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By Stephen R. Grano, Jon Glatthaar, Philippe Steinier, Christopher J. Greet

"The importance of the oxygen content of sulphide mineral pulps in determining which reactions occur, and their subsequent influence on flotation behaviour is grossly underestimated in most operating concentrators. While pH is routinely monitored, Eh and dissolved oxygen measurements are obtained infrequently. However, dissolved oxygen measurements in conjunction with other pulp chemical parameters (i.e. pH, Eh, and EDTA extractable metal ion analysis), can provide valuable insight into where and what type of reactions are occurring within a circuit. Unfortunately, these readings yield “instantaneous” measurements of the pulp chemical parameters.What is needed is a means of establishing how reactive a pulp is, and how this reactivity changes as components of the system are manipulated. Oxygen demand provides an opportunity to do this. Several attempts at measuring the oxygen demand of a pulp have been made in the past with varying degrees of success. Most notable among these are Noranda and BOC Gases.Learning from these experiences, Magotteaux have developed the MagO2 ® demand vessel to measure the oxygen demand of mineral pulps. This paper described the apparatus, and through a case study on Broken Hill lead/zinc ore demonstrates how the MagO2 ® demand vessel is used.INTRODUCTIONThe role of oxygen in flotation is complex. While a considerable body of work exists demonstrating the strong involvement of oxygen in the interactions between sulphide minerals and collector (Gaudin and Finkelstein, 1965; Gaudin, 1974; Woods, 1984; Laajalehto, Nowak and Suoninen, 1993), the presence of oxygen can also affect the oxidation state of sulphide and non-sulphide minerals, which can impact on their flotation behaviour. Further, sulphide mineral oxidation is related to their oxygen demand (Spira and Rosenblum, 1994)."

Jan 1, 2004

By A. R. Miller, R. A. Stanton, M. J. Male, G. R. Cluff

"The Dubawnt Group consists of continental sedimentary and volcanic rocks which fill structural depressions - Baker Lake Basin, Yathkyed Lake and Angikuni Lake subbasins- whose evolution was controlled by late Aphebian extension, between 1.9-1.8 Ga. Structurally controlled uranium mineralization having the signature U + Mo + Ag + Pb + Cu ± Zn is spatially related to (i) intersecting fault systems that record multiple movements, (ii) chemically reactive lithologies containing sulphide, chlorite or graphite/ carbonaceous matter in the Archean and Aphebian basement complex and as alkaline volcanics of the overlying Dubawnt Group and (iii) areas containing thick successions of basal Dubawnt Group red clastic sediments.The most significant uranium occurrence found to date is the Lac Cinquante deposit, which contains 14 million pounds U3O8 of drill-indicated reserves. Mineralization is hosted in Archean meta-volcanic and metasedimentary rocks of the Henik Group adjacent to the basal Dubawnt unconformity in the northeastern A ngikuni Lake subbasin and occurs as plunging pods in and peripheral to a fractured and brecciated tuffaceous meta-sediment- sulphide+ carbonaceous exhalite. This deposit exhibits many features typified by the classical vein deposit at Beaverlodge, northern Saskatchewan.Epigenetic stratabound U + Cu + Ag ± Mo mineralization, typified by the 74-1E prospect in the eastern Baker Lake Basin, is hosted in thermally altered Kazan redbeds adjacent to alkaline dykes.At the eastern end of the Baker Lake Basin, small prospects having an elemental signature U + Se + Cu + Ag +Au are interpreted as unconformity-related mineralization associated with the Helikian The/on Basin.The Dubawnt Group rocks of the Baker Lake Basin, subbasins and adjacent basement complex contain uranium mineralization of two eras- Late Aphebian and Helikian."

Jan 1, 1986

By Roy Lindsay, Paul O'Hara, Gary Halverson

"The New Britannia Minesite is located in Snow Lake, Manitoba, 420 miles north of Winnipeg (figure 1). The mine previously operated from 1949 to 1958 extracting some 5.39 million tons of ore at a 0.150 opt gold grade. From 1959 to 1986 the property was held by Nor-Acme and Hudson Bay Exploration and Development and in 1987 High River Resources Ltd. Optioned the property, dewatered the mine and conducted a diamond drill program between the 1 780 and 2400 levels. In 1988 two companies, Nor-Acme Mines Ltd. and High River Gold Mines Ltd., negotiated an option agreement with INCO Gold whereby !NCO assumed management control of all site exploration work. During this period, a bulk sample of 10,000 tons was extracted from the 1780 level with no further exploration recorded after its removal. Both Hudson Bay Exploration and Development and INCO Gold conducted feasibility studies on reactivating the property but at a calculated capital cost of Cdn $70 to $80 million found the rate of return on their investment unacceptable.In 1991 !NCO Gold merged its interest with the assets of TVX Gold Inc. and in February 1994 TVX Gold Inc. and High River Gold Mines Ltd. entered into a joint venture partnership to develop the Snow Lake property, naming TVX Gold Inc. the operator. Upon completion of a feasibility study in April 1994 by Bharti Engineering Associates Inc., a decision was made to reopen the Britannia Mine at an established project cost of US $33 million.Project construction commenced in July 1994 with the hoist house excavation. The first concrete for the hoist house level footings was poured on August 4, 1994 and the project was completed on October 1, 1995 at a cost of US $36 million. The first gold pour took place November 4, 1995.This paper not only presents the metallurgical aspects of the operation but also describes the novel approach used to complete the design and construction of the site facilities."

Jan 1, 1996

By Eugene Nel, Johan Theron, Chris Martin, Hans Raabe

"Impala Platinum Limited is the world’s second largest platinum producer, producing more than 1.7 million ounces of the precious metal last year, much of this from the UG-2 reef located in the Bushveld Complex, South Africa. As part of Impala’s ongoing expansion programme, tonnage through their principal UG-2 processing facility, near Rustenburg, was increased 40% in 2001.To accommodate the increased throughput, the role of the existing primary mills was converted from conventional semi-autogenous grinding units, to attrition and selective grinding units, operating in fully autogenous mode. The finer chromite and coarser silicate components in the mill discharge are then separated by screening and processed in dedicated circuits downstream. This way, the need to spend considerable capital to increase primary grinding capacity was averted.In the last year, considerable work has been conducted to evaluate and optimise the two downstream circuits. This has involved an optimisation programme of sampling and diagnostic flotation testing, supported with QemSCAN analysis. This paper will describe the operation of the new circuit. It will also describe some of the more novel aspects and interesting findings from the optimisation programme.INTRODUCTIONThe South African platinum industry is the world’s largest producer of platinum and the world’s second largest producer of palladium. Located in a wide area north of Johannesburg, the industry mines ores from the Bushveld Complex, one of the world’s great mineral treasure chests, containing over 70 percent of the world’s platinum, as well as extensive reserves of the other PGE (platinum group elements), chrome, manganese and vanadium. The industry employs about 180,000 people in, predominantly, underground mines, which together form an almost unbroken circle of mining operations 200 km in diameter."

Jan 1, 2004

By Derek H. C. Wilton, David T. W. Evans

"Abstract - The Midas Pond gold prospect, central Newfoundland, is hosted by sheared and altered felsic and mafic pyroclastic rocks of the Tulks Hill volcanics, Victoria Lake Group, and has been trenched and tested by 19 diamond-drill holes. Gold values are sporadic, with the best diamond-drill intersection assaying 7.3 g/t over 0.9 m, and the highest grade channel sample containing 14.7 g/t over 1.15 m. Alteration and mineralization are confined to a 200 m wide brittle-ductile shear zone. This shear zone formed in response to regional D1 deformation, and the shear zone fabric parallels the regional S1 foliation. D2 deformation resulted in broad Z-shaped flexuring of the shear zone. The deformation was probably related to the ca. 396 Ma to 420 Ma Salinic Orogeny.Advanced argillic alteration and an extensive halo of Fe-carbonate and pyrite surround the gold mineralization. Alteration minerals include pyrophyllite, paragonite, quartz, plagioclase, chlorite, fluorite, Fe-carbonate, and pyrite. As such, the alteration seems to reflect combined epithermal (argillic) and mesothermal (carbonate) mineralizing environments. The argillic alteration and fluorite represent a regional hydrothermal effect on the felsic volcanic rocks; whereas, the Fe-carbonate and pyrite represent a mesothermal alteration associated with auriferous quartz veins. The Au, which is spatially associated with pyrite, occurs in three structurally-controlled vein sets. These veins are confined to the contact between a highly deformed breccia (the banded mafic tuff) and structurally overlying, altered felsic tuffaceous rocks. The vein sets include: V1 boudinage veins that parallel the shear-zone fabric (C-shear veins), and V2 and V3 extensional fracture veins which are controlled by an S2 fracture cleavage. V1 veins are the earliest and contain the lowest concentrations of Au. V2 and V3 veins are concentrated within the hinges of the D2 flexures.Pb isotope data for galena separates indicate that the Pb in the vein systems was probably of local derivation. Sulfur, C, and O isotope data for mineral separates are similar to data for typical mesothermal lode gold deposits. Fluid inclusion data suggest the presence of at least three hydrothermal fluid types in the region, viz., (1) an early saline fluid which produced the argillic alteration, (2) a CO2-bearing fluid directly related to the auriferous mineralization, and (3) H2O-NaCl fluids which flowed through the Midas Pond shear zone at a lateral distance from the zone of mineralization. The mineralizing fluids are interpreted to have been CO3 -2-rich types which originated through metamorphic dehydration and decarbonation of mixed island-arc and continental crustal rocks. Gold precipitation resulted from the reaction of these fluids with the Fe-rich breccia unit. Pre-existing and simultaneously crystallizing pyrite served as loci for Au precipitation."

Jan 1, 2000

By Hiroaki Sakurai

Using batch reactors equipped with CO and CO2 gas sensor, CO oxidation over Au catalysts in room air has been investigated and compared with Pt catalysts. For both Au and Pt catalysts, the logarithm plot of CO concentration data during initial 10 min are well fitted by straight line, which mean the first order dependence on the CO concentration between 10 and 10,000ppm. The rate constant value (k) over Au and Pt catalyst generally decrease with increasing initial CO concentration above 100ppm. The value decrease especially rapidly between 100ppm and 1,000ppm over Pt catalysts, which should be due to the strong adsorption of CO on Pt. The k value over Au catalyst has become ten times or more as large as the Pt catalysts at 1,000ppm. Already for the initial concentration of 100ppm CO, the strongly adsorbed CO on Pt metal has been clearly observed by FT-IR during the reaction over Pt/Al2O3. A part of the strongly adsorbed CO has been remained on Pt after the disappearance of gas phase CO, and has gradually changed to gas phase CO2. Such strongly adsorbed species on Au has never been observed on Au/TiO2 under the same reaction conditions. These features of Au catalysts are favorable for indoor air purification.

Oct 1, 2003

By David R. Skuse, Jacek A. Kostuch, Steven M. Fortier

"Particulate ground calcium carbonate (GCC) is used as a filler and coating pigment in a wide range of applications including papers, paints, plastics and films. In this paper we will overview the requirements for GCC used in both filling and coating applications in the paper industry and highlight the processes used in the production of these materials.INTRODUCTIONCalcium carbonate is both abundant and very widely distributed occurring most commonly as limestone, marble and chalk (Harben 2002). Given, the high purity, whiteness and relative inertness of these materials it is not surprising that they are heavily utilised in a range of industrial applications. Worldwide ground calcium carbonate (GCC) capacity is estimated at 50.5 million tonnes per year (Roskill, 2002). This usage is divided between relatively coarse materials that are used in applications such as landscaping, cultured marble and carpet backing and finer grades that find application in plastics, rubbers, inks, paints and paper. Given the usage of calcium carbonate products across a very wide range of consumer products, the outlook for GCC is very promising with growth expected in many markets. Growth is anticipated across many applications in the emerging nations and more specifically in paper applications on a global basis.Over the last several decades the GCC processing industry has evolved to be well adapted to both the cost effective production and delivery of standard products and the production of high performance speciality products. Many of the standard unit operations found in the metaliferous raw material processing industry are also used, albeit in some cases in modified form, in the processing of GCC. Coarse products (diameter > 3 - 10 µm) are typically produced by dry processing routes. Whereas, the finer products are typically produced by a combination of wet and dry processing."

Jan 1, 2004

By S. Banisi, H. R. Iran-Manesh, M. R. Shayestefar, H. Shekarchyan

"Flotation circuit of the Sarcheshmeh copper mine processes 41,000 t/d of ore at 0.9% Cu. Chalcopyrite and chalcocite are the main copper bearing minerals which are concentrated in three stages of roughing, cleaning and recleaning. Due to major changes in the reagent addition regime, make-up balls combination, and throughput to the primary mills an increase of 2.6% (from 87.2% to 89.8%) in the sulfide copper recovery was obtained during a period of six years. In order to investigate a rather large variation of monthly recovery (i.e., from 89.0 to 91.2%) of the plant after implementation of the changes, a study was undertaken to trace mineralogically possible causes of such a behavior. During a five-month period, monthly composite samples of feed and tailings of the flotation circuit were taken. At the first stage, the polished sample preparation method and the mineral counting procedure were optimized through a detailed study. Liberation degrees and types of locking of valuable minerals in both streams were determined in three size intervals of +75, +38 and –38 microns. It was found that for both recovery levels (i.e., 89% and 91.2%), there was no significant difference in the liberation degrees of valuable minerals in the flotation feed; the average liberation degree was 57.1% with a standard deviation of 3.1%. On the other hand, in the case of high recovery level (i.e., 91.2%) there was a reduction of 15% in the amount of free valuable minerals in the tailings stream. The highest reduction was found for the -38 micron size range in particular for chalcocite. It was concluded that compared to the grinding circuit the change in the flotation circuit had the significant effect on the plant recovery increase.INTRODUCTIONThe Sarcheshmeh copper ore body contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and currently processes 41,000 t/d of ore. The concentrator has been in operation since 1982. Last year, the concentrator produced 130,000 tonnes of copper and 4,000 tonnes of molybednite concentrate. An expansion to the plant which will increase the throughput by 50% is under construction and will be effective in 2003.After three stages of crushing, the ore with a F80 of 12.7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70% finer than 75 microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 30.5% Cu is obtained after cleaning and re-cleaning stages. At the present time, the average sulfide copper recovery of the plant is 89.8% which varies depending on the operating conditions and ore type."

Jan 1, 2003

By R. J. McLeod

"CONTROL STRATEGYThe Lake Dufault Division of Falconbridge Copper Limited has been concentrating a complex copper zinc ore since late 1964. An ARL X-ray on stream analyzer was installed in 1966 for process control. A Digital Equip-ment Corporation PDP8 was added in 1968 for more complete control. To improve the system the computer was exchanged for a Moded PDP-81 in 1971.The new computer is time sharing with 8K core memory and 32K disc storage. A new interface was installed to accommodate 14 X-ray streams and additional analog signals for process control. The system gave us additional capacity and flexibility to make changes in operating programs and control strategy while on line. As the computer is used for process control a modified focal language was chosen as the operating language for ease of operation. This language is more suitable for process control than for statistical work.The main components of the control system are(a) Computer(b) Interface(c) Production Control X-ray Quantometer(d) Teletype terminals(e)Reagent feeders(f) Sample SystemThe operation of the system consists in the computer selecting the various streams to be analyzed by a PCXQ Quantometer. When the flowing sample is presented to the X-ray the intensities of the various elements are read by the computer from analog to digital converter, the assays are then computed. From the tonnage and assays the computer is programmed to determine the amount of reagent added to various parts of the circuit. The computer drives the feeders via the interface for the required amount of reagent. After following a certain sequence the computer prints out the performance and control data on an ASR35 Teletype. The data is printed out approximately every seven minutes. Any des¬ired changes in the program or strategy can be made during operation via an ASR33 Teletype connected to the computer."

Jan 1, 1973

By Seher Ata

"Virtual reality, a three-dimensional computer generated environment, has become recognized delivery system for many forms of education. This article describes the application of virtual reality to mineral processing education. An interactive mineral processing visualisation module has been developed at University of New South Wales (UNSW), Australia. The module provides students with an overview of a base metal concentrator, details about each stage of the process, as well as revealing how the mined ore progresses from stage to stage. The module also involves developing a number of instructional based plant layouts and flowsheets in the virtual environment that are intended to assist the user in understanding the essential components of the base metal concentrator.INTRODUCTIONVirtual Reality (VR) is the creation of an artificial environment that is experienced through sights and sounds provided by a computer (Squelch, 2001). The simulated environment is achieved through a host of technologies such as three-dimensional graphics, audio feedback and special peripheral devices to produce interactive environments.VR has been used in diverse fields including medicine (Riener & Harders, 2012), entertainment (Hsu, 2011), military (Manojlovich, Prasithsangaree, Hughes, Chen, & Lewis, 2003), manufacturing (Zimmermann, 2008; Jiang, 2011), and chemical processing (Schofield, Lester, & Wilson 2005; Squires, Andersen, Reklaitis, Jayakumar, & Carmichael, 2014). VR is also becoming recognized delivery system for many forms of education, including engineering education (Bell & Fogler, 1996; Bell & Scott, 1998; Shin, 2002). For example, virtual laboratories have been designed and developed to teach students fundemental features of the heterogeneous catalytic mechanisms and absorption columns (Bell & Fogler, 1995), the multi-phase and multi-component blast furnace iron making process (Babich & Senk, 2009) and to guide students to identify various safety measures while working in real laboratory (Bell & Fogler, 1996)."

Jan 1, 2016

By Michel Ruel

"PID loops – also known as base layers or regulatory controls – form the foundation of any plant’s control layer and it is generally accepted that PID loop health has a direct impact on the plant’s bottom line. Keeping these thousands of control loops in good health has a direct impact on the plant’s bottom line: it reduces variability, improves quality and throughput, and decreases energy costs and raw material usage. This has been well proven and documented in many articles. In the last ten years, technology has evolved: control engineers can now keep track of control loop performance and link it to the root causes of variability. However, they lack industry-wide best practices and criteria for determining what can be considered as excellent, good, fair, or poor performance. To ensure that PID control loops continue to perform well and meet their objectives, control engineers need a combination of (a) an appropriate monitoring technology and (b) best practices for doing the maintenance of base layer controls.Most plants have limited resources and operate with an increasing number of constraints; therefore, using the right tools and including reports in daily workflow is key for success. This paper suggests roles and responsibilities of key players needed to work toward control performance best practices and discuss organisational changes to succeed.INTRODUCTIONAlthough PID controllers are reliable workhorses in the process industry, they are often underrated. Since the 1980’s, computer control has evolved and the control algorithms used by control engineers have become increasingly complex. However, PID controllers still handle over 90% of the control loops in operating plants. Table 1 shows the savings that can be realized by achieving best-practice in several different process control categories (Brisk, 2004). The savings are expressed as a percentage of production costs."

Jan 1, 2011

By Steven Townend

Mining-related activities have been known to create a challenging operating environment for mining companies located in close proximity to communities. Issues such as noise, vibrations from mining operations, land use and emissions are often a concern for community residents. In order to develop good community relationships it is necessary to take a proactive approach. This paper documents this approach and also deals with the social implications for Vale associated with mining activities in the heart of the community of Copper Cliff, Ontario, Canada.

May 1, 2011

By Stephen L. Chryssoulis

"""Preg-robbing"" of gold by carbonaceous matter during the cyanidation of certain types of carbonaceous gold ores is well documented. Recent studies established that ""preg-robbing"" of gold is not limited to carbonaceous matter. Gold sorbed on the surface of pyrite grains was detected and quantified by TOF-LIMS (Time of Flight Laser Ionization Mass Spectrometry). Crystallites of pyrite from a number of ores from different geological environments have been shown to have gold on their surface apparently sorbed from the ore forming solutions. Surface gold accounts for significant fractions of the gold head assay. Preg-robbing of gold by pyrite from pregnant cyanide solutions was also documented, and accounts for significant losses to tailings. Preventative measures are discussed.1.0 IntroductionThe detection and subsequent quantification of gold sorbed on the surface of pyrite particulates came about during routine determinations of the deportment of gold employing the comprehensive mineralogical approach (Chryssoulis and Cabri, 1990). In some pyritic gold ores it was discovered that the sum of the various forms in which gold ""conventionally"" occurs, was short of the gold assay. The mineralogical procedure used involves the independent determination of each fraction of gold, in other words there is no form of gold which is calculated ""by difference"". The systematic shortfall after having added the forms of gold listed in Table 1 led to the inquiry for the 'missing' gold and its discovery on the surface of pyrite grains, such as crystal facets and fractured surfaces.Preg-robbing of gold by pyrite from pregnant solutions was first described by Lloyd. In his studies, preg-robbing was measured by changes in the solutions/solids gold assays. This paper describes the first application of a direct measurement method for surface gold on pyrite particles from untreated and processed samples, its impact on gold deportment and processing. The advantage of the direct measurement lies in the absence of interference from other forms of gold, leading to more accurate and precise determinations of this unconventional form of gold."

Jan 1, 1997

By R. Tipman, T. C. Burnett

"A general computer program has been written to calculate material balances using multiple regression techniques. The program can handle metal assays or size distribution data obtained in multiple surveys of the flotation circuit. The ""best fit"" weight split is calculated between the input and product streams by minimizing the sum of squares of the residual errors using all of the available data. The program includes an assay adjustment feature in which each assay is recalculated to fit the ""best fit"" mass balance. Thus assay or sampling errors can be easily identified. Also the assays can be statistically weighted so the most precise measurements are given the most influence on the material balance. The computer output reports the mass balance, the actual and corrected assays, the percent metal recoveries and the significance and confidence levels for the weight splits.The program enables a rapid and accurate evaluation of mass balances from large masses of data obtained in multiple surveys around a flotation circuit. The effects of changing process variables can be quickly evaluated with statistical confidence."

Jan 1, 1978

By Grant Small, Jessica Kinal, Christopher J. Greet

"The conversion from an electrochemically reactive grinding media (forged steel) to a more electrochemically inert alloy (high chrome white iron) not only reduces the wear rate of the grinding media, but also has an impact on the grinding chemistry. Typically the grinding chemistry becomes more oxidising, with less reducing Eh values and more dissolved oxygen in the pulp. There is also a decrease in the EDTA extractable iron, which is an indication of the change in the media corrosion. These changes are indicative of alterations in the surface chemistry of the minerals that the operator is trying to separate. For porphyry copper ores the changes in the pulp and surface chemistry not only affect the copper sulphide minerals, but also impact the iron sulphides (i.e. pyrite and pyrrhotite). Generally, with more oxidising pulp chemical conditions during grinding there is an increase in the oxidation of the iron sulphides which renders their surfaces hydrophilic, thereby depressing flotation. This leads to improved selectivity for copper sulphides against iron sulphides.INTRODUCTIONPorphyry copper deposits are the dominant source of copper that is mined today to satisfy global demand. These style of deposits typically contain one percent copper mostly as chalcopyrite, but may contain other copper bearing minerals (for example, bornite, chalcocite, azurite, malachite), small quantities of pyrite and quartz. Porphyry copper deposits also contain economically significant quantities of gold, silver and molybdenum. Interestingly, the majority of the world’s porphyry copper deposits are concentrated along tectonic plate boundaries (Figure 1)."

Jan 1, 2016

By Catalin Florin Petre, Elahe Ghasemian Langeroudi, Abdelaaziz Azizi, Éric Proulx, Caroline Olsen, Paul Blatter, Faïçal Larachi, Claude Gagnon

"The recovery of gold from ores is often accompanied by the release of other species in the leach solution. This state of affairs leads to depleted free cyanide levels in the slurry. Therefore, separation and quantification of these cyanicides and free cyanide at different stages of the cyanidation process as well as in waste solutions is crucial to provide mitigation tools by preventing leaching of deleterious metals for environmental considerations.COREM and the research group of Prof. Larachi have been working together on the control of gold passivation and cyanicides during cyanidation for several years. Previously, a first capillary electrophoresis (CE) protocol for the speciation of sulfur and cyanicides (SCN-, Cu, Fe) during cyanidation of gold complex sulfide ores was developed and validated for assessing industrial process water.The separation of zinc cyanide complexes used to be confronted with a number of difficulties due to the weak and/or undetectable cyanocomplexes in formally available CE protocols. Moreover, according to our knowledge, no direct CE protocol exists to separate free cyanide. Therefore, a new study aimed at developing a second CE protocol for the detection and quantification of cyanide complexes of zinc and nickel as well as of free cyanide in the cyanidation process water.To achieve this goal, six common carrier electrolytes such as pyridine, trimellitic acid, 4-methylbenzylamine, sodium chromate, phthalic acid and tris base were studied, using an indirect UV detection method. The best results were obtained using sodium chromate for which all ions were successfully separated and quantified. In addition, the effect of electric field strength, injection volume, electro-osmotic flow (EOF) modifier and background electrolyte (BGE) concentration were examined, while peak height, peak area and noise were considered for optimization.As a result, the new protocol is expected to complete the initial CE protocol by detecting cyanide complexes of zinc and nickel as well as free cyanide. Moreover, analytical determination of free cyanide in the presence of weak cyanide complexes achieved by the new protocol was also compared to conventional titration using silver nitrate solution. This new CE protocol will contribute to applied research and help plants to better understand and eventually control the behaviour of cyanidation circuits."

Jan 1, 2011

By A. Vien, A. J. Neale, B. C. Flintoff, R. P. Edwards

Froth flotation is one of the most widely used and effective processes for mineral beneficiation. First introduced in 1911, flotation technology has seen many developments over the past 80+ years. Innovations in reagent chemistry, equipment design, process analysis and process control have given design and plant engineers a powerful set of "tools" for process optimization. However, it does not follow that all flotation systems are optimized. As Klimpel observes: "The problem with the industrial flotation process is that it is relatively easy to get reasonable results, and relatively difficult to get excellent results" Klimpel (I 988). While reasonable was sufficient in the past, competitive forces will make excellent necessary in the future. Judging by the activities in many Canadian plants this transition is already underway. This paper examines the role of some of the optimization "tools" in effecting this change.

Jan 1, 1994

By Q. Zhang

The necessary capability of the gravity transportation pipeline system for cemented coal gangue backfilling at the Suncun Coal Mine, China, is about 74.4 m3?h-1 according to mining production and working times in the mine. It is estimated that the working velocity and maximum pipe length-backfill depth ratio of the backfill system are 3.82m?s-1 and 5.4, respectively and that the probable backfill capability of the system is 110.18m3?h-1. Results of hydraulic calculations for the backfill transportation system show that the designed backfill system is reliable in flowability and sufficient for backfill capability needs.

May 1, 2007

By Bjarne Ekberg

"The most economical way of dewatering mineral concentrates is to reduce the moisture content in the material mechanically using thickeners and filtration avoiding thermal drying whenever possible. In addition to this, the dewatering process should produce low moisture cake, high quality liquid, consume little energy. As a part of the dewatering process The CERAMEC® capillary filter has been proven to meet these requirements in over 150 installations. The filtration is done by using ceramic filter plates with small pore size. The capillary action in the filter medium secures gas free filtration at good vacuum, and due to the small pore size, filtrate is crystal clean and particle free. The energy consumption is minimal. This paper will discuss results from filters installed at Pyhäsalmi Mine Oy in Finland where the technology was has been used since the late eighties. Results from more recent installations like Los Pelambres in Chile and LKAB in Sweden will also be discussed.INTRODUCTIONThe idea of using capillary action to make dewatering more efficient was invented two decades ago. Ten years later whole filter plants utilizing the new method were delivered to mine concentrators for dewatering of mineral concentrates. Further development of ceramic membrane plates made it possible to meet the requirements in iron ore dewatering. In addition to low cake moisture, high capacity and low energy consumption, there are a lot of environmental advantages in using capillary filtration. One of them is clear filtrate.CAPILLARY FILTRATIONA micro-porous filter material behaves like a large number of narrow capillaries forming a network. When a pressure difference ?P is applied over the wetted, hydrophilic pore with the radius r, the force striving to push the water out of the pore will be ?Ppr2. The force striving to hold the water in the pore will be the vector force 2pr? cosa of the surface tension ? and the cosine contact angle a. Equalling those forces and solving the equation for ?P we get"

Jan 1, 2003

By Eugen Gluck, Gus Van Weert, Peter Kondos

"Microwaves have the capability to heat up sulphides, especially clusters of particles of approx. 1 mm. Some sulphides absorb microwaves more readily than others. Molybdenite is especially effective in this regard, possibly due to its flaky nature and/or electrical conductivity. Even where it occurs in low concentrations in a deposit, individual rocks may be ore grade due to the high monetary value of MoS2. Such rocks often result from crushing mined veinlets or stockwork, or are contained in the cutoff grade fraction of ROM. Machine segregation of rocks high in MoS2 by infrared sensors after microwaving could therefore advantageously be used to upgrade lower grade ore between Mine and Mill. This would reduce the size of the latter, and thus its CAPEX and OPEX. Such upgrading could also yield shipping ore for a distant Mill, or extend ore reserves.Barrick Gold Corp. has been supporting the development of MW/IR sulphide sorting for the past three years. The results of MW/IR sorting work on molybdenite and other (pyritic) ore samples from a variety of sources are being presented here.INTRODUCTIONThis paper looks at mechanized, i.e. machine ore sorting technologies currently available and under development, and what conditions would be needed for the potential application of such ore sorting to sulphide mining and milling. Current machine sorting involves no-contact sensing technology for rocks, and signal processing after sensing to activate airblast segregation of certain rocks, normally the smallest mass to keep compressed air costs down.The forerunner of modern sorting is probably magnetic separation, which utilizes an inherent property of certain ores to divert it into mag and non-mags fractions. Radiometric ore sorters, which have been applied successfully for decades in the pre-concentration of uranium ores (Wotruba and Riedel, 2006) initiated modern sorting. In the 90’s, sensor-based machine sorting became a viable means of increasing the overall economic recovery of a resource. This technology became driven by the availability of low cost computing equipment and the concurrent development of algorithms, and by the availability of extremely fast response sensors and air actuators, allowing the sorting equipment to run faster, dropping the cost per tonne. It has been in industrial minerals processing that rock sorting has been most widely adopted, not really surprising. Liberation occurs on a different scale than in the base metal industry. Most industrial minerals are mined from massive deposits, requiring (in the past) no upgrading. Many of these operations now run into product contamination problems, which ore sorting can solve. One illustration: in Finland, a quarry is separating limestone from dolomite at 500 tonnes / hour, with individual rocks weighing up to 15 kg. Many of these industrial minerals operations have stockpiles of earlier discarded below-quality rocks, now being reprocessed with the help of ore sorting. The economics of this are very favourable, going from zero or negative value (stockpiles can not be left when closing the mine) to full product value for at least a portion of the stockpile. This suggests that in the future the economics of overburden sorting could become attractive under the right circumstances and such treatment could well become an integral part of open pit mine development."

Jan 1, 2009