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By Ashu Garg, Anirban Bhattacharya

"Friction stir spot welding of aluminum alloy AA6061-T6 sheets was performed with circular (plunge depths 0.4 and 0.6 mm), square and triangular tool pin (plunge depth 0.4 mm) with constant 0.2 mm shoulder penetration to characterize various zones of weld nugget. It was observed that the depth of the stir zone formed below the tool pin is comparatively similar for different tool pins but wider for circular tool pin. The size of another stir zone formed at the interface of tool pin and a tool shoulder is observed to be larger for triangular and square tool pin due to the higher swept rate. Predicted strain from finite element analysis, calculated strain rate using Zener-Hollomon relationship and experimentally measured grain size distribution indicates severe amount of plastic deformation in-and-around the nugget/spot region. Finer grains in various stir zones were observed than thermo-mechanically and heat affected zones. Grain size (at distribution peaks) in stir zones varied around 2.54 µm to 3.69 µm for different tool pin profiles as compared to base metal grain size of 20 µm. Microhardness results indicate that the welded region is quite softened than base metal and maximum hardness is mostly observed around the thermo-mechanically affected zone.INTRODUCTION Friction stir spot welding (FSSW) is widely used for joining the sheets of materials like aluminum, copper, magnesium, etc. The process begins by plunging a rotating tool (generally having a pin and a shoulder) into the sheets to be welded. Continuous stirring of the tool and downward plunging force generates localized heat due to friction at the tool-sheet interface and plastic deformation of the sheet metal. The material gets softened and the plasticized material adjacent to the tool pin starts flowing due to the action of tool rotation and tool plunge thereby causing intermixing and bonding between the overlapped sheets. The tool stirring also promotes grain refinement in the weld nugget associated with high strain, strain rate and thermal cycle. The formation of new microstructure also affects the mechanical properties and efficiency of FSSW joints. Studies also showed that the tool pin design and tool shoulder feature exerts a noteworthy influence on the material flow and intermixing during the FSSW process (Reilly et al., 2015; Hirasawa et al., 2010). Sarkar et al. (2016) studied the material flow and intermixing during FSSW using tracer material method and reported that the size and width of flow zone increases with tool penetration depth. The influence of tool rotational speed on microstructure and stir zone temperature was investigated during FSSW of dissimilar AA6061-AA5754 alloys (Gerlich et al., 2007). They reported that the average grain size in stir zone of AA6061 weld increases with increase in tool rotational speed. In another work, Gerlich et al. (2008) studied the local melting and tool slippage during FSSW of Al alloys. Tool slippage was investigated by calculating the strain rate using Zener-Hollomon relation. Garg and Bhattacharya (2017a) studied the effect of dwell time, tool pin profiles and tool rotational speed on shear strength, microstructure, temperature and strain distribution during FSSW of AA6061. In another work, Garg and Bhattacharya (2017b) analyzed the effect of different tool pins and pinless tools on the shear strength and microstructure during similar and dissimilar FSSW of AA6061-T6 and pure Cu. Chang et al. (2004) proposed mathematical relationship between the average grain size and Zener-Hollomon parameter during friction stir processing of Mg alloy. Solhjoo (2010) presented a mathematical approach to determine the critical strain as a function of peak strain required for initiation of dynamic recrystallization in austenitic stainless steel. Fratini and Buffa (2005) also proposed the numerical model to determine the grain size during continuous dynamic recrystallization phenomenon."

Jan 1, 2018

By T. K. Bundtzen, C. B. Green

Exploration expenditures in Alaska last year amounted to $8.9 million. This was comparable to 1985's $9.1 million. Development expenditures dropped 29%, $24.3 million in 1986 vs. $34.1 million in 1985. The exploration industry is restructuring and stabilizing after the loss of major mineral firms during the last few years. These included Anaconda Minerals, Asarco, Hecla Mining, Enserch Exploration, Phillips Minerals Division, Exxon Minerals, Noranda Inc., General Crude, Mohawk Oil & Gas, Inspiration Development, Teton Exploration, and St. Joe Minerals Division. Some of these companies were mineral subsidiaries of oil companies and were either dissolved or redirected to programs outside of Alaska. However, recent entry exploration firms include Echo Bay Mines Ltd., Long Lac Minerals, and Exvenco. They are busy evaluating prospects and mineral developments in the southeastern panhandle. In the 1970s, about $254 million was spent on Alaska mineral exploration. Of this, about 5% ($12 million) was for nonmetallics and coal, about 26% was directed at precious metals ($66 million) mainly gold, and 69% ($175.3 million) for the base metals zinc, copper, molybdenum, tin, tungsten, and nickel. Since the early 1980s, trends have reversed. Of the nearly $196.3 million spent from 1981-1986, 48% has been for precious metals ($94.3 million) and 40% on nonmetallics and coal. In the last two years, nearly 70% of the Alaskan exploration dollar has been spent in search of precious metals. Three gold skarns were explored during the year - the Nixon Fork project in western Alaska (Battle Mountain Mining Co.), the Nebesna and Rambler lodes of the northern Wrangell Mountains (Nebesna Mining Partners), and the Zackley project near Paxson in southcentral Alaska (Nerco Minerals). Nearly 7.6 km (25,000 ft) of diamond and rotary drilling were conducted on these three properties. Aspen Exploration announced that significant gold mineralization was found under the Nome coastal plain in western Alaska. Meridian Minerals joint ventured with Resource Associates of Alaska, exploring precious metal

Jan 5, 1987

By E. T. Turkdogan

This is a compilation and a critical review of the data on the Fe-Ca-0 ternary system. Using the results on the reductiorz-equilibria, an oxygen potential diagram is drawn for the greater part of the system. A number of univariant systems and invariant points, not determined experimentally, are evaluated by making use of the theorem on univariant curves intersecting at an invariant point. The formation of solid solutions and ternary compounds and the crystal structures of some of the phases in the composition-diagram are given for a feu! temperatures. DURING the past thirty years there has been a continued interest in the study of the Fe-Ca-0 system. A detailed literature survey made by white1 in 1943 indicated that further work was required to clarify the phase relationships; in fact, the work carried out in the subsequent years, reviewed by Burdese2 in 1954, made a valuable contribution to a better understanding of this subject. Most of the data were obtained by the step-wise reduction of mixtures of iron oxides and calcium ferrites. However, there is some uncertainty about the phase relationships in this system, arising mainly from insufficient use of thermodynamic concepts in the construction of phase diagrams. In this paper an attempt is made to establish the invariant points from the available data. OXYGEN POTENTIAL DIAGRAM Schenck and coworkers3,4 were the early investigators who studied part of this system by the step- wise reduction method and suggested the formation of two ternary compounds, CaO.FeO.Fe2O3 and 2Ca0.5Fe0.2Fez03, the latter being referred to as point X. They also deduced from their results that the phases Y (8.74Ca0.32.5Fe0.8.74Fe2O3 and Z (2.02CaO-97.98FeO) were formed near the w?stite corner of the system. Martin and voge15 postulated the existence of the compounds CaO.9FeO and 4Ca0.3Fe3O4; the former is very close to the composition of point Z and the latter to that of CaO.FeO-Fe2O3. The most valuable contribution to the presen knowledge on this system was made by Cirilli and Burdese6-8 who showed by X-ray and chemical anal yses that there were two ternary compounds, CaO-Fe0.Fe2O3 and CaO.3FeO-FezO3; the former is the same as that suggested by Schenck et al. and the latter is close to their point X. The results of Cirilli and Burdese show that the phases Y and Z postulated by Schenk et al. are solid solutions of calcium oxide in w?stite. In most of the above-mentioned reduction-equilibria measurements carbon monoxide-carbon dioxide mixtures were used and in a few cases hydrogen-water vapor mixtures were employed. Using the

Jan 1, 1962

By China University of Mining and Technology, P. Zhang, C. Zhou, C. Duan

"Recovering pyrite from the gangue with high sulfur content is of great significance for both economic development and environment protection in China. Due to the global water shortage and high cost in wet separation processes, it is urgent to explore more efficient energy and water conservation method in mineral processing field. This study has proposed an innovative method based on density difference for fine pyrite enrichment by vibration fluidized bed. In this study, the total sulfur content (TSC) of the gangue sample is 19.18%, and the pyrite is disseminated with fine granularity in the gangue which should be crushed for dissociation. The combination and dissociation experiment of -6mm gangue shows that the dominant density of -6+3mm, -3+1mm and -1+0.5mm comminuted material is +2.9g/cm3. Based on the analysis of characteristic, the effects of various factors on the separation performance were experimental studied. The results show that gas velocity, vibration intensity and bed height all have the significant effects. With the increases of superficial gas velocity, vibration intensity and bed height, the separation performance all presents a decreasing tendency. Additionally, the TSC of -6+3mm, -3+1mm and -1+0.5mm materials are respectively up to 37.94% , 35.43% and 30.61% at the optimum conditions, which are the 1.72?1.90 and 2.29 times as much as the TSC of raw material, respectively. This study demonstrates the vibrated fluidized bed can recovery pyrite from the gangue effectively.INTRODUCTIONWith the increasing mining and separation of coal, the yield of gangue has a further growth tendency, which has become one of the largest reserves of industrial waste (Querol et al., 2008). However, many harmful elements, such as S?NOx and Hg, is existed in the gangue leading the serious damage to the soil and environment (Hao, Yun, Zhanyuan, Sen, & Song, 2013). In addition, the economic would be suffered from the loss resulting in the occupied of arable land caused by the accumulation of gangue (Yeheyis, Shang, & Yanful, 2009; Zhou, Liu, Yan, Fang, & Wang, 2012). Therefore, the government has put forward the policies of ""green mining"" in China (Xing & Gao, 2009; R. Zhang, Ai, Zhou, Ju, & Zhang, 2015; Zheng, Du, Li, Qiu, & Yang, 2015). Among different research areas of coal utilization, extracting the useful minerals has become one of hot topics (Ledin & Pedersen, 1996; P. Patra & Natarajan, 2003; Partha Patra & Natarajan, 2004). At present, many researchers has devoted to the desulfurization of coal all over the world. As result, the sulfur element, which is mainly existed in the presence of pyrite, would transferred in the tailings, namely the gangue. Meanwhile, the pyrite is important raw materials to produce rubber, paper, textile and match. Consequently, recovering the pyrite from the gangue is not only suitable to the requirement of ""green mining"", but it could turn the waste into the treasure having the important significance."

Jan 1, 2016

By Ernest G. Enck

"The Rockets' Red Glare" of the Fourth of July is produced by strontium compounds. However, strontium has a number of less spectacular uses; i.e. in, or in connection with, the manufacture of ceramics, caustic soda, glass, railway and truck signal flares, beet sugar and steel. The principal ore of strontium for use both as the mineral and for production of compounds is celestite (SrSO4). This mineral varies in color from white to pink or blue depending on presence of impurities. It has a hardness of about 3.5 and specific gravity of 3.9. It is brittle and has perfect basal and prismatic cleavages. The high grade ore is obtained from England, hence it has become the standard for all other producing areas. (See analyses, Table 1.) The most objectionable impurity in English celestite is iron, coming mostly from adhering clay. On the other hand, Mexican celestite, while no higher in strontium sulfate content, is extremely low in iron (less than 0.2 pct), hence it is more desirable for certain uses. Most of the celestite in Spain and in the United States is high in calcium and barium, and commonly high in iron, and requires some form of beneficiation in order to be equal to English ore. The natural carbonate (SrCO3), or strontianite, is less important than celestite as a source of strontium, because it is less abundant and is not so widespread in its occurrence. Furthermore, it generally occurs with calcite (CaCO3) and lead sulfide (PbS), and for most uses these impurities are detrimental. This mineral is generally white or yellowish, forming needle-like crystals. It has a hardness of about 3.7 and a specific gravity of 3.68-3.8. The mineral is brittle and has an imperfect cleavage. A typical analysis of German strontianite is shown in Table 1. [ ] Distribution of Deposits UNITED STATES Occurrences of strontium minerals are known in Arkansas, Arizona, California, Illinois, Ohio, Pennsylvania, Tennessee, Texas, and Washington. Celestite occurs in the Vulture Mountains, Maricopa County, Arizona in beds three to ten feet thick associated with sandstone, gypsum, and barite. Because of the low strontium content, approximately 86 pct SrSO4, it has no commercial value. A large deposit of celestite occurs in San Bernardino County, California, in the Cady Mountains near Argus Station, about eight miles west of Ludlow. The celestite here is interbedded with shaly and clayey tuff in a zone about 300 ft thick. Massive, finely crystalline ore has been recovered with an analysis

Jan 1, 1960

By F. Schott, M. James, G. May, E. Baker, C. Johnson, R. Bauer

Explosive demolition typically utilizes cutting charges to sever columns, detonating cord to time charges and provide an initiation path, and dynamite as a kicker charge. The kicker charges of dynamite are used to “move” columns out of alignment, causing collapse. Demolition projects involving dynamite can pose significant health and safety risks to workers and the public. Nitroglycerin in dynamite can cause dizziness, fainting, and other health problems. Moreover, dynamite placed directly on columns can result in fragmentation and cutoffs, preventing other charges from being initiated and resulting in incomplete demolition. Fragmentation can occur from columns and travel significant distances from the initiation point, sometimes reaching hundreds of meters away. This fragmentation can pose serious dangers to anyone in the vicinity, including workers and members of the public, as the debris can cause severe injuries and property damage. The force and velocity of the fragmented material can be unpredictable and difficult to control, making it important to take proper safety precautions and consider alternative demolition methods that minimize the risk of fragmentation. Previous work concluded that casing charges in water showed that a reduced dynamite charge mass could still successfully kick the charge out of alignment. This study aims to investigate the use of Pentolite boosters in water-cased charges as a safer alternative to dynamite-based demolition. The research involved testing various amounts of dynamite and pentolite boosters in water to compare their effectiveness in moving a hanging W-beam, which swung freely like a ballistic pendulum. Water-cased charges consistently move the column at a higher velocity than the traditional dynamite charge placed directly on the column. The method of water-casing increased the area of impact and impulse felt by the column, improving demolition efficiency when compared to traditional demolition methods as found in previous studies. Pentolite water-cased charges moved the column at 7.8 meters/second (m/s) while the dynamite water charge moved the column at 5.9 m/s. The increased strength and explosive properties of the pentolite contributed to this increase in velocity. This study showed that it is feasible to remove dynamite from demolition projects by utilizing pentolite boosters and that when considering safety, explosive properties, and effectiveness, pentolite boosters can be cost effective as well.

Jan 1, 2024

By H. R. Banks

IF you have ever travelled in the valley lying between the Selkirks and the Rockies in the East Koorenay district, you will have noted that the former mountains are rounded and massive, while the serrated peaks of the latter, fingering into the sky, bring an entirely different. picture. These two mountain ranges, with the comparatively level valley between, serve splendidly to introduce the subject for discussion. It is rather strange that, despite the fact that wear is undoubredly the greatest force with which human ingenuity bas to contend, it has come in for very little study from the stand point of pure science. Empiricism has been the sole ally in the fight for improvement! That we may have a clear understanding as to what we mean by wear, I would include in the term the breaking dawn of ail solid matter, from the natural wearing dawn of the mountains previously mentioned, to the hale in the mill pipe-line, which forces one to shut-down-usually at some un-earthly hour-to carry out a repair. It seems a far cry from mountains to mill launders or pipe-lines, but, magnified sufficiently, most of the materials with which we have to deal would show surfaces not unlike those we see around us. The progressive steps of wear, or ?erosion' as our geological friends would prefer to term it, are exemplified in the two ranges of mountains and the valley between. True, the wearing dawn by natural forces is a slow process. The aeons which have passed since first these mountains were formed seem endless. The natural forces pitted against them seem puny in the light of the interminable rime that has been needed to effect the changes. But here, as in the case of the materials with which we are dealing day by day, the combination of many forces ultimately brings about that condition which we describe as 'worn out'. In the case of the mountains, it is when they are finally levelled into plains, and in the case of equipment which we use, it is when that equipment will no longer serve its purpose.

Jan 1, 1943

By William A. Napier

The Mantaro Phosphate Property is located ~ 250 km east of Lima, Peru in the Andean altiplano near the city of Huancayo, Junin District. The Mantaro deposit is a mineralized zone of phosphatic rock currently defined by surface outcrops, trenches and drilling extending over a strike length of more than 30 km and a width of more than 5 km covering ~27,700 hectares. Mineralization is exposed as three roughly parallel exposures (?mantos?) trending in a northwest-southeast direction along the Mancaspico syncline. Estimated mineral resources1 contained in Manto 1 of the Property (4% P2O5 cut-off) as of February 21, 2010, are: Measured 5.548 million tonnes @ 10.8% P2O5 Indicated 33.975 million tonnes @ 9.9% P2O5 Measured + Indicated 39.523 million tonnes @ 10.0 % P2O5 Inferred² 376.265 million tonnes @ 9.0% P2O5 1Tonnes rounded to the nearest 1,000 and grade to 1 decimal place. 2Inferred material reported with no cut-off and an assumed grade. There is considerable potential to expand the resource base. Mantos 2 and 3 of the deposit have been geologically mapped and exhibit surface mineralization widths similar to Manto 1. Given that the deposit is of marine sedimentary origin, it is reasonable to infer that comparable grades and depth of mineralization are present within Mantos 2 and 3. Based on this assumption, the potential mineral deposits within Mantos 2 and 3 are estimated to be approximately: Manto 2 425-435 million tonnes @ 9% P2O5 Manto 3 280-290 million tonnes @ 9 % P2O5 These potential quantities and grade are conceptual in nature, there has been insufficient exploration to define a mineral resource and it is uncertain if further exploration will result in these targets being delineated as a mineral resource. However, should such conceptual resources be confirmed by trenching and drilling, the Mantaro Phosphate Property would rank as one of the most significant phosphate deposits in the world.

May 1, 2011

By Qiang Zhong, Bin Xu, Qian Li, Yongbin Yang, Tao Jiang

Viscosity of slag determines the production efficiency, energy consumption and distribution of elements between metal and slag, which is very important for pyrometallurgy. Slag of goldantimony ore blast furnace smelting has seldom been studied. In this paper, the viscosities of gold-antimony ore smelting slags of different composition have been studied by the rotating cylinder method. The results showed that, for a slag of 38.95% SiO2, 16.17% CaO, 25.97% FeO, 10.25% Al2O3, 5.17% MgO, the viscosity can be decreased by reducing 3.24%-8.5% SiO2 or increasing 3.31%-9.56% CaO content. Complex SixOy z- from SiO2 acts as the main cause for the high viscosity in a slag of high SiO2. The increasing of CaO causes the decreasing of the amount of SixOy z- and the O2- dissociated from CaO breaks the complex SixOy z-, which can decrease the viscosity. Viscosity of different composition slag in the appropriate range temperature can be calculated from the Arrhenius equation.

Jan 1, 2015

By Frank K. McIntosh

The Hamme tungsten district is in Vance County, N. C., and Mecklenburg County, Va. Principal development has been in Vance County. The district is approximately 8 miles long by 1 mile wide and extends northeast-southwest. Its center is about 3 miles N. 65° W. of Townsville, N. C. The occurrence of tungsten in the district was first reported in 1901, but it was not until the Hamme brothers revived interest in the deposits in 1942 that commercial development began. The Bureau of Mines, as part of the war minerals program, began exploration and development of the district in June 1943 and completed it in December 1943. The Federal Geological Survey cooperated by mapping the topography and geology and logging the drill cores. The program included mapping, trenching, sampling, diamond drilling, and analyses and beneficiation of ore samples, The principal ore mineral is hubnerite, which occurs in quartz veins within the schist and granite. The veins are generally lenticular along the strike and dip. About 50 quartz veins have been noted in the area, but many are barren or slightly mineralized.

Jan 1, 1948

By Horiszt G

his report is going to point to that the effect of the mining dewatering on the area of Transdanubian Mountain Range has reached a phase when the cost of dewatering and providing damages can seriously jeopardize a profitable mining operation. Up to 60s the interest of mining had been dominant only, but since the begining of 80s the conceptions of industrial development and the value of enviroment protection have been changed. The natural karstwater balance of the TMR can be presented (Figure Land 2.) and the present situation of it points to that the descharge has exceeded the reacharge in 50 %. During the past 10 years the decreasing of the stored karstic water resourches was 1.1 km . The decreasing of the spring yields reached 80-82 % of the natural ones. (Figure 3-4.). Conservation of the present discharge may lead up to the totaly drain of the karstwater regime. A computer aid control system had been to develop by the bauxite mining and using of it the yield of dewatering decreased and a moderate rising of the water table has started since 1986. A recunstruction was made at the biggest thermal-medicinal lake its springs have had their source in 40 meter depth inside a spring cave at the bottom of the lake. Earlier the spring yield decreased due to the dewatering activity of mines. As a result of using of the CAC system and the providing works at the thermal sprino,the karstwater balance has got in the state of equilibrum, the first cost was decreased and spring yield was increased and the enviromental limits were adverted from the way of mining.

Jan 1, 1988

By Bryce T. Tripp

Utah produces a wide variety of industrial rock and mineral commodities, valued in 1998 at $534 million (28 percent of the total non-fuel mineral production of Utah). Major commodities produced in 1998 include: halite; potash and magnesium chloride; Portland cement; sand and gravel; car- bonates including lime, limestone, and dolomite; phosphate; crushed stone; clays; perlite; gypsum; and sulfur and sulfuric acid. Commodities produced in lesser amounts include: diatomite; pumice; silica; lightweight aggregate; gemstones, ornamental stone, and mineral and fossil specimens; byproduct sulfur and sulfuric acid; silica; and building stone. The years 1993 through 1998 were a period of steady growth in industrial rock and mineral production. However, some commodities have grown much more rapidly than others. The robust western U.S. economy has stimulated production of construction-related commodities like sand and gravel, raw materials for Portland cement, lime, and building stone, resulting in exploration for raw materials, development of new quarries, and expansion of existing plants. Noteworthy specific developments include: (1) opening of new aggregate operations and buyouts of small aggregate operations by large national and international firms, (2) expansion of a lime operation and two cement plants, and (3) development of several new gypsum mines. The future of the industrial minerals industry in Utah looks promising despite a more restrictive regulatory environment and a growing anti-development attitude among its citizens. While Utah has become less pro-development than it was prior to the 1990s, it is still moderate compared to strongly anti-development states, so companies have some motivation to choose Utah in their strategic mineral development plans. As long as the western states' economies continue to grow, Utah's industrial minerals industry should thrive.

Jan 1, 2001

By V. S. Gischig, G. Preisig

Hydraulic stimulation of deep reservoirs is an essential procedure for developing engineered/enhanced geothermal systems (EGS), but also in other Geo-energy contexts. The goal is enhancing permeability to such a degree that fluid flow rates within the reservoir are sufficiently high for an economically productive reservoir. Two fracture stimulation mechanisms are distinguished that may occur concurrently during the hydraulic treatment: 1) During hydro-fracturing (HF) new tensile fractures are propagated from the borehole by means of a fluid pressure overcoming the minimal principle stress d3 plus the tensile strength T0 of intact rock. In case of a pre-existing fracture oriented normal to d 3 , the fracture can be opened by exceeding d 3 only. Fluid injection is performed via small packed intervals for creating a stack of hydraulic fractures. 2) During hydro-shearing (HS), over-pressure induces slip along pre-existing fractures that are favourably oriented in the stress field for reactivation in shear. Such stimulation is usually performed in a large packed interval or in an open borehole. Which mechanism occurs predominantly during stimulation depends on the rock mass structure and in-situ stress field, but also on the orientation of discontinuities intersecting the open-hole section and thus being pressurized. Both mechanisms also differ in how they affect fracture permeability. While permeability gained by HS is mostly irreversible due to rearrangement of asperity contacts accompanied with shear dilation, permeability enhanced during HF reduces nearly reversible after pressurization unless proppant is used to ensure permanent apertures. In this contribution, we critically discuss the pros and cons of both mechanisms regarding efficiency of enhancing permeability and the associated hazard of induced earthquakes based on literature review and numerical modelling. We review literature that reports on how much permeability required for productive EGS reservoirs and how much permanent permeability can be gained by stimulation. We also compile information regarding the degree of seismicity induced during HFor HS-dominated stimulation procedures, together with conceptual studies that reveal characteristics of seismicity associated with the two mechanisms. Many observations and models indicate that HF may have a higher tendency of being aseismic, while felt seismic events are usually associated with HS. Further, we present a hydro-mechanically coupled fracture flow model that investigates, if and to what degree the stimulation strategy can be designed such that one of the two mechanisms is evoked and dominates over the other. It shows that HS may dominate in presence of larger persistent fractures nearly optimallyoriented in the stress field, even if HF is attempted in short packed intervals. The model further demonstrates that stress transfer during HS promotes the development of permeability across an anisotropic layer of the stimulated rock instead of a large volume. Hence, the study sheds light onto the feasibility of creating productive EGS reservoirs in crystalline rock at several kilometres depths.

Jan 1, 2015

By M. T. Hepworth, T. P. Papazoglou

Hydrogen diffusion in hcp and bcc titanium in the temperature range 610° to 900°C was measured by reacting cylindrical specimens of high-purity titanium at constant temperature with small constant pressures of hydrogen of the order of a few Torr. In the range 0 to 6.7 at. pct H in hcp titanium, the diffusion coefficient D in sq cm per sec is given by: where T is in °K and R in cal per g-atom OK. Only three measurements of diffusivity in bcc titanium were made: at 900' : the diffusivity in ß titanium was found to be 1.8 x 10-4 sq crn per sec. McQUILLAN1 has studied the constitution of the Ti-H system and reported the concentration of hydrogen as a function of pressure of hydrogen and temperature. He found hydrogen absorption was reversible and rapid at temperatures above 500°C in both crystallographic modifications, the a (hcp) phase and the ß (bcc) phase, with the latter phase stabilized by hydrogen additions. Wasilewski and Kehl 2 measured the diffusivity of hydrogen in hcp and bcc Ti-H alloys. For bcc alloys, they reacted cylindrical specimens of titanium with hydrogen gas at 1 atm pressure. They measured the rate of absorption of hydrogen isothermally on specimens ranging from zero hydrogen content when above the transformation temperature to hydrogen contents sufficient to stabilize the bcc phase when below the transformation temperature. By integrating Fick's second law for a cylindrical geometry, assuming a diffusion coefficient independent of composition, they calculated diffusivities as a function of temperature. In the range 650" to 1000°C their results in bcc titanium yielded the expression: where D is in sq cm per sec, T in OK, and R the gas constant in cal per g-atom-OK. Their studies on the hcp a phase were conducted by exposing long cylindrical titanium specimens to hydrogen at a sufficiently high pressure to establish a surface layer of fl phase 80 to 120 u thick for the duration of an isothermal experiment. Concentration profiles were then determined by hydrogen analysis from chips obtained upon machining quenched specimens. The diffusivity of hydrogen was then calculated yielding the expression: The present investigation was undertaken principally to redetermine the diffusivity data on a titanium by a direct absorption from the gas phase at sufficiently low hydrogen pressures to avoid the presence of a surface bcc phase and also to check the diffusivity data at low hydrogen concentrations in the bcc stmcture. EXPERIMENTAL PROCEDURE High-purity electrolytic sponge titanium (99.9 pct) of BHN 91 was arc-melted, forged, rolled, and machined into cylinders of final hardness, upon annealing, of BHN 92. Cylindrical specimens of two sets of dimensions were used: 1.524 by 2.931 cm and 1.905 by 3.663 cm diam and length, respectively. The experimental apparatus used for annealing specimens and for admitting known amounts of hydrogen at constant pressure is shown in Fig. 1. In a typical experiment, a specimen was lightly abraded with fine-grain silicon carbide, washed with water and detergent, and then thoroughly degreased with reagent-grade tri-chlorethylene and acetone. The specimen was suspended by a Chrome1 wire in the center of a quartz furnace tube, without contact with the tube, and heated to 925°C (as measured by a thermocouple adjacent to the specimen, outside the tube) for a period of at least 4 hr under a vacuum of from 10-6 to -7 Torr as measured by an ionization gage. The furnace temperature was then adjusted to the temperature chosen for the particular diffusion study and the specimen allowed to equilibrate thermally. Hydrogen was then ad-

Jan 1, 1969

By E. A. Brocchi

This work is dedicated to the chemical treatment of a typical EAF dust by chlorine content agents. The residue contains 48% Fe2O3 and 28% ZnO mainly in the franklinite structural form. The others less compounds are: 4.00% CaO, 2.60% MnO, 2.20% MgO, 1.08% PbO, 0.36% Cr2O3, 0.21% B2O3, 0.03% CdO and 0.01% NiO. The experiments purpose is selectively to remove zinc from the residue leaving the iron behind. Thermodynamics studies have indicated some roasting possibilities. The experimental results have shown that both HCl leaching and carbochlorination will remove iron and zinc without any selectivity. However, either the chlorine or the calcium chloride roasting seems to form, preferentially, the zinc chloride. So, it will be presented how the EAF Dust can be treated by the using of chlorine roastings process such as carbochlorination in order to separate the zinc and iron present in the frankilinite, main EAF dust content.

Jan 1, 2014

By S. R. B. Cooke, C. E. Thurston, G. Kudo

The trend toward utilization of low grade iron ores means that more efficient methods must be developed for their concentration. The collecting ability of fatty acids derived from fish oils has been extensively investigated by Cooke.' Tuna oil, a byproduct of the tuna canning industry, is one of the lower priced fish oils. Utilization of tuna oil fatty acids as collectors in the flotation of iron ore might be economically feasible under certain market conditions, especially if their efficiency were high. Crude or unfractionated tuna oil fatty acids, and five fractions derived therefrom, were tested for their ability to concentrate a commercial specularite ore from northern Michigan. A commercial fatty acid derived from tall oil, and commonly used in nonsulfide flotation, was used as a reference. The crude fatty acids were obtained by simple saponification of tuna oil. Fractions A and B were obtained by acetone precipitation of the crude acids at -5O and -2S°C, respectively. Fraction C was obtained by a partial fractional distillation at 12S°C and at a pressure of 3y in a centrifugal molecular still in order to remove the shortest and longest chain fatty acids of tuna oil as well as oxidation products present in the original mixture. Fractions D and E were prepared by a chilling process in order to precipitate the unwanted saturated fatty acids. Yields and iodine values of the materials used are listed below: The seven samples were used as collectors in a laboratory procedure patterned after the commercial process for flotation of Michigan specularite ore. The outline of the procedure is that previously described1

Jan 1, 1962

By Leszek Maldzinski

The present concept assumes carrying out the process of controlled nitriding with NH3 alone. This is a simpler process than that using two-component mixes of ammonia diluted with N2 or NH3diss. The regulation of the chemical composition of the atmosphere in the retort, and therefore the regulation of the nitriding potential KN, is obtained through the variation of the inflow rate of NH3 into the retort. What is a completely new things in a relevant process, the inflow of NH3 into the furnace is at times reduced to zero, which widens the range of the gas composition in the retort (and by the same token, of KN). The amount of NH3 introduced into the furnace is regulated (controlled) with the aid of a gas analyzer (for example an infrared analyzer). The gas analyzer opens and closes periodically the NH3 inlet valve with a frequency maintaining a desired gas composition (a desired KN) in the retort. The concept was based on experimental and theoretical investigations in term of thermodynamic and kinetic of gas nitriding. Investigations were carried out in a laboratory furnace with a quartz tube and also in an industrial furnace with a steel retort and a circulating fan. Nitriding was performed using NH3, NH3+H2, NH3+NH3diss. mixtures. In an industrial furnace the supply of NH3 into the retort was periodically closed, though with an operating circulation fan. The studies demonstrated that the growth rate of nitrided layer depends only on the composition of the atmosphere, (or KN), in the retort. It depends neither on a type of atmosphere introduced into furnace (NH3, NH3+NH3diss. or NH3+H2) nor a type of furnace (laboratory with a quartz tube or industrial with steel retort and fan). The results proved also that entirely closing of NH3 supply to the retort does not affect the growth rate of nitrided layer. A detailed analyses of the results was performed in a paper.

Aug 16, 2017

By R. G. Davies, P. Beardmore, T. L. Johnston

The flow stress of a series of Ni-Cr-A1 alloys consisting of a dispersion of y' (based on Ni3Al) in a rnatrix of nickel-base solid solution y has been measured at temperatures up to 950°C as a fwzction of the volume fraction of y'. At high temperatures the flow stress is controlled by the amount of Y' in the alloy, i.e., the higher the volume fraction of y', the greater is the flow stress. This simple relationship is not obeyed at low temperatures in so far as a peak in the flow stress-volume fraction relation occurs at about 25 pct y'. The variation in the mechanical properlies of these alloys as a function of both temperature and volume fraction of y' has been correlated with changes in distribution of both the dislocations and y'. The results are interpreted on the basis that at low temperatures the y matrix is strengthened significantly bv the presence of a hyperfine y' precipitate due to decomposition on cooling; at high temperatures the y matrix is a single phase of low strength. It is clearly recognized that the high temperature strength of most nickel-base superalloys depends upon a dispersion of the ordered fcc phase y', based on Ni3A1, in a fcc solid solution matrix y based on nickel. Although the volume fraction of y' varies widely from about 0.2 in Nimonic 80A to about 0.6 in Mar-M200, all such nickel-base alloys manifest an unusual insensi-tivity of the flow stress with respect to temperature. In Mar-M200 for example, the 0.2 pct flow stress remains essentially constant from room temperature to 750°C. The conclusion has been drawn1 that the characteristically low temperature dependence of the flow stress of y-y' nickel-base alloys is obtained when the state of dispersion of y' is such that dislocations are forced to cut through the y' particles at the onset of yielding. When the spacing between the y' particles is so large that the flow stress is controlled by dislocation bowing between particles, then the initial flow stress decreases progressively with an increase in temperature at a rate determined by changes in elastic properties. The same conclusion is inherent in the detailed, mechanistic model of the deformation process in commercial superalloys which has been developed by Copley and ear' in which the temperature independent flow stress is attributed primarily to the contribution of the antiphase boundary energy created in the y' particles during deformation. In this theory the temperature insensitivity of the flow stress is a reflection of the constant antiphase boundary energy as a function of temperature. An important microstructural parameter that is relevant to the explanations that have been suggested' to account for the temperature insensitivity of the flow stress is the volume fraction of y'. To vary the latter to any significant extent in a given commercial alloy is clearly difficult. However, it is possible in a relatively simple Ni-Al-Cr ternary system which manifests analogous microstructures in terms of the distribution of y' in y and contains specific alloys which have flow properties that depend on temperature in a manner quite similar to their more complex commercial counterparts. Hornbogen et . have studied precipitation phenomena and deformation mechanisms in such alloys but only where the y' volume fraction was small (less than 0.2) and the y' particle size varied from less than 100A up to a maximum of -1000A. In the present study, a series of alloys was prepared in which the volume percent of y' at 900°C was varied from 0 to 100 pct with the y' particle size (of the order 0.5 p) comparable to the sizes obtained in commercial superalloys. Particular attention has been given to the relationship between variations in the volume fraction and distribution of y' and the temperature dependence of the flow stress EXPERIMENTAL TECHNIQUES The Ni-Cr-Al system was selected because it is well characterized, bears a close relationship to commercial alloys, and offers the advantage of an extra degree of freedom over a binary system. In the present investigation, a series of alloys across the tie line between NisA1 and Ni3Cr (Ni3Cr is not an in-termetallic compound, the nomenclature is only used to designate the composition) were vacuum cast. The pseudobinary6 and the composition of the alloys used are shown in Fig. 1. It is important to note that the compositions of the y phase and the y' phase in the two-phase alloys was always the same. Alloy compositions were selected from the binary diagram, Fig. 1, in order that aging at 900°C would produce from 0 (100 pct y) to 100 pct y' by volume percent. (The size of the y' particles produced during the equilibrium aging treatment increased as the volume fraction of y' increased, ranging from about 0.2 p at low volume fractions up to about 0.8 p at the highest volume fraction.) The y' phase is based on the inter-metallic compound Ni,A1 which has the fcc LIZ type superlattice structure, and chromium substitutes for aluminum in the structure. The y phase is a disordered fcc solid solution. The alloys were heat treated at 1150°C for 2 hr, air cooled to room temperature, and finally annealed for 16 hr at 900°C. The rods were then centerless ground to 0.25 in. diam and cut into compression samples 0.5 in. long. The compression tests were made on an In-stron machine at a strain rate of 7 x 10"4 sec-'. A rapid heating radiant heat furnace was used which minimized the heating and temperature stabilization time to 10 min for the highest testing temperature. All the tests were stopped after 5 pct plastic strain.

Jan 1, 1970

By Kazuyoshi Kamimura, Masaya Kawata

"It has been 30 years since the cement deep mixing (CDM) method developed in Japan. CDM method has been applied to many structures. While various technical improvements have been implemented in the meantime, the single-axial and double-axial technologies used at the time of its initial development are still prevalent.In response to the recent trend of reducing construction costs, we developed a triple-axial CDM method called the “Lemni 2/3 Method.” This method uses two lemniscate motions caused by newly developed auxiliary stirring devices and employs a double-axial injection method in which the cement slurry injection takes place only from the outer two axes. In this way, it is possible to create a stabilized body around the three axes. Moreover, this method does not require substantial equipment investment as conventional construction machine and facilities can be used without modification and large volume work is possible.With these technologies, this method can achieve a substantial reduction in the construction period and cost, while ensuring the same level of improvement quality as conventional methods. As a result, this method is being applied to ground improvement work in a variety of places.Lemni 2/3 Method was first put to practical use in 2004. Since then, the method has been used for ten projects. In this paper, we show some application examples of this method.OUTLINE OF TRIPLE-AXIAL CDM METHOD (LEMNI 2/3 METHOD)In the newly developed CDM method (Lemni 2/3 Method), work efficiency is improved by employing triple-axial stirring blades instead of the conventional single- or double-axial type. Existing conventional construction facilities for double-axial type can be used with only minor equipment additions, because the cement slurry injection takes place only from the outer two axes.Construction Machine and Construction MethodThe combination of major construction machines of the Lemni 2/3 Method differs little from the standard specifications of the double-axial type as shown in Fig. 1. Existing work control equipment can be used without modification, which is further evidence of the simplicity, convenience, and economy of the new method. The Fig. 2 photo shows a full view of the construction machine, and the Fig. 3 photo shows the stirring blades and the auxiliary stirring devices. The work procedure for the Lemni 2/3 Method is shown in Fig. 4."

Jan 1, 2015

By Frank Foote, Willard L. Bruner, Eric R. Jette, Y. New york

The alloys of gold and iron were investigated in 1907 by Isaac and Tammann,l who determined the thermal diagram for the entire system by thermal analysis and microscopic examination. They also reviewed the previous literature. Since that time the present authors have been able to find only two additional references. Guertler and Schulze2 examined the electrical resistance of iron alloys containing up to 40 per cent by weight of gold between 0" and 200" C.; the alloys were in the form of wires. The main result of this work was to confirm the solid solubility limit found by Isaac and Tammann; namely, about 20 per cent Au. More recently, Shih3 has examined the magnetic properties of gold alloys containing up to 10 weight per cent iron and particularly the range below 5 per cent. The alloys in the lower range were found to be paramagnetic; the 10 per cent alloy was ferromagnetic. The present investigation was undertaken to determine the solid solubility limits at various temperatures, particularly below the a-y transformation point of iron, since these solubilities are of some importance in connection with the working of the alloys in the manufacture of certain "grey" and "blue" golds. Materials and Methods The gold was obtained from the U. S. Metals Refining Co. and contained 99.99+ per cent Au. The electrolytic iron had been annealed in hydrogen and contained impurities as follows: P, 0.035; Si, 0.001; S, C, Mn, Cu, each 0.01 per cent. Weighed quantities of the two metals were placed in small crucibles lined with pure sintered MgO; a saturated solution of magnesium nitrate

Jan 1, 1934