Search Documents

By W. M. Silva, PAP. Miotto, M. A. P. Silva, V. P. Ramos, L. R. M. Bittencourt

The major cause of breakdown of anode baking furnace fluewalls is chemical corrosion, which leads to deterioration of the properties of the bricks. Subsequent deformation of the fluewalls occurs, and also extensive cracking of the lining is observed. The present work studies the major changes of the brick during the operation of the furnace, after 22, 60 and 90 cycles of baking; in two different regions: upper and lower. Due to excellent cleaning conditions of the butts, negligible amounts of fluorine were found in the bricks. The major contaminants found were carbon, sulfur and alkali compounds, all of them present in the anode baked during the process.

Jan 1, 2004

By G. Viramontes-Gamboa

Approximately 70% of world copper reserves consist of the mineral chalcopyrite, and much international effort has focused on its study. Ultimate objectives include the development of environmentally friendly alternatives to smelting, and technologies to treat low-grade ores, for which concentration and smelting are economically unviable. Unfortunately, chalcopyrite leaching is inefficient in H2S04-Fe2(S04)3-FeS04 solutions, which is considered to be the most desirable oxidizing medium for leaching of copper sulfides, since the chemistry is well known, corrosion of industrial equipment is negligible, subsequent copper recovery by SXlEW is well established, and environmental impact is minimal. The main reason for this inefficiency is the self-passivation of chalcopyrite. We have devoted considerable effort in the understanding of this phenomenon, and have developed a predictive electrochemical methodology capable of establishing a priori the precise range of potentials within which chalcopyrite leaches and where it is passivated. Since potential control is a critical parameter in chalcopyrite leaching, this experimental methodology can be very useful for establishing the best conditions to leach chalcopyrite. In this paper, the scientific foundations of this predictive experimental technique are presented, and its practical application is demonstrated by comparing its predictions with leaching experiments from the literature.

Jan 1, 2007

By Amir Karami, Derek Kinakin, Catherine Schmid

The Mathews Stability Graph Method (Mathews et al., 1981) has been used by geotechnical engineers and mining engineers for over 40 years to estimate the performance of longhole open stopes in underground mines. The method is widely used and accepted by practitioners because it is relatively simple to use and can be modified to account for observed performance at a given mining operation. While the simplicity of the method increases its accessibility and utilization, it does not intrinsically account for variability in the various inputs, including rockmass quality, structure, stress, or stope orientation. This paper presents a modified approach for the Stability Graph Method, whereby Python scripts are used to process available geotechnical datasets and combine them with actual or potential distributions of Q parameters, induced stress, structure, or stope orientation. The resulting Stability Numbers are then plotted as a contoured distribution on the Stability Graph.  This allows the practitioner to quickly incorporate large datasets into the analyses, while also developing an understanding of how variability in rockmass quality, induced stress, structure, or stope orientation could affect stope stability.  This paper presents the fundamental principles of the Stability Graph method, the Python script and workflow, and two case studies to demonstrate the utility of the tool.

Oct 1, 2024

By A. B. Irwin

"Discussion at MeetingDR. D. DERRY (Ventures Limited) referring to the diagram (Figure 15) which shows a transverse structure section across the Central Slocan area, asked what the assumed structure at depth was, remarking that dips are steeper and more uniform at depth and that the contortions with gently-dipping axial planes are at higher elevations. He wondered whether the section represented ,part of a very large fold with steeply-dipping axial plane.MR. J. D. LITTLE (Canadian Exploration, Limited) replied that E. B. Mayo (Kelowna Exploration Company) and others had considered that the entire section illustrated faces to the southwest and represents part of the lower limb of a great overturned •syncline which is concave toward the southwest.DR. R. DEWIT (Geological Survey) remarked that the photograph of a ripple mark (Figure 7) showed internal lamination conformable to the ripple mark and wondered if the structure was not due to slumping during consolidation, since the normal mode of formation of ripple mark would seem to preclude the possibility of such internal stratification.MR. LITTLE remarked that in his opinion such structures should not be depended upon alone with-out other confirmatory evidence of the direction of tops of beds."

Jan 1, 1952

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By P .. D. Vaillancourt, D. F. Sangster

Several occurrences of disseminated galena, including a former producing mine, are found in Pennsylvanian fluviatile sandstone of the Salmon River Basin, Cape Breton Island, Nova Scotia. Detailed study of the distribution of these occurrences has revealed that highest galena concentrations are found in sandstone overlying channel-shaped depressions in felsic basement rocks. These buried depressions, in turn, correlate in position with modern streams in areas of basement exposure. This correspondence suggests that the latter are at least partially controlled by an exhumed Pennsylvanian topography. If this is correct, then several other streams in the area, lying on basement, may be used to locate possible undiscovered lead deposits in sandstones of the Salmon River Basin.

Jan 1, 1990

By W. Dresler

"A major Canadian chromite deposit at Bird River, Manitoba is one of the largest known chromite reserves in North America but it exhibits low chromium contents and low chromium to iron ratios. Commercial beneficiation techniques permit these ores to be upgraded to concentrations which, however, remain inferior to most other ores and concentrates used worldwide f or production of high-carbon ferrochromium. Analyses for reduction of low-grade concentrates by submerged-arc electrofurnace techniques predict chromium contents between 45.9% and 51% for a high-carbon ferrochromium alloy. Relatively high over-all chromium recoveries between 79.5% and 91. 1% can be achieved. Alloy compositions for Cr, Fe, C and Si are determined for various burdens with low-grade concentrates. Consumption data per ton contained chromium are obtained for electric power, coke, concentrate, quartzite and limestone. The data are compared with those of high-carbon ferrochromium producers in South Africa. Economic aspects are discussed and compared with a South African reference study.IntroductionThe present ferrochromium demand in the western world is estimated at approximately 1.7 Mt with a consumption of approximately 0.36 Mt in the U.S.III and 0.03 Mt in Canada'-', A low estimate of the installed production capacity for ferrochromium in the non -communist world is 2.4 Mt. This production capacity of ferrochromium by far exceeds the demand, which is also evident from the fact that no shortage in supply of ferrochromium to the world markets was encountered in the past. Supply-demand comparisons therefore suggest that in the foreseeable future no new chromite or chromium producers should enter the world markets unless superior chromites or superior technologies are successful in competing with existing producers. Neither one of these conditions exist presently in Ca nada or the U.S., although essentially no ferrochromium is produced and no chromite is mined in these countries at the present time."

Jan 1, 1986

By R. M. Bustin

"Extensive deposits of tectonically sheared coal of the Mist Mountain Formation occur in the south eastern Canadian Cordillera. The quality of the coal varies markedly; it is commonly partially oxidized and poor washability characteristics.Oxidation of the sheared coal has been promoted by its fine grain-size and by fractures in adjacent rocks which have facilitated penetration of atmospheric oxygen and circulation of oxygenated waters. Oxidation has resulted in a loss of coking power, a decrease in vitrinite reflectance, and an Increase In oxygen and decrease in carbon content.The relatively low clean coal yields of the sheared coal are primarily the result of the greater volume of mineral matter present, which in turn reflects both the greater susceptibility to shearing of coal with abundant rock partings and the shearing and dissemination throughout the coal of formerly discrete rock partings. The high ash content of some sheared coal seams may be artificial, resulting from the difficulty in distinguishing and separating sheared roof rock and floor strata from the coal seam during mining. There is little variation between the quality of the washed sheared and unsheared coal, with the exception of the somewhat higher ash content of the clean sheared coal compared to clean unsheared coal. This poorer separation of the ash from the organic fraction of the sheared coal is considered to be a product of the large amount of fines present as well as the local formation of aggregates of organic material and ash resulting from plastic flowage of the vitrite and clarite during shearing.IntroductionIn the southeastern Canadian Cordillera, coal seams of the Lower Cretaceous Mist Mountain Formation (Gibson, 1979 were in part sheared and comminuted during Late Cretaceous and Tertiary tectonism . Extensive deposits of sheared coal exist, and even in areas of mild deformation the coal may be locally sheared (Bustin, 1979). The quality of the sheared coal varies notably; it is commonly oxidized even far from the present weathering horizon, and locally has a disproportionately large amount of ash and poor washability characteristics even far from the present weathering horizon and locally has a disproportionately large amount of ash and poor washability characteristics."

Jan 1, 1982

By Dave N. K., T. P. Lim

"A fast, reliable and accurate method for radium-226 determination in environmental water samples has been devised, using an alpha spectroscopic technique. The correlation between barium-133 and radium-226 in the barium-radium sulphate precipitation mechanism was studied and in the limited experimental recovery range, the coefficient of correlation was r = 0.986. A self-absorption study for various barium carrier concentrations was also undertaken to obtain the least broadening of alpha energy line widths. An optimum value of 0.3 mg barium carrier was obtained for chemical recovery in the range of 85%.IntroductionWith the increase in uranium mining activities, the migration and spread of radioactivity via various environmental pathways is of great concern. Because of its inherent biological hazard and relatively long half-life, (approximately 1620 years), raidum-226 is frequently monitored as a measure of radioactive contamination of the environment. It is, therefore, necessary to modify existing methods for rapid determination of radium-226 in environmental samples for quick corrective measures in the event of seepage, dam leakage or discharge violations."

Jan 1, 1981

By John Rowson, Caitlin Brown, Kebbi Hughes, Joseph Esslifie-Dughan

The McClean Lake mill in northern Saskatchewan, Canada, is operated by Orano Canada Inc. and has been in production for the last 20 years. The tailings preparation process at the mill has been designed with decommissioning in mind, to produce tailings that are geochemically stable over the long-term within the site’s tailings management facility. Twenty years of study have contributed to a detailed understanding of geochemical and geotechnical properties of the McClean Lake tailings. Validation of the tailings properties has occurred through in-situ sampling campaigns conducted initially every year, and later every five years. Each sampling campaign has applied the same rigorous sampling procedure to provide data with useful correlations year over year. Each campaign result compares elements such as the inherent variability of the tailings, consolidation of the tailings and variations in the tailings placement methods. We will discuss lessons learned from seven sampling campaigns over 20 years and present data to show the reliable tracking of geochemical evolution of the in-situ tailings over time; providing opportunities for continuous improvements.

Jan 1, 2020

By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By R. Bonnar, R. J. McH. Clark

"The Cheminis gold mineralization zone is approximately 6.5 km west of the Kerr Addison Mine along the Larder Lake Shear Zone, in the southern part of the Abitibi Greenstone Belt. The zone is very similar in appearance to the flow ore at the Kerr Addison Mine and occurs at the same stratigraphic position. Drilling has demonstrated that the gold mineralization at Cheminis persists to a depth of over 3000 ft .The mineralization is hosted by a pyritic, tuffaceous sediment which occurs within a sequence of volcanics and sediments which have been pervasively carbonatized. The gold is largely enclosed within pyrite grains and the amount of gold in the layers of pyrite increases in the layers closest to a graphitic f ault zone.It is suggested that the gold mineralization may be primarily related to the syngenetic sulphide concentrations formed during fumarolic activity on the seafloor along the Larder Lake Shear Zone. At a later stage a hydrothermal event associated with alkalic volcanism may have resulted in regional carbonatization and further concentration of the gold in the vicinity of fault zones."

Jan 1, 1987

By B. Garitte, O. K. Mahabadi, P. Marschall, A. Lisjak, H. R. Müller, T. Vietor, G. Grasselli

Numerous research studies have shown that clay rock formations exhibit favourable characteristics for the deep geological disposal of radioactive waste. However, one main concern is that the favourable long-term isolation properties of the intact rock mass could be negatively affected by the formation of an excavation damaged zone (EDZ) around the underground openings. The goal of this paper is to present new rock mechanics insights into the phenomena involved in the EDZ formation and evolution processes in Opalinus Clay, a clay shale currently being assessed as a potential host rock for an underground repository in Northern Switzerland. More specifically, discontinuum-based computer simulations, using a hybrid finite-discrete element method (FDEM) approach, were applied to two case studies considering circular excavations in an anisotropic Opalinus Clay formation. In the first case study, numerical modelling was applied to the HG-A experiment, a long-term in-situ test carried out at the Mont Terri underground rock laboratory to investigate the hydro-mechanical response of a backfilled and sealed microtunnel. A mechanistic analysis of the fracturing processes involved in the EDZ formation was carried out. In the second case study, the long-term effect of the bentonite backfill swelling on the EDZ around an emplacement was numerically analyzed. Overall, the simulation results highlight short-term distinctive rock failure kinematics due to the bedded rock structure, as well as a long-term reduction of the excavation-induced fracture porosity in response to mechanical loading.

Jan 1, 2015

By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019

By J. E. Udd, L. B. Geller

"Responding to requests by the Canadian mining industry and the mine regulatory authorities, the Canada Centre for Mineral and Energy Technology (CANMET) undertook a major research project on evaluation of wire rope testing in 1986. The objectives were to document, analyze, and clarify - in basic operational terms the reasons for ongoing mine shaft wire rope failures that occur despite mandatory non-destructive testing (NDT) with electromagnetic (EM) instruments on a routine basis.The project's investigative scope and depth was unprecedented. It could not have been successfully completed without the wholehearted cooperation of industry, research organizations, and mine-inspectorates at both national and international levels.The project's goals were attained. II was shown that, at present, the problem areas in Canada are oj a human , rather than of a hardware-related nature. Consequently, the principal recommendations are concerned with a more widespread, more uniform and thorough operator training and certification process at industrial and regulatory levels. Secondary suggestions concern areas of hardware-related improvements.In this paper an up-to-date general overview is given of the major project results. A n extensive reference list is also provided of papers that contain all relevant documentation in detail."

Jan 1, 1992

By H. R. Manouchehri, A. Weh

"High voltage electric pulse comminution (SELFRAG) relies on inducing electrical breakdown that occurs when the resistivity of a dielectric is insufficient to completely block all transfer of electricity while the conductivity is not high enough to fully accommodate the flow of electricity without considerable changes to the crystal lattice. The technology is based on introducing the electrical discharges into solids immersed in water and placed between two electrodes. The technology has received significant attention since investigations have revealed the potential for fully fragmenting particles or pre-weakening rocks in order to reduce the energy consumption in comminution practices, improve liberation and potentially increase the recovery in mineral processing. Mineralogical analysis of samples showed possible liberation at coarser sizes by high voltage breakage in comparison with conventional mechanical comminution.This study explored the potential of implementing SELFRAG to treat the Sandvik’s Mittersill mine tungsten ore (scheelite) for recovery improvement. Accordingly, standard SELFRAG tests were conducted on four samples from the tungsten process plant to evaluate the energy-breakage relation and potential to liberate the value minerals at coarser size fraction for recovery improvement. The size reduction of the ore after processing with SELFRAG revealed that size deportment occurs at 0.4, 0.2, and 0.1 mm, which indicated potential liberation of gangue and target minerals at respective sizes. In comparison with conventional milling, the difference is the deportment of values into 0.4 mm sizes, which was, to some extent, confirmed by SEM liberation analysis. However, more tests are needed to proof the concept. The study has indicated that, despite consuming more energy in comparison with conventional mechanical comminution, there are promising prospects in liberating the values at coarser fraction and improve recovery by making use of SELFRAG. The energy consumption can be reduced through customized generator and equipment setup, which must be further investigated."

Jan 1, 2016

By Robert M. Hopkins, Craig C. Monahan

A corrosion survey was performed on ten selected H-piles which support a reinforced concrete wharf located at Trepassey, Newfoundland. Approximately 900 thickness measurements were taken at twelve different locations in each off our zones on the steel piles: the splash (atmospheric) zone, the intertidal zone, the low tide zone and the submerged zone. Results show that over the 2o-year life of the wharf, corrosion has been most severe in the splash, low tide and submerged zones with average corrosion rates for the flanges of 6.95, 9.45 and 6.86 mils per year (mpy}, respectively, and average corrosion rates for the webs of 5.13, 4.12 and 3.45 mpy, respectively. Minimal attack was found in the intertidal zone where the average corrosion rate was only 1.66 mpy on the flanges and 1.37 mpy on the webs. Such a pattern of attack is frequently observed f or steel piles partly submerged in seawater. The abnormally low corrosion rate associated with the intertidal zone is generally explained as being due to cathodic protection induced by the high corrosion rate in the adjacent low tide zone. Analysis of the corrosion data obtained for the Trepassey wharf would suggest that this explanation might be incorrect. An alternate hypothesis has been brought forward which better accounts for the extremely low corrosion rate observed in the intertidal zones of these piles.

Jan 1, 1990

By B. A. Kjarsgaard, C. J. Mwenifumbo

"Abstract - Natural gamma-ray measurements were made in the GSC Smeaton drillhole as part of the borehole geophysical classification of kimberlite pipe 169. In addition, forty samples of Cretaceous sediments (shales, siltstones, and sandstones) and thirty-five kimberlite samples, selected from the drill core, were analyzed for major and trace elements. These elements included potassium (K), uranium (U), and thorium (Th), which are the main naturally-occurring radioactive elements.Different phases of the kimberlite, and the Cretaceous sediments which show variations in the gamma-ray activity, can be easily delineated on the gamma-ray logs. The gamma-ray logs indicate that the radioactivity in the kimberlite derives mainly from Th, and, to a lesser extent, U. Most of the kimberlite units are enriched in Th and U relative to the Cretaceous sediments, and these radioelements are mainly hosted by accessory apatite and perovskite, and minor zircon. Potassium concentrations are low in the kimberlite. The higher K concentration in the sediments clearly distinguishes the Cretaceous sediments from the kimberlite.The U/K and Th/K ratios show important and distinct differences between the two major types of volcaniclastic kimberlite. Kimberlite lapillistones have higher U/K and Th/K ratios than the olivine crystal tuffs. Furthermore, standardized U/K and Th/K geophysical logs can be used to separate marine reworked olivine shoreface sands from other shallow marine sediments that contain kimberlitic detritus. The identification of different phases and/or stratigraphic facies of kimberlite on the basis of radioelement distributions means that gamma-ray spectrometry can assist exploration, particularly in regard to diamond grade distribution."

Jan 1, 1999

By T. L. Lee, D. Y. Tan, J. Mi

Considerable progress has been made in studying the mechanism and effectiveness of using ultrasound waves to manipulate alloy solidification microstructure, However, uncertainties remain in both the underlying physics of how microstructure evolve under ultrasonic waves, and the best technological approach to control the final microstructure and properties. We used the ultrafast synchrotron X-ray phase contrast imaging facility housed at the Advanced Photon Source, Argonne National Laboratory, USA to study in-situ the highly transient and dynamic interactions between the liquid metal and ultrasonic waves/bubbles. The dynamics of ultrasonic bubbles in liquid metal and their interactions with the solidifying phases were captured in-situ for the first time. The experiments were complemented by the simulations of the acoustic pressure field, the pulsing of the bubbles and the associated forces acting onto the solidifying phases, providing more quantitative understanding for using ultrasound to control the growth of dendritic grains and to enhance grain multiplication effects for grain refinement.

Jan 1, 2014

By H. K. Olsen, B. Thomassen, H. K. Schønwandt, L. Grahl-Madsen, H. Stendal

The central part of the early Proterozoic Ketilidian orogen in South Greenland consists of an I-type granitoid batholith transected by four regional NE-SW-trending shear zones. Thebatholith was probably emplaced during subduction, from the south toward the Archaean craton in the north, in a sinistral transpressional system. A regional sediment sampling program covering5000km2shows a close connection between a gold-mineralized trend and one of the major shearzones within the epizonal facies of the batholith. The gold mineralization is not directly related to the major shear zones, but occurs in quartz-veined and silicified second-order structures. High-grade(up to 114 ppm Au over 6 m) low-tonnage mineralization is found within these second-order structures cutting both amphibolites and granitoids. The mineralization is characterized by negligible or small alteration halos. Gold is associated with various element combinations of enhanced As-Bi-W-Cu, which indicate that the mineralization is mesothermal in origin.

Jan 1, 1995