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By L. Y. Wang

In order to produce the iron and steel products with high quality and decrease the output of steel tailings, the quality of molten iron is a critical factor for iron and steel companies, especially the content of sulfidic in molten iron. Hot metal pre-treatment, an important and effective method to desulphur, is widely used in steel production. Millions of tons of slag from desulphurization and slag skimming are produced each year in China, and many more times this amount is stored in slag dams because of the lack of effective means to deal with it. In order to achieve the goal of sustain-able development, recycling these slag becomes necessary. The main objective of this paper is to study the composition characteristics of slag that from desulphurization and slag skimming. The sample was obtained from Anshan Iron and Steel Group Corporation, processed by hot metal pre-treatment. In this study, the chemical components and the mineral compositions of sample were tested. The results of chemical components and iron chemistry phase analysis showed that the iron and sulphide content in this sample were high, and the iron products existed mainly in the form of magnetite, metallic iron, ferrosilite. X-ray diffraction (XRD) and scanning electron microscope (SEM) results indicated that the sample included metallic iron, ferrate, wustite, metasilicate, aluminate, aluminosilicate, white lime and soon. Grading magnetic separation test work showed that magnetic separation was an effective method to recovery iron products and decrease the sulphide content in concentrate, and the tailing could be used as the raw material or padding in cement production.

Jan 1, 2014

By L. Gutierrez, M. Jeldres, R. J. Jeldres

"Clays are present in a large number of mineral deposits and are commonly found as gangue. Its complex chemical structure, characterised by anisotropic surfaces, makes its presence a permanent challenge for flotation operations, increasing the reagent consumption, decreasing the quality of the concentrate, and changing the rheological properties of the system. In this context, the main objective of this research is to improve the floatability of chalcopyrite minerals in the presence of clays by using guar gum, a low molecular weight organic polymer, which acts as a surface coating agent for clays. Clay Minerals Society provided the kaolinite sample and the chalcopyrite sample was purified from mineralized rock specimens obtained from Ward’s Natural Science Establishment. Micro flotation tests were carried out in a 150 cm3 Partridge-Smith cell, using compressed air as the gas phase at a flow rate of 80 cm3/min. Potassium amyl xanthate (PAX) and methyl isobutyl carbinol (MIBC) were used as a collector and a frother, respectively. The results showed that the use of guar gum improves the recovery of chalcopyrite in the presence of kaolinite because it induces the formation of clay aggregates that settle by gravitational effects, preventing the 'coating effect' and decreasing excessive collector consumption. pH played a key role in the guar gum performance, which was most effective at highly alkaline conditions (pH 11), where the copper recovery improved from 73% to 90%. The work has significant implications for the mineral flotation in the presence of clay minerals.INTRODUCTION The mining industry is continuously confronted with challenges that alert the sustainability of the sector. There is little availability of water, the grade of the deposits are getting smaller, and the gangue is becoming more complex. Usually, clays are part of the gangue in numerous systems, including copper ore, porphyry, nickel, platinum, etc. (Senior & Thomas, 2005). The structure is mainly composed of layers of tetrahedral silica (T) and octahedral alumina (O) that join in certain proportions: 1: 1 (T-O) and 2: 1 (T-O-T) (Theng, 2012). Also, they expose two crystallographically different surfaces: the faces, which tend to be negatively charged, and the edges, which carry a charge that changes from positive to negative depending on the pH (Van Olphen, 1977). One of the most common clays in copper deposits is kaolinite, whose structure is composed of an octahedral sheet of gibbsite bound to a tetrahedral silica sheet in the ratio 1:1"

Jan 1, 2018

By Xianjun Lyu, Junxiang Wang, Peng Wu, Minjie Lian

"In recent years, the efficient cementation of mine tailings is a new way to manage mine solid wastes. The traditional cement materials have a slow setting time, large dosage and poor cementation strength for fine aggregate such as mine tailings. Therefore, the preparation of new type cementitious materials for the cementation of fine tailings has great potential in the treatment of mine waste solids. The paper mainly focuses on exploring the critical factors affecting the cementing performance of granulated blast furnace slag and its performance in the cementation of fine aggregate. Results indicate that the fineness of slag has a significant effect on its cementitious activity and Portland cement clinker has a better stimulation effect on the cementitious properties of slag than lime. And, anhydrite has a better early stimulation effect on the cementitious properties of alkali-activated slag compared to semi-hydrated gypsum and dihydrate gypsum. According to a series of tests on the cementation of fine iron tailings, the optimal ratio of slag, Portland cement clinker and anhydrite is determined as 60:30:10. Compared with P.O 42.5 ordinary Portland cement, the new slag based cementitious material shows much better cementing performance on fine tailings sample. Under the dosage of 12%, the compressive strength of fine tailings mortar using slag-based cementitious material in 3 curing days is increased to 168% that of using P.O 42.5 ordinary Portland cement, while the compressive strength in 28 days curing period is increased to 194%."

Jan 1, 2018

By Qiuyang Hong, Bo Li, Dongyun Liang

"A weathering-crust niobium-rare earth-bearing deposit is formed by the weathering alterationof alkaline granite, which is refractory due to its low grade and complex properties. The mineralogicalcomposition of ore, the grain size of majorminerals as well as the occurrence of Nb and REE are studied in this paper using MLA combined with traditional methods. According to the results, a wide range of Nb-Ti-REE compound minerals including titanoniobite, uranpyrochlore, chlopinite, samarskite and ilmenorutile areformed for the extensive isomorphous substitution among the elements of Nb, Ta, REE, Fe, Ti, U and Th. The occurrence of REE is extremely complex. First, the REEexistingas rare earth minerals including monazite, xenotime, bastnaesite,etcaccount for 21%. Second, the REEexist in the lattice of Nb and Zr minerals as isomorphous additions, which account for 18%. Third, the REE exist as colloidal rare earthdeposit,which account for 35%. Last, the REEexistingas ion-adsorption-type rare earth,which are adsorbedon the kaolinite in the form of hydrated hydroxyl ions, account for 26%.Based on the results of mineralogy, the combined technology process "mineral processing- hydrometallurgical separation" is needed to deal with the ore. The mineral processing tests show that, for the feed ore containing Nb2O5 0.065%, REO 0.13%, an Nb-REE concentrate containing Nb2O5 1.38%, REO 1.98% can be gained by "high intensity magnetic separation-regrinding-gravity separation by shaking tables". The recovery of Nb2O5 and REO is 62.42% and 44.78% respectively. The Nb-REE concentrate is dealt by the metallurgy process "direct reduction- acid leaching & acidulating- neutralization & precipitation- chlorination & distillation" and the rare earth oxide of 92.34% REO as well as the Nb-Zr oxide of 24.62% Nb2O5 can be obtained with the recovery of REO and Nb2O5 being 76.83% and 59.37% respectively."

Jan 1, 2014

With shortage of sulfide nickel ores, laterite ore was paid more attention by scientists. Because its grade is commonly lower than sulfide nickel ores, laterite ore can not be utilized effectively be-coming the bottleneck of study. Leaching laterite ores from Yuanjing, Yunnan province, organic ac-ids show better selective than sulfide acid in nickel and cobalt recovery. Organic acid has low de-pendent on pH, keeping leaching capability even higher than 3. On the other side, when pH up to 2, sulfide acid can not leach laterite ores any more. After four kinds of organic acid leaching laterite ores, besides citrate, malate and succinate have good leaching and effectively selective capability. Especially, succinate has the best selective leaching capability of nickel and cobalt in four kinds of organic acids for latter anion purification and separation. Isolated from waste water with sugar, Aspergillus niger (zs1) has great capability to produce organic acids and vigorous growth. Laterite ores have been respectively processed by direct-leaching and indirect-leaching. Indirect-leaching gives a better result than direct-leaching. Extraction of nick-el by indirect-leaching reaches 44.3%, far more than that of direct-leaching. Moreover extraction of nickel at pulp density of 5% is higher than that at pulp density of 10%, reaching 63% in 11 days and extraction of cobalt also is 48.1% in the same period. Compared with nickel and cobalt, iron gives low extraction in solution, containing organic acids produced by Aspergillus niger .

Jan 1, 2014

By Graeme Heyes, Warren J. Bruckard, Michael A. Somerville

"Over the past few years CSIRO Minerals has been conducting research aimed at developing a continuous copper converting process to replace the traditional two-stage batch process that is currently used to produce blister copper. Sirosmelt type reactors and calcium-ferrite (lime-based) slags have been used rather than the conventional iron silicate slags. The research work has now been extended to focus on the development of a single-stage continuous copper making process (so-called direct copper converting) in which copper concentrates are converted to low-sulfur blister copper in a single step, that is the smelting and converting steps occur in one continuous stage.One feature of the direct copper converting process is that copper losses to the slag phase can be high, meaning the slag produced needs to be treated to recover the copper value. The feasibility of the whole copper making process will most likely depend on the efficiency and cost effectiveness of the copper recovery stage. Flotation has been identified as the most economical option to recover the copper from direct copper converting slags where it has been estimated that a copper recovery from the slag of above 90% is required to make the overall single stage copper making process economically feasible.A limited series of laboratory batch flotation tests was conducted on a suite of calcium-ferrite-based slags made in laboratory smelting trials. Copper sulfide concentrates from MIM were used as feed-stocks. The objectives of this work were to develop a robust flotation process to maximise the copper recovery and iron rejection from slags made in the process, and to establish operating conditions for future continuous flotation pilot plant trials.The slags treated included a reduced low copper slag, an oxidised high copper slag composite, and a very reduced low copper self-pulverising slag. The copper content of the slags varied from 2.9% to 14% Cu and the CaO/Fe ratio varied between 0.30 and 0.54. In general, the higher the copper content the more oxidised the slag. The copper was present as metallic copper, oxide copper and copper-calcium ferrite phases with the phase mix related to smelting conditions. The slags were crushed, ground, wet-screened at 355 or 210 µm to remove coarse metallic particles of copper, and floated at natural pH (about pH 11) using reagents and conditions appropriate for the selective recovery of the copper phases. Reagent additions were typically 200 g/t KEX and 500 g/t Na2S.9H2O and the grind size was generally a P80 of about 40 µm."

Jan 1, 2003

By Alireza Javadi Nooshabadi, Kota Hanumantha Rao

Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by sulphide minerals during grinding was examined. It was found that pyrite (FeS2), chalcopyrite (CuFeS2), sphalerite ((Zn, Fe) S), and galena (PbS) generated H2O2 in pulp liquid during wet grinding and also when the freshly ground solids are placed in water immediately after dry grinding. Pyrite produced more H2O2 than other minerals and the order of H2O2 production by the minerals was found to be pyrite > chalcopyrite > sphalerite > galena. The pH of the water influenced the extent of hydrogen peroxide formation with greater amounts of H2O2 produced at highly acidic pH. Furthermore, the effect of mixed sulphide minerals, i.e., pyrite-chalcopyrite, pyrite-galena, chalcopyrite-galena and sphalerite-pyrite, sphalerite-chalcopyrite and sphalerite-galena on the formation of H2O2 showed increasing H2O2 formation with increasing pyrite fraction. There is clear correlation of the amount of H2O2 production with the rest potential of the sulphide minerals; the greater the rest potential of a mineral the greater the formation of H2O2. This study highlights the necessity of revisiting the electrochemical and/or galvanic interactions between sulphide minerals, and interaction mechanisms between pyrite and other sulphide minerals in terms of their flotation behavior in the context of inevitable H2O2 existence in the pulp liquid.

Jan 1, 2014

By T. Suzuki

Acid leach liquors from spent lithium-ion batteries employing lithium cobalt dioxide (LiCoO2) as a cathode active material contain valuable metals such as cobalt and lithium, as well as common metals such as aluminum and copper. The objective of this study was to develop a hydrometallurgical process providing a high selectively between aluminum, cobalt, copper, and lithium from hydrochloric acid solutions. Batch experiment results showed that selective hydroxide precipitation approach was not suitable because a significant amount of cobalt and lithium was co-precipitated with aluminum and copper hydroxides. In contrast, batch experiments and the subsequent data analysis indicated that the sequence of solvent extraction circuits using PC-88A, Acorga M5640, and tri-n-octylamine (TOA) extractants effectively separates four metals of interest. In the first circuit of the proposed process, copper was selectively extracted by Acorga M5640 at the pH 1.0-2.0. Aluminum, cobalt, and lithium remain in the aqueous phase. In the second circuit, aluminium is selectively extracted by PC-88A at pH 2.0-2.5. For the separation of remaining cobalt and lithium, Acorga M5640 provided higher separation efficiency compared to PC-88A single extractant and PC-88A/TOA mixed extractant. However, the stripping efficiency of cobalt from the Acorga M5640 organic phase was found to be low (less than 10 %). Therefore, PC-88A/TOA mixed extractant rather than Acorga M5640 is an advisable choice for the separation of cobalt and lithium. Keywords: spent lithium-ion secondary batteries, solvent extraction, lithium, cobalt

Sep 1, 2012

By J. Faitli

The Lake Balaton is the biggest and for many reasons the most important lake in Hungary. To preserve its healthy nature it is necessary to remove the accumulated mud time to time, similarly to the many living waters, lakes and rivers everywhere. Typical existing technologies (mechanical, hydraulic) require large depositional areas, where the removed slurry and mud is dewatered through very long time. One problem is the non existence of an economical mud thickening technology. Another major problem is that current methods remove the sand fraction with the mud as well. Many times sand has to be complemented from outer sources to endanger the natural balance of the living water. By the financial support of the NKFP 3A/068/2004 Hungarian Research Project our consortium has been looking for the solution to the above mentioned problems. The original ideas of the project were: 1. Sand should be separated and returned to the water by hydrocyclon; 2. New mud thickener should be developed based on the principle that vibrating rods can force settling and packing of mud particles. The work was started by fundamental research with different samples from Lake Balaton and River Bodrog. An automated settling column (45L) has been built for the investigation of the effect of vibrating rods on the settling behavior of suspensions. An optical sensor has been developed by with the settling curve (height of settling slurry as function of time) can be automatically measured. Different vibrating methods and parameters have been tested by the application of a linear motor and mechanical eccentric drive. On the basis of the fundamental research a new thickener, called the rod ? lamella thickener has been developed and an industrial size (50m3/h) mud removing technology has been built. Main parts of the technology are the traditional dredging barge and the thickening technology. The thickening and sand separation technology is tugged by the dredging ship. Its main elements are the homogenization tank, slurry pump, hydrocyclon and the rod ? lamella thickener. In this unit lamellas carry out pre-thickening, then vibrating rods further increase the concentration. The thickened mud is transported out by a screw - of which revolution number is precisely controlled - against a spring supported valve. Paper reports about the design, building, water probe and on-site tests of this mud removing technology. Two new patents had been presented, one is about the rod ? lamella thickener and the other is about the mud removing technology with sand separation.

Jan 1, 2014

By Jacob Masliyah, Zhenghe Xu, Lujie Yan

"Understanding adsorption mechanism of polymeric organic process modifierssuch as carboxymethyl cellulose (CMC) on talc hasbeen a major challenge due to anisotropic nature of talc basal planes and edge surfaces. The main objective of this study is to investigate the adsorption of CMC on the basal planes and edge surfaces of talc.Smooth basal plane and edge surfaces of talc were prepared successfully by simple cleavage and sophisticated ultramicrotome cutting method, respectively. The prepared surfaces were characterized by atomic force microscope (AFM) imaging to be sufficiently smooth for colloidal probe force measurements using AFM. Anisotropic surface charge characteristics were determined,with the basal planes to carry a permanent negative surface charge and edge surfaces featuring a pH-dependent charge characteristic. The adsorption of CMC on talc basal plane and edge surfaces at pH 9 in KClaqueous solutions of various ionic strengths wasinvestigated by in situ AFM imaging technique. Themorphology of adsorbed CMC on talc basal planes and edge surfaces was found to be significantly different, due to different binding mechanisms involved. Interaction of CMC with the talc basal plane was found to bedominated by hydrophobic interactions while its binding with the talc edge surface was mainly through chemical complexation and hydrogen bond. The amount of CMC adsorbed on both talc basal planes and edge surfaces increased with increasing ionic strengthof solutions. The methodology developed in our study opens the door to probe polymer adsorption on anisotropic phyllosilicate surfaces, which can help us better understand the mechanism of polymer adsorption on specific mineral faces."

Jan 1, 2014

By Renato S. Costa, Afonso H. Martins, Flávia D. Mendes

"This paper presents some important aspects regarding the ion exchange treatment of an Ni and Co sulphate acidic liquor using chelating resins. Chelating resins possessing iminodiacetic or bis-picolylamine functional groups were compared in terms of nickel and cobalt recovery. The experimental resin with bispicolylamine functionalities (Dowex M4195) was evaluated with respect to Ni and Co uptake, and compared with Rohm &Haas commercial chelating iminodiacetate acid resin.The use of selective ion exchange to recover metals from sulphuric acid liquors has been studied for a long time. Companhia Vale do Rio Doce (CVRD) has been actively involved in hydrometallurgical applications of IX and has researched in selecting the optimum resin for nickel and cobalt selective removal and the design of a suitable IX circuit. When an IX operation is contemplated for a specific application, it is followed a screening process which generally involves consideration of the solution composition and pH, speciation of the metals in the liquor to be treated and other possible techniques that can be applied to achieve the desired specifications or recoveries. Once a decision has been made to use IX for a specific application, relevant testwork should be done to select the most cost-effective resin and design the IX circuit to achieve the desired criteria. The experimental part dealt with the working conditions, resin characteristics and the influence upon the resin maximum exchange capacity of the following factors: nickel concentration, temperature, pH and resin-to-solution ratio. Based on the experimental data obtained, it has been proposed a innovative technological treatment"

Jan 1, 2003

By J. K. Qu

As one of the key inorganic chemical industries, the chromate chemical industry has spawned extensively public concerns due to the resulted environmental pollution. The cleaner production technology for chromium compounds bases on sub-molten salt medium developed by the Institute of Process Engineering, Chinese Academy of Sciences has greatly decreased the reaction temperature and energy consumption, significantly in-creased the utilization ratio of the chromium element, and successfully achieved the comprehensive utilization of chromite resources and zero emission of chromium-containing residue. The separation process of production is the most important components in the cleaner technology. In this work, we studied two parts: the first is the removal of SiO2, Al3+ from the system and the recycling utilization of alkali metal medium through adding Ca(OH)2 and CaO; the second is to get more pure K2CrO4 crystalloid and remove K2CO3 from KOH solution through evaporation to prepare raw material for manufacturing Cr2O3 and get 50%(wt) KOH. The results obtained show that Ca(OH)2 can remove Al3+ more than CaO and has lower caustic ratio than CaO when they were added 110% of theoretic quantity. The optimal pure K2CrO4(96%) can be gained at 45 Celsius degree in 30% KOH solution and K2CO3 in 50% KOH solution could be decreased to 3.5%(wt) at 40 Celsius degree. And then K2CO3 can be causticized with adding Ca(OH)2 to recycle potassium alkali. The impure material can be re-moved and suitable raw material for manufacturing Cr2O3 can be gotten and reaction medium can be also recycled in this process technology, realizing cleaner production effectively.

Jan 1, 2014

By M. Amani, A. Akbarinasab, M. Bazmandeh

The fourth iron ore production plant at Golgohar mining and industrial company consists a ball mill and wet medium intensity magnetic separators (3500 Guss). The ball mill product applies directly into MIMS and the MIMS concentrate directly transfers to the low intensity magnet separators (LIMS). The thickener is used for dewatering of MIMS and LIMS tailings. By sampling from streams of ball mill and separators, it was defined that the grade and iron recovery were 60% and 80% respectively while they would be 66% and 90% respectively based on the designing documentation. The average of P80 in the ball mill was 342 micron in a month that is coarser than optimized value. This problem was related to unsuitable operation of grinding. For optimization of grinding efficiency, the amount of charge volume was investigated as a variable. The measurements illustrated 32% charge volume. For increasing grinding efficiency, the charge volume was increased 1% and 1.6% in two stages. The results showed ball mill power draw average reached from 3650 kw to 4120 kw and the average P80 reached to 329 micron. All of parameters calculated about 35 day before and after change. Average of Ball mill feed iron ore grade before and after change was 49.24% and 50.32% respectively. This change caused an increase in efficiency of MIMS, where the enrichment ratio and concentrate grade increased 2% and 1.9% respectively. For increasing the iron grade of the MIMS concentrate; the orifice of the tail flow exit pipe changed from 4 inch to 6 inch and the concentrate grade increased 2%.

Jan 1, 2014

By K. Amano, K. Haga, Y. Watanabe, A. Shibayama, A. Batnasan, A. Battsengel

"Apatite is an important host mineral in igneous and metamorphic rocks for production of phosphate fertilizers and phosphoric acid, and a potential source of rare earth elements (REE) production. For dissolution of REEs, sulfuric acid is better leaching reagent to develop the economical viable process for recovering of rare earth elements from apatite ore. However, the efficiency of rare earth elements dissolution in H2SO4 is about 30 % due to the formation of calcium phosphate or calcium sulfate as precipitate. On the other hands, phosphorus is mainly produced from phosphate ore. However, when treating rare earth elements containing phosphate ore, rare earth elements were discharged. Hence, development of novel apatite ore treatment process is required for effective utilization of natural resources. In this study, apatite deposit associated with REE was treated with sulfuric acid leaching and two stage precipitation by oxalic acid (C2H2O4) and magnesium chloride (MgCl2) for recovering REE and phosphorus, individually. Results showed that it can be seen the vast majority of La (87.5%), Ce (87.3 %), Pr (86.1 %), Nd (85.2 %) and Y (90.9 %) were dissolved in 1 mol/L diluted H2SO4 solution from the apatite ore. As average leaching rate of REE, over 85% of REE were leached by the condition. In the first stage precipitation using the obtained pregnant leach solution from leaching, over 90% of REE was precipitated by oxalic acid addition after controlling pH to 1 by NH4OH solution. After pH changed to 8.5, over 90% of phosphorus was recovered as precipitate by magnesium chloride addition in second stage precipitation"

Jan 1, 2018

By M. L. Torem, R. H. Rojas, A. G. Merma

"Fine particle recovery by conventional flotation processes is very low mainly due to the low probability of bubble/particle collision and adhesion. In order to solve the problem of low particle recovery, several flotation technologies have been developed to increase bubble/particle collision efficiency. Among these technologies, the electroflotation process stands out. This process has advantages in the generation of microbubbles (<100 µm) and in the production of different amounts of hydrogen and oxygen microbubbles. These advantages favorably influence the fine particle floatability, due to the greater probability of particle/bubble collision and adhesion. The electroflotation tests were conducted for a hematite/sodium oleate system in a Partridge-Smith modified electroflotation binary cell of 0.38 L usable volume. The sodium oleate concentration, particle size, pH and current density were evaluated. Satisfactory results in the recovery of hematite were found at pH values of 7, reaching hematite floatability of 99% and 90% with hydrogen and oxygen bubbles, respectively.INTRODUCTIONThe flotation recovery of fine and ultrafine particles is normally very low and is caused by several factors, among them, the low probability of collision and adhesion bubble-particle, the difficulty to overcome the energy barrier (entrainment and entrapment), low selectivity, surface oxidation and mineralogical changes (Schulze et al., 1989; Waters et al., 2008; Shahbazi et al., 2010). This problem can be overcome by decreasing the bubble size or by increasing the apparent particle size. However, it is worth noting that the use of small bubbles or micro bubbles also involves some disadvantages such as their low momentum resulting in a slower process comparing with conventional flotation. Electroflotation is an attractive alternative for treating fine particles with small bubbles less than 100 µm, generated by the electrolysis of water. Electroflotation is one of the variants of the flotation process, where the gaseous phase is produced by electrolysis of an aqueous solution, generating oxygen and hydrogen bubbles (Sarkar, 2010; Gupta and Ali, 2012). These smaller size bubbles allow the recovery of fine particles by increasing the collision efficiency. This process is versatile and competitive in relation to other techniques such as dissolved air flotation and dispersed air flotation because the electroflotation units are smaller, more compact and require less maintenance and less operating cost than other flotation units (Zouboulis and Matis, 1995,). In addition, the electroflotation process is a clean technique and provides results in a short time, requiring only the investment in the electroflotation cell construction stage and the choice of the electrodes (Ketkar et al., 1991; Sarkar et al., 2010; Sun et al., 2011). In this sense, this study assesses the effect of pH, particle size and sodium oleate concentration on electroflotation of hematite fines."

Jan 1, 2018

By K. C. Corin

It is well known that the grinding circuit plays a crucial role in flotation. The effect of pulp chemistry during grinding is often overlooked. It is believed that the surface properties of the minerals can be adjusted during flotation rather than during grinding. However, recent development in surface analysis techniques (TOF-SIMS, XPS, and AES etc.) have proven that the hydrophilic iron hydroxides formed at the mineral surface during grinding make it difficult for collector adsorption, which may result in poor grades and recoveries of the valuable minerals. This study investigated the effect of the pulp chemistry conditions during milling and the subsequent effects on flotation performance of an Nkomati ore. The results have shown that there was approximately 10 % increase in Ni recovery, when the ore was ground at a dissolved oxygen (DO) concentration of 0 ppm (DO-0) in comparison to no gas control during the grinding stage. However, when the pH was changed from 9 to 11, no gas control resulted in a 20 % decrease in the Ni recovery compared to only 5 % decrease in the Ni recovery at DO-0. A noteworthy observation is that controlling a combination of DO and pH during grinding is of critical importance for better floatability and selectivity for such a system. It also became clear from this study that the presence of oxygen is critical to the consumption of xanthate, which is consistent with the general literature. It has been established that grinding at lower DO levels/redox potentials (Eh) in the presence of xanthate significantly improves the flotation performance of the valuable minerals.

Sep 1, 2012

By T. Wang

A new kind of mixed chelate collector was prepared in order to separate gangue (mainly quartz) and iron minerals efficiently during room temperature. The collector was was composed of two chelate collectors DES and DA. Floatation tests were carried out under 28?C with mixed magnetic concentrates of Donganshan sintering plant, and optimal test conditions were obtained, in which a direct floatation was undertaken and then a close circuit reverse floatation tests ( one roughing, one cleaning, and two scavenging), and a result of Fe grade of siderite concentrate 36.49%, Fe recovery of siderite concentrate 10.65%, Fe grade of final concentrate 66.27%, Fe recovery of final concentrate 78.25%, and Fe grade of tailing 16.22% was gained. Fourier Transform Infrared (FTIR) Spectra and Zeta potential of siderite and quartz adsorbed the DES and DA collectors before and after were measured in order to analyze the reaction between the collector and minerals. Furthermore, Molecule electronegativity of DES and DA was calculated by Electronegativity Proportionality Principle (EPP). Results showed that DES molecules have five active adsorbing sites and their molecule electronegativity was stronger while DA molecules have three active adsorbing sites, which all make the mixed collector has efficiently collecting performance. Zeta potential results of Quartz and siderite showed that at pH 11.5 both kinds of particles charged negative and at this pH value the mixed collector were mainly anionic collectors which indicate that electrostatic adsorption does not exist at this situation. FTIR results showed that characteristic peaks of the mixed collector changed before and after adsorption with the minerals, which means that there exists chemical adsorption or hydrogen bonding.

Jan 1, 2014

By Alejandro Rubio-Lopetegui, Gonzalo Montes-Atenas

The occurrence of Enargite (Cu3AsS4) in hydrometallurgical plants bears a number of challenges. One question lies on how Copper and Arsenic can be selectively extracted from the solid surface structure when immersed in aqueous solution. The leaching of Enargite in ambient conditions has been extensively studied; nevertheless, challenges regarding the process kinetics and surface structures enabling the extraction process remain ill-understood. Prior knowledge indicates that different conditions of pH, Eh, temperature, speciation of the aqueous phase or variations of these parameters defines the overall rate at which metals and other elements will be transferred to the solution. One aspect that the research studies have seldom addressed involves studying the main features of the surface structures formed during the leaching process at the outmost surface atomic layer. Such structures will mediate between the solid bulk and the solution to undertake subsequent stages of leaching process. The aim of this research work is to critically analyze the state of the art of Enargite electrochemistry from the mediator formation-dissolution mechanisms standpoint occurring at the mineral-solution interface. The most probable mediator species reported in the literature were found to be: Arsenolite and Sulfur (acidic media), Covellite (acidic and alkaline media) and Tenorite (alkaline media). As a result of this analysis, it was observed that the surface speciation was not in full agreement with the previous knowledge suggested to explain Enargite leaching reactions and, therefore, modified Eh-pH diagrams are presented. The acquired insights on the surface structures rising from the Enargite-aqueous solution interactions is further revised to provide new experimental protocols towards selectively separating Copper and Arsenic through hydrometallurgical paths.

Jan 1, 2014

By B. K. Mohapatra

Small manganese ore bodies in south Odisha, India occurs both as stratiform and stratabound ore bodies. These two ore bodies show contrasting mineralogical, petrographical and chemical characteristics. Stratiform type of Mn-ores consists of manganese, iron and silicate- phases in approximately same proportion. In contrast, stratabound ore bodies contain a high proportion of manganese oxides, silicates and phosphorus phases. Phosphorus is found within apatite in the stratabound ore bodies while in the stratiform ore it occurs as an adsorbed state with iron phase (goethite). Both ore bodies are low-grade (17-23% Mn) therefore do not have a market value. However, the stratabound ores are enriched in phosphorus (P2O5: >1%) compared to the stratiform ores. Both the ore types were processed through gravity, magnetic and roast reduction followed by magnetic separation techniques. The strata bound ore could be upgraded to 33% Mn from a feed of 23% by combination of dry and wet magnetic separation methods. But the phosphorus content also suits up (P2O5: 1.2%) in the processed product making it unsuitable for further use. The stratiform ores do not respond to either gravity or magnetic separation because of close association of manganese with iron phases. However, this could be beneficiated through roast reduction followed by magnetic separation. An ore with 17% Mn content could be upgraded to 40% Mn with a 42% yield and 78% recovery. The goethite, having phosphorus, converts to magnetite and is retained within the magnetic fraction, thereby reducing the concentration of phosphorus in the non-magnetic fraction, which becomes the product. This report demonstrates the influence of ore petrology in determining the up-gradational potential of manganese ore in the southern Odisha, India. Keywords: manganese ore, physical beneficiation, phosphorus rich ore

Sep 1, 2012

By Xingshi Yang, Ghislain Bournival, Seher Ata

"Particle-laden interfaces are a fundamental research topic in froth flotation since the process involves particle-coated bubbles in both the pulp and the froth phase. In most experimental studies the characteristics of the particle layer in multi-bubble systems are poorly defined. An experimental setup has been developed based on a Langmuir-Blodgett (L-B) trough. The modified trough allowed introducing an air bubble beneath the particle monolayer formed at the air-water interface which made the study of the interaction between the bubble and the monolayer under various pH values possible. The monolayer characteristics of the particles were also studied and compared in terms of surface pressure (?-A) isotherms and packing factor. On compression, the particles formed branched structure at high pH whereas a uniform monolayer was formed at lower pH. Observations related to the behavior of particles during compression and expansion cycles, and the coalescence of a bare bubble with the flat particle laden interface were provided and the implication of the results for flotation process was discussed.INTRODUCTIONFroth flotation is known for its versatility and ability to concentrate low-grade, complex ores. It is considered a physico-chemical process in which particles attach to air bubbles, depending on their hydrophobicity as well as other factors, and are carried to the surface to form a froth layer. Reagents are used to stabilize bubbles and the froth layer (Pugh, 1996). However, particles, which are carried by the bubbles or entrained, significantly contribute to the stability of the froth phase (Ata et al., 2003; Zanin et al., 2009; Bournival et al., 2015a). Their relevance in mineral processing has led to a number of fundamental studies on the effect of particles and their properties on the process of froth flotation.Flotation systems are particularly difficult to characterize due to the broad range of properties of particles (e.g. size, liberation, hydrophobicity, etc.) and inconsistent operational conditions (e.g. changes in water quality, reagent addition, etc.). Several studies have made the use of well characterized particles in laboratory conditions. Such studies allowed the finding of an optimal contact angle for the stabilization of the froth phase (Johansson and Pugh, 1992; Ata et al., 2002). Froths have a large number of bubbles so that individual interactions are not observed. The study of two bubbles allows to determine the stability of the bubbles, with particles, and to some extend the stability of the bubble-particle aggregate (Gourram-Badri et al., 1997; Bournival et al., 2015b). The removing of particles between two bubbles may also be studied from a Scheludko cell (Johansson and Pugh, 1992) or by observing a bubble with a flat interface (Sethumadhavan et al., 2002). However, these systems provide limited information on the arrangement of the particles."

Jan 1, 2018