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By J. Walter Snavely

PRESENT-DAY processing in many industries, calcining, sintering, briquetting, beneficiation and nodulizing, increasingly calls for the handling of large volumes of hot bulk materials. Various types of conveyors have been employed. This discussion will cover the factors governing their selection. For temperature ranges up to 400°F, or approximately 200°C, a wide range of conveyors is available. Special constructions of rubber conveyor belts. steel conveyor belts, vibrating and shaker conveyors, apron conveyors, and drag chain conveyors, all are used successfully. As temperatures go well above 400°F, however, choice of conveyors is narrowly limited. This paper will consider the problem of handling bulk materials only where the temperatures exceed 400°F.

Jan 5, 1953

By G. Carman Ridland

Front Range, Colorado: The majority of the rocks comprising the Front Range of Colorado are pre- Cambrian schists, gneisses, and intrusives which have been elevated to form part of the Southern Rocky Mountain physiographic province. The region is noted mainly for its production of gold and silver, but ores of tungsten, fluorspar, uranium, copper, and iron have been worked. Geological literature describes pitchblende and other radioactive minerals occurring at Jamestown, Boulder County; Central City, Gilpin County; and Lawson, Clear Creek County (fig. 1). These three adjoining counties cover most of the highly mineralized section of the Front Range which extends from James- town to Breckenridge. As far as the writer is aware, uranium has been found only in the portion north-east of Lawson.

Jan 1, 1950

By G. A. Colligan, G. L. F. Powell

A new experimental technique has been developed to study nucleation behavior in eutectic alloys. It is somewhat similar to that applied by Sundquist and Mondolfo1 but with the advantages that: 1) bulk samples are undercooled instead of small droplets thus allowing the thermal behavior to be monitored by a thermocouple immersed in the sample, and 2) nucleation behavior is investigated in the same sample on either side of the eutectic composition by adding additional component to the sample under controlled conditions which preclude the addition of nu-cleation contaminants. Sundquist and Mondolfo carried out ]nucleation ex-periments on a large number of eutectic alloy sys-tems and concluded that nonreciprocal nucleation operated. If one phase a was a good nucleant for the other phase 0, then B was a poor nucleant for a. This was determined experinlentally by comparing the nucleation temperatures of 100 to 300 u diameter droplets of hypereutectic and hypoeutectic composition cooled from above the liquidus and from a temperature between the liquidus and the eutectic temperature. Primary phase a was concluded to be an efficient nucleant for the other phase B, if the following experimental result was obtained. Referring to Fig. 1, the temperature TI at which a drop of hypereutectic alloy of composition B froze when cooled from above the B liquidus was noted. This was the nucleation temperature for B in the absence of a. A drop of hypoeutectic alloy of composition A was then frozen from temperature T2 between the a liquidus and the eutectic temperature. The temperature T3 at which the eutectic nucleated in the presence of the primary or proeutec-tic a was noted. If this temperature T3 was higher than the temperature TI at which the B nucleated in a hypereutectic alloy, it was concluded that the primary a had nucleated the 6. This temperature T3, representing a certain undercooling below the equilibrium eutectic temperature Te , was designated ?TB by a> the undercooling below T, for nucleation of 13 by a. If there was no substantial difference in nucleation temperature between the hypereutectic drop cooled from above the /3 liquidus and the hypo-eutectic drop cooled from a temperature between the a liquidus and the eutectic temperature, it was considered that the a nucleated B at an undercooling equal to or greater than that at which P nucleated from a hypereutectic alloy. Sundquist and Mondolfo1 found that faceted primary crystals were good nucle-ants for metals that grow as orthogonal dendrites when present as the primary phase. Jackson2 has questioned Sundquist and Mondolfo's technique and proposed that in Sundquist and Mon-dolfo's samples, such as composition A, primary a retained B in reentrant grooves at their surfaces when heated to a temperature above the eutectic but below the a liquidus. This objection was suggested by experiments with organic eutectics where reten-

Jan 1, 1970

By M. W. Hayward

THE object of this paper is to record and tabulate the data and field observations obtained by the writers and their associates during 10 years of intensive study of lead-zinc deposits in the Cretaceous limestone areas in Northern Mexico, particularly in mines owned by the Cia Minera de Peñoles, S. A. At the El Paso meeting of the Institute in October, 1930, J. G. Barry made the suggestion that a committee be appointed to correlate the ideas and theories which have been put forth by the numerous engineers and geologists who, during recent years, have made a study of the ore deposits in the area under consideration. The first step in a work of this nature would be to record all of the observed facts, and these facts would have to be accepted by those who attempted to formulate a theory of ore deposition. It is with this idea in mind that the writers have described as accurately as possible the actual, observed facts pertaining to the occurrence of the lead-zinc ores in dolomites or dolomitic horizons. By most writers the term "dolomite" is loosely used to designate magnesium-bearing limestones, regardless of the percentage of MgO present. Since no true dolomites exist in the areas to be described, we shall also loosely use the terms dolomite or dolomitic limestone to desig-nate those beds having a magnesia content of 5 per cent MgO or more. For a number of years the writers have been impressed with the fact that in areas where dolomite beds occur a large percentage of the lead ore is found in these beds, in spite of the fact that such beds may be overlain or underlain by pure limestone, which one would assume to be just as favorable for replacement as the dolomite, if not more so on account of its being more soluble in acid solutions than the dolomite. It is true that in some limestone areas, such as the Erupcion-Ahumada districts, Chihuahua, and Providencia, Zacatecas, where no dolomite beds have been found, large tonnages of lead ores have been mined. We venture to predict, however, that had there been dolomitic beds in these areas, the

Jan 1, 1932

By C. M. Fellman

THE over-all picture of safety in mining has been encouraging during the past few years, and in mining activities as a whole the trend in accident occurrence is downward. This is the more noteworthy when the type of labor used in mines during the war period is taken into consideration. The drafting of young mining employees into the armed services and the departure of others for work in other war industries took a heavy toll of young, husky, active men. Their places were taken in large part by older men who returned to the mines, or by inexperienced men with little if any knowledge of mining. Despite the lack of labor and especially of skilled labor, and the difficulty of obtaining new equipment as well as maintaining and replacing worn or broken equipment, and numerous other difficulties the mining industry not only reached and maintained maximum production but made the increase with little if any sacrifice of safety. In fact, in many instances better safety records were. established than in normal

Jan 1, 1946

By Thomas Egleston

DURING the year 1873, my attention was called to the frequent accidents, resulting from the breaking of rails, on the different railroads in this' country, and I was requested to investigate the subject. The plan of investigation I proposed was to ascertain, in as many cases as possible, the exact hist* of broken rails, both in this country and in Europe; to collect information in Europe relating to the tests which rails used there were required to undergo, and to experiment upon the pieces of rails broken on the road, with a view to ascertain whether their fracture was due to their chemical constitution, bad manufacture, to a reduction in strength owing to temperature, or to physical changes in the constitution of the rail. The investigation was commenced by the collection of statistics, and for this purpose I spent several months in Europe, collecting information on the subject of broken rails, as well as the life of iron and steel rails generally, and inquiring into the systems of purchasing and of testing them employed by the railroads there, intending, on my return, to make a series of analyses of rails broken, both in this country and in Europe; to ascertain, if possible, how far great cold had an influence on the fracture; to examine whether the rail broken, either on the road or afterwards, underwent, at or about the fracture, any physical change, and to make a series of experiments on the strength of rails manufactured in the United States or sold in the American market. Unfortunately, the panic of 1873 came on, just before my return from Europe, and prevented the carrying out of the larger part of the plan proposed; as, however, I had collected in the meantime, a large number of statistics of different kinds from all parts of Europe, and had made a number of interesting experiments and investigations, I have thought it would be worth while to communicate some

By Albert Sauveur

Iron, like other metals, solidifies through the formation of dendritic crystals; iron alloys forming solid solutions, like other solid solutions, solidify likewise through the formation of dendritic crystals. The alloying elements or impurities as well as the inclusions segregate generally in the interstices, or "fillings," between the axes and branches of the dendrites; that is, in the portions last to solidify. This results in dendritic segregation or heterogeneity, which is generally persistent and makes possible the revelation of the dendritic crystallization of the metal through the selective action of a suitable etching reagent.' For this purpose, a cuprie solution, such as Le Chatelier's, is generally used, copper being deposited on the pure, or relatively pure, ferrite present in the axes while the fillings remain free, or relatively free, from copper deposition. The dendritic structure, formed on solidification in a steel containing 0.50 per cent. carbon, 0.37 per cent. manganese, 0.12 per cent. silicon, 0.07 per cent. sulfur, and 0.035 per cent. phosphorus is shown, after treatment with Le Chatelier reagent, in Fig. 1 under a magnification of 8 diameters. Commercial steel always contains inclusions of manganese sulfide, which are located in the fillings of the dendrites. Comstock has shown that boiling sodium picrate imparts a dark coloration to these inclusions. We find that this reagent likewise reveals dendritic segregations in commercial steel, as shown in Fig. 2, under a magnification of 8 diameters. which represents the same spot as that shown in Fig. 1. The fillings have been darkened while the axes remain white, the action being, therefore, the reverse of that of cupric reagents. On closer examination, under higher magnification (Fig. 3) it is found that the picrate blackens the small particles of manganese sulfide, that these are frequently surrounded by a rim of white, or relatively white, ferrite, and that both the ferrite

Jan 1, 1924

By J. A. Herbst, D. W. Fuerstenau

This paper examines the zero order production phenomenon in the context of the size discretized batch grinding model. A restrictive interrelationship between the selection and breakage parameters of the model, which is mathematically sufficient to ensure zero order behavior, is delineated. Based on this interrelationship, a scheme is developed for predicting the values of the selection and breakage parameters for all size fractions from a minimum of experimental data. To test this scheme, dolomite was ground in a laboratory batch ball mill. Successful simulation of the comminution behavior of this system was achieved using the batch grinding model with the parameter values obtained from the proposed scheme. Historically, a preponderance of comminution research has centered on attempts to relate breakage energy to the performance of comminution machines. Concomitantly, grinding data were interpreted almost exclusively in terms of inherently empirical energy-size reduction relationships1-3 or "laws of comminution"4- 6 which were based on highly oversimplified descriptions of the fracture process. In some instances, these relationships provide a crude basis for the correlation of experimental data, but, invariably, this approach is inadequate for meaningful process simulation. The control and optimum design of comminution circuits require a mathematical model capable of depicting the size reduction behavior of every size fraction for grinding conditions of technological importance. Energy-size relationships do not provide this detailed information. For example, an energy-size analysis for batch ball-milled dolomite has recently been completed in the authors' laboratories.7 This analysis provided a satisfactory correlation between the hypothetical size modulus, which characterizes only the finer portion of the size distribution, and the input energy. However, this relation did not constitute an adequate description of the complete system. In general, one of two distinct viewpoints toward simulation has been adopted in recent comminution research. The first approach focuses on the fracture of single mineral specimens, with the essential aim of representing the over-all process in terms of the breakage characteristics of individual particles and the characteristics of the stress field which the particles experience within the particular size reduction device. As illustrated by Harris's review,' the actual incorporation of single-specimen fracture information into a description of the behavior of a multiparticle comminution system has seldom been attempted. The only model to accomplish this incorporation was the one developed by Schönert.8 The Schonert model treats single-passage grinding machines in terms of a distribution of effective loads acting on a particle, a distribution of required particle breakage energies, and the breakage product distribution. However, the use of single-particle fracture behavior to derive models of the size reduction process is at present limited to machines in which the particle residence time is approximately equal to the time required to apply stress. As a result, Schönert's analysis cannot be used to advantage to simulate the complex environment which prevails within a tumbling mill. For multiple-passage systems a second approach to the description of comminution processes has been more fruitful. This approach entails the formulation of a mathematical model which is phenomenological in nature in that it lumps together the entire spectrum of stress-application events which prevail in a system under a given set of operating conditions. The appropriately defined average of these individual events is then considered to characterize the over-all breakage properties of the device. Thus, to analyze the performance of a tumbling mill, the manner in which the particles of a particular size (or size fraction) are stressed need not be distinguished. Instead, a single parameter is assumed to represent the resistance of that size to fracture, given the average grinding environment which exists in the mill. The isolation of such a parameter and a related set of quantities, which constitute the breakage product size distribution for the average event in this size fraction, allows the formulation of physically meaningful descriptive equations capable of yielding precise and detailed information for simulation.

Jan 1, 1969

By J. A. Bownocker

The existence of petroleum in the rocks of Ohio and Indiana seems to have been first shown by wells dug for salt. The fuel, however, was objectionable owing to its odor and inflammability. Not until the Drake well was drilled in 1859 did the people appreciate the value of rock oil, and then they at once began plans to secure the coveted fuel. The first successful well in these two states was near Macksburg, in southeast Ohio, where at a depth of 59 ft. (17 m.) oil was found in commercial quantity (1860). A year later this fuel was secured on Cow Run, in the same county, and at about the same time in Noble, Morgan and perhaps other counties in that part of Ohio. The second great step in the production of oil in Ohio and Indiana was taken in 1884 when the reservoir of natural gas in the Trenton limestone of northwest Ohio was tapped, and where a year later oil was secured in the same formation. Petroleum in this limestone was obtained in Indiana in 1889.' The third step in the production of oil in Ohio and Indiana is associated with the Clinton sand of Ohio. Natural gas in large volume was discovered in that rock at Lancaster, in 1887, and the area has been extended until it has become the largest individual producer in the world. The presence of natural gas in such great volume all but demonstrated to the driller that oil lay hidden near by. Soon the search for it was started but not until 1899 was petroleum in commercial quantity found in the Clinton sand, and a large pool was not located in it until 1907. The fourth step in the developrllrnt of the industry was taken in 1913, when the pool in Sullivan County, in western Indiana, was opened. The producing rock is the Huron sandstone, which is the topmost member of the Mississippian system.²

Jan 1, 1921

By D. N. Stevens, D. N. Bloom, M. A. Klugman

This paper represents a portion of a larger study concerning dispersion of major, minor and trace elements in wall-rock about orebodies in part of the Colorado Mineral Belt. This phase of the work pertains to the Mg/Ca ratio variations in wall-rock adjacent to orebodies in two mines, one in the Horseshoe Mining District (Hilltop mine), and the other in the Alma Mining District (Phillips mine). The two districts lie adjacent to one another, the Horseshoe District on the south and the Alma District on the north, and are commonly referred to as one, the Alma-Horseshoe Mining District. The Alma-Horseshoe Mining District is located 80 miles southwest of Denver, Colo., (Fig. 1) in Park County, on the eastern slope of the Mosquito range. The area is typified by rugged relief with altitudes of from 10,500 to 14,000 ft. The Horseshoe District is separated from the Lead-ville Mining District by the crest of the Mosquito range, with the Leadville District to the west. The Alma-Horseshoe District has been considered as peripherial to the Leadville District, and has not received the detailed attention that the Leadville District has. These two mines were selected for this study because of their ease of access; the attitude of the workings and the drill holes to the known mineralization; the similarity of the mineralization; and because the mineralization occurs in carbonates in both mines but are of different ages. In the Hilltop mine mineralization is confined to the Leadville dolomite (Mis-issippian) and is principally lead with subordinate zinc and silver. In the Phillips mine the mineralization occurs in the Peerless dolomite and shale (Cambrian) and in the Manitou dolomite (Ordovician) and is principally zinc with subordinate lead, silver,

Jan 1, 1964

By H. G. Moulton

H G. MOULTON should not be confused with the famous economist of the same name. Our H. G. stands for Herbert George, whereas the chief of the Brookings Institution is Harold Glenn. Like most so- called New York members of the Institute's hoard, Mr. Moulton came from the West, in this case from Idaho where he was born, and Oregon, where he was educated at the University of Oregon. His early work included such jobs as mucker, assayer, smelter, chemist, mine surveyor, draftsman, engineer on surveys and construction, and assistant on mine examinations. In 1909 he was engaged as mining engineer by the firm of Eugene Meyer, Jr. S' Co., continuing with them for the next eight years.

Jan 1, 1937

By Philip H. Nelson, Richard Lingle

Vibrating wire stressmeters (VWS's) and borehole deformation gages (BDG) were deployed in two in-situ heater experiments at Stripa, Sweden to determine the thermally induced stress changes in the rock mass. The heater experiments ran for 18 months, including a six- month cool-down period after the heaters were turned off. Gages were installed in both horizontal and vertical boreholes and were subjected to temperatures ranging from 10°C to 120°C, depending upon the distance of a gage from the central heater. Most gages operated in a moist environment because groundwater flowed into many of the instrument boreholes during the experiments Of the 36 VWS's installed, six failed. Failures were attributed to corrosion of the vibrating wire due to moisture entering the gage body. Of the 30 BDG's installed at the beginning of the experiments, 22 failed, also as the result of water entering the gage body. Modification and reinstallation of the gages eliminated the problem of water infiltration, but much data from early stages of the experiments was lost due to gage failures. Calibration of the VWS in blocks of Stripa granite showed a lack of repeatability. Variability in calibration results are attributed to seating effects, to variations in the elastic modulus of the rock, and to changes in temperature. These three effects combined to produce an error judged to be approximately ±33% of the stress changes measured at Stripa. In contrast, the major source of error in determining stress with the BDG appears to be the uncertainty in rock modulus and thermal expansion coefficient. Sample calculations based on data acquired near the end of the experiments (during cool-down)

Jan 1, 1982

By R. E. Rettger

The area referred to in this paper is the southern part of the Permian Basin lying in southwest Texas and southeast New Mexico (Fig. I). Those fields lying along the northern rim of the basin; namely, the Panhandle fields, are not included. The fields within this area are

Jan 1, 1930

By H. A. Deans

A three-parameter mathematical model for one-dimensional flow in porous media is developed. The objective of the model is to predict accurately the longitudinal dispersion associated with the flow of either gases or liquids over a wide range of Reynolds number. A qualitative analysis of the model parameters is given. Published experimental pulse-response curves are compared with results predicted by the model. Several general types of problems are given for which the model can be used. INTRODUCTION The problem of multicomponent single-phase flow through porous media is encountered in the study of petroleum reservoirs, gas chromatographic and ion-exchange columns, industrial fixed-bed con-tacters and elsewhere. These particular examples span the wide range of flow conditions possible; Reynolds numbers of less than l0-4 are not unusual in oil-production problems, while values in excess of 103 are common in large fixed-bed operations. The study of flow-dependent transport phenomena is complicated both by the changes in the character of the flow over this range, and by the irregularity of the flow boundaries inherent to porous media. Dispersion is one of the important phenomena known to depend fundamentally on flow conditions as well as on fluid and medium properties. As used in this paper, the term "dispersion" refers to the observed mixing of fluid elements of different composition which occurs in flow systems. The actual mechanism may be one or more of a number listed below. Only dispersion in the direction of the mean flow (referred to as axial or longitudinal dispersion, or mixing) is considered here, although lateral dispersion arises as part of certain coupled mechanisms. MECHANISMS FOR LONGITUDINAL DISPERSION A number of distinct mechanisms are known3,5,7,8 to contribute to the phenomenon of longitudinal dispersion. The more important of these are as follows. 1. Molecular diffusion in the flow direction. 2. Turbulent (cell) mixing. 3. Lateral transport processes coupled with velocity and/or residence time distributions, including: (a) "Taylor" diffusion caused by the interaction of velocity profiles in individual voids with lateral molecular diffusion; (b) separation and remixing or interdiffusion of streams having different velocities around particles; and (c) the couplipg of gross velocity profiles, caused by viscous instability or inhomogeneous porosity, with lateral dispersion. 4. Finite mass-transfer rate between a porous matrix and the flowing phase, and finite diffusion rate inside elements of the porous matrix. It is a well documented fact that these mechanisms, whether acting individually or in combinations, produce essentially similar integral effects. The observed dispersion can be described approximately by solutions of the diffusion equation with a properly chosen dispersion coefficient. Necessary conditions for equivalence between dispersion and diffusion are discussed by Klinkenberg and Sjenitzer.7 Apparently these conditions are not satisfied exactly in many real systems. "Best fit" solutions of the diffusion equation often depart appreciably from measured breakthrough curves for the usual pulse- or step-forced experimental systems. In particular, pulse response curves usually show some degree of asymmetry and "tailing" which cannot be reproduced by the one-parameter diffusion model. The three-parameter model proposed herein attempts to produce these effects in a realistic manner. Asymmetry and tailing are predicted for certain sets of parameter values, while for other sets the new model agrees with the diffusion model. VELOCITY DEPENDENCE OF DISPERSION Molecular diffusion apparently controls at sufficiently low Reynolds number in both gas and liquid systems.*l3 At Re > 20, turbulent cell mixing is dominant for gases flowing at low pressure; the data of McHenry and Wilhelm8 show that the mixing cell is approximately 1 particle diameter long in random sphere packs. on the other hand, the data

By Robert C. Freas, William H. Lane, David J. Krohn

Maysville, Kentucky, is the location of Dravo Lime company's new 9 070 mt(10,000 tons) per day limestone mine and 2 727 mt (3000 tons) per day calcination plant. This complex has been designed as a unit, and capitalizes on recent technological advances. Geologically the Dravo facility is.located on the eastern flank of the Cincinnati Arch, with the high calcium limestone being found at a depth of approximately 274 m (900 ft). A systems approach has been employed in designing and equipping the mine. This allows for maximum production while maintaining flexibility and versatility. All hydraulic drilling, large LHD equipment, and an extendable mine conveyor system are utilized in a five-part mining cycle. A modular concept modifies the room and pillar system to optimize ventilation. The limestone is calcined in three 5.18 x 61.87 m (17 x 203 ft) KVS rotary kilns with a design capacity of 909 mt (1000 tons) per day of lime per kiln. The kilns are coal fired and equipped with preheaters. Lime storage is provided by three 57 m (186 ft) high concrete silos with a combined capacity of 40 909 mt.

Jan 1, 1976

By Carlos D. da Gama, Charles R. Nelson

Griffith’s theory of brittle fracture, as modified by McClintock and Walsh to fit rock behavior in cases of failure by compression, has been successfully applied in various fields of rock mechanics. Extension of the Griffith's criterion to rock blasting problems may also be more representative of rock behavior than the simple consideration of a criterion of failure based on the dynamic tensile strength of the material. If consideration is given to pre-existing cracks within rock structure, occurring not only because of the discontinuous properties of rocks, but also as a result of drilling operations that normally precede blasting, those cracks can be propagated under the action of the dynamic stresses (radial and tangential) induced by the passage of the wave emitted by the explosion. Conditions for initiation and propagation of pre-existing cracks are deduced in terms of rock properties and explosives performance. Influence of the different variables governing the phenomenon is discussed after considering an actual example. Results seem to be well correlated with experimental evidence of radial cracking observed in blasting with high explosives acting within hard rock.

Jan 1, 1971

By L. J. Murphy

The production of crude oil in the United States is exceeding consumption by one-quarter million barrels per day and, with the possibilities of West Texas, this condition of overproduction, unless controlled, is likely to continue for some time. The resulting low price of oil has caused the operator to observe closely his lease operating costs. The installation of more efficient and reliable machinery has followed and it can well be said that the art of producing oil is on the threshold of a new era. In this advancement electricity has played a leading part. This paper covers only the problem of electricity as applied to lease operation and does not consider other phases of the industry, such as drilling and pipe-line pumping, in which electric power has been utilized economically. In considering electrification of pumping wells, the first question the operator asks is whether or not his costs will be reduced and the second question is whether or not the production will be increased. The third question, although in effect it is closely allied to the first, is the cost of power. The last question can be answered only after a thorough analysis of operating conditions and a study of the power rates prevailing in the particular field under consideration. Within the past few years, the power companies have realized the desirability of a steady 24-hr, pumping load, have made their rates for oil-field service particularly attractive, and in general have shown splendid cooperation in assisting the oil companies in the satisfactory application of electric power to their leases. When everything is taken into consideration, the first cost is practically the same for electric drive as for gas engines when pumping on the beam with individual motors. This cost, at prevailing prices, should aver-age approximately $2200 to $2400 per installation when using 15 to 35-hp., two-speed pumping equipment, including motor and control, countershaft, motor house, belt, installation charges, and a prorated portion of the cost of transmission lines and transformers for serving a number of wells. Since there is practically no difference in the cost of the two installations, it is evident that electricity, to justify its consideration, must have a lower operating cost or produce more oil.

Jan 1, 1928

By G. F. Loughlin

Nearly 55 years have elapsed since the U. S. Geological Survey was organized. During this period the mineral industries have grown from infancy or early childhood to well developed maturity, and some mining industries appear to be declining. Decline in mining is even more conspicuous in certain districts, or even states, than in any mining industry as a whole, and discoveries or developments of important new districts have been very few in recent years. Our reserves of most metals and nonmetals are adequate for many years of normal production, subject to changes in rate of exploitation that may be caused by foreign competition and by changes in technology and market conditions; but the declining production of many districts and the scarcity of important new discoveries to compensate for them is cause for some apprehension. It is likely that future production will depend to a considerable extent on deep exploration and on the thorough examination of places in and adjoining existing districts where significant outcrops are lacking and only apparently insignificant geologic features offer encouraging clues—more so than on the discovery of entirely new districts. Even the possible discovery of new districts, which have escaped the intensive search by the nontechnical prospector, must be dependent on geologic information. There is therefore no need for argument as to the value of geology to the mining industry; and the need of continuing to advance the science. The U. S. Geological Survey's past contributions to mining geology, as expressed in its official reports and other publications, are recognized by Ransome in his historical review of mining geology in the Lindgren volume.' These contributions have helped to form the basis of modern mining geology, which has grown rapidly in the last 25 years. This growth has witnessed the organization and maintenance of geologic staffs by mining companies in several districts, and their detailed work, together with the fact that nearly all of the larger mining districts have

Jan 1, 1935

By M. R. J. Wyllie, H. W. Patnode

In the quantitative interpretation of electric log data it is essential to know the formation factor, defined as the ratio of the resistivity of the formation 100 per cent saturated with brine to the resistivity of the brine.' This concept implies that the formation factor for any given rock is constant irrespective of the resistivity of the brine or solution with which it is saturated. It is apparent that this can be true only when the rock matrix is wholly non-conductive. As reservoir rocks may contain clay or shale having an appreciable conductance one may expect these constituents to influence the determination of true formation factor. The formation factor may be theoretically derived from log data by dividing the resistivity of the mud filtrate invaded formation by the resistivity of the mud filtrate. Such a method of calculntion has implicit in it the assumption that the fluids in the invaded formation are wholly replaced by mud filtrate. that the solid matrix is non-conducting, and that the formation factor of the invaded zone is identical with the formation factor of the uninvaded zone. Since the validity of the first two basic assumptions regarding the insulating character of porous matrices and the displacement of the interstitial fluids in porous media do not appear to be fully established, the formation factors of a number of cores and clay slurries have been measured under conditions suitable for verifying the assumptions and the extent of any errors inherent in them. CORE STUDIES Apparatus and Procedure Resistivity measurements were made on short cylindrical permeable cores which had been previously mounted in lucite.2 The cores were clamped by means of insulated bolts between brass plates about 5 cm square and 1 cm in thickness. The plates were provided with a ring seal to prevent leakage between them and the core mount, and had a centrally located orifice so that fluids could be flowed through the mounted core. The brass mounting plates were used as electrodes and any current flow between them necessarily passed only through the constituents of the intervening core. Fluid saturation of the core, and fluid flow through the core, were effected by a centrifugal pump connected to the outflow end of the core, thus providing a differential pressure across the core of approximately one atmosphere. The procedure used was first to evacuate each core by means of the pump and then to saturate the core with an aqueous sodium chloride solution of known resistivity. The resistance of the core was measured and flow of the solution through the core continued for sufficient time to establish a constant resistance reading. After equilibrium had been reached with one solution, another sodium chloride solution of a different resistivity was flowed through the core and the flow continued until a constant resistance reading was again obtained. This procedure was continued until resistance measurements of the core had been made with a series of solutions within a salinity range from 1.0N NaCl to distilled water. The data obtained enabled the apparent formation factor of given porous rocks when saturated with fluids of different resistivity to be computed and also provided information regarding the ability of an invading fluid to displace interstitial water from a core. Results Berea Sandstone — The first core examined was a specimen of Berea sandstone." This core had been cut essentially parallel to the bedding for permeability studies. The core was clamped in the core holder and saturated with 1.0N NaCl solution and the resistance determined. It was subsequently flushed and the resistance measured when saturated in turn with 0.1N, 0.025N, 0.01N, .005N sodium chloride solutions and finally with distilled water. In flushing the core with each

Jan 1, 1950

By F. A. Hames, D. S. Eppelsheimer

The ferromagnetic copper-manganese-aluminum and copper-manganese-tin alloys (Heusler alloys) owe their ferromagnetism to the beta phases (body-centered cubic structure) in their respective systems.l,2,3 The ternary beta phase regions in these systems are extensions of the beta fields of the binary copper-aluminum and copper-tin systems into the ternary models of the copper-manganese-aluminum and copper-manganese-tin systems respectively. X ray analysis has indicated the presence of long-range order in the more strongly magnetic alloys.3,4,5 The ideal ordered structure is obtained in alloys of compositions Cu2MnAl and Cu2MnSn; the copper atoms occupy positions at cube centers while the aluminum (tin) and manganese atoms alternate at cube corners. This atomic arrangement is illustrated in Fig 1. The compositions Cu2MnAl and Cu2MnSn are also those that show maximum magnetic saturation moment. 3,4,6,7 Departures from these compositions result in a decrease in the degree of order attainable and a decrease in magnetic saturation moment. In view of the chemical similarities of aluminum, tin, indium, and gallium, and the existence of beta phases in the binary systems copper-indium and copper-gallium, it may be suspected that ternary beta phases exist in the systems copper-manganese-indium and copper-manganese-gallium, and that these are ferromagnetic. The purpose of this investigation was to determine whether ferromagnetic beta phases exist in the systems copper-manganese-indium and copper-manganese-gallium analogous to the ferromagnetic beta phases in the systems copper-manganese-aluminum and copper-manganese-tin. Previous Work At the time this investigation was started no information could be found regarding the constitution of copper-manganese-indium and copper-manganese-gallium alloys, nor of the binary manganese-indium and man-

Jan 1, 1950