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By Jun Xiao, Yucai Zhou, Yanhong Dong, Daixiong Chen

"In this article research on the mineralogical characteristics and beneficiation process for a copper molybdenum deposits in Heilongjiang province of China has been carried out. Chemical analysis, X-ray diffraction(XRD) and Quantitative Evaluation of Minerals by SCANning electron microscopy (QEMSCAN) were conducted on samples. The bulk analysis results showed that: (1) Comprehensive recovery and separation of molybdenum & copper minerals was feasible by the flowsheet of first copper-molybdenum mixed flotation after grinding the ore samples to 61.88% -74µm and then separation flotation of copper and molybdenum after regrinding the Cu-Mo mixed concentrate to 83.26% -38 µm. The results highlight relationship between mineralogical characteristics of ore and comprehensive benefication method. (2) the combination of "" Sodium sulphide and sodium thioglycolate "" reagents are effective inhibitors of copper-molybdenum mixed concentrate, their selectivity performance is better than that of single reagent. Good flotation indexes were gained that might be directive experience to similar cases. KEYWORDS Mineralogical characteristics; molybdenite; chalcopyrite; flotation separation; inhibitor INTRODUCTION Copper and molybdenum metals are widely used in the field of metallurgy, aerospace, national defence, etc. Copper –molybdenum sulphide ore is an important source of copper and molybdenum metals. At present flotation is still the preferred methods to deal with the copper-molybdenum sulphide minerals (Yin, Z., Sun, W.et al. 2017; Ansari, A., & Pawlik, M. 2007; Hirajima, T., Miki, et al. 2017). Copper and molybdenum sulphide ores usually have the similarly good nature floatability(Miki, H., Matsuoka, et al. 2017), meanwhile most molybdenum sulphide ore has tiny grained-size(Castro, S., & Laskowski, J. S. 2015.) and closed relationship with other sulphide and gangue minerals which result in the coper and molybdenum separation problem. Base on the nature of the ore and flotation properties of the individual minerals contained in the ore, there are two methods are usually used to deal with the copper – molybdenum ore, including bulk molybdenum/copper flotation followed by separation of copper and molybdenum minerals, sequential molybdenum/ copper flotation(Liu, G. Y., Lu, et al. 2012). The latter method has the shortcoming of hard to activate the depressed copper minerals in the previous molybdenum flotation process, which may result in a large loss of the copper from concentrate, this disadvantage would avoid while adopting the former method. bulk flotation followed by separation process is to get the copper-molybdenum concentrate from raw ore first then separate flotation the molybdenum and copper minerals, benefit from the excellent floatability of both molybdenum and copper minerals ( Malhotra, D., Rowe, R. M., & Bhasin, A. K. 1986; Cao, Z., Yue, et al. 2017 ), it really easy to obtain the mixed concentrate. In order to get the high quality copper and molybdenum concentrate, the key technologies and difficulties are to realize the separation of the copper and molybdenum minerals which have the very similar natural floatability (Raghavan, S., & Hsu, L. L. 2015; Nakhaei, F. 2014)."

Jan 1, 2018

By H. G. Hedlund

Tailings in Mining Industry can be handled in different ways. Today tailings disposal is in focus by projecting new plants as well as treating and handling of old Tailings dams.The trend today is to process minerals, detoxify the Tailings and place them as dry surface Deposition or Underground Backfill. This paper will briefly present five different Mining plants in North and Central America, where Tailings have to be dewatered for dry depositing. The Metso-Sala VPA is a filter especially developed for dewatering and drying of Mineral Concentrate and Mineral Tailings. Keywords: tailings disposal, dewatering, drying, mineral tailings

Sep 1, 2012

By R. Marandi

Biosorption of heavy metals can be an effective process for the removal of heavy metal ions from aqueous solutions. In this study, the adsorption properties of nonliving (boiling in NaOH) biomass of phanerochaete chrysosporium. For Pb (II) and Zn (II) were investigated by using batch adsorption techniques. The effects of initial metal ion concentration, initial pH, biosorbent concentration, stirring speed, effect of temperature and contact time on biosorption efficiency were studied. Experimental results indicated that the uptake capacity and adsorption yield of one metal ion were reduced by the presence of the other metal ion. In the experiments the optimum pH value was found out 6.0. The experimental adsorption data were fitted to the Langmuir and Frundlich adsorption models. The highest metals uptake was calculated for Zn (II) and Pb (II) were 57 and 87 respectively. desorption of heavy metal ions was performed by 50 mM HNO3 solution. The results indicated that the biomass of p.chrysosporium is a suitable biosorbent for removing heavy metals ion from aqueous solution.

Jan 1, 2014

By L. Kuzev

Unknown and unpopular vibrational grinding mills possibilities to horizontal working chambers have been discussed. They can be realized under normal conditions with the typical values of vibrations applied with vibrational grinding which are: vibration frequency from 15 Hz to 50 Hz, vibration amplitude to 6 mm and vibration geometry. These possibilities constantly increase involving new raw materials and processes. Vibration grinding is possible with other technological process accompanied by intensified technological processing, while the process decreases. In many cases these technological decisions are original.

Jan 1, 2014

By T. Fraszczak, U. A. Peuker, T. Mütze, T. Leißner, A. Wikedzi

The present paper highlights on the comminution and liberation properties of two greisen-type lithium bearing-mica ore blends (L1, L2) subjected to different breakage devices; cone crusher (CC), roller crusher (RC), rotor beater mill (RBM) and a screen mill (SM). The particle size distribution (PSD) of the products from each device were evaluated to search for an appropriate PSD model using Gates-Gaudin-Schuhmann (GGS) and Rosin-Rammler (RR) functions. In order to determine an appropriate function that could better describe the PSDs from the devices used, the coefficient of determination (R2) was used as a criterion. In terms of mineral liberation studies, due to costs, only products from rotor beater mill (RBM) were examined through an automated scanning electron microscope (SEM) technique. It was found that RBM, RC and SM products were better described by the RR model than the GGS model with higher R2 values (0.97-1.0). However, cone crusher products for L1 were better described by GSS model, while that for L2 were better described by RR model. In terms of the spread of size distribution as indicated by RR model parameters, RC products were more uniformly distributed compared to products from other devices, for both ore blends. Also the RBM products were more scattered than products from other devices. The results indicate that the composition of individual ore blends affected the comminution products PSDs since different PSD model parameters were obtained for samples comminuted by same devices. The modal mineralogy of the two ore blends indicate both to be rich in quartz, topaz, zinnwaldite and muscovite. Further, the result indicate that, for both ore blends, zinnwaldite phase is more enriched in the fraction < 250 µm. Moreover, better liberation of zinnwaldite is observed for L1 compared to L2. This could be explained by differences of the two ore blends in three aspects; the nature of mineral association, reduction ratio of the fractions analysed and the nature of spread of the size distribution.

Jan 1, 2018

By F. Ngoroma

Concentrators processing PGM bearing ores make use of polysaccharide depressants to reduce the recovery of the undesired naturally floatable gangue minerals, mainly silicates, present in the ore. Recent work has shown that high depressant dosages can completely depress naturally floatable gangue and thus prevent it from reporting to the concentrate. These high depressant dosages can, however, have a negative effect on the recovery of valuable minerals present in the ore by reducing the stability of the froth. In order to counterbalance the effects of depressant addition, frothers are added. It is, however, preferable to maintain independent control over bubble size and froth stability which is difficult to achieve with only one frother. An alternative strategy is, to use a blend of frothers, e.g. a weaker frother in combination with a stronger frother. Such a system allows an additional degree of freedom: changing the ratio of the two frothers, that would provide more independent control of bubble size and froth stability. This study demonstrates, through the use of batch flotation tests, how blending low molecular weight alcohols with commercially available frothers impact the solids and water recovery, as well as the valuable mineral recovery and concentrate grade in different PGM ores. Higher water and solids recoveries together with higher valuable mineral recoveries (>90% copper and >70% nickel) were obtained from tests using frother blends.

Sep 1, 2012

By W. M. Zeng

A mixed culture of moderately thermophilic microorganisms was enriched from Acid Mine Drainage (AMD) samples collected from several chalcopyrite mines in China,which can leach copper from chalcopyrite effectively. Its tolerance to chalcopyrite was brought up to 80 g/L after being adapted to gradually increased concentrations of chalcopyrite. The effects of several leaching variables on copper recovery in Stirred Tank Reactor had been investigated. The ore contained chalcopyrite (62.2%) and galena (25.6%) as the main sulfide minerals. The results of the tests show that it is possible, operating at 8% of pulp density to attain copper extraction of 75% in 44 days. The leaching rate of chalcopyrite tends to increase with the dissolution of total iron. Microscopic counts of microorganisms in the solution tend to be higher at low pH range. Furthermore, the analyses of leached residues indicate that the passivation of this chalcopyrite is mainly due to the formation of a mass of jarosite and anglesite (about 48.3% and 21.7% in residue respectively), other than elemental sulphur layer. The bacterial community composition was analyzed by using amplified ribosomal DNA restriction analysis (ARDRA). Two moderately thermophilic bacteria species were identified as Leptospi-rillum ferriphilum and Acidithiobacillus caldus, with different proportion in the bio-pulp, 67% and 33%, respectively.

Jan 1, 2014

By P. Bevilacqua

In this paper the possibility to complete the copper recovery and to enrich in PVC a mixture of plastic granules obtained by grinding electrical cables are investigated. The recovery of a large part of the copper still present among the plastic granules was possible by means of a mechanical screening, the finer polymeric fraction was collected, at the same time. In order to complete the copper polymer separation the following techniques were employed. Counter current separation in water, static dense medium separation with zinc chloride solution and copper extraction with nitric acid and subsequent electrolytic deposition. A Tri-Flo® dynamic dense medium separator was employed in order to separate the lighter polymeric fraction, from the heavier polymeric fraction, mainly PVC. Water or a salt-water solution was employed to feed the separator device.

Jan 1, 2014

By A. S. Chekmarev, T. Z. Lygina, K. G. Egorova, A. V. Skvorcov

"We have conducted analytical and technological evaluation of sepiolite containing clay. The possible areas of application of the sepiolite have been investigated and complex methods of enrichment of natural sepiolite have been identified. It was determined that for preserving the structure of minerals after processing the most effective method of the natural agglomerates disintegration was the soft abrasion of the clay fraction up to 0,5 mm. Disintegration of sepiolite clay along with using high energy-stressed effects on the matrix can deteriorate the rheological properties of clay suspensions and reduce the yield of drilling mud and sorption properties. To improve the quality of clay powders we used combined gravity-modifying method of wet enrichment. After the wet enrichment the yield of drilling mud increased up to 12.7 m3/t, with the addition of MgO up to 20,3 m3/t. It was noted that drilling muds contenting more than 50% of sepiolite are stable in mineralized (salt) waters. Based on the studied activated sepiolite rocks we obtained the effective heat-insulating materials with relatively low thermal conductivity – 0,165 W/m·K, average strength – 7,29 MPa and water absorption-49,0%.INTRODUCTION The modern development of the Russian economy requires the implementation of scientific and technical tasks. The solutions of it involves a radical reduction in energy, heat losses and material consumption of products, rational and efficient using of all types of resources, as well as the using of new types of mineral raw materials and materials based on it. An example of a new type of mineral raw materials for Russia is sepiolite containing rocks, due to unconventional conditions for their soils accumulation in the climate of the Far North. Sepiolite is a unique type of nonmetallic mineral. It is formed in soils, marine and saline basins, occurs in carbonate and carbonate-clay rocks in the form of lenses and lens – shaped layers, rarely nodules, loose powdery masses, shell-like concretions. Sepiolite may have a soft porous macroscopic appearance or less often the structure of the fibrous mass. Color of sepiolite is from white to cream with gray, green, pink and even crimson shade depending on the degree of pollution. Sepiolite can be in two forms - a-sepiolite (parasepiolite), which occurs in the form of large packets of crystalline fibers and ß-sepiolite, which occurs in the form of amorphous aggregates or small flat rounded particles. The sepiolite fibers have a length of from 0.2 to 2 Å, width from 100 to 300 Å, the thickness from 50 to 100 Å (Geological dictionary, 1973)."

Jan 1, 2018

By M. Taheri

Multiple Attribute Decision Making (MADM) method is applied to select tailings site of the Gol-e-Gohar Iron Ore Processing Plant in the Kerman province, south-eastern of Iran. To select tailings site, screening is applied on eight location proposed by Binnie and Granges. Consequently three sites identified for further studies. Evaluation factors include only the most important factors such as efficiency ratio, elevation and distance to processing facilities, occurrence of faults and fractures. Crisp values such as efficiency ratio, elevation and distance can be determined by measurements and calculations, but some factors such as occurrence of faults and fractures are presented as linguistic values that can be described with triangular fuzzy numbers. Based on evaluation values obtained an optimal tailings site can be selected using a modified Technique of ranking Preferences by Similarity to the Ideal Solution (TOPSIS) given crisp data and linguistic variables as the alternatives of attributes. Each attribute?s weight is assigned using the analytic hierarchy process. The final ranking order aids in the selection of tailings site. Finally, the stages of modified TOPSIS method were applied and site No.2 situated in 5400m to the mill was selected as the best alternative.

Jan 1, 2014

By E. L. Chanturiya

During the mineral processing of pyrites sulphide ores of some deposits of Russia loss of gold with tailings and pyrite concentrates amounts up to 40%~90%. The problem of selective allocation of gold-bearing pyrite is crucial. There are 4 mineralogy-technological groups of pyrite determined in copper-zinc sulphide ores, based on the increase of contents of gold in pyrite. The gold associated with group 4 pyrite contents of 85% the total mass of gold found in the pyrite. The flotation behaviour of the enriched fractions of pyrite (98%), of the allocated from the ore of Gay deposit, were studied essentially in various conditions ?? and the charge of Butyl xanthogenate of potassium (ButX). Some products of selective pyrite flotation were investigated by methods of scanning electronic microscopy, energy-dispersive and X-ray spectral microanalyses, definition of specific resistance and thermoelectric moving force.

Jan 1, 2014

By Z. G. Li

The large-scale vibrating screen has been applied widely in coal industry and other industrial areas as a kind of important device. As vibration mechanical device, it works very hardly and works in very bad environment so that the structure of screen is damaged easily. Therefore, it is very important that how to detect the fault of structure as early as possible to make the repair schedule reasonably and economically and to avoid the body hurt and device damage. As a kind of important structure of vibrating screen, the lower crossbeam is the main carrying structure and it is easily damaged, so it is regarded as a researched object in this thesis and it is tested under the load in the laboratory. Based on the test, acoustic emission wave signals can be got-ten by modern acoustic emission testing technique. Then, the ?wavelet packet - energy? from the characteristics of acquiring signals is used as neural network input vector. In the BP network structure design, the design of a hidden layer with variable number of BP network is established. Based on the error by contrast, the best nerve number can be identified in the hidden layer. Through integrated analysis, using Levenberg-Marquard BP study algorithm, network-training errors are relatively small, the acoustic emission signal is used in BP neural network as a pattern of recognition. In Matlab6.5, neural network model identification is created and taking advantage of nonlinearity and the ability of learning and memory of Neural Network, this model is fixed by training structure of network with training samples. The work presented shows that acoustical emission signal processing and research on early fatigue fault diagnosis based on the wavelet and the neural network is viable.

Jan 1, 2014

By S. H. He

This paper focuses on the influence of pulp oxygen content on the separation of pentlandite and pyrrhotite contained in two different process streams in the Clarabelle Mill, operated by VALE INCO. The two process streams are (i) the scavenger cleaner feed, the product of regrinding the thickened, scavenged concentrate and the B cleaned tail produced from treating the non-magnetic fraction of the milled run of mine ore, and (ii) the magnetic concentrate which is the magnetic fraction of the milled run of mine ore. In the Clarabelle Mill, sulphite (SO32-) and TETA (triethylenete-tramine) are together used to selectively depress pyrrhotite from pentlandite. These depressants pre-ferentially decompose collector and/or sulphur enriched species at the pyrrhotite surface, an appar-ently essential mechanism in pyrrhotite depression from the scavenger cleaner feed stream. Selectivity in depression may originate from differences in the electrochemical rest potential of pyrrhotite and pentlandite. As both minerals are susceptible to oxidation, aeration in conditioning and flotation plays a key role in selective flotation. Important differences in the flotation behavior of pentlandite and pyrrhotite from the magnetic concentrate and the scavenger cleaner streams are highlighted in

Jan 1, 2014

By C. H. Zhou

Cryogenic grinding of Printed Circuit Board will bring less pollution, reduce energy costs, smaller particles, regular particle size, efficient process, separation various materials due to different fracture toughness. Systemic studies of recycling discarded Printed Circuit Board (PCB) by low-temperature modification and cryogenic grinding have been made in this paper. Firstly test mechanical property of PCB at different low-temperature, including impact strength, flexural strength, and shear strength. Do experiment on the power consumption of different cooling temperature, The results show that the average power consumption is lower between -30? to -60? and the average power is decrease in evidence at -30?. Use ZKB type double roll shear crusher to crush PCB to 20mm×20mm particle size, in a temperature range of -10 ~ -30? Used R type mill to grind sample to minus 3mm under different working condition, the average power consumption is decrease in evidence from -10 ? to -30 ?, power consumption is the lest at rotational speed is 1180rpm.

Jan 1, 2014

By M. Roy

Coke combustion during sintering process is significantly governed by coke breeze size distribution, which in turn affect sinter quality i.e. sinter granulometry, Tumbler index, Reduction Degradation Index and Reducibility Index of sinter. To know the effect of microfines of coke breeze on sintering process parameters, pot sintering tests were conducted and it was found that when microfines are eliminated and optimum coke size (1-3mm) is used yield of sinter increased by more than 7%. Similarly productivity increased by 9%, the strength of sinter i.e. ISO Tumbler Index increased by 2.3% and +10mm sinter size increased by 5.5%. Controlling of microfines during crushing and by improving crushing index will result in improved quality and productivity of sinter with lesser amount of coke breeze. This paper describes that how to optimize solid fuel i.e. coke breeze consumption in sintering process through granulometry control. Keywords: iron ore sintering, coke breeze granulometry, productivity of sinter, quality of sinter

Sep 1, 2012

By In-Kuk Bae, Kwang-suk You, Joobeom Seo, Kwanghyun Bea, Hyung-Seok Kim

Arsenic in base metal sulfide ores is highly penalized owing to high costs for its control in metallurgical processing. The arsenic element in the lead-zinc ore, which is target ore in this study, has been shown to be in the form of arsenopyrite. Experimental work in this study is about arsenic rejection flotation, using depressant suitable for the removal of arsenopyrite from the Pb concentrate. The arsenic rejection flotation also included the oxidation treatment of Pb concentrate with H2O2. In this study, the Pb concentrates containing 80.7% Pb and 0.25% as was obtained with the additions of aluminosulfate as arsenic depressant. And through IR measurement, it was also known that the addition of aluminosulfate during arsenic rejection flotation formed calcium aluminosulfate hydrates on the surface of arsenopyrite particle, resulting in rendering arsenopyrite hydrophilic.

Jan 1, 2014

By D. Z. Wei

Amine collectors with different structures and length of carbon-chain have been widely used in oxide minerals flotation. In this paper, we synthesized one kind of binary amine, N-dodecylethyl- enediamine, and studied its flotation performance. From the results, we can see N-dodecylethylenediamine which has excellent frothability, is a new type of chelating surfactants. And it also has fine catchability to quartz and hematite. The recoveries of quartz and hematite increase with the augment of N-dodecylethylenediamine concentration. When the dosage of collector reaches 100g/t, the recoveries of quartz and hematite achieve 95.30% and 87.89% respectively. Meanwhile, the influence of pH on the flotation recovery of hematite is studied and test results showed that, as pH increases, the flotation recovery rises until pH=9. And the recovery reaches its maximum in alkalescence. The collector has better flotation capability to quartz than to hematite. And the maximum recovery of quartz is gained in alkaline media, which reaches 97.87%. Finally, the flotation mechanism of N-dodecylethylenediamine is discussed through the measurement of infrared spectroscopy.

Jan 1, 2014

By C. L. Xiao

With reference to the test report carried out by Guangzhou Nonferrous Metal Research Institute in 1983, the mineral process flow sheet of Yichun Tantalum-niobium mine is determined based on the characters of ores and successful experiences in light of the problems in the existing flowsheet: The ore is desilted before crushing; the primary slime is separately treated; the staged grinding process used while the fine slime is collectedly treated with tantalum and niobium as the main recoveries and lepidolite and feldspar powder as the secondary. The flowsheet is featured by comprehensive recovery, low investment and low energy cost.

Jan 1, 2014

By I. D. Ustinov, V. A. Arsentyev, A. O. Mezenin, A. M. Gerasimov

"The solid mineral raw materials of the sediment deposits containing the argillaceous variations such as the coal and the potash ores are the most multi-tonnage solid minerals mined and processed in the territory of the Russian Federation. Both types of the deposits have relatively simple geology aspects with large and medium-sized solids and as a rule, the most often, with the regular bedding which are characterized by the fitchery thickness and the internal structure. Such deposits are very difficult for mining and processing. The thermal modification of this of ores allows changing the physico-chemical properties of its components in such a way that their further processing - grinding, separation, transportation and storage can be carried out without the use of process water or significantly reduces its consumption. The purpose of the present study is to increase the efficiency of the mineral processing containing the layered aluminum silicate by reducing their negative impact on the basic dressing processes, the separation of suspended matters and the storage of waste. INTRODUCTION Many deposits of minerals are associated with the presence of layered silicates such as the argil, mudstones, argillaceous slate - highly hydrophilic mineral varieties which have the ability to swell in the water. This ability to self-disperse creates the great difficulties both for the extraction and the processing of such ores. Since the dressing of most minerals is associated with the use of wet processes, where in contact with water the swelling layered silicates are dispersed to a particle size of less than 50 µm, but due to their high hydrophylic property they form bonds that promote the formation of so-called structured suspensions having increased viscosity. In this case the structured suspensions make it difficult to perform the separation operations as the classification, the gravity and magnetic separation, the flotation and thickening and filtration operations."

Jan 1, 2018

By Azin Zangooi, Cesar Gomez, James Finch

Frother concentration is a variable which significantly affects the flotation performance by decreasing bubble size and helping froth stabilization. Variations in frother concentration, which mostly go unnoticed in industrial operations, may affect these functions. Some factors that can cause variations include the fact that frothers are normally dosed based on feed tonnage and not solution concentration, unstable frother delivery, incomplete dissolution for low solubility frothers, addition of frother-free wash water, remnant frother in recycle waters and frother partitioning to the froth. A colorimetric technique developed for determining frother concentration on site makes it possible to detect the occurrence of these problems and to establish their magnitude, allowing conditions to be adjusted to reduce frother concentration variations. By sampling and analysis, frother distribution throughout a circuit can be established, referred to as ‘frother distribution mapping’. Experiences at several concentrators processing sulphide ores are used to illustrate time restrictions for sample analysis, and to demonstrate temporal and spatial frother concentration changes as a consequence of variations in the grinding stage, recycled waters containing frother, and frother partitioning.

Jan 1, 2014