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By V. Prasad, A. Afacan, K. Popli, S. Dubljevic

Froth flotation is one of the most common and widely used separation processes in the mineral processing industry; however, its complexity means that complete understanding of the process has not yet been achieved. A dynamic fundamental model is needed to enhance the understanding of the process and to improve process control. It is challenging to capture all the phenomena involved; hence, we propose a multiscale modeling approach with a framework ranging from macroscopic (equipment scale) to microscopic (attachment, detachment) models along with distribution models for ore particle sizes. Real-time froth properties are obtained using a vision-based sensing system. These measurements can be used for developing a soft sensor for grade using statistical methods such as PCR (principal component regression) and PLS (partial least squares) regression. The fundamental model is updated in real-time using extended Kalman filtering. Attachment dynamics are studied for different particle size distributions. The modeling and soft sensing is tested on batch flotation cell for the pure mineral galena with different particle size distributions using Xanthate and MIBC as collector and frother, respectively. The model, online measurements and soft sensor are useful in developing monitoring methods for froth flotation.

Jan 1, 2015

By José Carlos Marques

This paper addresses recent calls to study the role of the state in private regulation. Using an historical, organizational-field approach, I trace and explain the evolution of public debates and interaction of different forms of regulatory initiatives dealing with Canada?s mining industry. The empirical evidence presented calls attention to the interaction amongst different regulatory forms, as well as the conditions under which the state will encourage fragmented initiatives, rather than facilitate and catalyze regulatory strengthening and consolidation. As such, my analysis: problematizes the underlying assumptions used as a starting point by the growing literature on the role of the state in private regulation; connects and juxtaposes recent scholarship to more established literature on regulatory state failure and self-regulation. I also contribute to the discussion on Canada?s CSR policy, outlining the likely regulatory effects of the current policy framework.

Aug 1, 2013

By V. V. Pankov, W. R. Chen, L. R. Zhao

Diffusion nickel aluminide and overlay NiCrAlY coatings were deposited on single crystal Ni-base superalloy CMSX-4 substrate using the chemical vapour deposition and cathodic arc evaporation techniques, respectively. The NiCrAlY coating underwent a post-deposition heat treatment in an argon atmosphere at 1100°C for 2 hours. All the coated specimens were subjected to furnace cyclic oxidation testing at 1000°C up to 1500 one-hour cycles. The morphology, elemental composition and phase constituents of the oxide scales formed on the coating surface were analyzed using scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction. It was observed that the diffusion aluminide coating experienced accelerated weight gain at an early stage of the test (150-400 cycles), whereas the overlay NiCrAlY coating fabricated by cathodic arc evaporation maintained steady-state weight gain throughout the entire 1500 cycle test duration. This difference in oxidation behaviour between the two types of coatings is attributed to the early development of nickel-aluminum spinel on the surface of the diffusion aluminide coating, in contrast to the stable aluminum oxide scale formed on the overlay NiCrAlY coating during cyclic oxidation testing.

Jan 1, 2015

By Farzad Khodabakhshi, Adrian P. Gerlich

"In this article, cold spraying process was utilized to coat the surface of AZ31 magnesium alloy with a layer of AA7075 aluminum alloy. Thereafter, friction-stir processing (FSP) was employed to enhance the microstructure and consolidate the deposited layer. The grain structure and phase morphology were studied along with indentation hardness before and after cold spraying and friction stir processing. The magnesium substrate had an initial hardness of 74 HV which increased to 102 HV after FSP due to refinement of grains to <2 µm. The aluminum coating layer, provided improved surface hardness up to 160 HV, which further increased to 173 HV after FSP was applied.INTRODUCTION Cold spray is a material deposition process which can be used for surface modification, since it deposits material on a metallic substrate with little heating by way of high velocity ballistic impacts. Using cold spray technology, it is possible to deposit a wide range of coatings with various thicknesses by controlling the characteristics of the feeding powder and metal substrate, gas temperature, gas pressure, powder feeding rate, nozzle geometry, and gun traverse velocity. This process has been recently employed for surface modification in various aircraft and automobile structural applications. This has led to a broad range of research using this process for production and modification of different metallic and non-metallic systems. In the present study, cold spray process was used to deposit a uniform layer of aluminum-zinc alloy (AA7075) on the surface of AZ31 magnesium alloy. This coating was subsequently treated by way of friction-stir processing (FSP) as a new post-spraying modification technique to enhance the structural homogeneity and densification of the coated aluminum layer. This method utilizes a non-consumable rotating tool with a specially designed shoulder and pin that is plunged into the surface of metal to be modified and then moved along the direction of interest. The localized frictional heating between the rotating tool and workpiece leads to softening of the materials around the pin, and material extrusion through a complex flow of material from the advancing toward the retreating side the tool. To the author’s best knowledge, only a few reports discuss the modification of a cold sprayed deposit by FSP process. The microstructure and mechanical properties of the cold sprayed layer and substrate before and after FSP modification were examined using optical observations (OM) and indentation hardness testing. Furthermore, the AZ31 alloy substrate alone was treated with FSP as well, for the aim of comparison to the processed coating."

Jan 1, 2017

By S. Esfahani, M. Barati

Heat recovery from blast furnace slags is often contradicted by another requirement, to generate amorphous slag for its use in cement production. As both the rate and extent of heat recovery and slag structure are determined by its cooling rate, a relation between the crystallization kinetics and the cooling conditions is highly desired. In this study, slags with different basicities were studied during non-isothermal cooling. Their continuous cooling transformation (CCT) diagram were plotted and compared with each other. Then, a mathematical model was developed that predicts the amount of crystallization during cooling. The results were validated by experiments performed by Single Hot Thermocouple Technique and image analysis. A second mathematical model that calculates temperature history of slag during its cooling was coupled with the above model, to allow optimizing the slag/air ratio for both heat recovery and slag glass content.

Jan 1, 2015

By C. Han, S. J. Zhou, Y. B. Shen, D. Z. Wei, P. Fang

"Collecting property of two hydroxamic acid collectors have different type of nonpolar structure to hemimorphite has been comparatively studied via monomineral flotation test, and the reason causes different collecting performance has been discussed from the view of relationship between molecular structure and collecting property. The flotation tests results show that C5-9 hydroxamic acid has an unbranched linear alkyl nonpolar group shows better collecting property to hemimorphite than cyclohexyl hydroxamic acid which has a naphthenic nonpolar group. FTIR detecting results show that the adsorption type of collector adsorbed on hemimorphite surface is chemical adsorption. Calculation results of polar group’s geometric structure parameters, polar group’s electron density distribution, octanol-water partition coefficient (logP) and molecular frontier orbital energy show that the key factor caused different collecting property of two collectors to hemimorphite is the logP; unbranched linear alkyl nonpolar group is more conducive than naphthenic nonpolar group to make hemimorphite particle more hydrophobic.INTRODUCTIONZinc-bearing mineral recovered from lead-zinc ores is the main source that people can obtain zinc resource from nature. However, natural sulfide ores are currently getting depleted steadily for the primary zinc source. In order to satisfy the future demand of zinc resource, there is an obvious recognition that the recovery of zinc oxidized minerals from the ores is a crucial alternative (Hosseini & Forssberg, 2007; Navidi Kashani & Rashchi, 2008).But the fact that can’t be ignored is the flotation of zinc oxidized minerals is much more difficult than that of zinc sulfide minerals, which is mainly due to the flotation characteristics of these zinc oxidized minerals such as lower selectivity and higher reagent consumption, as well as complex and variety of lead-zinc ores. Presently, there have been many various beneficiation technologies used for recovering zinc oxidized minerals and dealing with ores for recovering metallic zinc such as flotation and hydrometallurgy (Abkhoshk, Jorjani, Al-Harahsheh, Rashchi, & Naazeri, 2014; Önal et al., 2005). But from an overall perspective, flotation is the most common method used for the beneficiation of zinc oxidized minerals, and there have been extensive investigations conducted on the flotation of zinc oxide ores (Ejtemaei, Gharabaghi, & Irannajad, 2014). Until now, the most well-known method used commercially for the flotation of zinc oxidized minerals is sulfidization with sodium sulfide and flotation with a cationic collector of amines containing from 8 to 18 carbon atoms. However, a major problem for this method is the large amount of fines and slime results in the increase of reagent consumption and promotes the phenomenon of slime-coating. For preclude this negative effect, the de-sliming and processing optimization is indispensible (Peres, Borges, & Galery, 1994; Salum, de Araujo, & Peres, 1992)."

Jan 1, 2016

By Joo Hyun Park, Hyun-Sik Park

"Gold is one of the most valuable and precious metals. But, the extraction efficiency of gold from natural resources is very low and labor-intensive due to very low concentration of gold, i.e.,1–5 ppm, which means that gold extraction processes produce extensive amounts of tailings. The gold content in printed circuit boards (PCB) from waste mobile phones is about 100 to 400 ppm, which is enormously greater than the concentration found in natural ores. Consequently, processes for recycling waste PCB and gold mine tailings become of increasing importance to maintain a sustainable society. As processing these waste materials by pyrometallurgical methods has become more economically attractive, understanding the thermodynamic behavior of gold in smelting slags under oxidizing and reducing conditions has become increasingly important. Therefore, in this study, the effects of slag chemistry, oxygen potential and temperature on gold solubility in smelting slags are discussed. From the results presented, the predominant species of gold is strongly dependent on the basicity of slag. Furthermore, more basic slags showed higher solubility of gold at a given oxygen partial pressure, and more oxidizing atmospheres enhanced the dissolution of gold to the molten slag phase. As a consequence, careful control of the slag composition during pyro-processing of gold-containing waste materials is required to maximize gold recovery. INTRODUCTIONGold has good physicochemical properties. Thus, it plays an increasingly important role in industrial applications. For example, over 300 tons of gold are used annually in electronic components (Hageluken &Corti, 2010).However, 75% of all gold ever produced has been extracted since 1910 and gold reserves in the world are becoming rapidly depleted (Louis & Pluchery, 2012).The cost of gold production and its price in the market have increased rapidly during last 20 years as shown in Figure 1, and interest in the recycling of gold-containing materials has naturally increased.The wastes from electronic equipment (e-wastes) contain large amounts of precious metals compared to their own respective ores, and therefore such wastes may be considered as a secondary source of valuable metals. For instance, the concentration of gold in natural ore is commonly 0.5–15 g/ton-ore (0.5–15 ppm), while its concentration in electronic circuit boards is over 10 times higher, typically being about 150 ppm in expansion cards and over 10,000 ppm in central processing units(Barbieri et al., 2010).Also, gold mine tailings are discharged after the flotation process as slurry form then stored near the operating plants (approx. 100 ton per day in one Korean gold mine). Gold mine tailings contain gold at about 1–2 g/ton. This is the reason why Au-containing materials such as e-wastes and mining wastes are highly important sources of gold (Yamasue et al., 2009)."

Jan 1, 2017

By Eduardo R. Rodrigues, Ankur Narang, Roberto Federico Ausas, U. T. Mello, Jose Maria Segura Serra, M. R. Lakshmikantha, Ignacio Carol, Kamal C. Das

"Modeling of big faults or weak planes of strong and weak discontinuities is of major importance to assess the Geomechanical behaviour of mining/civil tunnel, reservoirs etc. For modelling fractures in Geomechanics, prior art has been limited to Interface Elements which suffer from numerical instability and where faults are required to be aligned with element edges. In this paper, we consider comparative study on finite elements for capturing strong discontinuities by means of elemental (EFEM) and nodal enrichments (XFEM) for Geomechanical applications. For general fracture scenarios, Oliver et al. (2008) have demonstrated advantages of EFEM over XFEM for including: (a) ease of modeling in any standard finite element code due to the possibility of static condensation, (b) higher accuracy in some cases for coarse meshes, and, (c) a reduced computational cost. However, there has been no work that considers cohesive fractures in Geomechanics. We present a numerical analysis based on a linear constitutive model and linear triangular elements for the bulk and a linear constitutive behaviour for the fault for a representative set of fault planes in a circular tunnel made in rock mass. In the numerical examples we consider both well-traced and bad-traced meshes. We focus on traction profile analysis for both EFEM and XFEM, since that is crucial to understand the cohesive fracture behaviour specially rock joint. Therefore in each case, shear, normal and stress ratio are compared across the two methods along the fault plane. This is the first such work that compares XFEM and EFEM behaviour for Geomechanics problems.For the considered class of problems and the sharp penalization approach without regularizations adopted, it can be observed that accuracy and robustness of EFEM may strongly depend on the fault orientation with respect to the element edges, while, XFEM is independent of fault alignment with element edges. It has been also observed that, with mesh refinement model, stress oscillation completely removed with XFEM however EFEM fails to provide oscillation free results with finer mesh in case bad-traced model. We also performed error analysis and found that in case of bad-traced mesh the average error in the XFEM is 84% smaller than of EFEM and for XFEM the error goes to zero with increasing mesh resolution, while for EFEM the error increases with mesh resolution. Thus, we experimentally demonstrate that, XFEM performs better than EFEM in terms of accuracy and rate of convergence with marginal increase in computational cost. This work hence provides novel insights on the application of XFEM and EFEM in Geomechanics."

Jan 1, 2015

By W. D. Freeborn

Slim-hole drilling and completion techniques were first used in the Cynthia area of the Pembina field, Alberta, by the Texaco Exploration Company in the summer of 1957. Prior to that time, eighty-eight wells had been drilled and completed in this area in a conventional manner. Subsequent to the initial four-well evaluation programme, twenty-one additional wells have been drilled using slim-hole techniques. No difficulty was encountered in the drilling and completion of slim-hole wells, or in obtaining production from them. A comparison of drilling and completion economics and practices has been made for slim-hole and conventionally completed wells. Penetration rates for both bit sizes (614 in. and 9 in.) were relatively equal. The shorter life of the smaller bits required the use of 15 per cent more bits per well, but the total trip time to change bits was similar for both hole sizes because of the higher hoisting speeds possible with the lighter drilling strings used in the slim holes and better hole conditions. Completion costs of the slim holes were reduced by 37 per cent as compared to the costs of conventional-type completions. This was made possible through the use of smaller well equipment, the elimination of tubing, and a reduction in rig time for completion operations.

Jan 1, 1958

By A. S. H. Kabir, I-H. Jung, J. Su, Yue. S., M. Sanjari

One of the major problems associated with conventional wrought magnesium alloys is the unwanted basal texture that forms during plastic deformation which generally does not change markedly after post-deformation annealing. Formation of precipitates on the recrystallized grain boundaries during annealing may affect the usual rotation of grains towards preferred basal direction resulting in texture weakening. In this study, Mg-Al-Sn alloy was hot compressed at 250°C and annealed at 350°C for various times. The initial as-deformed microstructure was partially dynamic recrystallized with dynamic precipitates on the grain boundaries. After annealing at 350°C, static recrystallization of the bimodal microstructure took place where at this temperature no static precipitates formed. The goal of this work was to study the effect of dynamic precipitation on the texture evolution during the annealing process. Texture evolution was studied during annealing by electron backscattered diffraction (EBSD) technique through a microstructure tracking process. It was found that precipitates on the recrystallized grain boundaries have significant effect on the usual rotation of the grains towards the basal direction, meaning significant texture weakening, which is beneficial for final mechanical properties.

Jan 1, 2015

By Marcel Vallée

"Abstract - Traditionally, the emphasis in ore and reserve inventory has been to provide fairly simple definitions and presentations for reporting to shareholders and the investing public. The recent introduction of the mineral resource category aims to take into account the "part of the deposit that cannot yet be produced or extracted legally and profitably." Recent proposals still place insufficient emphasis on relating resource/reserve reporting definitions more closely to the needs of mining and exploration operators for the estimation and inventory of these basic material assets.In most schemes, significant ambiguities and shortcomings remain. These concern the potential economic interest of resources, the concept of continuity which is fundamental to the estimation of volumes, mass and grades, the objectives of the production feasibility study and the requirements of the geology, engineering and economic appraisals leading to it, and the "availability" of the permits required to start mine development. Up to now, no industry-wide formal consensus has yet been reached for any of these steps, nor for reconciliation between successive statements.A resource/reserve inventory scheme is presented here that is based on ISO 9000 principles and the Australasian system. Explicit criteria and transition points are proposed to define resource and reserve. Similarly, appropriate criteria are proposed to classify the three mineral resource and two ore reserve categories, based on geological and value continuity and on the objectives of the feasibility study. This scheme offers a way to develop ISO 9001 certification of resource/reserve estimation procedures for mining operations and supply exploration companies with an appropriate inventory system, to allow better information for the shareholders and the investing public.Résumé - L’objectif des inventaires des minerais et des réserves est, depuis le début du siècle, de fournir des définitions simples et d’ordre général visant les actionnaires et le public investisseur. L’introduction d’une catégorie de « ressources minérales » fournira un cadre tenant compte de la "portion d’un gisement qui ne peut encore être extraite ou exploitée légalement et à profit." Cependant, les propositions récentes de systèmes d’inventaires ne comportent pas des définitions des ressources et réserves qui tiennent compte suffisamment des besoins des opérateurs en exploitation et en exploration minière.La plupart des systèmes comportent des ambiguïtés et des carences. Citons la susceptibilité d’exploitation commerciale des ressources, la continuité qui est au centre de l’estimation des volumes, masses et teneurs, les objectifs de l’étude de la faisabilité de la mise en production, le niveau requis des travaux de géologie, d’ingénierie et d’économique qui y mènent, ainsi que la disponibilité des permis dont dépend la mise en production. Il n’y a jusqu’à maintenant aucun consensus dans l’industrie sur ces points, ni sur des procédures de réconciliation entre les estimations successives.Le système d’inventaire des ressources/réserves proposé ici s’appuie sur la structure ISO 9000 et le système australien. Des critères et des points tournants explicites sont établis pour définir les ressources et les réserves. De même, les définitions des trois catégories de ressources et deux catégories de réserves, s’apparent sur la continuité de la géologie et des teneurs et sur les objectifs de l’étude de la faisabilité. Ce projet offre une voie pour développer les critères de la certification ISO 9001 pour les opérations minières, tout en fournissant un système approprié d’inventaire aux compagnies d’exploration, pour mieux informer les actionnaires et les investisseurs potentiels."

Jan 1, 1998

By F. Nava-Alonso, E. Pérez-García, A. Uribe-Salas, J. C. Fuentes-Aceituno, A. A. González-Ibarra, E. N. Castillo-Ventureño

"Precious metals cannot easily be recovered from tellurides by the standard cyanidation process. This work assesses the cyanidation of synthetic samples of precious metals tellurides and explores some alternatives for the leaching of these species (i.e. cyanidation in presence of lead nitrate and thiosulfate leaching). For this purpose, three chemical systems were studied: (1) cyanidation of silver telluride and the effect of lead (II) nitrate addition, (2) cyanidation at high alkalinity and high cyanide concentration of a gold-gold telluride sample containing tellurium and tellurium dioxide, and (3) thiosulfate leaching of silver telluride employing cupric sulfate as oxidant and EDTA as complexing agent for copper. Results showed that standard cyanidation dissolves 10.5% of silver from silver telluride in six hours, while with the addition of 100 mg/L lead increased the silver dissolution up to 100% in the same time. The standard cyanidation of the gold-gold telluride sample dissolves only metallic gold in six hours, while when cyanide concentration and pH were increased, gold and gold telluride were simultaneously dissolved. Finally, thiosulfate leaching dissolves 43.1% of silver from silver telluride in six hours.INTRODUCTION Precious metals tellurides are classified as refractory ores due to the difficulties associated with processing them by the standard cyanidation method. The increasing presence of gold/silver tellurides in some deposits around the world, specifically in Sonora, Mexico, requires new approaches to the cyanidation process, or the development of new leaching techniques. Treatments have been proposed for the recovery of gold and silver from their tellurides, including roasting, preoxidation, cyanidation with lead nitrate, and the use of leaching agents other than cyanide (Zhang, et al., 2010; Ellis and Deschenes, 2016). This work presents preliminary results of three options to recover precious metals from pure tellurides: the cyanidation of gold telluride at high cyanide concentration and high alkalinity, the addition of lead nitrate to the standard cyanidation process, and the use of sodium thiosulfate as leaching reagent."

Jan 1, 2017

By Neillm Alastair S.

"This paper looks at what has happened in the past decade in the rare earth industry, particularly for those companies outside China trying to develop alternative projects to the Chinese dominated supply chain. The rare earth industry has gone through a metamorphosis over the past decade. The industry was basically unknown outside China until overnight it became the next hot topic on the financial streets of Canada and Australia. Suddenly various junior miners shifted from uranium and other out-of-favor commodities to rare earths as funds were easy to access from an investment community that did not understand the complexities of the space. The initial funding was done on traditional junior mining metrics of grade and deposit size. This has morphed over time to:1) Lights versus heavies2) Making a concentrate3) The importance of separation4) Off-take agreementsAt the peak of the market frenzy certain flagship operations were built using the “Not Made in China” moniker. Unfortunately certain errors were made during implementation, which are finally coming to the surface and making the rest of the pack wondering what will happen next. A review and update of some of the mistakes made and lessons learned will be discussed.BACKGROUNDAbout ten years ago awareness started to form around the rare earth industry and various groups recognized that because of the closure of Molycorp, Mountain Pass, and the dominance of China, there was a risk of uncertainty of reliable supply. This was not news for those active in the industry like Rhodia (now Solvay), the Japanese, South Koreans and other key consumers but to others it was like a light went on and rare earths became the new “.com” trend for investment banks, investors and some mining companies looking for the next hot topic.In the late 1990’s Molycorp accounted for around 20-25% of the world’s supply of rare earths, mostly lights (La, Ce, Pr and Nd), with small amounts of heavies from other sources. Then environmental issues forced the closure of the operation at Mountain Pass. Within six months China had increased production to plug the gap in supply. Around that time China was developing a strategy to leverage their position in rare earths and implemented a series of regulations to increase the value added component of rare earths inside China."

Jan 1, 2016

By L. Narhi, K. Haavanlammi

"Approximately two thirds of annual nickel production is used as a raw material in the making of stainless steel, and about 60% of these nickel products are in the form of metallic nickel such as nickel cathode or briquettes. In the stainless-steel production process nickel is blended with iron and chrome-based raw materials, and metallic nickel is typically only required for final steel fine-tuning. Outotec offers a new FeCrNi technology to enhance the nickel value chain for stainless steel producers. This involves the use of an HPAL-based intermediate nickel product (e.g., mixed hydroxides or NiO) as raw material in the Outotec FeCrNi process, for the production of a FeCrNi Master Alloy. The new process, designated as the FeCrNi process, offers multiple benefits compared to existing technologies such as: higher tolerance for impurities in the HPAL intermediate product, avoiding the need for further nickel refining, and the improved recovery of all metals in the FeCr process. The complete new FeCrNi value chain is based on proven technologies such as HPAL and the Outotec FeCr-process. This new innovative and promising value chain offers improved efficiencies for the HPAL based nickel production process combined with excellent sustainability aspects.INTRODUCTION In today’s global economy there is a constant need to improve the efficiency and sustainability of the metals production. The requirements for modern metal refining are tightening and cost efficient, safe and sustainable operation is the precondition for all investment. Outotec is offering now a novel way to combine FeCr and Nickel production to create a completely new value chain to source nickel to stainless steel. BACKGROUND Nickel The current nickel mine production is in the level of 2,000 tons annually and it is split 44% from sulphide based deposits and 56% from laterite deposits (Figure 1). Most (40%) of the nickel is refined to pure nickel metal whereas other products are FeNi (19%) and Nickel Pig Iron NPI (20%) (Roskill). The remaining part, roughly 21%, is nickel chemicals and intermediates. Most of the new investments in nickel are in the direct shipping of laterite to produce nickel pig iron. HPAL process is considered in few projects but no major HPAL projects have been started since the Ambatovy plant in Madagascar. Ambatovy reached the commercial production in 2014. The main primary nickel used is stainless steel manufacturing. In the year 2016 about 68% (~1,360 kt) of primary nickel production was used in stainless steel."

Jan 1, 2017

By ByongPil Lee, Changkyu Lee, Jin Gyun Park, Hyung Sub Eom, Sung-Koo Jo, Jae-Young Lee, Gilsoo Han

"A new hydrometallurgical process for nickel extraction from a low grade laterite ore such as limonite has been developed by RIST and POSCO. This POSCO Nickel Extraction Process (PosNEP) consists of five main processes: ore reduction using hydrogen as a reductant; acid leaching at atmospheric pressure and temperature; cementation by the use of reduced-ore seed; production of the main product such as ferronickel or a high purity nickel compound; and production of by-products such as cobalt and iron in the forms of cobalt sulfate and iron oxide. In addition, hydrogen produced in acid leaching and hydrochloric acid regenerated in pyrohydrolysis for iron oxide production can be reused in the process, which makes PosNEP more cost-effective. The performance of PosNEP has been proven through pilot tests, showing that this process is economically and technically viable. In this paper, basic concepts and detailed test results of PosNEP are shown.INTRODUCTIONNickel has been extracted from two types of ore, sulfide and oxide ore. Nickel and cobalt usually occur together in the ores. The principal ore mineral of the sulfide is pentlandite, (Ni,Fe)9S8, which is easily beneficiated to produce sulfide concentrates(Moats & Davenport, 2014). These concentrates are usually treated by smelting and converting to make a matte. The produced matte is then purified through either hydrometallurgical or pyrometallurgical processes to produce high-purity nickel. In general, this process for sulfide ore has been known as a more cost-effective process than that for oxide ore.The oxide ore is laterite comprised of two different ore types, saprolite and limonite. The main nickel-bearing mineral of saprolite is nickeliferrous garnierite,(Mg,Ni)6Si4O10(OH)8, and that of limonite is nickeliferrous goethite (Fe,Ni)O·OH ore (Moats & Davenport, 2014). Since the saprolite has high contents of nickel and slag formers (MgO and SiO2) and a low content of iron, it tends to be treated by a pyrometallurgical smelting process such as calcination and electric furnace techniques to produce ferronickel for use in stainless steel. In this process, the cobalt in the ferronickel does not have any economic value."

Jan 1, 2017

By Jo Render

Expectations of your management approach ??Life of mine applicability ??Tailor scale of activity to scale of project ??Assess impacts, risks, and opportunities ??Use global good practice, backed up by rigorous analysis ??Support with trained monitoring and evaluation team ??Information infrastructure to allow ongoing trend analysis and tracking of progress ??Public reporting using standardized indicators Yes, we are talking about a ?management system?

May 1, 2011

By J. Robison, H. Pieterse, C. C. Smith, M. Luque, S. Chipman

Phase change during pressure let down releases significant amounts of energy that must be controlled to avoid undo wear and tear on equipment. Hydrometallurgical slurries require flow control equipment (valves and tanks) made of expensive materials to withstand the abrasive, and often corrosive nature of the slurry. Presented is a model of the nozzle of a let-down choke which is designed to control the flow pattern that exits the choke (valve) as it enters the receiving tank. This model can be used to design chokes which allow for the dissipation of the energy released during pressure let down by spreading the stream over a significant portion of the slurry pool in the receiving tank to minimize wear on equipment near the nozzle exit and the bottom of the slurry tank. An example uses the model to choose the nozzle expansion (area) ratio to select the outlet slurry velocity and slurry expansion angle.

Jan 1, 2004

By G. Granata, C. Tokoro, T. Kato

"The goal of this study was to evaluate the effectiveness of mechanochemical activation by planetary milling as method to enhance the recovery of cerium from rare earth ores. For this purpose, a weathered ore was first ground by planetary milling and then leached by sulfuric acid. The influence of planetary milling was investigated by assisting the experiments with X-ray absorption fine structure (XAFS) in cerium LIII-edge and inductively coupled plasma spectrometry to measure the concentration of cerium dissolved by leaching. Results showed that, by increasing the grinding time, although the particle size of the specimen increased due to agglomeration, the recovery of cerium significantly increased. This finding clearly indicated that a smaller particle size actually hinders the recovery of cerium. In particular, XAFS analysis revealed that the longer the grinding time, the more tetravalent cerium could be converted into trivalent cerium and such conversion, also called mechanochemical reaction was beneficial to the recovery of cerium. Based on the obtained results, it was confirmed that approximately 70% of cerium could be recovered by mechanochemically activated leaching of rare earth ores.INTRODUCTION Rare earth elements (REEs) are a group of 17 chemically similar metallic elements comprising lanthanides, scandium and yttrium. Since REEs have various unique physical and/or chemical properties, they have become essential materials for advanced application (Adachi, 2015). REEs used in industry are usually supplied as rare earth minerals. In the last decades, flotation, gravity separation, magnetic separation and leaching have been widely applied to recovery of REEs from rare earth minerals like monazite (Archana, Rekha, Manis, Jitendra, & Jin, 2015). Among these operations, leaching has been widely studied in the recent years to improve the state of the art (Archana, Rekha, Manis, Jitendra, & Jin, 2015; Xiao, Feng, Huang, Huang, Chen, Liu, Wang, & Long, 2016; Farzaneh, Fereshteh, & Ahmad, 2017). Aiming to enhance recovery of REEs from rare earth minerals, a possible advancement of leaching technology could be the mechanochemically activation of the ore by high-intensity milling (Alorro, 2016). In the mechanochemical activation, an improvement of the leaching performances can be achieved through high-intensity milling operations which result into a dramatic decrease of the mineral particle size with a consequent improvement of the physical kinetics of leaching. Furthermore, the high mechanical energy provided to the sample during milling can determine the rupture of the crystal structure of the mineral, thereby transforming it into a more leachable form."

Jan 1, 2017

By F. Romero

In the last four years, Compañia Minera Doña Ines de Collahuasi has been working in the application of advanced multivariate statistical techniques for the improvement of the metallurgical processes. In this paper the main conclusions for the application of multivariable analysis to the EW process are presented; including the identification of (target) process patterns according to throughput and quality criteria. Based on the process patterns, process variables hierarchies were identified by selecting the most influential ones, as well as to identify and isolate the root causes of pattern deviations and sub-standard operating conditions, cause-effect relationships were established, leading to the definition of process policies and controls to give early corrections to potential failures. The analysis was focused on cathode quality, specifically in its sulfur content, using an empirical model based on those variables that from a phenomenological and statistical stand point appeared to be the most influencing ones.

Jan 1, 2007

By J. -M. Lalancette, D. Lemieux, C. Chouinard

"A gold bearing concentrate containing 107 g/T of gold, 9.3% copper and 706 ppm of mercury was processed at the demonstration scale for the extraction of gold and copper using a cyanide free process. The concentrate was generated through flotation to upgrade the gold and copper grade, but also showed contamination with mercury. This concentrate was submitted to the DST process demonstration plant. The concentrate was first oxidized using a fluidized bed to produce a calcine. The mercury was volatilized during the oxidation stage with an efficiency higher than 98%. The mercury was condensed and removed from the sulfuric acid using a thiosulphate process. Copper was extracted from the calcine as copper sulphate using diluted sulfuric acid. The solid remaining after acid leaching was submitted to the DST chlorination process for gold extraction. Under optimized conditions, a gold extraction of 97.3% was achieved in the chlorination reactor. Gold was recovered from the pregnant brine by precipitation on silica using a DST proprietary process.INTRODUCTION Dundee Sustainable Technologies Inc. (DST) offers proprietary metallurgical processes for the treatment of material from the mining industry. DST processes enable the extraction of precious metals and for the removal and stabilization of contaminants, such as arsenic, from ores and concentrates. DST provides environmentally-friendly, viable and efficient processes, capable of handling complex and refractory ores which cannot be processed with conventional approaches due to metallurgical issues or environmental considerations. Several mining jurisdictions around the world have banned or restricted the use of cyanide. DST has developed a closed loop chlorination process as an alternative to the conventional cyanidation process for the extraction of precious metals from minerals. The tailings from the process are inert from toxic substances such as cyanide and organic compounds, are sulphide depleted which means they do not generate acid, and thus, meet and/or exceed environmental norms. The process has demonstrated excellent gold recoveries within a fraction of the time needed for cyanidation to obtain similar results. Moreover, the closed loop process does not generate any liquid effluent and does not consume much water: it only requires a water make-up to compensate for moisture leaving with the tailings and by-products, and seawater may be used. The improved environmental footprint of the DST process has been certified by the Environment Technology Validation program (ETV) which provides an independent evaluation of the performance claims of innovative technologies."

Jan 1, 2017