Search Documents

By Walker G. S, Sparrow G. J

Dissolution of S02 into water-acetone mixtures results in the formation of 2-hydroxy-2-propane sulphonic acid. The pH, or acid strength, of water-carbonyl-S02 mix- tures can be controlled by varying the concen- tration of the carbonyl compound or the rate at which S02 is added to the water-carbonyl mixture during a reaction. The ease with which the acid strength of these mixtures can be controlled means that they have significant potential for use as a selective lixiviant. We have used water-acetone-S02 mixtures to selectively dissolve phosphate minerals in Christmas Island and Duchess phosphate ores and also uranium minerals in Yeelirrie uranium ore and Olympic Dam copper concentrate.

Jan 1, 1987

The first continuous pressure disk filter took up industrial-scale operation in Germany in 1976. This paper comments on major components of pressure filter facilities from the point of view of industrial-plant suppliers. For lack of time aspects of economy have not been commented upon. The paper elucidates a number of process-engineering inter-relations. It outlines important development trends from the angle of a machine-building company.

Jan 1, 1989

About 3km2 of the central Luise Caldera, in which the Lihir orebody is located, is geothermally active wit.lj gas seeps and fumaroles, and in some areas, a water table at boiling point.The proposed mine, adjacent to Luise Harbor, will be excavated to more than 200m below sea level and will extend into the geothermal system to depths at which current rock temperatures are 170¦C.

Jan 1, 1994

By R Dunne, D Yan

In flotation where a bulk flotation concentrate is produced or a gangue sulfide such as pyrite contaminates a concentrate, residual collector has to be removed from the sulfide surfaces to allow selective separation in a subsequent flotation step. Depending on the sulfide mineral, the main species that needs to be removed when using a xanthate collector is either a metal xanthate or dixanthogen. For the identification of surface species, specific solvents may be used to remove each species û metal xanthates are known to be soluble in acetone whilst dixanthogens are known to be soluble in non-polar solvents such as diethyl ether. Xanthates break down with time, temperature and pH into various decomposition products. The major decomposition product is dixanthogen which can aid flotation but other products such as perxanthate and carbon disulfide can have an adverse effect on flotation. Various analytical techniques can be employed to monitor the formation of decomposition products on the surface of the mineral and in solution. The best of these is ultraviolet spectroscopy as it has diagnostic peaks for decomposition product determination. In this work two approaches were taken to understand the relationship between the flotation of a chalcopyrite and pyrite from an ore containing these two minerals. One approach was to remove the xanthate species with an organic solvent and then use ultraviolet spectroscopy to determine the concentration of dissolved species. The second method involved measuring xanthate decomposition in solution by measuring the residual xanthate concentration using ultraviolet spectroscopy. These experiments confirmed the species adsorb at the surface of the mineral and how these species affect the recovery and grade of the valuable mineral. In both cases pH and temperature were varied and two xanthate collectors (SEX and PAX) were used to study these relationships. These relationships could be applied to industrial flotation systems and allow for more accurate determination of optimal xanthate dosage and hence save on reagent costs.

Jan 1, 2005

By D P. Obeng, L Reemeyer, R Holmes

The Zinifex Century Mine employs a large number of Detritor mills for fine and ultra-fine grinding to liberate silica and sphalerite at 80 per cent passing 7.5 microns before final zinc flotation. A joint project between CSIRO Minerals and the Zinifex Century Mine was carried out to evaluate the Detritor mill performance. Plant surveys were conducted around the Detritors in conjunction with laboratory tests. The survey data showed that the Detritors in the ultra-fine milling circuit performed well. They reduced a feed F80 sizing of 46 microns to a product P80 sizing of 7.5 microns at a gross energy consumption of 37.2 kWh/t. Scale-up of ultra-fine milling Detritors was studied using a 0.55 kW laboratory batch unit and a 355 kW full-scale Detritor by processing Century zinc concentrate with 1 mm sand media. The results indicated that the 0.55 kW laboratory mill underestimated the energy consumption of the full-scale Detritor by about 20 per cent for a product P80 of seven microns. The performances of a horizontal IsaMill and a vertical Detritor were compared as ultra-fine milling devices for processing Century zinc concentrate. The experimental data demonstrated that, when using the same grinding media, the energy efficiency of the two mills is similar despite the difference in mill designs. The Detritors used for regrind duty at the Century Mine performed poorly when processing feed at 80 per cent passing 88 micron. The energy consumption was high and the product size distribution was broad with particles above 100 microns in the feed unbroken and particles below ten microns overground. A coarser ceramic media of 3 mm was therefore tested in a laboratory Detritor to process the regrind Detritor feed as an alternative to the 1 mm Colorado sand used at the Century Mine. The ceramic media reduced the energy consumption significantly and produced a narrower product size distribution, which is more desirable for the downstream flotation process.

Jan 1, 2007

INDEX OF CONTENTSIntroductionChemical compositionsNormally Cooled MattesPort Kembla mattesMount Lyell matteMount Morgan matteGranulated MattesConclusionsIllustrationsINTRODUCTIONIn a previous paper in these Proceedings(l) an account was given of the composition of some copper-lead mattes from the Port Pirie Smelters. The research programme of the Mineragraphic Section of the Commonwealth Scientific and Industrial Research organization has since been extended to copper-iron mattes from Port Kembla (The Electrolytic Refining ana Smelting Co. of Australia), Mount Lyell (The Mount Lyell Mining and Railway Co.) and Mouilt Morgan (Mount Morga:p. Ltd.).Chemical Composition of the Mattes.The mattes examined have a considerable range in chemical composition, as is shown by their analyses (Table 1).

Jan 1, 1949

By M M. M LT Tassinari, A B. Braz, L M. SantÆAgostino, C Ulsen

Several mineral resources have been recognised to alkaline igneous rocks. In general, these mineralisations present low P grades, so a complex concentration process is required to achieve commercial grade concentrates. This process is guided not only by the ore characteristics, such as apatite grain size and liberation degree, gangue minerals and slimes content, but also by different apatite varieties, iron oxi-hydroxide surface coating and roughness. The main techniques applied to apatite and phosphate ore characterisation, such as optical microscopy, cathodoluminescence (CL) microscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), surface techniques and magnetic separation are discussed, aiming to evaluate distinct apatite varieties and their technological behaviour.

Jan 1, 2008

The 1980's has seen a revolution in gold mine developments in Australasia. We are witnessing a near ten fold increase in all phases of gold mine development ranging from exploration through to production. Ounces produced have yet to mirror this activity but have increased from a low point of 600,000 in 1980 to 1,800,000 ounces in 1985 in Australia alone. In 1980 the region had less than 10 gold mines, yet 14 new mines started production in 1985 and as many as 28 might start up in the next 18 months. Developing gold mines in the 1980's in Australasia has not been the easiest of jobs, yet the great number of new developments suggest that we have entered a new era that will rank in history along with the 1850's, 1890's and 1930's as high points.Within- our Australasian region two very distinctive styles of gold deposits are being discovered and developed. On the Australian mainland the new mines are in geologically old rocks and are mostly the low grade haloes surrounding worked out high grade deposits. Most are limited life open pit operations depending on recent innovative carbon-in-pulp or heap leach technology. In the Pacific Islands region the style of discoveries are geologically recent, large bulk-low-grade deposits often geologically analogous to porphyry copper deposits. These deposits are typically 10 to 20 times larger than those being proved up on the Australian mainland.

Jan 1, 1986

By G Swayn, J Harpley

Spent Pot Lining (SPL) is an unavoidable waste product of the electrolytic process in the smelting of aluminium. SPL is considered to be a hazardous waste in various countries because it contains significant quantities of absorbed fluoride along with traces of cyanide. The disposal of SPL has been primarily in landfill because of difficulties in the development of a successful techno-economic SPL treatment process. Increasing concern about SPL landfilling practices is resulting in regulations in some countries to ban this form of disposal. As a consequence stock piling of SPL is occurring in an increasing number of countries pending the development of a successful treatment process. In 1992 Portland Aluminium investigated a SPL treatment process based on pyrometallurgical technology and approached a company called Ausmelt in Dandenong, Victoria, Australia, to ascertain if their submerged lance technology furnace process would be suitable to treat SPL. This approach resulted in Portland Aluminium, Alcoa and Ausmelt personnel working together on trials during 1992 - 1994 in Ausmelt's demonstration furnace to produce a slag and off gases containing hydrogen and sodium fluoride. The trials also evaluated the effect of oxygen enrichment to increase the concentration of hydrogen fluoride and the ability to recycle sodium fluoride particulate produced as the furnace off gases cooled. Other separate developmental work by Portland Aluminium, using CSIRO, resulted in the production of aluminium fluoride from the offgases from the pyrometallurgical process. The results of these projects influenced Portland Aluminium and Alcoa to authorise up to $A26 400 000 in December 1995 to construct a Research and Development processing facility to treat SPL at Portland. The Portland Aluminium unique gas treatment process converts hydrogen fluoride in the furnace offgases to aluminium fluoride in a multistage fluidised bed reactor, designed by Portland Aluminium. The aluminium fluoride produced in the reactor has been trialed successfully in Alcoa's aluminium smelting process as a replacement for imported aluminium fluoride. The installation in mid-2001 of a slag granulation system has enabled the production of a granulated vitreous slag having leachability qualities that conform to Victorian EPA criteria for the unrestricted use of the granulated vitreous slag from 'The Alcoa Portland SPL Process'. The unrestricted use of the granulated slag successfully completes 'The Alcoa Portland SPL Process' which treats the hazardous waste material SPL and converts it into non hazardous useful products.

Jan 1, 2002

By N DavT

Pyritic tailings from the Quirke mine waste management area in Elliot Lake, Ontario were subjected to long-term column leaching experiments in two PVC columns measuring 122 cm in height and 15.2 cm in diameter. At the end of the leaching experiments, the columns were taken apart and sampled at 5 cm intervals for quantitative mineralogical and geochemical characterisation. Each column is represented by a total of ten samples. Polished sections, prepared from the samples, were studied by optical microscopy, scanning electron microscopy, electron microprobe and X-ray diffraction techniques. Mineral quantities were determined based on linear mixing models of whole rock and mineral compositions. Pyrite particle sizes were measured by image analysis interfaced to an electron microprobe. The tailings are coarse-grained (ie 96 per cent passing 75 ¦m) and composed of quartz, K-feldspar, muscovite and pyrite. Pyrite is homogenous and occurs as liberated particles displaying angular to subangular boundaries with strong dissolution features at the end of the leaching experiments. Based on up to 3518 particles measured in a sample, pyrite particle sizes range from 1.7 to 78.6 ¦m. Pyrite concentrations vary from 0.1 to 7.8 wt per cent, depending upon their location from the top of the columns. These correspond to pyrite losses of up to 99 per cent from their original level of 7.2 wt per cent in the upper half of the columns. Pyrite oxidation rates in terms of moles of pyrite oxidised per mole of pyrite per square metre per second were calculated from the effluent data and the measured pyrite particle sizes. The rates vary from 1.71+10-12 to 5.78+10-10 mole+m-2+s-1 within the 1.5 to 3.5 pH range for 10 ¦m particles. These results are comparable with the published oxidation rates at pH 2 where the dissolved oxygen is the only oxidant.

Jan 1, 2003

On Wednesday 11th November, 1970, a series of violent explosions occur-- red within No.1 Basic Oxygen Steelmak- ing (B.O.S.) furnace at the Whyalla Works of the Broken Hill Proprietary Co. Ltd., (B.H.P.) when the furnace was moved immediately prior to tapping. Water from a burnt out flux chute had flooded the bath while the furnace was tilted slightly towards the tapping side waiting to tap. Although no one was injured, dam- age in excess of $54 000 was caused to the hood and superstructure. The water hydrated the burnt dolomite refractory lining some of which sub- sequently collapsed exposing bare fur- nace shell over part of the cone.

Jan 1, 1975

By Hammett PHJ

Oil Exploration Companies are primarily interested in how much oil or gas is present in the rocks in an area in which an exploratory well is drilled. The solution of this problem requires a combined effort on the part of the petroleum geologists, drilling engineers, logging and drilling contractors. To help in'explaining how the drilling and evaluation is earried out the paper has been divided into two sertions, one titled Drilling which is presented by Mr. P.H.J.-Hammett and the seeond titled Evaluation which is presented by Mr. R.M.L. Elliott. A typical Perth Basin Well has been chosen as art example for this presentation. In Figure 1A is shown the type of sandstone and shale sequence encountered in this area.

Jan 1, 1964

By G P. W Suyantara, Y Tanaka, T Hirajima, Y Aoki, K Sasaki, H Miki

The effect of sodium sulfite (Na2SO3) on the flotation behaviour of bornite and tennantite is reported in this work. Flotation tests were performed using pure minerals of bornite and tennantite under various concentrations of sodium sulfite at pH 9. The flotation results indicated that sodium sulfite exhibited a depressing effect on the floatability of bornite in the presence of 0.1 mM PAX. However, tennantite remained floatable after the addition of sodium sulfite in the presence of 0.1 mM PAX. The flotation tests using mixed bornite and tennantite confirmed the flotation results of single minerals. Surface characterisation using X-ray photoelectron spectroscopy (XPS) was performed to explain the flotation results. A mechanism is proposed based on the XPS analysis results.

Aug 24, 2022

By D B, M A. Sares, D W. Coulter, D C. Peters

This presentation discusses NASA-funded research on the ability of hyperspectral remote sensing to map diagnostic acid rock drainage (ARD) mineralogy that adversely affects water quality within watershed and to determine the relative contributions of natural ARD sources of metals and acidity to that drainage. Ground-based reflectance spectroscopy, combined with water chemistry, is used to identify mineralogical and chemical variations throughout a watershed. Integrated with hyperspectral data acquired from airborne remote sensing platforms, such as the NASA Airborne Visible Infrared Imaging Spectrometer (AVIRIS) sensor, a methodology has been developed that should improve environmental assessments and tracking of impacts on and from drainages. Phase I of this project focuses on a drainage basin (Lake Creek), tributary to the upper Arkansas River in central Colorado, which is impacted by natural acid rock drainage from areas of high-sulfide hydrothermal alteration. This project builds upon research and inventory efforts by the Colorado Geological Survey (CGS) to identify hydrothermal alteration that is the primary source or is contributing to acidic and toxic drainage in Colorado. This presentation will cover ground and airborne hyperspectral remote sensing techniques and results and water analyses for seasonal high-flow and low-flow conditions in Lake Creek. Identifying correlations between mineralogy, especially mineralogy that can be identified through airborne remote sensing, and water chemistry is a key focus of this project. Of particular interest are low-pH iron phases such as jarosite, ferrihydrite, schwertmannite, copiapite, and transitional amorphous phases as well as AlOH phases from higher, although still acidic, pH environments which are observed to mix with the iron precipitates within the streams draining from the hydrothermal systems. Drainage in the Lake Creek watershed derives from the Grizzly Peak caldera (Oligocene), which exhibits extensive hydrothermal alteration. Alteration types include silicic, quartz-sericite, quartz-sericite-pyrite, advanced argillic, and argillic. By understanding the chemistry of a naturally impacted drainage and its relationship to the surrounding geology, the project goal is to allow more efficient and complete identification of such sources in mineralised terranes through remote sensing technology.

Jan 1, 2003

By Ciminelli VST

Thiourea leaching has been applied to a refractory gold concentrate previously treated by bacterial oxidation. Following the bio-oxidation, gold has been leached in acidic thiourea solutions, under different pH(1 - 2.4), thiourea concentrations (2 - 15 g/1), ferric ion concentrations (0.04 - 3 g/1) and temperatures (298 - 333 K). Through this procedure, it was possible to increase gold extraction from 40 to 77 per cent. The increase in temperature raised gold extraction and reduced reagent consumption. Sodium sulphite addition was also very effective in lowering thiourea consumption. Staged leaching operations with interstage acid washing and carbon-in-leach experiments were tested, in an attempt to increase gold extraction. The results of thiourea leaching were compared with those obtained with cyanidation.

Jan 1, 1993

A recent boom in the mining and minerals sector has seen the creation of an increasing number of graduate roles. These positions offer varying experiences, many with the larger international mining houses, some with the smaller players. Regardless of the company, and regardless of the program structure, there are a few key points that a graduate can follow to ensure he or she extracts the most from any graduate experience.

Jan 1, 2007

Two continuous computer controlled, remote air analysis (RAA) systems operate at The Zinc Corporation, Limited (ZC) to give early warning in case of an underground fire at ZC or New Broken Hill Consolidated Limited (NBHC) mines. Air drawn from underground sampling points via a tube bundle system is analysed for carbon monoxide and carbon dioxide. An alarm is sounded if the concentrations of these gases exceed bench mark figures.

Jan 1, 1983

By Tobin GJ

Testwork carried out in the cooling water circuit at the Yabulu treatment plant of the Greenvale Joint Venturers (Metals Exploration Queensland Pty. Ltd. and Freeport Queensland Nickel Incorporated) since 1980 has resulted in significant improvements to both fouling and corrosion control. At the same time corrosion inhibitor costs have been reduced.Acrylate-type silt dispersants were identified as the most effective means of sediment control in the circuit. An increase in the cathodic component of the corrosion inhibitor coupled with a relatively minor adjustment to water pH has yielded a two to three fold reduction in corrosion rate. It has been established that these lower corrosion rates can be sustained in the face of a 20% reduction in corrosion inhibitor addition rate. Further improvements are indicated with a change of raw water algicide.

Jan 1, 1985

By Hutchings AA

This paper describes MIM's experience in arranging and executing project financings for coal projects at Oaky Creek and Newlands and Collinsville and the port facility of Abbot Point.The financings had their origins in the late 1970's and culminated with the opening of these projects during 1983 and 1984.MIM's financing developments therefore span an important period in the development of resource projects in Australia.Resources projects have been growing in both scale and complexity of financing requirements.

Jan 1, 1985

By V K. Singh, G Sural

The problem of spontaneous heating/fire is very common in coal mines all over the world. The coal industry faces many problems day by day due to the occurrence of spontaneous heating in the open pit coal mines. Presently, about 70 per cent of total coal production in Indian mines is being carried out by open pit mining. Fire in coal, particularly in open pit mines not only causes irreparable loss of natural wealth but also damages the surface structures and pollutes the environment. It is well known that 75 per cent of the fires occur due to the spontaneous combustion of coal. Spontaneous heating is a very common occurrence in coal mines and is a major factor contributing to mine fire. The liability of coal to spontaneous heating causes many serious problems before, during and after mining. In opencast mines, coal immediately oxidises and catches fire due to the intrinsic characteristics of coal, such as low rank, high moisture, high volatile matter, presence of sulfur in the form of pyrites, low crossing point temperature (CPT) and ignition point temperature (IPT) value and less incubation period. In opencast mines, when the coal benches are left idle for a longer time, heat accumulation takes place in favourable conditions and sometimes leads to fire. The purpose of this paper is to present the different successful case studies regarding the safety management of open pit coal mines from occurrences of spontaneous heating/fire.

Jan 1, 2007