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By F. Qi, T. Frišcic, C. Mottillo

"One of the principal goals of modern industry is to minimize the environmental impact and increase the materials- and energy-efficiency of transforming raw materials into valuable products. This paper will highlight our latest laboratory-scale research in low-energy, low-solvent reactivity of metal oxides and their conversion into popular metal-organic frameworks (MOFs), zeolitic imidazolate frameworks (e.g. Basolite® Z1200 component ZIF-8), and metallodrugs (e.g. bismuth subsalicylate, active component of Pepto-Bismol®). Mechanochemical ion- and liquid-assisted grinding (ILAG) and ""accelerated aging"" techniques will be presented, along with novel low-energy and solvent-free approaches, inspired by geological weathering processes, for converting metal oxides into metal-organic materials. INTRODUCTIONThe development of environmentally-friendly processes, which would in the same time be more materials- and energy-efficient than the existing ones, is one of the central concerns of modern chemical research. In that sense, the focus of the chemist has been mainly on the preparation of carbon-based organic molecules and adaptation of traditional organic synthesis to the recently delineated ideals of Green Chemistry. However, there is a growing realization within the chemistry community that significant energy, materials, and ecology-related benefits can be achieved and, indeed, targeted in the transformations of materials that are typically associated with inorganic chemistry and minerals processing. The principal aim of this highlight contribution is to illustrate how, through the use of approaches associated with solventfree chemistry and mechanochemistry (James et al., 2012), one can develop a clean and efficient system of chemical and materials transformations involving oxide precursors that normally belong to the realm of inorganic chemistry and mineral processing. In particular, this contribution will provide an overview of the recently developed mechanochemical and solvent-free reactivity of metal oxides towards small organic molecules. These mechanochemical reactions, including the methods of liquid-assisted grinding (LAG, Frišcic & Jones, 2009) and ion- and liquid-assisted grinding (ILAG, Frišcic, 2010), have so far provided a radically different means to construct advanced metal-organic materials (e.g. porous metal-organic frameworks, [MOFs] or metallodrugs) by rehabilitating metal oxides as precursors, eliminating the use of bulk organic solvents, and avoiding the use of high temperatures."

Jan 1, 2012

By Michel Aubertin

Les digues de retenue de résidus miniers devraient être conçues de façon à supporter les charges les plus défavorables qui puissent être anticipées. Les nombreux incidents survenus au cours des dernières années à travers le monde montrent toutefois que la stabilité de ces ouvrages reste encore problématique. Les cas de rupture les plus courants sont reliés aux glissements le long des pentes, à la liquéfaction des rejets, au débordement des bassins, ainsi qu?à l'érosion régressive et de surface. Après avoir rappelé la nature et l?importance des certains incidents récents, l?origine de ces problèmes est brièvement présentée. On aborde ensuite le lien entre les critères à adopter pour la conception des ouvrages et les risques associés à leur rupture. De nouvelles avenues pour aider à contrôler certains problèmes sont enfin discutées, en mettant l?emphase sur la codisposition des roches stériles dans le parc à résidus miniers.

Nov 1, 2002

By S. L. Aaroe

"TYRETHANE PRODUCTSTyrethane® is the family brand name which has been adopted by The W. S. Tyler Company of Canada, Limited to identify its polyurethane products. Since we have been manufacturing Woven Wire Cloth for over one hundred years and have been the innovator for most of the product improvements and developments of that industry, it is only natural that our first and primary efforts involve the use of Tyrethane® as a screening medium. The product is ideal for application in the mining industry and other operations where the rate of wear on existing media is exceptionally high.In the event that you have already had some experience with polyurethane it should be poirted cut that there are many grades of the material. The polyurethane used in Tyrethane® Products will be compounded in a variety of chemistries and different heat treatments will be used to develop best mechanical properties to handle specific applications. However Tyrethane® will not be a ""cure all"" but when it is properly applied as a screening medium it will assist by lowering the unit cost for screened materials.Prior to an explanation of the advantages of Tyrethane® let's review the conventional screening media whose applications may be considered as good candidates for replacement by Tyrethane®.1.,Woven Wire Cloth.2.,Perforated metal screens.3.,Rubber faced perforated metal screens.4.,Perforated rubber screens.5.,Cast steel screen segments and weldiments.6.,Profile wire.In most cases a Tyrethane® section is designed for a one for one replacement of the material now being used. It is rarely necessary to modify the screening equipment to enable you to install the Tyrethane® Product although it may be desirable to take some steps to improve the service life of hold down components such as Clamping Strips or Tension Members. Those parts can be encapsulated in polyurethane if necessary.To fabricate the Tyrethane® section we have three basic building blocks. They are: (1) Small molded segments having square or slotted openings, (2) Reinforcing material and (3) the raw liquid polyurethane."

Jan 1, 1976

By Owen Matthews

Introduction For the past year and a half, the mill of Cochenour Willans Gold Mines, Limited, McKenzie Island, Ontario has been roasting arsenopyrite-gold concentrates, prior to cyanidation, by means of a roaster employing techniques that are new and novel. The roaster is known as the Dorrco 'fluo-solids reactor', and the technique as 'fluidization'. The reactor has demonstrated its ability to roast a flotation concentrate containing arsenopyrite, pyrite, stibnite, small quantities of other sulphides, and some lime silicates and carbonates, yielding a calcine consisting mainly of porous iron oxide, plus the gold values. This calcine is readily amenable to cyanidation. Bulk shipments of concentrates to a distant custom smelter, as practised prior to this installation, has thus been eliminated, with appreciable savings in smelting charges, freight costs, and interest losses during shipment and smelting. This is the pioneer installation of fluo-solids roasting at a Canadian mill and up to the present performance results have not been published. It is the purpose of this paper to present the information now available for the benefit of other millmen who may be confronted with identical or similar problems to those encountered and solved at Cochenour Willans.

Jan 1, 1949

By T. Liu, C. Shi, T. Fu, M. Zhong

Water inrush in coal mines is induced by the imbalance of the groundwater flow field and the engineering geo-mechanics field. Therefore, to prevent water inrush it is important to predict the critical hydraulic pressure of water inrush in coal seam floors. This paper will investigate a method for conducting theoretical forecasting of the critical hydraulic pressure of water inrush in coal seam floors by adopting the combination method of a genetic algorithm-neural network. First, the topology structure of a neural network (NN) based on genetic algorithms (GA) will be determined and then the critical pressure of water inrush in a coal seam floor using the chosen NN will be predicted. Finally, theoretical forecasting results will be compared with actual measurement results to determine the feasibility and applicability of this method.

Jan 1, 2008

By Andrew R. Marchbank

The application of biologically assisted methods for metal extraction in the mining industry has a long history, but development of modern techniques has been relatively slow. There is, however, a resurgence of interest in the industry with the recent development of methods to successfully treat base metals concentrates. Two major pilot plant programs for treatment of chalcopyrite concentrates have been initiated in the past year and results from one are beginning to be released. This paper provides an overview of methods that have been applied in the past; from the earliest deliberate applications of the technology, through the copper and uranium heap and dump leach applications, the more highly engineered agitated tank leach gold applications and the developments currently taking place in the industry.

May 1, 2002

By J. P. Dick

THIS paper is a description of the milling practice and metallurgy at the Moneta Porcupine mine, Timmins, Ontario. The results obtained with an all-cyanide circuit and later with flotation followed by cyanidation are described. The ?investigation which prompted the various changes in milling practice have also been dealt with. Moneta ore is possibly the most refractory now being milled in the Porcupine district. This is due to the ultra fine state in which the gold occurs and to its intimate association with pyrite. No doubt there is ore of similar characteristics on the neighbouring properties but it probably forms only a small portion of the tonnage being mined, whereas at Moneta the bulk of the ore requires an extremely fine grind to liberate the gold. The fineness to which an ore can be ground economically has gone far beyond what was thought to be the limit only a few years ago. Formerly, a set of standard screens was all that was required to measure the fineness to which an ore was ground. At present, the Haultain infrasizer is practically indispensable, and the nominal micron has become a familiar unit of measurement to all those dealing with the problems of fine grinding.

Jan 1, 1941

By H. Ewaschuk

"INTRODUCTIONRio Algom's Stanleigh Mill in Elliot Lake began production in June of 1983. The highly instrumented mill treats uranium ore at an average rate of 3900 metric tons per day. To help ensure a good start-up and low operating costs, an extensive training program was undertaken prior to and during start-up. This presentation describes how an unconventional operating crew were combined to form an operating unit with a high efficiency in terms of production and labour utilization. I would like to point out at the outset that the operating philosophy, and the role of the supervisors and the operators as set up at Stanleigh is not unique. Indeed, I have seen the same results at a couple of small plants where efficiency meant survival. However, these situations appeared to be the exception, and it was not readily apparent how similar results could be obtained in a larger plant. A factor that existed at the time was low labour turnover. As in most parts of Canada, jobs were easy to get in the Elliot Lake camp in the late 1970's. This, and other factors, contributed to an unusually high labour turnover. This changed dramatically in the early 1980's. Indeed, Rio's two other operating mills, Quirke and Panel reduced crew sizes at this time to reduce operating costs. As a result all of Stanleigh's operators came from Quirke and Panel with experience varying from 4 to 7 years. The experience that operators had was obviously of benefit and served to reduce the scope of the training program from what would have been required with inexperienced personnel."

Jan 1, 1985

By N. W. Bliss

"Bauxite has been the almost universal ore of aluminum for about 100 years, with most of the world's reserves oc¬curring in the developing countries. As a result of fiscal and political activities prompted in part by the energy crisis, the formation of the IBA combined with increasing freight and labour costs, these reserves are no longer as competitive or as secure as they once were. This has given fresh impetus to the development of processes for alumina production that utilize raw material other than bauxite. Canada has no bauxite and it is prudent to look for alter¬native raw materials within our own boundaries suitable for one of these processes.Of the three igneous rocks that have been used as a source of alumina, only anorthosite is considered as a potential source in Canada. The Al content would be extracted by a sinter process, which currently requires a raw material with a. minimum of 28% Al2O2. Thus, about 4 tons of anorthosite and 10 to 12 tons of limestone are needed to produce one ton of alumina. There are two petrologically distinct types of anorthosite, one containing the plagioclase andesine-labradorite and around 26% Al2O3, and the other containing upwards of 30% Al2O3, in by¬townite-anorthite; for our purposes they may be con¬sidered as low- and high-alumina anorthosite respectively. The high-alumina anorthosites are somewhat rare; the low-alumina anorthosites are much more common, partic¬ularly in Eastern Canada. Geologically speaking, there is no shortage of anorthosite in Canada. The reserves are im¬mense, although their low Al2O3 content coupled with con¬siderations of location, access and proximity to limestone could be constraints to their development. Fly ash from coal-fired thermal power stations and nepheline syenite can also be used in a sinter process, but neither is likely to be utilized in Canada in the immediate future.The H+ process utilizes an acid attack to leach Al from a raw material with at least 20% Al2O3. One of the best raw materials is kaolinite-bearing clay; not only is it high in Al, but most of it can be extracted. With the possible exception of the Whitemud clay in Saskatchewan, Canada is apparently deficient in clays with sufficient reserves to support an alumina plant utilizing the H+ process. Low-alumina clays with illite and montmorillonite may also prove to be a suitable raw material if advantageously sited with respect to industrial centers. The average shale con¬tains only 15% Al2O33, much of which may be contained in minerals, such as feldspar, not amenable to acid leaching. If shale is used as a source of alumina, it will be because it contains some other valuable commodity, such as oil or uranium, the extraction of which leaves the spent shale upgraded in extractable Al2O3 and lowers the over-all costs to a point where it is economic, Thus, rejects from coal washing plants are most commonly considered as a source of alumina; they are already mined, are available in large and ever increasing amounts, and may contain significant amounts of combustible material which upgrades the Al2O3, content of the resulting ash. Coal rejects from existing and developing coalfields in Alberta and British Columbia are a possible source of raw material, but present data indicate they may contain insufficient Al2O3."

Jan 1, 1976

By Alfred Annor

Deep mining requires innovative approaches in ground control technology and the search for new ground support materials including backfill. There is a need to look at mine waste materials that may be available in deep mines to assess their suitability for use as composite backfill. Composite materials are widely used in all areas of engineering because of their unique and often superior structural properties compared to those of the singular constituent materials. Over the past few years, there has been a growing interest towards the investigation and use of various types of composite backfill materials as special applications fill in mines. A research project is being conducted at CANMET- Mining and Mineral Sciences Laboratories, Natural Resources Canada, to investigate the properties of potential ground support materials for use in deep mines. As part of this investigation, composite backfill materials were prepared by combining waste rock aggregates and mill tailings in various ratios, to determine their optimal mix proportions for strength development. A few cemented rockfill and straight tailings paste backfill samples were also prepared and were used as controls for the study. Two sample sizes were used for the investigation in order to evaluate the scale effects on the material behaviour. A set of samples were cured at 44 EC to simulate the anticipated temperature conditions in deep mines. A second set of samples were cured at 23 EC to provide engineering reference data. The test results show that compared to either the cemented rockfill or the straight tailings pastefill material, the composite backfill samples were the strongest and stiffest of all the test materials investigated in this study. The composite backfill samples also produced the lowest void ratio and porosity values compared to the cemented rockfill and the straight tailings backfill material. This paper will present the results of the laboratory investigations to date. It will also outline the on-going work at CANMET - Mining and Mineral Sciences Laboratories to further assess the ground support potential and viability of using composite fills in deep mines.

May 1, 2003

By L. Boyd, A. Charland, G. Potts, D. Fragomeni, N. O. Lotter

"The Raglan orebody and concentrator has been the subject of study in Process Mineralogy at Falconbridge since 1998. (Lotter and Tuzun, 1998) The orebody is classified into three distinct textural groups, or end members. These are referred to as disseminated, net-textured, and Massive Sulphides, and differ in terms of mineral grain size, nickel grade, hardness, and mineral association. In this paper, it will be shown that the sampling and characterisation of each end member on an individual basis develops a higher-level understanding of the processing requirements and behaviour of the mixture of ore as presented to the mill.The end members have been used in robust prediction of recovery at various grind size p80 from laboratory scale High Confidence Flotation Tests. Weighted mean mixtures of the end members have been mathematically combined to determine impact of textural distribution on metallurgical performance as a function of grind size.The ore end members also vary in hardness and breakage mechanism and have been used to model throughput capability for existing, optimized and retrofit grinding circuits. This modeling has provided a range of expected throughputs as the relative proportions of each end member varies.Finally, the differing grinding requirement per end member has led to the development of grinding and flotation strategy that increases rougher flotation recovery and provides flowsheet options for a concentrator expansion. This leads to further understanding of the plant performance as a function of ore mixture."

Jan 1, 2005

By Michael J. Kelly

IAMGOLD?s Westwood project is the site for the largest, by volume, bored vent raise in North America. When completed, it will be the fifth largest bored worldwide in a single pass. This paper will review the highest capacity raise drill system ever built (Redbore 100); as well as the technical difficulties in a single pass boring a 2,773 ft x 20 ft to 22 ft diameter raise. The difficult ground conditions and associated problems will be reviewed, as well as the solutions to overcome them. Use of the RVDS drilling tool to achieve .04% accuracy (14.5?) and the Geotube® water filtration system will also be covered.

Oct 1, 2010

By Pablo González, Rodolfo Espinosa, Jose-Luis Noyola, Sergio Cossio

"Minera Penmont, at La Herradura, is a joint venture between Industrias Peñoles, S.A. de C.V., and Newmont Mining Corporation. The mine is located in the northern Mexican state of Sonora. La Herradura consists of an open pit mine with two-stage crushing and heap leaching facility, the gold is recovered from the pregnant solution using the Merrill-Crowe process; production began in July 1998. La Herradura produces about 130,000 gold ounces per year, and treatment capacity is 22,000 tonnes/day. Ore mineralization occurs in a shear zone with quartz and native gold. Gold distribution is quite heterogeneous due to the coarse visible gold, in some coarser particles ranging from 100 to 600 microns.Sampling and assaying protocols where established during exploration and prior to starting up operations, based on nomographs developed from early heterogeneity tests. But, as the coarse gold problem became noticeable, it was necessary to develop new sampling protocols to have an acceptable relative standard deviation to control the fundamental error within ± 15%.An experimental program was developed and conducted on a selected ore block made of 195 blastholes; regular ore grade control procedures were applied to both sets of data to evaluate the difference in results between the protocol established prior to starting up operations (“existing”) and the new protocol (“leaching”). In the “existing” protocol, subsampling is done through riffle splitters, and coning and quartering. Fire assaying is used to estimate the gold content, on a 50 g sample. In the “leaching” protocol a 12,000 g sample was bottle rolled cyanide leached, and the leach residue was assayed on a 50 g sample using fire assaying, and a weighted average total gold content was calculated. Currently, a new alternative method is being evaluated, where sub-sampling is done using rotary splitters, and fire assay on a 50 g sample; in this “rotary sampling” protocol and for comparison purposes, gold assays were also repeated using the “leaching” protocol.Test results were compared in three groups < 0.30 g/t (below cut-off), 0.30 to 0.8 g/t, and >0.8 g/t. Overall. Results show that the protocol established prior to starting up operations underestimates the gold assays. Detailed technical results, alternative options, and their implications are discussed in the paper."

Jan 1, 2003

By A. D. Yell

"Recovery of water is always a major factor in the Beneficiation process. As Preparation Plants become larger the recovery of water for reuse, is a critical cost consideration. Tema Isenmann Inc in conjunction with our sister Company Multotec Manufacturing, has over the years, developed numerous different Screen Panels, Sieve Bends and Static Screens for dewatering. This paper will focus on a new innovation, the TeePee™ Panel which has double the open area of conventional Screen Panels. This results in efficient dewatering (reduced filter cake moistures) which allows for the use of smaller Vibrating Screens or increased capacity on existing Vibrating Screens. A major factor in the efficiency of any Screen Panel, including TeePee™ Panels, is the performance of the Vibrating Screen. If the Vibrating Screen does not have the required gravitational force or screen area to drain it will not dewater efficiently. Therefore a holistic approach has to be taken where the Vibrating Screen needs to operate at an optimal level, in conjunction with the correct Screen Panels, to achieve efficient dewatering. Key performance areas for Vibrating Screens are therefore detailed in this paper with an emphasis on important dewatering criteria. Case studies of different dewatering applications are included, where the use of TeePee™ Panels, has shown a marked improvement over conventional flat Screen Panels in reduction of filter cake moisture content.INTRODUCTION Dewatering can be done in a number of different ways and is largely dependent on the ore type, the particle size distribution and to what extent one needs to dewater will determine the method used. There are a number of different dewatering methods that can be used for particles above 200 micron, including Screen Bowl Centrifuges, Filter Presses, Static Screens, Static Sieve Bends and Vibrating Screens. This paper will focus primarily on Vibrating Dewatering Screens showing improved drainage and a reduction in the filter cake moisture content. KEY PERFORMANCE CRITERIAL FOR VIBRATING DEWATERING SCREENS For clarification the critical key performance criteria for Vibrating Dewatering Screens are set out in this paper. Dewatering Screens Vibrating Dewatering Screens are normally linear motion, either horizontal or inclined at 5 to 7° upwards with a vertical or back sloped plate at 45° to the rest of the screen deck. The back plate will often have screen panels in them to increase the dewatering capability, as shown in Figure 2 below."

Jan 1, 2017

By N. I. Basuki, E. T. C. Spooner

"The Bongara area, northern Peru, contains Zn-Pb mineralization with characteristics typical of Mississippi Valley-type (MVT) systems. The northwest-southeast-trending late Triassic-Jurassic car¬bonate host rocks of the Pucará Group were locally replaced by early (D1) and late (D2) dolomite. Fluid inclusion microthermometric data from dolomite and sphalerite are typical of MVT ore fluids (78° to 187°C; ~15-23 wt.% CaCl2 equivalent), and do not show apparent covariation between temperature and salinity.Homogenization temperature data from D1 and D2 dolomite show a decrease from northern (mean Th = 138°C) to central (mean Th = 126°C) to southern areas (mean Th = 102°C), suggesting fluid flow from north to south. Assuming a geothermal gradient of ~30°C/km and an average surface temperature of ~20°C, the lower temperature limits might approximate the ambient host-rock temperatures, whereas the upper temperature limits may represent minimum temperatures of a deeper aquifer, probably at a maximum depth of ~6000 m. The lower temperature limits are also similar to the estimated temperatures if dolomitization and mineralization took place in the Late Cretaceous at ~2000-3000 m depth, probably during the formation of the Peruvian fold and thrust belt near the present day Peru-Ecuador border.Fluid inclusion data show that the fluids in each studied location had relatively uniform temperatures and salinities during dolomitization and mineralization. A significant salinity drop and a slight temperature decrease are observed during late calcite precipitation, suggesting mixing of brines with dilute, cooler fluids."

Jan 1, 2009

By Glenn Norris, Tyler Buckingham

"Gold recovery gains in the order of one to two percent have been realized in 2009 due to changes in the operation of the grinding circuits at Barrick Gold Corporation’s Hemlo - Williams Mill. The initiative known as “split milling” involves milling low grade open pit ore in one grinding circuit and higher grade underground ore in the other grinding circuit under different conditions.The philosophy of split milling involves processing higher grade underground ore at a lower throughput rate and a finer grind while milling lower grade open pit ore at a higher throughput rate and a coarser grind. Bench scale tests showed that the recovery relationship for underground ore sources was much more grind sensitive than that of open pit ore. This relationship proved to hold in the plant. The gold recovery gain due to finer grinding of the higher grade ore is much greater than the recovery loss due to coarser grinding on the lower grade ore. Since the majority of gold is being recovered at a higher rate, this results in higher overall plant gold recovery when compared to the traditional operation philosophy of blending the ore sources.The challenges for achieving the maximum benefits of split milling were two fold; the need to increase throughput on the open pit ore milling circuit and a means of grinding finer on the underground circuit. The former was met with an increase in SAG (Semi-Autogenous Grinding) mill ball charge, a basic “drill to mill” blasting campaign and changes to the primary gyratory crusher. The latter was met with a reduced SAG mill ball charge and a higher milling density. The resulting benefits in additional gold recovered are in the order of $3-5 million per annum.INTRODUCTIONThe Williams Mill processes ore from three different ore sources, the David Bell Mine (DB), the Williams Underground Mine (WUG) and the Williams Open Pit (OP). All three ore sources are located within the Hemlo camp in Northwestern Ontario adjacent to the Trans-Canada Highway. The Williams Mill was built in the mid 1980’s at which time it was designed to process 3,000 dry metric tonnes per day through a 22’ SAG mill in series with a 16’ ball mill. In 1988 a Mill expansion doubled the mill capacity by adding a second identical grinding circuit. A photo of the current grinding circuit can be seen in Figure 1. Today the Williams Mill processes an average of 8,000 tonnes per day of which approximately 60% is from the Williams Open Pit."

Jan 1, 2010

By D. E. Deegan, P. M. Keeley, N. A. Rowson, T. Stachowski

An investigation into the use of Tetronics International’s thermal plasma technology based pyrometallurgical smelting process for the recovery of both platinum and rhenium was conducted. 1000 kg of Pt-Re catalysts containing 0.36 wt% Pt and 0.21 wt% Re was blended with fluxing agents, reducing agents and an iron based collector metal precursor and then fed into a plasma furnace over five individual trials at Tetronics International’s facility in Swindon, UK. Both platinum and rhenium partitioned to an iron rich collector metal phase in the furnace, which formed in-situ and accumulated beneath a less dense slag phase, derived from the inorganic substrate of the catalyst, and was easily separable. The levels of Pt and Re concentration achieved in the iron collector made it suitable for subsequent final refining. Technical recovery efficiencies of =98% for both platinum and rhenium were achieved and the concentrations of the metals in the recovered metal bullion were 2.23 wt% Pt and 1.35 wt% Re.

Jan 1, 2015

By C. H. Lee, K. Adham, D. Lemieux, J. P. Mai, A. M. S. Hussein, S. Francey

Copper concentrates contain an increasing amount of arsenic, as the older sources of cleaner ores are depleted. At the same time, the market-determined price penalties on arsenic rich concentrates are rising due to limited arsenic treatment capacity at smelters and increasingly stringent environmental emissions limits, necessitating arsenic removal from the copper concentrates. Heating the concentrate to about 700°C can remove significant amounts of arsenic (as elemental and/or sulfide); however, it is important to achieve that removal economically and with due consideration to post-roasting arsenic (toxic waste) treatment. A comparison is made among different roasting options (kilns, multi-hearths and fluid beds) to qualify their potential application to arsenic roasting of copper concentrates. Both direct and indirect methods of heating as well as inert, air and oxygen atmosphere options are considered. Technology comparisons are made with respect to the roaster’s operation, its off-gas treatment and arsenic stabilization. INTRODUCTION In the last twenty years, the arsenic content in globally produced copper concentrates have risen steadily due to the depletion of cleaner ores and the increase in complex concentrate production. Smelter contracts typically limit arsenic to less than 0.5wt%, with a penalty paid per unit of additional arsenic and other contaminants such as antimony. While penalties can vary, they can be on the order of $70/dry metric tonne of concentrate per 1% of arsenic. Strategies used by miners to avoid the price penalties have been to blend clean and complex concentrates, and to remove arsenic from complex concentrates to achieve smelter limits. Arsenic can be removed from copper concentrates by the heat-induced decomposition of the predominant enargite mineral (Cu3AsS4) at ~700°C. Roasting at such elevated temperature is a commercially proven option, but still suffers from process, cost and environmental challenges. After roasting, the released arsenic sulfide fumes can be separated from most of the entrained concentrate dust in cyclones. Then, the As2S3 laden off-gas can be oxidized to generate a still volatile oxide (As2O3), which can be further separated from the residual concentrate dust in a hot electrostatic separator. Next, the off-gas can be cooled with air or water, to either deposit the arsenic oxide in a dry or dissolved state. Dissolved arsenic acid can be oxidized to As(V) and reacted with iron to yield a stabilized ferrihydrite precipitate or scorodite that can be safely disposed. In the case of dry arsenic trioxide, it can be mixed with reactants (e.g. iron) and fluxes before thermal stabilization in a glass matrix, thus eliminating the need for costly oxidation.

Jan 1, 2019

By Y. Guglielmi, C. Gout, P. Henry, P. Dick

The key questions about fault reactivation in shales concern the potential enhanced fluid displacement through a previously low-permeability aseismic shale formation. Here we selected a critically-stressed fault cross-cutting the underground research facility of Tournemire (France) which is located in Toarcian shales. Several inclined boreholes were drilled across the 8.5 m thick fault zone characterized by a fractured damage zone (FDZ) and a central 2.4 m thick complex core (FC) made of multiple shear bands with gouge intercalated with highly fractured lenses. The fault was pressurized using a straddle packer system defining a 2.4m long injection chamber normal to the fault surface. Three fault zone intervals were tested, two in the fault damage zone and one in the fault core. A three-dimensional displacement sensor set in the chamber allowed continuous synchronous coupled monitoring of fault movements, injection pressure and flow rate. An anticlockwise 0.22-to-0.05 mm fault slip was captured associated with a 10-to-100 hydraulic aperture increase of the fault. Preliminary analyses of the experiments show that leakage in the fault zone is controlled by strength and stress magnitude contrasts between the fault core and the fault damage zone. Fault damage zone discontinuities display a much higher peak static friction angle than the fault core shear zones, respectively of 34 and 22° that could be related to complex interactions between healing and sealing processes. Fault core leakage is much more dependent on strain than on effective stress variations. Discontinuous, pulse-like leakage, develops following complex failure processes that may simultaneously take place in the gouge zones and along the large pre-existing discontinuities. Such results may be of importance in evaluating fault seal integrity in oil and gas exploration, production or CO2 storage or underground excavations monitoring.

Jan 1, 2015

By Chuck Edwards

"Cameco operates the high-grade McArthur River uranium mine in northern Saskatchewan, and is constructing the high-grade Cigar Lake uranium mine. Cameco has studied the concept of underground milling of high-grade uranium ore. Compared to conventional milling on surface, the underground milling scheme appears to offer significant cost savings and a lower environmental impact. This paper describes the underground milling scheme, presents process flowsheets and plant layouts, and provides an assessment of potential benefits from underground milling.INTRODUCTIONCameco CorporationCameco is the world’s largest uranium producer, with three operations in Saskatchewan (Rabbit Lake mine/mill, McArthur River mine, and Key Lake mill), two in the United States (Crow Butte and Smith/Highland ISL operations) and two new mines being developed in Canada (Cigar Lake project) and Kazakhstan (Inkai project). Cameco provides uranium fuel refining and conversion services at its Blind River and Port Hope facilities in Ontario. Cameco is part owner (31.6%) of Bruce Power that leases eight nuclear power plants located in southern Ontario. Cameco is the majority shareholder in Centerra Gold Inc., which operates gold mines in the Kyrgyz Republic and in Mongolia.Global Uranium Production RequirementsCentral to Cameco’s view of future uranium supply requirements is the belief that the world is experiencing a nuclear renaissance. This belief is supported by a number of developments, including:•,?Countries representing half the world’s population are now constructing new nuclear power plants. Many countries without nuclear power have begun to plan for it, seeking reliability, clean air and energy independence.•,?Accelerated growth for this industry is also becoming much more likely. In Asia, primarily in China and India, 92 reactors are under construction, on order or planned to help meet rapidly expanding economic needs. Other Asian countries, such as Vietnam and Indonesia, with large populations and rapidly growing economies, are also expected to follow.•,?In the United States the “Energy Policy Act of 2005”, the first energy legislation introduced in over a decade, was signed. This legislation includes provisions recognizing, for the first time at a national level, the clean air contribution of nuclear energy and its critical role in meeting energy security. Upon signing this landmark legislation President Bush stated, “We will start building nuclear power plants by the end of this decade.”"

Jan 1, 2007