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By Willis GM

The matte-metal-equilibria in the system Pb-Cu-S have been studied at temperatures between 720 and 920¦C by direct sampling and D.T.A. methods. These results are compared with those of other workers. The applications of such data to a continuous copper drossing process, and to a number of other metallurgical processes are discussed.

Jan 1, 1975

Don Hausen was a pioneer in the field of quantitative mineralogy. Methodology that he developed at Newmont almost 40 years ago is still employed today, only the technology has advanced. Petrographic methods were stressed with an emphasis on alteration, mineralisation and paragenesis. Methodologies employed by Don on the Carlin deposit were applied to developing the Carlin Trend by helping to work out lithology and structure, which ultimately led to the discovery of deep high-grade deposits. Quantitative methods used by Don on San Manuel, Copper Creek and Superior, Arizona were applied to the development of the Batu Hijau Deposit in Indonesia. Advancements in technology since DonÆs time have made the mineralogist much more efficient. Manual measurement of peak heights off of strip charts for semiquantitative XRD has been replaced by software that does Rietveld refinement and whole pattern fitting. Hand contouring of XRD data has been replaced by digitised data incorporated into geologic models. Optical point counting, which would take a dayÆs work to process 1000 points, has been replaced by automated SEM methods where 20 000 points are possible in an hour. The use of the optical microscope remains relatively unchanged, and still remains as Don emphasised the æeyesÆ of mineral exploration. However, the information can be relayed much more quickly with digital image capture and electronic data transfer. Don insisted on becoming involved in projects at the grassroots level and supporting the project through mine closure. This made the mineralogist a liaison between exploration geologists, mine geologists, metallurgists and mine engineers. The methodology that Don helped develop continues to provide invaluable support to Newmont geologists and metallurgists worldwide today.

Jan 1, 2008

By Pinczewski WV, Nowak LP, Tanzil WBU, Jenkins DR, McCarthy MJ

An experimental and theoretical study has been made of the drainage behaviour of two-dimensional packed beds drained from an outlet in the sidewall of the bed in order to identify the fundamental me- chanisms involved. Under these conditions a grad- ient develops in the air-liquid interface in the direction of flow with the interface tilting towards the outlet. This results in a significant volume of liquid being retained in the packing on completion of draining when the interface first reaches the bed outlet. Residual liquid volume and the shape of the air-liquid interface as a function of time were det- ermined experimentally in a two-dimensional packed bed where the packing consisted of glass spheres ranging in size from 0.6 to 10 mm dia. and the bed was drained at superficial liquid velocities rang- ing from 0.007 to 0.32cm/s. The test liquids used were water, glycerine/water solutions and kerosene resulting in a viscosity range of 1 to 10 mPa.s and a surface tension range of 0.0243 to 0.072 N/m. Assuming laminar flow within the bed, a compu- tational model was developed to predict both the liquid residual ratio and the temporal evolution of the drainage profile within the bed. The computed results were in good agreement with the experimental data over the entire range of conditions invest- igated. the computational model was used to estimate the relative importance of the effects of changes in hearth conditions on residual slag volume for typ- ical blast furnace operating conditions. On the basis of the computed results it is concluded that coke quality is a major parameter affecting hearth drainage performance.

Jan 1, 1981

The Myra Falls minesite, of Westmin Resources Limited, is located at the geographic centre of Vancouver Island, within the confines of Strathcona Provincial Park. The operation includes two active underground mines, II-W and Lynx, together with a modem 3650 1/d milling facility. Recent exploration successes will lead to the commissioning of a third mining area in late-1993 - The Battle/Gap Mine. These ore deposits are complexly metal-zoned volcanogenic massive sulphides of Devonian age, hosted in the Myra Formation of the Sicker Group volcanic assemblage. Three distinct felsic volcanic units are defined within the 450 metre thick Myra Formation. They are, from oldest to youngest, the H-W Horizon, the LMP Horizon and the Upper Rhyolite Unit. Massive sulphide mineralisation occurs throughout the property in the H-W and LMP Horizons. There are a number of orebody types, including polymetallic massive sulphides, polymetallic disseminated sulphides, zoned pyritic massive sulphides, elastic sulphide zones and stringer sulphide zones. Individual orebodies range in size from 10 000 tonne zinc-rich polymetallic lenses to the ten million tonne, zoned massive sulphide H-W main lens. The property has been in continuous operation for 26 years, producing over 13 Mt of ore averaging 2.2 g/t Au, 64.0 g/t Ag, 1.9 per cent Cu, 0.6 per cent Pb, and 5.6 per cent Zn. Current geological reserves stand at 12.5 Mt at a comparable grade, including 4 Mt of recently discovered high grade ore in the Battle and Gap Zones. Mining and milling methods have evolved over time to enable successful extraction and milling of these complex ores. Change is on-going with the recent conversion of the H-W Mine to large-scale bulk mining methods, and the development of effective computerised ore reserve calculation and mine planning tools. These changes, in concert with successful exploration techniques that led to recent high grade ore discoveries, have breathed new life into the operation and should assure its present and future viability.

Jan 1, 1993

A thick sequence of alkaline intrusions and volcanic rocks underlies a Quaternary caldera on Liliir Island. The sequence is host to a still active sub-aerial hydrothermal system and associated epithermal gold mineralisation. Sub-horizontal alteration horizons exhibit progressively increasing chondrite norma-lised (La/Lu) en and (La/Sm) cn ratios from unaltered shoshonites, to the potassic alteration zone, to the argillic altera-tion zone to the advanced argillic alte-ration zone. The increasing fractionation of HEE, and especially of LHEE, up the alteration sequence is the result of de-creasing pH, temperature and alkalinity of the hydrothermal fluids with increa-sing alteration intensity. HRE3 were especially mobile in argillic and advanced argillic alteration units characterised by acid fluid conditions and large fluid volumes. Abundant Cl, S and CO2 within the hydrothermal fluids and thus abundant REE complexing agents and large fluid volumes favoured the mobility of REE during hydro-thermal alteration of the volcanic rocks and intrusions. Steam escape, mixing of the gases with groundwater and a change from a magmatic neutral chloride hydro-thermal system to a meteoric acid sulphate system was accompanied by liquid/vapour ratio changes, pronounced alkalinity, pH and temperature decreases, and fluid/rock ratio increases. This caused the mobili-sation, fractionation and deposition of PF.F.

Jan 1, 1990

About 20 percent of world gold production has been contributed by gold deposits in Archaean greenstone belts, of which ca 2100 tonnes of gold has been produced from Archaean greenstone belts in Western Australia (Phillips, in press). These deposits are, therefore, important exploration targets and an under-standing of their nature and genesis can help to formulate exploration strategies and delineate potential targets.A literature survey of Archaean granitoid-greenstone terrains indicates that a wide variety of lithologies host gold deposits. The major part of production from the Yilgarn Block, Western Australia, has come from mafic volcanics andintrusives (70% of production),with significant contributions from BIF-hosted ores (15%) and low production from sediments, felsic volcanics, porphyry intrusives and granitoids (Groves et al., in press). Similarly, most

Jan 1, 1984

This monograph presents a unified theory of adsorption and desorption of aurocyanide on activated carbon. This theory has proved useful for CIP/CIL carbon adsorption and Zadra and AARL elution process and equipment design; in accounting for the effects of various water qualities and process temperatures; and in the development of reagents to improve these processes. The theory presented is based on rigorous fundamentals : Classical Eyring theory links initial first order kinetics with Langmuir isotherm equilibria, and this isotherm is demonstrated for the first time to be a consequence of the activated complex postulate of Eyring theory. Simple extension to Freundlich conditions at high solution tenors is possible, but not presented. Supporting entropy data determined by the author includes practically all the pioneering CIP plants built in South Africa and Australia in the early 1980s.

Jan 1, 1991

By Baafi E. Y

In this paper, impact of expert systems development is examined from the coal mining point of view. Some introductory concepts about expert systems are explained with a view to identifying possible beneficial applications of expert systems in coal Mining.

Jan 1, 1988

By B P. Wrench, M J. Gowan, P J. Chapman

Embankment dams constructed mainly of sand or non-plastic fine soils are susceptible to liquefaction, particularly in high-rainfall, high-seismicity environments where there is sufficient water to saturate the materials and sufficient energy from an earthquake to cause liquefaction. This paper shows the process adopted to review the stability of an existing cross-valley, centreline-raised cyclone tailings sand embankment dam.The study showed that two-dimensional stability analyses did not sufficiently capture the potential for instability, overestimating the depth of the critical failure surface. Instead, three-dimensional modelling was required to provide a reasonable representation. Post-liquefaction stability analyses carried out using the three-dimensional model indicated an adequate factor of safety (FoS). The FoS under seismic conditions was still considered to be a concern based on pseudostatic analyses (but noting the limitations of the analysis method).Earthquake-induced settlements were estimated using an empirical approach based on case history records (Swaisgood, 2003). The post-earthquake event settlement was estimated to be in the order of 600 mm, which is considered to be acceptable for the embankment, taking account of the proposed long-term freeboard of more than 8 m under operating conditions and 2 m under the probable maximum flood condition.CITATION:Chapman, P J, Wrench, B P and Gowan, M J, 2015. Review of static and seismic stability of a cross-valley sand tailings embankment in a high-rainfall, high-seismicity setting, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 163–172 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

A description is given of a detailed examination of a coal bore core and of attempts to predict properties of equivalent "as-mined" coal using the bore core data so obtained. The accuracy of the prediction was measured by testing independently a large sample of coal which was produced under near mining conditions from a site adjacent to the bore core. Very encouraging results were obtained particularly in the prediction of size and ash distributions and washability characteristics of run-of-mine Coal.

Jan 1, 1972

By Koppe JC, Strieder AJ

The Rivera Crystalline Island (RCI) is an erosional window of the intracontinental Parana Basin that outcrops in the Rivera Department, north of Uruguay. RCI is made up mainly by Precambrian granites, metasediments and granite-gneisses. This island is crosscut by a dextral transcurrent shear zone system, the Rivera Shear System (RSS). The bulk strain ellipsoid was defined by previous work and has allowed the evaluation of shear dynamics. The geometry of the shear system is made up of two shear directions: E-W (P-shear), which turn right to NW-SE direction (R-shear), leading to the development of extensional bends. The shear zone system was developed in brittle-ductile to brittle regimes, under temperature conditions compatible with greenschist facies metamorphism. The shear zones are marked by an intensive fracture cleavage development. Mylonites develop only in narrow, discontinuous higher strain zones. Internally, the shear zones are dominated by intrusive rocks, mainly granites, dacites and diorites. Hydrothermal alteration has been developed in several areas.The economic significance of RCI is given by several small gold deposits, which have been exploited since 1869. One major new gold mine is under development, the San Gregorio Gold Mine. This gold deposit is locally controlled by a dilatant site where R-shear turns right to P-shear. Mine lithologies were deeply altered by hydrothermal fluids in the dilatant structure. This work presents the lineament-structural analysis carried out to identify similar structural patterns in all RCI sites favourable to host other gold deposits. The exploration program also considered remote sensing, geology, geophysical and geochemical survey.

Jan 1, 1997

By A Gerson, S Miller, R Smart, J Thomas

Environmental Geochemistry International (EGi) and the Ian Wark Research Institute (IWRI) collaborated in a three-year Australian Minerals Industry Research Association (AMIRA) research project (Project Number P387A) focussed on the prediction and kinetic control of acid mine drainage. As part of this project, single addition, and sequential net acid generation (NAG) testing was carried out on sulfide mineral samples. The test samples comprised a range of synthetic waste materials prepared using a quartz bulk and controlled quantities of the commonly occurring sulfide minerals; pyrite (FeS2), pyrrhotite (Fe7S8), arsenopyrite (AsFeS), chalcopyrite (CuFeS2), chalcocite (Cu2S), covellite (CuS), bornite (Cu5FeS4), galena (PbS) and sphalerite (ZnS). NAG test results clearly show that there are significant differences between the acid forming potential of sulfide minerals. The NAG test results for each mineral were compared with theoretical acidity values (NAPP*). The NAPP* calculation was based on stoichiometric oxidation reactions assumed for each of the sulfide minerals. Sequential NAG values for pyrite corresponds closely to predicted NAPP* values, confirming the assumption that pyrite oxidation occurs according to the stoichiometry assumed. For the pyrite sample with 5 wt per cent S, two NAG stages were sufficient for all of the sulfur to be released to solution. Since sulfides in waste materials will generally be dominated by pyrite, results also confirm the validity of including NAG testing for ARD evaluation of most waste rock. NAG testing confirms that of the sulfide minerals examined, only pyrite, pyrrhotite, arsenopyrite and chalcopyrite are acid producing, ie able to produce leachate with a pH less than 4.5. In the case of sphalerite, galena, bornite, chalcocite and covellite the pH of the final NAG solution was greater than 4.5. The significant differences between the acid forming potential of different sulfide minerals could lead to overestimation of acid producing potentials based on NAPP values calculated from total per cent S alone, ie assuming all S is present as pyrite. The oxidation of galena during the NAG test resulted in the consumption of acid. The examination of the galena surface by X-ray photoelectron spectroscopy (XPS) after oxidation in peroxide solution indicated the presence of polysulfide. The reaction of sulfide to polysulfide is acid consuming, thus explaining the net acid consuming behaviour of galena in the NAG test. This reaction pathway may provide a possible explanation for the lower than expected acid production observed for some of the other sulfide minerals examined.

Jan 1, 2003

By B Walker, A Robertson, C Wels, S Fortin

A background characterisation study was carried out in the Sangre de Cristo mountains, New Mexico, to: quantify naturally occurring contaminant loads from mineralised areas; define site-specific background concentrations; and to determine key factors controlling spatial and temporal variations in contaminant concentrations. The study included a comprehensive sampling and testing program (paste pH/EC, ABA, leach extraction tests) of soil/bedrock from mineralised areas (including erosional scars), and a ground water and surface water quality monitoring program in selected mineralised watersheds. Results demonstrate that high concentrations of contaminants occur naturally in ground and surface water draining the mineralised area of the Red River basin. The erosional scars were found to represent the major source of acid rock drainage (ARD) (~66 per cent) in this area due to: high rates of weathering and erosion, which continually exposes sulfide-bearing outcrops; and high rates of run-off as a result of high elevation and lack of vegetation. The scar material is generally very acidic (paste pH ranges from 8.5 to 1.5; average = 3.6) with highly elevated concentrations of sulfate and leachable metals. The composition and concentration of leachable metals vary significantly, not only between scars but also within a given scar. While all streams draining the various scar watersheds are highly acidic, each has a characteristic æfingerprintÆ of sulfate and metal concentrations. Most of the run-off from the scars infiltrates into alluvial debris flow aprons and reaches the Red River via groundwater flow.

Jan 1, 2003

By Nightingale R, Johnson B, Bensley C, Vince A, Keast-Jones R

In order to counter the massive increase in the level of near gravity material that would follow the reduction in dense-medium cyclone separation density at B.H.P. Slab and Plate Product Division's B and C coal preparation plants, "wing tank" systems to control medium density to within ¦0.005RD units have been installed. However, despite very precise density control, cyclone metallurgical performance has been less than satisfactory. The approaches taken to identify the causes of this poor performance and to justify alterations in operational and maintenance practices are presented.

Jan 1, 1987

The discovery of nickel sulphide deposits at Kambalda in 1966 heralded the development of ò an industry with a capital value of over $1.5 billion producing about 10% of the western world's nickel. ò an unprecedented exploration boom in which over $200 mil- lion was expended in 10 years in the search for nickel deposits. ò a major new class of nickel deposits stimulating exploration for similar deposits overseas. and rapidly propelled a struggling small mining and exploration company to become one of Australia's corporate giants, provid- ing a much-needed stimulus to economic activity in a region suffering from a severe downturn in its principal industry, gold mining. Production of nickel in Western Australia commenced at Kam- balda in 1967 and grew rapidly to a rate of over 30,000 t of con- tained nickel per annum in 1970, 40,000 t in 1973 and 50,000 t in 1975. Early production was aided by a shortage of nickel on the world market due to disruption of supply from the major Canadian producers, resulting in high free market prices for the metal. Since these early years, the industry has experienced a number of cycles of indifferent health due principally to market developments overseas, although the level of production of nickel in Western Australia remained fairly consistent. The two most serious of these, in 1977-8 and 1985-6, forced the closure of a number of mines. Current nickel prices are allowing remaining producers to enjoy a measure of relative prosperity, although there is little general speculation that this will be long-lived. Nickel deposits discovered in the exploration boom were almost exclusively related to ultramafic rocks. Volcanic peridotite (komatiite)-associated deposits, exemplified by the Kambalda ore- bodies, were the targets of initial exploration which was concen- trated on ultramafic sequences near lower stratigraphic contacts with underlying mafic rocks. Subsequently, discoveries made in coarse-grained dunites in interpreted intrusive settings broadened the search parameters.

Jan 1, 1988

By Gibbons S. L, Ritchie I. M, Murr D. M

Fundamental studies on the transformations of iron oxides have been carried out and related to the solution conditions in the Becher process. The results show that a number of iron oxide interconversion reactions occur in the aeration reactor with the products depending on the pH, temperature and oxidation potential of the aeration liquor. It is concluded that the lack of process control in the aeration reactor of the Becher process significantly hinders the ability to predict and produce high quality single phase iron oxides of a consistent colour.

Jan 1, 1990

By J J. McNee and, J Crusius, T F. Pedersen

The use of water covers is a globally-applied method for minimising acid rock drainage (ARD) and metal leaching. Although the subaqueous disposal of potentially acid-generating materials has been shown to effectively limit ARD, under certain scenarios, metal remobilisation can occur at circum-neutral pH. The following paper presents data from four case studies in which metal mobility from submerged mine waste resulted in degradation to water quality in the overlying water cover. Subcentimetre resolution profiling of dissolved constituents across the tailings-water interface (dialysis arrays), in conjunction with mineralogical information, were used to elucidate the controls governing metal mobility. The data illustrate four pathways of metal remobilisation, including: the release of zinc via the oxidative remineralisation of metal-rich organics at the tailings-water interface; enhanced remobilisation of arsenic as a result of anthropogenic eutrophication; the release of copper resulting from the pH-driven dissolution of treatment sludges; and the release of radium from uranium mill tailings due to the dissolution of radiobarite [(Ra,Ba)SO4] by sulfate-reducing bacteria. The results highlight the conclusion that the chemical stability of submerged tailings reflects both: the solid-phase characteristics of the tailings material; and the physical, chemical and biological characteristics of the depositional environment. In particular, the data illustrate that rigorous characterisation of both the waste solids and receiving environment must be performed in order to assess their compatibility. The results have relevance to the management of tailings repositories including constructed impoundments, pit lakes and natural lakes.

Jan 1, 2003

A BRIEF account of the water-power potentialities of Tasmania is given, together with possible applications of the power commercially. A short history of the Waddamana development is then given, and the main works are described.WATER POWER POTENTIALITIESTasmania is an island of approximately 24,500 sq. miles area (exclusive of small islands). An area of 12,000 sq. miles is at an elevation of over 1000 ft. above sea-level, and of 2300 sq. miles at over 3000 ft. above sea-level. Average annual rainfall varies from' over 140 in. on West Coast to 20 in. on East Coast, and for the whole island averages 48.5 in. The total water-power available, based on conservative figures for run off and efficiency, is 6,000,000 b.h.p. Only a small percentage of this total will, under present conditions, and under likely conditions in the immediate future, be capable of being developed commercially.An extensive hydro-metric and water-power survey is at present being carried out in order to collect information concerning the most promising water-power schemes. Already 400,000 b.h.p. has been located in different proposals, and there is still a large area of very likely country along the West Coast which has not been investigated yet. Tasmania thus has very vast power potentialities, which, combined with good ports and communications and wonderful mineral and timber resources, should augur well for the establishment of the great key industries, particularly chemical and metallurgical.

Jan 1, 1923

By Y Li

An ilmenite ore from the Murray Basin was initially characterised using combined X-ray Fluorescence Spectroscopy (XRF), X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM) and Electron Probe Microanalysis (EPMA) techniques. XRF analysis showed the ilmenite sample contained 58.7 wt per cent TiO2 and 26.2 wt per cent Fe2O3. Major impurities included: Cr2O3 (4.5 wt per cent), Al2O3 (2.7 wt per cent), SiO2 (1.9 wt per cent), Mn3O4 (1.5 wt per cent) and MgO (1.1 wt per cent). Manganese and magnesium were present as solid solution components within the ilmenite lattice while the elevated Al2O3 and SiO2 levels were due to separate aluminosilicate gangue minerals. Chromium was associated with discrete chrome spinel gangue phases of variable composition, (Fe,Mg)(Cr,Al)2O4. Quantitative XRD analysis of the sample identified rutile (12 per cent), ilmenite (11 per cent), and pseudorutile (67 per cent) as the main titanium-containing phases and chrome-rich spinels (seven per cent) as the major impurity phase. Minor quartz, aluminosilicates, zircon and monazite were also present. The ilmenite was mixed with synthetic graphite, pressed into pellets and reduced carbothermally in nitrogen at 1200 and 1400°C with C/O molar ratio of 1.2. Titanium oxide in the ilmenite was converted to titanium oxycarbonitride. Iron oxides were reduced to metallic iron. The Changes of impurities as a result of reduction was examined by SEM and EPMA analyses. Iron and chromium oxides within Fe-rich chromite were reduced to form a Fe-Cr-C alloy. Mg-rich chrome spinels were partly reduced at 1200°C. Zircon particles were not reduced at 1200°C, but were significantly reduced at 1400°C, with the particles becoming porous and the silicon being removed.

Oct 5, 2011

By Davey P. T, Tsambourakis G

Mineralogical analysis of supergene sulphide ore recovered from areas close to the underground workings at the abandoned Mutooroo (South Australia) mine shows that the original sulphide minerals have undergone substantial alteration. The cause of this alteration is believed to be contact with the highly saline, acidic mine water. The copper is now present as a sulphide that can best be described as a copper- and iron-delicient chalcopyrite, CuxFeyS2, where in most cases x < y. The values of x and y vary from point-to-point within each grain.Leach tests under a variety of conditions show that dissolution of the copper from the supergene sulphide ore can be readily achieved, particularly when compared with the behaviour of Mt Isa chalcopyrite concentrate. For the supergene sulphide ore, an increase in the acidity and the iron(lll) concentration of the leachant re ults in an increase in the rate of copper dissolution.The results are briefly discussed in terms of the experimental in-situ leaching operation at Mutooroo, South Australia.

Jan 1, 1986