Search Documents

By E. E. Cudby

"FOLLOWING the Leduc discovery •by Imperial Oil in 1947, The California Standard Company began to acquire land in the area immediately west of Edmonton and in line with the Leduc reef trend (Figure 1).The California Standard Winter-burn Province No. 1 in Lsd. 10, Section 4, Township 53, Range 25, West 4th, which was spudded, on the basis of a seismic anomaly, in December, 1949, failed to find reef. This well was located on the eastern .edge of a large land block which California Standard and Imperial Oil had pooled as a joint venture, with California Standard a:s the operator (Figure 2).The culmination •of an extensive exploration and land aquisition programme was the drilling of the California Standard-Acheson Province No. 1 well .in Lsd. 13, Section 2, Township 53, Range 26, West 4th. On August 24th, 1950, a drill stem test was run in the D-3 zone which had been encountered at 4,969 feet, and a flow rate of 702 barrels per day •of 36° gravity oil was obtained. Just previously, Imperial Oil had completed a similar programme in the Stony Plain Reserve with the swabbing-in of Imperial Stony Plain No. 1. These two discoveries set off a drilling programme to determine the extent and value of the oil accumulation.Subsequent drilling of wells some successful .and others not by several other companies as well as California Standard bias, .to date, still left much to be determined as to the approximate delineation of the productive limits of the Ache-son-Stony Plain area. However, to August 31st, 1951, there were twenty-one D-3 producers north of the reserve and three in the Stony Plain Reserve."

Jan 1, 1952

By J. Trojacek

A large-scale development in exploration and production of uranium ores in the Czech Republic was done in the 2nd half of the 20th century. Many uranium deposits were discovered in the territory of the Czech Republic. Over a period of 50 years approximately, 110 000 tons of uranium in concentrate were produced. Different mining methods were developed and used. One of the most considerable deposits in the Czech Republic is the site Hamr na Jezere ? Straz pod Ralskem where both mining methods ? the underground mining and the acidic in-situ leaching ? were used. The extensive production of uranium led to widespread environmental impacts and contamination of groundwaters. Over the period of ?chemical? leaching of uranium (ca. 32 years), a total of more than 4 million tons of sulphuric acid and other chemicals have been injected into the ground. Most of the products (approximately 99.5 %) of the acids reactions with the rocks are located in the Cenomanian aquifer. The contamination of Cenomanian aquifer covers an area larger than 27 km2. The influenced volume of groundwater is more than 380 million m3. The total amount of dissolved SO4 2- is about 3.6 million tons. Approximately 0.5 % of the contamination is located in the Turonian aquifer. After 1990, a large-scale environmental program was established and the Czech government decided to liquidate the ISL Mine and start the remediation in 1996. The remediation consists of contaminated groundwater pumping, removing of the contaminants and discharging or reinjection of treated water. The objectives of the remedial activities are the followings : to restore the aquifer to a condition guaranteeing continuing usability of Turonian water of Northern Bohemia Cretaceous, to decommission boreholes and surface installations and to incorporate the surface of leaching fields into the ecosystems taking into account regional systems of ecological stability and urban plans. Nowadays four main remedial technological installations for reaching of these aims are used - the ?Station for Acid Solutions Liquidation No. One?, the ?Mother liquor reprocessing? station, the ?Neutralization and Decontamination Station NDS 6? and the ?Neutralization and Decontamination Station NDS 10?. Total capacity of this complex is sufficient to reach the target values of remedial parameters in 2037. The remediation action consists of: pumping of residual solution to the surface, separating uranium from the solution and reprocessing contaminants into commercially usable or ecologically storable products. It is expected that the amount of withdrawn contaminants will vary from 80 000 to 120 000 tons per year. Total costs of all remediation activities are expected to be in excess of 1.5 billion EUR.

Aug 1, 2013

By K. Tempel

In December of 1999, Newmont Mining Corporation’s Eastern Nevada Operations commissioned its commercial biooxidation facility. The commercial biooxidation facility is a refractory gold whole ore heap process that uses bacteria to assist with the oxidation of sulfide minerals thus liberating occluded gold for further processing by cyanide for gold extraction. Before the commercial biooxidation facility was started, a decade of research went in to developing this state-of-the-art process. During final design and construction of the commercial facility a decline in gold price necessitated cost saving and project scope changes. As a result, the biooxidation process experienced many challenges. Some of the more significant challenges include poor heap permeability due to haul truck stacking, unhealthy bacteria population due to a lack of solution aeration, and insufficient biooxidation time because of limited pad space and high carbonate content in the ore. This paper discusses the many challenges encountered and addressed during the first 2-3 years of commercial biooxidation operation.

Jan 1, 2003

By Paul Averitt

The U. S. Geological Survey has been actively engaged in work on coal for more than 50 years. During this long period we have released more than 300 publications containing information about coal and coal reserves, including details on the thickness, distribution, and quality of coal, and the structure and stratigraphy of the coal-bearing rocks. We have also cooperated with state surveys on many similar publications. For many areas these reports are the only reliable published data on our resources of coal. During the last several years we have substantially increased our activities above the wartime low. We now have field work in progress, or reports in preparation, on 13 detailed mapping projects distributed as follows: 1. Pennsylvania anthracite field 2. Casselman Basin, Md. 3. Leslie County, Ky. 4. Deep River field, N. C. 5. Coosa field, Ala. 6. Powder River field, Mont. 7. Spotted Horse field, Wyo. 8. Yampa field, Colo. 9. Paonia field, Colo. 10. Trinidad field, Colo. 11. Durango field, Colo. 12. Chaco River area, N. M. 13. Lewis and Thurston County fields, Wash. For two of these areas; the Paonia field, Colo., and the Coosa field, Ala., we have published recently preliminary reports, and final reports are in preparation. In addition, we are nearing completion of a coal reserve study of Montana, and are beginning similar studies in several other states, as part of a program of revising our estimate of national coal resources on the basis of presently available data. Factors Involved in Making Estimates Our responsibilities include detailed field mapping to secure information on areas of outcrop of coal beds, their range in thickness, nature of roof rock, amount of overburden, correlation of the beds, stratigraphy and structure of the coal-bearing rocks, and the preparation of coal reserve figures based on these data. The computation and estimation of resources of coal in the ground, like that of resources of other mineral commodities, involves consideration of many additional purely geological factors that can be appraised best through such regional studies. Regional variations in the thickness and texture of rocks overlying and underlying coal beds, for example, give evidence as to the probable position of the edges of the basin of coal deposition, or may aid in the delineation of sand-filled channels that sometimes cut out coal beds. It is apparent that the detailed field studies, in which data are gathered, are the basis for coal reserve studies, and in our present program these two phases of work are being carried on together. Previous Coal Reserve Estimates For many years we have been aware

Jan 1, 1950

By Jameel Menashi

Aqueous solutions of Na2Cr04 can be reduced with CO to produce hydrous Cr203 and NaHCO3/Na2CO3. CH3OH, HCOO and HCHO in the presence of CO2 also reduce Cr 6+ and yield similar products. It is shown that the rate of Cr6+ reduction can be represented by the expression -d[Cr6+]/dt=k[Cr6+)1/2[R] where [R] is the aqueous phase concentration of CH3OH, HCOO- or CO. With these three reductants, the activation energies for the reduction processes are comparable and are of the order of 100 kJ/mole. Rapid reduction rates are attained at temperatures in excess of 220°C and, with these three reductants, a green acid-insoluble readily filterable hydrous Cr203 is formed. With HCHO significant reduction of Cr6+ occurs at about 80-100°C and an acid-soluble violet modification of hydrous Cr2O3 is formed. The reduction process is reasonably selective: solutions of Na2CrO4 contaminated with Mo6+ and W6+ can be reduced to yield a Cr2O3 product with significantly reduced contaminant levels. These findings are utilized as a basis for a process for recovering chromium from secondary source materials.

Jan 1, 1984

By E. Vilaescusa, J. Eloranta

The work presented in this paper investigates the influence of non-ideal detonation characteristics related to the blasthole diameter, base emulsion sensitivity (micro-balloon sensitised versus unsensitised) and percent emulsion on the explosive shock energy available to break rock using ANFOemulsion blends. A series of theoretical equal powder factor bench blasting patterns with hole diameters of 127mm (5”), 140mm (5.5”), 152mm (6”) and 165mm (6.5”) are compared to assess the non-ideal confined shock-state work energies. The Non-Ideal Shock Energy Factor (NSEF), which is the available shock energy per cubic meter of blasted material (MJ/m3) or kilocalories per cubic yard (kcal/yd3), is used to compare the different blasting patterns charged with a range of ANFO-emulsion blends from zero to 50% emulsion.

Jan 1, 2012

By Hedley TP

Success for underground coal mine operators in the 1990's and beyond will be dependent upon better understanding of the dynamics of their operating environment, and extension of emerging technologies to reach new levels of output and productivity. The Collieries Division of B.H.P. Steel International Group clearly identifies with the concept of business/product life cycles - and the need to adopt strategies that can drive the business successfully into the future. Three main thrusts within BHP Collieries Division relate to: 1) Detailed assessment of current mines to determine: a) The real output potential of the current facilities. b) What factors now inhibit the full potential from being realised. c) Opportunities that exist to enhance overall mine performance. 2) Based upon the findings of these studies, putting into place cost effective strategies and systems for the ongoing "tuning" of the mine. 3) of new/improved technology primarily in areas of: a) Coal cutting and underground coal clearance. b) Controlling the overall mine gas Regime.

Jan 1, 1987

By Carlos De la Vega, Clever Oriel

Compañía Minera Huarón, mina subterránea del grupo Panamerican Silver, es una mina polimetálica, el cual en su estructura geológica cuenta con vetas angostas de muy buena ley, donde el ancho de veta varía de 0.4 m. a 1.2 m. y para ejecutar las preparaciones manteniendo un promedio de ley diluido que les genere ganancia, se realizaba el método de voladura en circado, para luego realizar la segunda voladura en desmonte, sin embargo este tipo de voladura generaba retrasos en el ciclo de minado de la preparación del block para la explotación, es en este escenario que surge la propuesta de la segregación de mineral-desmonte en un solo evento haciendo uso de la tecnología del eDev™ II, que es un detonador electrónico con alta precisión en sus retardos

Sep 29, 2023

By D. C. Holloway

Ceramic projectiles made from 94% to 99% alumina with a nominal mass of 3.1 gms were fired into granite blocks. The average compressive strength of the ceramic was 800 MPa and that of the rock was 135 MPa. Flat, ogive, conical and pyramidal nose shapes were evaluated at velocities ranging from 450 to 1400 m/sec. It was found that the conical and pyramidal nose shapes at the higher velocities did a significant amount of damage to the rock. On the average, they removed 10 5mm3 of rock and were six and ten times better than the flat and ogive nose shapes. It was also observed that increases in volume occur in discrete steps. This process is highly dependent on the ability of the projectile to penetrate the rock.

Jan 1, 1984

By B Roach, P M. Ashley, B Hooper

Mineral occurrences of the Hillgrove Au-Sb-W district are hosted in late Palaeozoic polydeformed, hornfelsed metasediments and Permo-Carboniferous granitoids of the NewEngland Orogen. In excess of 204 individual occurrences have been identified to date with the mineralisation developed as strike extensive (>20 km of known veining) and potentially depth extensive steeply dipping fissures. These are contained within an elongate area measuring some 9 km by 6 km in surface dimensions. Recorded gold production of 720 000 ounces along with current resources in the order of 340 000 ounces highlight the significance of this district. Historical antimony production is estimated at in excess of 50 000 metric tonnes. Significant tungsten of over 2000 t in the form of scheelite has also been produced from the field. Mineralisation is developed in veins, vein breccias, sheeted veins, network stockworks and as alteration sulfide haloes to the main structures. The vast majority of fissures are subvertical and vary in widths of up to 20 m in places. Paragenetic studies have previously indicated that the earliest mineralising event was a scheelite-bearing phase of quartz veining. Subsequent phases of arsenopyrite-pyrite-quartz-carbonate veining were accompanied by gold and minor base metal sulfides. Alteration is typically sericite-ankerite-quartz. Overprinting stibnite-quartz veining with gold-electrum, aurostibite and arsenopyrite form an important subsequent phase. Veining can be inferred from historical records to extend for vertical depths of over 1 km.

Jan 1, 2004

By N. Weidner, V. A. Samaranayake, K. Awuah-Offei, S. Que

"This research sought to facilitate improved stakeholder (community) analysis using discrete choice theory (DCT). The work considered 16 project attributes and four demographic factors. The discrete choice experiment was conducted in Salt Lake City, Utah to illustrate the usefulness of DCT in mining stakeholder analysis. The data was used in discrete choice modeling of individual preferences. The approach answers three important questions for enhanced stakeholder analysis: (1) What are the factors that affect individual preferences? (2) What is the effect of demographics on individual preferences? (3) What is the value of environmental and social impacts to individuals in the community? INTRODUCTION Stakeholder analysis is crucial for effective stakeholder engagement because it is important to identify and characterize stakeholders in order to effectively engage in dialogue with them. This is not only true for all stakeholders but true for characterizing the members of a particular stakeholder. The local community is usually the largest and most diverse single stakeholder group. Also, the local community is perhaps the most important stakeholder group. Thus, analysis of the local community is essential for project management. Conventional mining stakeholder analysis is a three-step process, which involves evaluating: (1) each stakeholder’s view of the project (positive, neutral, or negative); (2) how influential each stakeholder is (high, medium, or low); and (3) how they will be impacted by the project (high, medium, or low) (ICMM, 2012). The results of this evaluation are documented in a stakeholder analysis matrix (Table 1), which is used to classify the stakeholders into three groups: highly influential supporter of the project, neutral about the project, and highly influential opponent of the project. This process can be used to describe groups of stakeholders (e.g. community, non-governmental organizations, etc.) or individuals making up a particular stakeholder group (e.g. members of the local community)."

Jan 1, 2016

By J. F. Wolff

CARL ZAPFFE, Brainerd, Minn. (communication to the Secretary*).¬Unless one has actually directed explorations for iron ore, it is doubtful whether the importance of Mr. Wolff's paper, the value of the information contained, and the large amount of detail work involved in what is set forth can be fully appreciated. It is indeed rare to get such a com-

Jan 3, 1917

By R. N. Stevens

GRAIN boundary sliding plays a part in the high-temperature deformation of polycrystalline solids, and many investigations1-11 have been carried out to determine the deformation contributed by this mechanism. The principal method employed has been to measure one of the components of the grain boundary displacement, see Fig. 1, at a large number of boundaries, and from the mean value so obtained to calculate the elongation contributed by sliding. A formula connecting these mean values and the elongation contributed is evidently required, and many have been derived. They are usually of the form where Egh is the tensile elongation contributed by sliding, is the mean value of the component, x, N is the mean number of grain boundaries intersecting a line of unit length, and K is a dimensionless parameter known as the averaging factor. Table I summarizes the equations used by various investigators. Examination of these shows that their derivations usually involve doubtful assumptions, and are often in serious error. The purpose of this note is to point out that rigorous solutions to the problem of calculating Egb from x have been available in the literature for some years.' Since this is so little known, and also the original derivations do not make some important points clear, it is proposed to rederive the basic equations. These will be extended further, and the conditions in which the extended equations may be applied will be indicated. The mean values of the components of the sliding vector (I, d, and I:, Fig. 1) will depend on the method by which boundaries are sampled in order to make measurements.3,11 Boundaries are usually sampled by marker lines parallel to the stress axis, or lines perpendicular to the stress axis, the measurement being made at the point where the marker line intercepts the boundary. We will denote the mean values determined by these various sampling methods as follows. lT, dT and vT are mean values obtained by making measurements at pointswhere a transverse line intercepts the boundary while lL, dL, and vl, are the mean values from a longitudinal line. The number of boundaries per unit length also may depend on the direction of measurement, and so we define NT and Nl to be the number of boundaries per unit length, after creep, in the transverse and longitudinal directions, respectively.

Jan 1, 1967

By Rudolf E. Pfister

One of the Swiss transalpine highways includes two remarkable tunnels: the 16.3 km long Gotthard Road Tunnel and the 9.3 km long twin tube Seelisberg Tunnel, both presently under construction. Large diameter shafts up to 900 m long are required for ventilation. Excavation techniques for rock formations ranging from loose sedimentary rock to granite and very hard siliceous limestone were carefully evaluated. The methods finally applied include excavation of shafts in hard rock, conventional drilling and blasting, excavation by ripper-tooth excavator ("Big John") in marlstone, shield protected heading in loose material and soft rock, and tunnel and shaft lining, both by poured concrete and by prefabricated elements. A critical review of the success of these methods can now be made after a five year construction period.

Jan 1, 1976

The Myra Falls minesite, of Westmin Resources Limited, is located at the geographic centre of Vancouver Island, within the confines of Strathcona Provincial Park. The operation includes two active underground mines, II-W and Lynx, together with a modem 3650 1/d milling facility. Recent exploration successes will lead to the commissioning of a third mining area in late-1993 - The Battle/Gap Mine. These ore deposits are complexly metal-zoned volcanogenic massive sulphides of Devonian age, hosted in the Myra Formation of the Sicker Group volcanic assemblage. Three distinct felsic volcanic units are defined within the 450 metre thick Myra Formation. They are, from oldest to youngest, the H-W Horizon, the LMP Horizon and the Upper Rhyolite Unit. Massive sulphide mineralisation occurs throughout the property in the H-W and LMP Horizons. There are a number of orebody types, including polymetallic massive sulphides, polymetallic disseminated sulphides, zoned pyritic massive sulphides, elastic sulphide zones and stringer sulphide zones. Individual orebodies range in size from 10 000 tonne zinc-rich polymetallic lenses to the ten million tonne, zoned massive sulphide H-W main lens. The property has been in continuous operation for 26 years, producing over 13 Mt of ore averaging 2.2 g/t Au, 64.0 g/t Ag, 1.9 per cent Cu, 0.6 per cent Pb, and 5.6 per cent Zn. Current geological reserves stand at 12.5 Mt at a comparable grade, including 4 Mt of recently discovered high grade ore in the Battle and Gap Zones. Mining and milling methods have evolved over time to enable successful extraction and milling of these complex ores. Change is on-going with the recent conversion of the H-W Mine to large-scale bulk mining methods, and the development of effective computerised ore reserve calculation and mine planning tools. These changes, in concert with successful exploration techniques that led to recent high grade ore discoveries, have breathed new life into the operation and should assure its present and future viability.

Jan 1, 1993

By K. Schimann, H. D. Knipping, J. P. Fouques

"The Cigar Lake uranium deposit, in the Athabasca area of north Saskatchewan, was discovered in May 1981 by Cogema (Canada) Ltd., as operator of the Waterbury Lake Joint Venture.The deposit, which is devoid of direct surface expression, is located at the unconformity between the Lower Proterozoic (Aphebian) Wollaston Group meta-sediments and the Middle Proterozoic (Helikian) Athabasca sandstone, at a depth of 410 m to 450 m below surface.At the end of 1984, the deposit had been defined by 105 mineralized holes over a length of 1800 m and a width of between 25m and 105m. It has the shape of flat-lying /em 5 m to 30m thick and shows a remarkable longitudinal and lateral continuity from the information obtained to date. A well defined bulge of the unconformity underlies the mineralized zone over its entire length.The deposit appears to be controlled by an east-west trending structure within which a particular rock facies (""augen gneiss'') has developed in the graphitic metapelites of the Wollaston Group. It is surrounded by a strong alteration halo affecting both sandstone and basement, characterized by extensive development of Mg-AI rich clay minerals (illite-chlorite). The mineralization is hosted principally by the Athabasca sandstone, and consists mainly of uraninite and sulfa-arsenides of nickel and cobalt. Numerous geochemical and geophysical surveys have been carried out in the Cigar Lake area, and although no specific geochemical or geophysical anomaly can be directly associated with the mineralized body, there may be locally a good coincidence.However, a combination of several methods proved extremely useful in interpreting the regional geology and defining the drilling targets within the favourable areas.Although the Cigar Lake deposit shows many similarities with several classical deposits of the Athabasca region, it is characterized by the intensity of its alteration processes and the presence of massive, extremely high grade mineralization.At the end of 1984, the global geological reserves estimated by geostatistics on the main mineralized ""pod"" of the deposit amounted to 110,000 metric tonnes of uranium at an average grade of 12.2% U, with a precision of 25% at the 95% confidence level."

Jan 1, 1986

By Tommy B. Thompson

The Cripple Creek diatreme-intrusive complex is known primarily for its vein telluride-gold ores. It is also known for the great vertical range of its major veins - >990 m (>3250 ft). Not as well-documented, however, are the ores dispersed into the wallrocks adjacent to veins, the ores associated with hydrothermal and tectonic breccias, or mineralized zones within fluvial, lacustrine and volcaniclastic rocks de- posited within the diatreme complex. The ore-gangue minerals were precipitated from oxidized, alkaline fluids that yielded an abundance of carbonate, sulfate and oxide minerals along with minor base metal sulfides and precious metal tellurides. Wallrock alteration is limited adjacent to veins and is more extensive within hydrothermal and tectonic breccias. Cripple Creek background The Cripple Creek district has a spectacular production history. More than 653 t (21 million oz) of gold were recovered between 1891 and 1959. Early published accounts documented the principal production from narrow- sheeted vein systems (Cross and Penrose, 1895; Lindgren and Ransome, 1906; Loughlin, 1927; Loughlin and Koschmann, 1935). Production also came from spectacular open-space fillings within the Cresson diatreme, also known as the Cresson “blow-out” (Patton, 1917; Patton and Wolf, 1915). Beginning in the mid- l96Os, more modern studies were initiated by the US Geological Survey (USGS) (Gott et al. , 1967, 1969; Kleinkopf et al., 1970) and by universities (Lane, 1976: Dwelley, 1984; Trippel, 1985; Thompson et al., 1985; Saunders, 1986; Birmingham, 1987; Eriksson, 1987; Nelson, 1989; Wood, 1990; Seibel, 1991).

Jan 1, 1992

By P. D. Bergman

To assess the efficacy and economics of producing power from coal, four open-cycle magnetohydrodynamic (MHD) processing schemes were selected for study. Each involved a different mode of coal combustion and level of gas cleanliness. The options considered were: (1) coal burned in a slagging combustor; (2) suspension gasification with slag removal prior to combustion; (3) parallel cyclone combustors, one operating fuel rich and the other operating with excess air; and (4) suspension gasification by the hot exhaust gases from the MHO duct with ash removed prior to combustion. Option 1 has the highest ash content in the combustion plasma and as a result would have the greatest operational difficulties associated with it. Options 2 and 4 have the cleanest MHD combustion plasma. For coal priced at $4/ton, the power generating cost of option 4,11.78 mills/Kw-hr, is the highest, with Option 1, at 9.04 mills/kW-hr the lowest. These costs may be compared with a conventional power cost of 9.92 mills/kW-hr for the late seventies. Capital costs of three of the four options were competitive with those of conventional thermal power plants employing stack gas S02 cleanup systems. Option 2 has the most favorable combination of operating characteristics and power cost. It was concluded that a clean, high-temperature working fluid can probably be produced from coal without leading to depressed system efficiencies and exorbitant capital costs.

Jan 1, 1973

By Tsembel Darjaa, Toru H. Okabe, Yoshiaki Umetsu

"With the purpose of extracting molybdenum and rhenium from molybdenum sulfide concentrate; .electrolysis of slurry, solvent extraction and ·precipitation operations were carried out. The slurry of the concentrate in 10 mass% NaCl aqueous solution was continuously circulated into a vertical type 10 stack bipolar electrolytic cell consisted of carbon electrode disks, and, the concentrate was dissolved by electrochemically generated oxidizers at 313 K. The current efficiency for molybdenum dissolution was 73 % after 10 hours electrolysis, and the leach solution was found to contain 0.2 mol/l of molybdenum and 4x10-5 mol/l rhenium. This result shows the dissolution is more than 8 times faster than that obtained using a single cell. The leach solution from electro-oxidation was then subjected to a solvent extraction for rhenium which is then recovered as sulfides. After rhenium separation, molybdenum was precipitated by pH adjustment, and solid MoO3 (H2O)x crystals, free of sulfate, were obtained from the leach solution containing large amount of so42-.IntroductionIn the past, electro-oxidation using a bipolar cell was applied for leaching molybdenite concentrate and ores at U. S. Bureau of Mines [1-3] and also at Bhabha Atomic Research Center [4]. In· these previous studies, Moebious type bipolar cells, in which electrode plates were vertically inserted into the free surface of the electrolyte, were employed and its effectiveness was demonstrated.Recently, the present authors studied on leaching of Mongolian molybdenite concentrate, and the effectiveness of leaching of the concentrate by electro-oxidation in alkaline and acidic NaCl solutions was demonstrated [5]. The leaching reaction during the process can be explained by the 18 electron transfer reaction of molybdenite (MoS2) with the oxidizers produced in-situ by electrolysis of NaCl aqueous solution. Further investigation was made with respect to various process parameters for electrooxidation such as pH, pulp density and temperature of the slurry, and the dissolution behavior of minor elements such as iron, copper, and rhenium [6]. Solubilities of molybdenum in the leach solution at, various temperatures and pH .was · studied, and feasibility of molybdenum recovery by hydrolysis of molybdenum species was demonstrated. By adjusting the pH of the leach solution, molybdenum oxides or hydroxides free from sulfate were successfully obtained from the solution containing large amount of sulfate ion. Rhenium present in the concentrate at a level of several tens of mass ppm was found to dissolve into the leach solution, and co-precipitate with the molybdenum compounds. Rhenium in the leach solutions, therefore, has to be recovered before precipitation of molybdenum, otherwise it is lost in the precipitate."

Jan 1, 2000

By Robert A. Colten, Frederick C. Hull, Robert F. Mehl

It is known that pearlite forms from austenite by a process of nucleation and growth, and that the rate of formation of pearlite may be described by a rate of nucleation and a rate of growth.l,2 The manner in which these two quantities operate to produce the observed isothermal reaction curve has been analyzed in a paper published in I939.3 Two types of process were described: (I) that in which nucleation occurs at the grain boundaries of the parent phase, with the nodules growing toward the centers of the grains, initially as hemispheres and then after impingement as roughly radial-columnar structures; and (2) that in which nucleation occurs generally, with the nodules growing to full spheres until impingement with other growing nodules restricts growth. Both cases are met in the formation of pearlite from austenite (Fig. I);2,4 the former, occurring near the knee of the S-curve, has been named "grain-boundary transformation," and the latter, occurring at temperatures near Ael, has been named "group-nodule transformation." In developing our knowledge of the factors that determine the rate of formation of pearlite from austenite, it is important1,2 to obtain data on the rate of nucleation and the rate of growth of pearlite. Such data, when obtained near the knee of the S-curve, will furnish information of use in understanding the factors that affect hardenabil-ity; when obtained at higher temperatures, such data will be useful in understanding the behavior of steels that during heat-treatment react to pearlite.2 It is the purpose of this paper to present data on the rate of nucleation and the rate of growth of pearlite in dependence upon composition, grain size, temperature, and the degree of homogeneity of the parent austenite. The studies are restricted chiefly to plain carbon commercial steels." Previous Data on Rate of nucleation and rate of Growth Data on the rate of nucleation and the rate of growth of pearlite have been published by Scheil and Lange-Weise,5 by Mirkin and Blanter,6,7 by Meh1,l and by Dorn, De Garmo and Flanigan.2, It is difficult to interpret the data, for in most cases too little information is given on austenitizing temperatures and times, the state of homogeneity of the austenite (presence or absence of carbide, etc.), austenite grain size, and mode of formation of pearlite at the temperatures given. Except for the approximations of Mehl and the work of Dorn, austenite grain size was disregarded, though it is well known

Jan 1, 1942