundary peaks are found to be lower and broader than predicted theoretically.' The above model can explain this by a distribution in the size of the interface areas, represented by a distribution in the parameter tO, and an overlap of spheres of relaxation, represented by a distribution in activation energies. Both these phenomena result in an over-all distribution in the relaxation time, which could affect the internal friction peak height, breadth, and also position. This relationship between the experimental data and theoretical calculations appears very promising in the study of interfacial relaxation mechanisms. THEORY A lognormal distribution in t can sometimes be used to adequately describe the spectrum of relaxation times governing an anelastic relaxation. wiechert9 originally suggested such a distribution to explain the elastic after-effect in solids. This choice is particularly applicable to grain boundary relaxation when considering Saltykov's work.'' He found a lognormal distribution in the grain sizes within a metal. Recently Nowick and Berry11 have introduced a log-normal distribution in T into the theoretical internal friction equations. The form of the distribution function is where z = In(r/rm), and Tm is the mean value of t. The parameter ß is a measure of the distribution and is the half-width of the distribution when is l/e of its maximum, IC/(O). Nowick and Berry have described the methods to obtain the parameters Tm, ß, and ?,J from experimental internal friction and creep test data. In the idealized case, where only one relaxation event occurs with one relaxation time, only ?J and T are necessary to completely describe the event, and 0 = 0. For the broader internal friction curves 6 is some positive number greater than zero. The larger the 6, the greater is the half-width of the distribution in In t.

Jan 1, 1967

By W. G. Liu

Phenyl malonic acid (PMA), a new chelating collector, which contains a phenyl structure and a malonic acid chelating group, has been synthesized and its collecting capabilities to calamine, hematite, quartz and hemimorphite are also studied in laboratory. From the experimental results, it can be seen that the PMA has somewhat flotation ability to calamine, hematite and quartz, while it nearly has no collecting ability to hemimorphite. With the increase of PMA concentration, the flotation recovery of calamine increases. When the dosage of PMA was 560g/t and at pH=7~9, the flotation recovery of calamine gets its maximum of 45.94%. The test results about the influence of pH on the flotation recovery of quartz show that the flotation recovery increases with the increase of pH, and the maximal flotation recovery can be gained in alkaline media. On the other hand, PMA has stronger flotation capability to hematite than to other minerals. The flotation recovery of minerals increases with increase of PMA concentration. When the dosage of PMA is 560g/t and at pH=5~7, the flotation recovery of hematite is 82.96%. Mean-while, the influence of pH on the flotation recovery of hematite was studied and test results showed that, as pH increases, the flotation recovery sharply rises until pH=4, then the increasing rate de-creases outstandingly, at pH=6 the flotation recovery reaches its maximum of 82.96% and it de-creases speedily in alkaline media. Finally, through the measurement of infrared spectroscopy and in terms of solution chemistry of collector, the flotation mechanism has been discussed. It was concluded that the adsorption of PMA on minerals surface is chemical adsorption in nature through two oxygen atoms in the polar group of phenyl malonic acid chelating with the metal ions of minerals surface to form a hexagon-cycle chelate complex: C(=O)-O-M-O-(O=)C.

Jan 1, 2014