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By Shamia Hoque, Charles Q. Jia

Smelter slags contain valuable metals such as Co, Ni and Cu in proportions of less than 1 wt% along with about 40 wt% of Fe and 15 wt% of Si. Although aqueous SO2 is a versatile lixiviant for transition metals, dissolving the slag in aqueous SO2 produces solutions in which Co and Ni concentrations are lower than that of Fe due to the low metal/ Fe ratio in the slag. To develop the options for increasing Co and Ni concentrations the solubility of slag in aqueous SO2 was studied experimentally and theoretically using OLI, a software package for simulating electrolytes chemistry. The modeling results correlated well with experimental results. The model suggested that the species dominating the system was FeSO3, which would precipitate out as FeSO3.3H2O when the concentration of Fe+2 reached 1.22 molal and the concentration of S032- was beyond 1.4 molal. In the experiments the influence of pH and solids loading were studied. The leach solution obtained after dissolution of slag at 50% solids loading had a pH of 1.85. On raising the pH to 3, precipitation occurred. Analysis of the solution collected after the addition of alkali showed over 50% reduction of Fe, Co and Ni. XRD analysis revealed the precipitate to be of amorphous nature due to the silica present. The analysis confirmed that the precipitate was mainly FeSO3.3H2O. The paper also discusses the potential impact of the slag on the environment.

Jan 1, 2004

By P. D. Barrette

This paper deals with the flow of granular materials in bins. A hybrid Lagrangian-Eulerian numerical model is introduced. The model is based on Particle-In-Cell (PIC) advection, and continuum equations describing a Mohr-Coulomb criterion. Experiments were conducted to test and verify the performance of the numerical model. Tests were done using three types of particles. Measurements of material properties and flow rates were carried out. Video records were also obtained and used to examine flow patterns. The results indicate that the numerical simulations produce deformation patterns and flow rates which are in good agreement with the experimental observations.

May 1, 2007

By N. Aydogan, H. Dundar, Å. Partapuoli, A. Fredriksson, P. Wikström, K. Tano, G. Adolfsson

The Autogenous milling of ores holds an increasing attraction as the focus moves towards reducing energy usage, both direct and embodied in grinding media. However, most of the early AG mills were converted to SAG for improved stability and increased throughput. This imposes a huge penalty in steel grinding media consumption. The LKAB iron ore operations in Sweden process highgrade magnetite through fully-autogenous milling lines to a final product P80 of about 45µm. The outcomes of P9O AMIRA research surveys, covering a wide range of mill fillings and throughputs and with different feed blends, are presented. Insights are provided on operational strategies, opportunities, the influence of feed size control and balancing the blend of competent gangue and softer magnetite. Areas of importance in the successful operation and control of energy-efficient autogenous circuits are highlighted.

Jan 1, 2012

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks, R. L. Sachdeva

"A combined shaft-electric furnace for the smelting of ores and the melting of metallized iron pellets is being developed. The materials are preheated, and in some cases pre-reduced, in the shaft before being transferred to the electric furnace, where melting or smelting is completed. It has been demonstrated that this combination of equipment will enable much of the relatively expensive electrical energy to be replaced by cheaper energy in the form of oil or natural gas, and preliminary experiments indicate that the total energy requirements for a melting or smelting operation are significantly reduced. Projections based on results obtained from the preliminary experiments indicate that further improvements will be possible when certain modifications to the equipment are completed."

Jan 1, 1968

By W. Keith Buck

This paper defines the discipline of mineral economics. By example, it describes the application of the tools of economic analysis to mineral problems - to problems in the areas of: mineral resource analysis and forecasting, mineral industry activity from exploration to distribution and marketing, mineral commodity analysis, and mineral policy analysis and policy formulation - all in a regional, national or international context.

Jan 1, 1972

By C. J. Brown

Regeneration of hydrochloric acid steel pickle liquors has traditionally been accomplished by pyrohydrolysis. However, a number of factors have recently conspired to reduce the attractiveness of this approach. Moreover, the process is not amenable to small-scale operations. On the other hand, the standard technique for regeneration of sulfuric acid pickle liquors, which is the low-temperature crystallization of ferrous sulfate is applicable to any size operation. A similar technique has recently been developed to regenerate hydrochloric acid. Sulfuric acid is added to the ferrous chloride-bearing spent HCl pickle liquor. The temperature is then reduced to below 0°C, resulting in the crystallization of ferrous sulfate heptahydrate and liberation of free hydrochloric acid. Depending upon the crystallization temperature, variable concentrations of sulfate are left in the regenerated acid. Although this residual sulfate has an impact on the pickling characteristics of the regenerated acid, tests have shown that by adjusting the conditions, pickling rates will be at least equal to those using pure HCI, and an acceptable surface finish will be produced.

Jan 1, 2006

By Wael Abdellah

Mine haulage drifts are the primary access to the mining blocks of an orebody in a multilevel mining system of a tabular ore deposit. The stability and functionality of haulage drifts are thus crucial to the success of a mining operation. Drift instability could lead to serious consequences such as injuries, production delays and higher operational cost. In this paper, the performance of the haulage drift stability is evaluated on the basis of the primary rock support system comprising 1.8 m resin grouted rebars in the drift walls and 2.1 m long bolt in the back. Two failure criteria namely the extent of Mohr-Coulomb yield zones around the drift, and linear elastic brittle shear failure are adopted and compared, with respect to lower level and same-level mining and filling sequence in the vicinity of the haulage drift. The case study is one of the #1 Shear East zone of the Garson Mine in Sudbury, Ontario. Random Monte Carlo (RMC) technique, which has been previously established to assess the haulage drift stability, is employed in this investigation. The RMC technique is used in conjunction with finite difference modelling software FLAC for random assignment of model input parameters in the FLAC grid. Deterministic model results reveal the drift behaviour in terms of deformation (convergence) and mining-induced stress distribution. Comparison between the two different criteria is carried out to determine which method is most suitable in evaluating unsatisfactory drift performance. The results are presented in terms of probability of instability and categorized with respect to failure condition and mining step. It is shown that the brittle shear failure condition based on linear elastic response calls for enhanced support system at a later mining step than what Mohr- Coulomb yielding condition does. The paper presents a detailed discussion of the stochastic analysis results.

Jun 1, 2012

By J. Fellowes, V. Landais, J. Robson, J. Carr

"Aerospace Al-Zn-Mg-Cu (7xxx) alloys are known to be susceptible to environmentally assisted cracking (EAC). This phenomenon has been studied intensively for many decades, leading to empirically adopted methods to mitigate this problem through overaging and composition design. In parallel, many theories have been developed to explain EAC in 7xxx, but none is yet universally accepted. Today, a number of emerging techniques offer potential to shed new light on EAC in 7xxx. The purpose of the present paper is to demonstrate how X-ray tomography (XCT) combined with electron microscopy can be used to identify the true crack path in 3-dimensions, and hence identify material for site specific electron microscopy analysis. Composition mapping over large areas to high accuracy has been performed using a modern electron microprobe analysis system. This has been combined with transmission electron microscopy to investigate local composition in matrix and precipitates at high resolution. This combination of techniques across length scales offers the potential to provide new insights into the links between local composition, microstructure, and EAC resistance.INTRODUCTION Environmentally-assisted cracking (EAC) is a phenomenon which dramatically decreases the performance of metals and can cause premature failure of large structures. Observed in situations where components were not subjected to critical loads and no widespread corrosion was involved, this type of brittle failure is extremely difficult to predict. The EAC designation covers a number of phenomena, e.g. stress corrosion cracking (SCC), hydrogen embrittlement (HE), corrosion fatigue (CF), etc. Initially identified in steels, EAC can also affect other metals such as high-performance aerospace aluminium alloys, and this phenomenon has been a concern for industries for decades. Extensive research has been conducted on the effects of various environments (moist air, saline water, dry hydrogen gas, etc.) on microstructures and crack propagation, however no consensus has been reached and the exact nature of the mechanisms that control EAC is still being debated (Birnbaum & Sofronis, 1994; Gangloff, 2007; Holroyd & Scamans, 2013; Lynch, 2012; Oriani, 1972; Scamans, Alani & Swann, 1976, Young & Scully, 2002)."

Jan 1, 2018

By T. Lamb

There are many honor stories about aluminum in the marine environment and many are not based on facts, so they are myths. Myths must be addressed before progress can be made. This paper attempts to dispel the myths and state the facts. A common perception is that aluminum ships cost significantly more than steel ships. This paper illustrates that even though the cost of the aluminum structure is over 50% more than the steel structure, an "equivalent" aluminum naval ship can be built within 7% of the acquisition price of a steel ship. This is possible because of the cascading benefits of the aluminum ship's significantly lighter weight. Aluminum ships also have a life-cycle cost advantage over steel ships because of reduced maintenance and fuel cost savings.

Jan 1, 2011

By W. J. Jenner

"Introduction The Saskatchewan Power Corporation is a provincial crown corporation which operates under a mandate to supply all customers within Saskatchewan with electricity and natural gas. The Saskatchewan Power Corporation operates two coal mines within the province of Saskatchewan. The Souris Valley Mine is located a few miles south of the city of Estevan and produces approximately 300 000 Mg of lignite per year. The lignite is shipped about four kilometres by truck and burned at the 882 MW Boundary Dam Power Station, also owned by the Saskatchewan Power Corporation. The Poplar River Mine is located just south-west of the town of Coronach, Saskatchewan which is some 190 kilo metres west of Estevan. This mine produces approximately 1 675 000 Mg of lignite per year. The lignite is shipped seven miles by rail to the Saskatchewan Power Corporation's Poplar River Power Station. The Poplar River Mine is the sole sup plier of fuel to the Poplar River Power Station, which generates some 300 MW of electrical power. A second 300 MW unit is due to be commissioned at the Poplar River Power Station in mid-1983 and the Poplar River Mine will have doubled its capacity to approximately 3 350 000 Mg per year by that time: Souris Valley Mine Geology The Souris Valley Mine extracts lignite from the Estevan seam of the Ravenscrag Formation. This formation is of Tertiary age and was deposited during the Paleocene Epoch. The Ravenscrag Formation outcrops throughout southern Saskatachewan and all coal mined in the province occurs in this formation. Ravenscrag sediments are deltaic in origin and are composed of a series of fine sands, silts, clay and lignite deposits."

Jan 1, 1985

By C. M. Díaz, P. J. Mackey, P. Coursol

In a recent paper [1], the present authors discussed calculated energy consumption numbers in copper sulphide concentrate smelting for four different smelting technologies. For the present study, from among these technologies, they selected the Noranda/Teniente continuous bath smelting followed by Peirce Smith (PS) converting route to investigate the impact on total energy requirement of some key process variations, such as tuyere injection of dry concentrate vs. slingering of wet concentrate over the molten bath, continuous converting vs. conventional batch PS converting and commercially proven slag cleaning alternatives. In their calculations, the authors used the same thermochemical model and methodology used in their earlier paper. This approach to explore plant design options provides an interesting basis for evaluating flowsheet modifications that could lead to significant copper smelting energy savings. The METSIM software was used in the present paper to carry out heat and mass balance computations for 8 different flowsheet configurations. The results are presented and discussed in the paper with respect to copper recoveries, energy requirements and CO2 emissions.

Jan 1, 2011

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By F. P. Hassani, J. F. Boily, A. M. O. Mohamed, M. Hossein

The optimal geochemical parameters required to form ellringite in a lime-remediated site have been investigated with the use of thermodynamic modelling. The speciation of sulphate and 10 metals analyzed in samples of a mine tailing from northern Quebec was calculated with a computer model. The model also includes calcium, which would result from the addition of lime to the system. Two speciation calculations were done. The first one is a hypothetical speciation before the onset of precipitation and was used to devise the stability fields of minerals susceptible of forming in high pHs. The stability fields were determined by building activity ratio diagrams with sulphate, aluminum and calcium species concentrations for pHs ranging from 4 to 14. The investigation was carried out for a 25°C solution with an ionic strength less than 0.12. Thermodynamics predict that an optimal stability field for ettringite in the mine tailing samples containing 10-3 mol/L SO4-2,10-2 mol/L of AI(OH)4 requires at least 10-2mol/L of Ca+2 and a pH larger than 11.6. The sulphate contents of the mine tailing samples, however, limit the precipitation of ettringite and monosulphate could be an end-precipitate. The second speciation is in equilibrium with precipitates and provides information on the speciation of the residual metals. If ellringite could be precipitated as a stable form, it could serve as a sorptive agent for residual metals, and, due to its binding properties, consolidate tailings.

Jan 1, 1995

By Gennaro Delisle

"Les Services TMG (Niobec) currently treat a niobium ore in the Chicoutimi area of Quebec. The mineral pyrochlore is present in a carbonatite deposit which assays 5% to 7% apatite.The ore is ground to minus 65 mesh and deslimed at 10 micrometres. Part of the carbonates are floated with a fatty acid emulsion and rejected to the tailings as a first step to ensure the proper conditions for the flotation of the pyrochlore concentrate. The carbonate concentrate is 65% minus 44 micrometres and is composed of dolomite, calcite, 22% apatite and a minor amount of silicates.A laboratory investigation was undertaken to determine the feasibility of extracting apatite from the carbonate concentrate. This led to the development of an economic flowsheet to produce high-grade apatite concentrate. The apatite is depressed with phosphoric acid, and the pH is adjusted at 4.8-5.0 with sulphuric acid. An additional amount of fatty acid is added to permit efficient flotation of the carbonates. 1n a second stage, the silicates left behind with the apatite concentrate can be removed by depressing the apatite with AIC3 while floating the silicates with a secondary amine.The results of the laboratory tests indicate the possibility of producing an apatite concentrate assaying 38.3% P2O5 (83.7% BPL) with a recovery of 66.2%. Pilot-plant tests undertaken at the concentrator yielded a concentrate of 34% P205 and recovery of 76%."

Jan 1, 1981

By M. Savich

A graphical method has been developed for the evaluation of the U.S. Occupational Safety and Health Act Noise Exposure Index and the Equivalent Continuous Sound Level. The method makes use of a noise survey form and a mechanical integrator with two sliders, and is less tedious and susceptible to error than alternative methods. The graphical method is adaptable to various codes for noise exposure and may be used with any instrument that measures noise level. One example of its application to a practical situation in a Canadian mine is given to demonstrate the procedure .

Jan 1, 1978

By R. I. Kraydenko, A. N. Dyachenko

"The possibility of SiO2 5N production by staged purification of ammonium hexafluosilicate (NH4)2SiF6 is discussed. High-purity silicon dioxide can be obtained with fluoridation of quartz concentrate by solid NH4F at 100 °C, with further sublimation of the product at 320 °C, its dissolution, ammonia hydrolysis, filtration and drying of SiO2•nH2O. This is accompanied by regeneration of the processing reagent - NH4F.INTRODUCTIONProduction of high-purity silica-5N (SiO2 content over 99.999%) is an important and urgent task of the modern chemical industry. This material is used in the manufacture of optical glass, optical fibers for internet cables, silicon for solar power and electronics.Quartz concentrate is raw material for the production of silicon dioxide. The existing technologies of synthetic silicon dioxide were introduced in the mid-twentieth century. These methods are energy-consuming, multi-step and do not meet stringent environmental requirements. In fact, as some conventional technologies became obsolete; it became necessary to develop new methods for the production of synthetic silica. We believe that the fluoride technology of processing of quartz materials by ammonium fluoride is the most promising direction.In industry, silicon dioxide marked ""Silica White"" is obtained by liquid-phase method. The method consists of the precipitation of amorphous silica from sodium silicate solutions with acids. The resulting product is filtered, washed and dried. Depending on the deposition conditions and nature of the coagulant the ""Silica White"" is acidic, neutral or alkaline. The dry product is subjected to grinding. The degree of dispersion and porosity of the particles of Silica White depends on the nature of decomposition agent (a substance that decomposes the silicate) and coagulant, conditions of sedimentation, filtration and drying. During the drying process the silica particles are sintered into aggregates of a few millimeters."

Jan 1, 2012

By Edouard Asselin, Tasawar Javed

This study was conducted as a part of ongoing work to characterize sulphide concentrate leach residues generated under CESL (Cominco Engineering Services Limited) and Vale pilot and demonstration plant medium temperature (150 °C) process conditions. Three different samples were analyzed. Derivative samples were prepared by extracting gypsum, sulphur and amorphous/poorly crystalline iron oxyhydroxide phases from the leach residues. Thermal behavior of the samples was studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) in the temperature range 25 to 800 °C in both air and nitrogen atmospheres, with XRD analyses both before and after heating. Thermal transformation temperatures for different iron oxides/oxyhydroxides present in hydrometallurgical leach residues vary over a wide range which suggests the variable crystallinity of the phases. Raman spectroscopic analysis was carried out to help identify the type of iron phases in the residues. Furthermore, hydroxylamine hydrochloride (HaHC) and oxalate extractions were used to compare the fractionation of the amorphous/poorly crystalline iron phases in the residues. Given the compositions of the residues, any thermal events in the temperature range of 200 °C to 480 °C were attributed to amorphous/poorly crystalline iron phases.

Jan 1, 2014

By L. Szecowka, M. Poskart, Siwka M. . J.

Oxides of nitrogen, created during combustion, are the most hazardous components of atmospheric pollution. However, it is possible to limit the negative influence of hazardous components on the natural environment. An experimental appartatus was built to determine the influence of the following "primary methods" on the reduction in concentration of NOx: air staging, reburning and flue gas recirculation. The influence of the simultaneous usage of the primary methods on reduction in NOx emissions was also examined. A significant increase in the efficiency of NOx reduction was achieved in two cases.

Jan 1, 2004

By József L. Margitfalvi

Different Au/MgO catalysts modified with Mn, and Fe were prepared by precipitation-deposition. The catalysts were characterized by XRD, FTIR, Temperature Programmed Reduction (TPR) and CO chemisorption and were tested in CO oxidation in the temperature range of 243-523 K. The catalytic tests using both Temperature Programmed Oxidation (TPO) technique and time on stream (TOS) experiments revealed the high activity of catalysts prepared. In TPO experiments the modification by Mn significantly increased the activity above 300 K, however in the subambient temperature range the activity decreased considerably. Catalysts modified by iron did not show any decrease in the activity below 300 K, while the activity at high temperature increased significantly. Catalysts modified by Mn, Fe showed higher activity, selectivity and stability in preferential CO oxidation, carried out in the presence of hydrogen than the unmodified Au/MgO catalysts. Results of in situ FTIR spectroscopy on both the base Au/MgO and the iron modified catalyst unambiguously revealed the formation of ionic gold in the presence of CO/O2 mixture. The formation of this species was strongly hindered in catalyst modified by manganese. Results obtained strongly support the need for the formation of "metal ion - metal nanocluster" ensemble sites. These sites are involved in the activation of the CO molecule prior to its reaction with atomic oxygen. It is suggested that at subambient temperature these ensemble sites contain mainly ionic forms of gold, while at higher temperature iron or manganese ions are involved in CO activation.

Oct 1, 2003

By B. Surender Mohan

Mother Earth being a treasure of minerals, it is prime duty of the mankind to preserve this natural source to ensure steady growth of the nation. Utmost care is to be taken to see that these natural resources are explored and exploited scientifically in a sustained manner to ensure that the resource base improves and last longer. In this backdrop, the topic of ?Lignite - its resource and technology options to exploit deep seated deposits? is an apt subject to be deliberated upon in the present context, where the shallow deposits may slowly get dwindled. I shall deliberate upon the resource base of lignite, production profiles of the last five decades, consumption pattern, demand / supply projections, future available technology options to exploit the deep seated deposits, growth trends of the sector etc. in my paper. With the available resource base and future technology options, I can confidentially make a statement that ?lignite will remain as cocontributor along with coal to India?s energy generation and may well maintain its same status in the 21st century too, as it has been in the later part of the twentieth century?.

Aug 1, 2013