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By M Araos, I Onederra

A novel explosive formulation that substitutes the use of ammonium nitrate (AN) with hydrogen peroxide (HP) as the main oxidising agent has been developed and tested as part of an Australian Coal Industry Research Program (ACARP) project. The main objective was to provide a step-change solution that has the potential to completely eliminate NOx fumes in blasting. The development of this HP/fuel-based explosive started with a comprehensive detonation characterisation program, consisting of unconfined velocity of detonation (VOD) measurements of samples at different diameters, densities and void sensitisation techniques. VOD results showed that the HP/fuel-based explosive mixtures behaved similarly to non-ideal commercial explosives; in that way mixtures could be tailored to achieve specific detonation performance targets. The next stage of testing in this development involved preliminary confined tests to evaluate the rock breakage potential of the HP/fuel-based explosive mixtures. Fully instrumented single-hole tests were conducted in a limestone quarry. Results from these preliminary trials confirmed the rock breakage performance of HP/fuel-based explosive mixtures. The confined VOD measured in one of the tests was 5100 m/s in a 102 mm diameter blasthole at a density of 0.96 g/ml. The corresponding borehole pressure measurement of this HP charge was 2.61 GPa with a detonation temperature of 2921°C. Based on near-field accelerations, both HP and ANFO charges displayed similar attenuation characteristics in the test conditions. Post-blast observations indicated that the breakage performance of the HP mixtures clearly reflected the in-hole detonation performance measurements obtained, confirming the ability of these explosive mixtures to both fragment and effectively displace the rock mass under evaluation. Further research work continues with the future commissioning of a prototype mixing and delivery unit, the successful completion and analysis of data from multiple-hole trials, and further characterisation work associated with product stability, reliability and performance under different geotechnical conditions.CITATION:Onederra, I and Araos, M, 2015. Detonation and breakage performance of a hydrogen peroxide-based explosive formulation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 565–574 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By T Mizuta, H Satoh, M Ogasawara, M Miyata, M Fukuyama

The Miocene Chichibu granitoids associated with the Chichibu skarn deposit are divided into North Body, South Body and Daikoku altered stock. Orebodies of the Chichibu skarn deposit are mainly distributed in the north-western part of the North Body and Daikoku altered stock. The North Body consists of magnetite-series granitoids ranging from tonalite to granodiorite and to monzogranite from the margins to the centre of the intrusion. The South Body consists of tonalite and granodiorite, and most of these rocks are also classified as magnetite-series granitoids. The Daikoku altered stock consists of a quartz diorite porphyry. The SiO2 contents of the granitic rocks of the North Body and South Body range from 61.6 to 70.7 wt per cent. During magmatic differentiation, Cu, As and Zn contents in fresh granitic rocks of the North Body and South Body increase with SiO2 content up to 63 wt per cent SiO2, and then progressively decrease with increasing SiO2 contents as SiO2 exceeds 65 wt per cent. Estimated pressure for the emplacement of the granitoids is about 0.5 kbars. Cathodoluminescence studies on quartz from those granitic rocks show that vapour rich two-phase fluid inclusions tend to occur in the core of quartz crystals, while halite-bearing poly-phase fluid inclusions occur in the margins of quartz crystals. The distribution of fluid inclusions suggests that fluid composition changed from low to high salinities during the growth of magmatic quartz crystals. Texture showing quartz crystals with an oval shape enclosed by radial aggregates of a mixture of fine-grained quartz, plagioclase and K-feldspar composing the groundmass of the monzogranite also suggests a pressure decrease during solidification of North Body. These findings show that high salinity fluids were present during magmatic differentiation and that Fe-Cu-Pb-Zn-Au-Ag skarn mineralisation of the Chichibu deposit was possibly associated with these high salinity fluids. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

The restructuring of the minerals industry has created new challenges for the design and delivery of professional development, and difficult decisions for potential participants. New technologies offer some new methods of delivery, but fall short in providing all of the benefits of face-to-face participation. This paper is intended to be a catalyst for discussion of the issues involved in delivery and participation in cost-effective, relevant and timely professional development.

Jan 1, 2000

Back at the turn of the century, the Eastern Goldfields region of Western Australia was entering its moment of glory. Development was going ahead at a cracking pace and miles of shaft and drives were being opened up. On the Great Boulder Gold mine alone, records show that there were two kilometres of shaft and 30 kilometres of -driving completed in the first five years of operation.Similar statistics were being achieved by hundreds of other mines on the Golden Mile and in other districts in WA.

Jan 1, 1993

By Martin JD, McNicol JH

The electrolytic zinc plant at Port Pirie South Australia, was designed and constructed to treat zinc oxide fume recovered by treatment of lead blast furnace slag in two fuming furnaces, The plant was commissioned in late 1967. The equipment installed and the oper- ating procedures adopted,'are described in some detail.

Jan 1, 1975

The chief use of manganese ore is in the production of ferromanganese alloys for steelmaking. Manganese ores generally occur in tropical areas, which influences the type of treatment required. Present methods of treatment are relatively unsophist- icated but demands by customers for tighter specifications will necessitate the installation of gravity concentrator at many mines At present only limited tonnages of minus j in. product can be sold hence future development will centre around methods of producing an agglomerate satisfactory to the smelter.

Jan 1, 1969

This paper provides an overview of current and future mine developments in the major island nations Indonesia, Papua New Guinea (PNG), New Zealand, and Fiji, and the French territory of New Caledonia. Many of the other 11 small island nations in the region, such as Vanuatu, Pulau and the Solomons have been the subject of considerable exploration orientated towards gold in the past few years but without any deposit found with confirmed economic viability.

Jan 1, 1990

Synthetic hollow microspheres have demonstrated reliable sensitization and detonation characteristics in industrial explosives for almost two decades. During that time, water gel formulations and use conditions have changed. The introduction of emulsion explosives has also dictated technical improvements in microsphere sensitizers. In contrast to microspheres, gassing or other sensitizing techniques often cannot satisfy the manufacturing and blasting characteristics required of today's explosives. This paper discusses the sensitizing properties of microspheres, formulating guidelines and quality considerations. Packaging, sampling, transfer, metering, mixing and pumping information is also provided.

Jan 1, 1990

By Chen B

In recent years great efforts have been made in the optimisation of ball mill operation. This paper describes a methodology developed for modelling and optimising the steady-state grinding process. Thirteen basic similarity numbers of the process are derived. Based on these similarity numbers, we build a group of mathematical models which give a full description of the relation between dependent and independent variables. The parameter estimation and multi-objective optimisation of the grinding process have been done using these models, and validated with experiments in a continuous laboratory-scale ball mill.

Jan 1, 1993

The exercise of preparing this paper has been both enjoyable and thought provoking.In carrying out the research I have spoken and written to many people. Without exception they have been eager to help, all have spoken of the high regard in which they held Dr Williams, not only as a metallurgist but also as a person.Review of GK's life reveals an enormous impact on the industry in which he worked and the people with whom he associated. Consideration of this impact inevitably leads to the question "what can we learn from his life and the way he went about his work?"

Jan 1, 1985

The topic for my address is Sharemarket Floats - Issues for Expert Valuers. I've decided to focus on three areas where current practice in the preparation of prospectus valuation reports for resource companies might be improved. My central theme is that the valuer for a float should augment the usual assessments of the value of the company or its assets, with some input on the way the share market might value the company's shares when they are listed. I will then look at the valuer's role in relation to vendor consideration, last I will look at his role in providing investors with some input on the risk dimensions of the new company.

Jan 1, 1989

Construction of Western Mining Corporation's nickel refinery at Kwinana, Western Australia, commenced in July, 1968. Production of 15,000 tons per annum of refined nickel metal will commence early in 1970, The plant will also produce approx- imately 150,000 tons of ammonium sulphate0 The ammonia leach process which was developed by Sherritt Gordon Mines Ltd., and has been in operation at their plant at Fort Saskatchewan, Alberta, Canada, for the past 15 years, will be used at Kwinana. The refinery will cost approximately 435 million, and will employ upwards of 250 people.

Jan 1, 1969

Mine scheduling is a process which represents what happens in a mine over time. An optimised plan involves selecting the best workable plan which meets a stated objective. This paper discusses some of the theory and philosophy behind mine scheduling and explains how scheduling is a step in the total iterative mine planning process. Several schedules may be necessary before arriving at a mine plan which can be considered optimal. A description of broadbrush and detailed scheduling is given and the features of computer assisted scheduling are also described. The use of mathematical modelling techniques in conjunction with scheduling to optimise the mine plan is explained. The need to incorporate these techniques to optimise the whole mining system rather than only a part, is emphasised.

Jan 1, 1991

Currently there are in excess of 200 companies listed on the New Zealand Stock Exchange and the total market value of all the listed shares amounts to $4.6 billion. The number of listed mining companies stands at nine and with a market value of $35 million accounts for less than one per cent of the total market capitalisation. In comparison, the Australian mining and energy sectors account for nearly 50 per cent of the total market capitalisation, which currently exceeds A$41 billion. Surprisingly the share markets in both countries were primarily founded on the discoveries of minerals last century.

Jan 1, 1982

The article presents methods of testing and recording of water amount pumped out in surface mining. The authors describe necessary recommendations how to carry out measurements so that one can separate the surface run-off and groundwater inflow from the total inflow. They demonstrate methods of evaluation of these kinds of inflow in open pits when water amount testing is carried out every eight and 24 hours as well as simple methods when only monthly records of water are available. The authors also describe procedures for evaluating the water inflow when an open pit is dewatered gravitationally and measurements in discharge channels are irregularly carried out.

Jan 1, 2003

By Wenya X, Bingchen C

About 60 per cent of magnesite ores of Haicheng Magnesium Mine, due to their low grade, are not currently commercially exploitable. In this paper, the flotabilities of the main component minerals of the ores were studied in detail with ether amine as collector. Based on. these, a new technique of reverse-direct flotation with single etheramine as collector for the beneficiation of the ores was developed. It gave highly satisfactory results. On the basis of the calculation by means of CNDO/2 method, of the studies of the solution chemistry of magnesite and of the adsorption tests and Zeta-potential measurements, the key mechanism in the new technique about activating effect of Ca2+ on the flotation of magnesite was suggested.

Jan 1, 1993

By Angove JE, Johnson GD

Sulphide concentrates are produced in a wide range of mineral processing operations. In the case of base metals they are further treated by smelting and/or hydrometallurgical techniques. In the case of refractory gold ores, sulphide concentrates containing gold are roasted or oxidised by various hydrometallurgical processes. This paper discusses the development of the Activox(R) Process which can provide an alternative method for treating sulphide concentrates. This process consists of fine or ultra-fine milling, followed by mild pressure oxidation to produce solutions of base metals or to liberate refractory gold. Base metal solutions (eg of nickel and cobalt) can be further processed by solvent extraction and electrowinning, while refractory gold can be recovered by cyanidation. The economics of the Activox(R) Process are often better than alternative oxidation techniques.

Jan 1, 1993

All too often engineers and project teams focus on building æthingsÆ, and they tend to see the key goals as meeting the project cost and schedule targets. We frequently compound the problem by unknowingly rewarding engineers for building bigger, more complex, more æbullet proofÆ and hence more costly æthingsÆ. Unfortunately the end result all too often ends up being a disappointment in terms of business performance. The term æshareholder valueÆ may never have entered the discussions during the development process. This paper deals with the fundamental issues, which tend to pre-dispose new developments to success or to failure. As project management concepts are not particularly complex, it begs the question why is it that the failure rate of new developments is so high? It is argued that the answer lies more in people behaviour issues than in project management tools and processes.

Jan 1, 2002

Explosives have been an important tool for unlocking minearl wealth from the earth's crust for several countries. In'the past, innovation in explosives technology, spurred on by industry needs has assisted the Mining Industry to improve productivity and reduce costs. A symbolic relationship exists between Explosives and Mining. Australia has vast mineral wealth. Our Mining Industry is of major importance to the Economy., The value of mineral produc- tion in 1987 was $25 million or 10% of GDP. Australian Mining is a business depending on international markets. The Mining Industry is our leading export earner, generating 44% of all export income. 60% of mineral production is exported. About half of these minerals are extracted using explosives. Explosives rank as one of the top three consumable expenditures for a mine. For example: A major open-cut iron or coal mine can spend $6 million dollar per annum on explosives.

Jan 1, 1988

By Warren R. P

When the original Mount Gunson joint venture, between CSR and United Uranium ceased operations in December 1971, an intensive ex- ploration campaign was launched to prospect for more ore in the Mount Gunson region. This campaign resulted in the discovery of the Cattle Grid deposit. A comprehensive sampling programme proved the existence of 4.6 million tonnes of ore, at a mean grade of 2.4% Cu, calculated at a 1.0% Cu cut-off. The planning and development programme that followed this discovery included not only the mining and metallurgical aspects of the exploration of the deposit, but also the en- vironmental aspects. Preliminary work included data collection with respect to meteorology, soil types, and existing flora and fauna.

Jan 1, 1976