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By E. Don Dilling, W. F. Holbrook, Lloyd R. Michels, James W. Pennington, Dwight L. Harris, Wm. F. Hergert, Cyrus L. Blogett, H. A. Doerner, Ernest A. Reige

"IntroductionA process for production of magnesium by carbothermal reduction was developed at Padentheirm, Austria, by the Austro Americanische Magnesit Corporation& an independent investigation of this and other processes was started in 1937 by the Bureau of Mines at Pullman, Wash., with the cooperation of Washington State College. 10/ A preliminary study of the Radentheirm pro¬cess, as revealed by the meager information then available, demonstrated the following two major disadvantages,The use of hydrogen for shock cooling requires an enormous volume of gas - about 1,000 cubic feet for condensing each pound of metal as a pyrophoric dust which must be completely separated from this gas. Then if the gas is to be recycled for repeated use, the CO produced by the reduction reaction must be separated from the hydrogen. These separations are costly from the standpoint of equipment and operation. 11/The condensate is an impure, pyrophoric metal powder that must be purified and converted to coherent form. This is accomplished by distillation or sublimation of the metal. Distillation on a large scale involves difficulties inherent in the high boiling point (1,107° C.) and the chemical activity of the metal. To avoid these difficulties, the metal is sublimed at 600° C. and of very low pressure. This is quite easily carried out as a batch operation but is a costly procedure. A continuous sublimation process has not been accompli shed."

May 1, 1945

By J. P. Walker

"INTRODUCTION Sponge iron has been made commercially since 1912 at a Swedish ceramic plant; and the product, known as Swedish disk-type nagger sponge iron, has an excellent reputation as a superior furnace feed wherever high-grade steels are made.The general procedure for making brickyard sponge iron was described frequent in Swedish technical journals before 1932 and at that time consisted in filling clay refractory containers, called saggers, with iron ore plus the necessary quantity of solid reducing agent and then firing in an ordinary ceramic kiln. Two types of sponge iron were made in this way: (1) An inferior, high-sulfur product obtained by mixing the ore and solid reducing agent; and (2) a high-grade, low-sulfur product made by filling the sagger with alternete layers of unmixed ore and reducer, yielding sintered disks of metallic iron particles.Swedish disk-type sponge iron of interest to the steel industry because it has a very low sulfur content, even when made by the use of low-grade, high-sulfur coals for reducing and firing. The Swedish product also contains little siliceous gangue residue and is almost phos¬phorus-free. To those features must be added the high metallic-iron content -90 to 96 percent - and freedom from even small amounts of the metals that are undesirable in steel making.The details essential for successful operation of this procedure are not known, especially as regards improvements said to have been made since 19;2. The Bureau of Mines therefore decided to determine some of these missing details, and this report records the results of the first set of experiments on the manufacture of brickyard or sagger sponge iron."

Sep 1, 1945

From the time of its establishment in 1910, the Federal Bureau of Nines has studied the carbonization of coal, and a considerable part of this effort has been devoted to investigations in the so-called low-temperature carbonization range, 450° to 700° C., in which there is minimum decomposition of primary products and maximum yield of Liquids - a yield two to threefold the amount produced in high-temperature carbonization at 900° to 1,200° C, The solid residue, char, or coke, produced in low-temperature carbonization is 70 to 80 percent of the coal charged and may be used directly as a smokeless fuel or for blending with coals to produce metallurgical coke, Although some thought was given to the use of tar and to the illuminating value of gas derived from lm-temperature carbonization, the main emphasis in early work of the Bureau of Mines was on the preparation of smokeless fuel, especially for home use, For example, a carbonizer was designed and operated for making char and briquets from North Dakota lignite without recovery of by- products; however, the shortage of high-temperature coal-tar products in the United States during World War I had already indicated the potential usefulness of low-temperature tar.

Jan 1, 1959

By J. Bruce Clemmer

In the experimental concentration of Vermont talc-magnesite ores, talc concentrates and tailings rich in magnesite were obtained. On account of the possible market value of the magnesite, the tailings are given consideration' in this report along with the talc. After some comments about the talc industry, the magnesite that accrued as tailings will be considered. Then the flotation results will follow.

Jan 1, 1936

By John D. Spencer

Clean energy production from coal, oil, and gas, and the development of these and other energy sources continued to be a major objective of the energy research program of the Bureau of Mines.3 In 1971 increased emphasis was placed on the production of fluid fuels and chemicals from coal. Advances were achieved in the development of the Synthane and Hydrane gasification processes for producing pipeline gas from coal (page 31), and progress was made in research on solid wastes utilization (page 2), and on liquid fuels production from coal (page 37); Coal mine safety, solid waste disposal and utilization, coal preparation and transport, and fundamental research on coal and related products also continued to be the subject of extensive research. Improved methods for extracting petroleum and natural gas without surface and subsurface pollution featured research on these vital fuel and energy sources. This research was highlighted by studies of the fracturing systems of reservoir rocks, including subsurface fracture mapping and new fracturing techniques to achieve optimum production of oil and gas (page 52). Of equal importance were projects on oil recovery by water or gas flooding (page 52), by steam injection (page 57), on the identification of oil spills (page 63), and on means to reduce vehicular exhaust emissions (page 66).

Jan 1, 1972

By B. W. Haynes

This Bureau of Mines report describes the laboratory processing of manganese nodules and the results of tailings characterization obtained during the cooperative program with the Department of Commerce's National Oceanic and Atmospheric Administration (NOAA) and the Bureau. Five technically feasible first-generation nodule processing methods were operated at bench scale to generate sufficient tailings and slags for physical and chemical analyses. A description is given for the laboratory operation of the individual unit operations of each process. The laboratory-generated tailings and slags were tested for physical properties, mineral content, elemental and ion content, and leachability for all five processes. The results of leachate testing using the Environmental Protection Agency extraction procedure (EP) toxicity test, the American Society for Testing and Materials shake extraction test, and the EPA-U.S. Army Corps of Engineers seawater elutriant test showed very low to negligible leaching of metals from the tailings and slags. Results of the EP toxicity test demonstrated that the wastes are nonhazardous as defined in the Resource Conservation and Recovery Act (Public Law 94-580).

Jan 1, 1985

By Ernest A. Curth

The Bureau of Mines and Old Ben Coal Co. concluded a cost-sharing contract in 1975, the objective of which was to demonstrate the Herrin No. 6 coalbed in southern Illinois can be mined safely by longwall methods. Under the agreement, three longwall panels are to be mined at Old Ben No. 24 mine. A premining investigation laid the groundwork for specifying a roof-support system designed to control hazardous ground. Old Ben Coal Co. and Bureau engineers selected lemiscate-type roof shields. A rock mechanics program and geological mapping provide early warning capability and criteria for future equipment design. The effect of mining on the surface was monitored by a surface survey to develop subsidence-prediction criteria for the Illinois coal basin. The first of the three longwall panels started up in September 1976 and was completed in May 1977. The major adverse condition was the occurrence of limestone concretions, called coal balls, in massive pods. The shields provided adequate roof control even in faulty ground. Operation of the second panel started on August 1, 1977, following panel-to-panel transfer of the equipment. The accident rate was low.

Jan 1, 1978

By Irvin G. Burough

ANDROS INCORPORATED has designed, manufactured and delivered four handheld C02 DETECTORS and three handheld CH4 DETECTORS. These instruments are for in-mine safety use. The DETECTORS incorporated an NDIR optical/electronic analyzer design in which exceptional zero stability is achieved by pressure modulation of the sample gas. This eliminates the need for daily calibration. This stability and the miniature design (2.5" x 4.5" x 4.5"; 4.5 lbs) of the C02/CH4 DETECTORS provide practical instruments suitable for routine safety inspections. This report includes the theory and design of the instruments as well as studies of gas-pressure modulation by a piezoceramic-driven Helmholtz resonator.

Jan 1, 1979

By P. B. Grote

The report provides a general description of DOM technology, sources for DOM technology, and identifies approaches and requirements for acquisition by the Enterprise of DOM technology by conventional means. The approaches identified assume the Enterprise enters into a contractual/ joint venture arrangement with an uncommitted and competent systems management firm at various stages of the DOM system acquisition process. The approaches provide for training through work/study as well as through direct participation in acquisition programs. The potential success of the alternatives are evaluated in terms of the likelihood of the acquisition of an ongoing Enterprise economic DOM operational capability. The study concludes that sources exist and that the Enterprise should under-take the development of its own technical capability through conceptual design prior to selecting its source for systems management expertise.

Jan 1, 1980

By Lon A. Williams

This appendix contains drawing lists and drawings of components and assemblies designed for the prototype portable and machine mounted lighting systems per Tasks II & IV of Contract No. H0220065.

Jan 1, 1976

By M. F. Koehler

[THE LITERATURE contains relatively few thermodynamic values for interoxidic compounds, and these often are unreliable. This is especially true of data for ferrites and aluminates for which heat of formation determinations may involve extreme experimental difficulties. This report contains the results of new experimental work for obtaining the heats of formation of five ferrites (Ca2Fe2O5, CaFe2O4, MgFe2O4,, NaFeO2, and LiFeO2) and one aluminate (CaAl4O7), and a review and revision of previous similar work of this laboratory on five aluminates (Ca3A12O6,, 12/7 CaO-Al2O3, CaAl2O4, NaA1O2, and LiAlO2), The results for the 11 compounds are combined with entropy and high-temperature heat content data to derive tables of heats and free energies of formation (both from the oxides and from the elements) for the temperature range 298° 1,800° K, The relative stabilities of the compounds are discussed. The presented data all have application to ceramic reactions, and those for the calcium and sodium aluminates are applicable in considering soda-lime sintering processes for extracting alumina from silicate minerals such as day and labradorite.]

Jan 1, 1961

By Kenneth L. Whitehead

After many years of research, the occurrence of pneumoconiosis, black lung disease, among miners has been related to the mass of respirable coal dust to which mining personnel have been exposed. Congress passed Public Law No. 91-173 in 1969, which limited the dust concentration of respirable dust allowed in the mine working areas to 2.0 mg /M3 as of December 31, 1972. As a result of these restrictions, much work has been done in determining methods of either eliminating or suppressing respirable dust. The purpose of this project is to determine the state-of-the-art in continuous mining machine bit technology, particularly with regard to dust production.

Jan 1, 1973

This report has been prepared in response to a request by the Bureau of Land Management (BLM) Fairbanks Alaska District Office that the Bureau of Mines quantitatively assess the potential supply of minerals from undiscovered deposits in the White Mountains National Recreation Area (WMNRA) and the western part of the North Steese National Conservation Area (SNCA) in Alaska. The assessment will be used to assist in future land-use decision-making. Resource Management Plans (RMPs) for the WMNRA and the SNCA were approved by the BLM in 1986. These plans imposed significant restrictions on new mineral development in the two areas. The level of public concern regarding these actions, especially on the part of the mining industry, has spurred BLM to seek additional information about the potential supply of minerals from the two areas with assistance from the Bureau of Mines. The assessment focuses on an area within the WMNRA and the SNCA which has been administratively closed to mineral entry. The study area encompassed approximately 1.24 million acres and included all of the WMNRA and the western portion of the North SNCA (fig. ES-1). Three quantitative estimates of the potential supply of minerals from the study area were developed: 1) For all lands in the study area, assuming that they are open to mineral entry-the baseline analysis; 2) For those lands which have been closed to mineral entry; and 3) For eleven prospective mineral activity areas, assuming that all are open to mineral entry.

Jan 1, 1989

By W. P. Yant

A previous report of the Bureau of Mines dealt with the toxicity of dichlorodifluoromethane5, a new refrigerant that has a remarkably low toxicity. Continued research by the Prigidaire Corporation6 and toxicological experiments performed in the Laboratory of Applied Physiology of the University of Cincinnati7 revealed another organic fluoride, dichlorotetrafluoroethane, whose toxicity also appeared to be of a very low order and whose physical-and chemical properties make it suitable for refrigeration purposes. In addition to low toxicity, safety in its use is further enhanced by its physical properties, which permit the design of equipment that operates at comparatively low pressures and hence mitigates the dangers and problems of leakage. The investigation described in this report was performed by the Bureau of Mines at the request and with the cooperation of the Frigidaire Corporation.

Jan 1, 1932

By Paul Zinner

Efforts to win an enriched manganiferous product from the Missouri Valley deposits of South Dakota have included an application of most known ore-dressing devices and have been largely unsuccessful. At least two methods showed some promise of success and were the subjects of detailed Investigation by the Bureau of Mines during the period from July 1945 to August 1947. A series of mining and beneficiation tests were undertaken to determine conditions under which the most feasible concentration methods could be employed and to define the limits of such applications in terms of the character of the final beneficiated product. In the absence of a significant current market for any conceivable product of beneficiation, the extent to which applied methods might be considered successful was measured in terms of ratios of recoveries to grade, regardless of the adaptability of such beneficiated products to further metallurgical or direct usage. The results of all investigations show that production of a shale-free, concretionary, manganese-bearing product by any known method requires great sacrifices in manganese recovery. Products of beneficiation, with specifications permitting some inclusion of shale, can probably be most effectively produced by methods employing specialized jigging equipment as the principal functional unit of a process.

Jan 1, 1949

By Mark Sheppard

The technical literature on the general subject of crushing contains many references to the work of investigators on the laws governing, and the factors entering into, the economical production of fine materials. In fine grinding, whether for the purpose of producing fine material, or for the unlocking of minerals in an ore, close control of the screen sizes of primary-crusher products is of secondary consideration and accordingly has received very little attention. The growth and development of the nonmetallic industries, however, have drawn more attention to primary crushing. Many of these industries are interested in the production of relatively coarse products that meet certain definite size specifications, a condition entirely different from that existing in the field of ore dressing. Under such conditions, a knowledge of the factors governing the selection and operation of primary-crushing equipment is essential to the economical production of a satisfactory material.

Jan 1, 1939

By Mark Sheppard

The technical literature on the general subject of crushing contains many references to the work of investigators on the laws governing, and the factors entering into, the economical production of fine materials. In fine grinding, whether for the purpose of producing fine material, or for the unlocking of minerals in an ore, close control of the screen sizes of primary-crusher products is of secondary consideration and accordingly has received very little attention. The growth and development of the nonmetallic industries, however, have drawn more attention to primary crushing. Many of these industries are interested in the production of relatively coarse products that meet certain definite size specifications, a condition entirely different from that existing in the field of ore dressing. Under such conditions, a knowledge of the factors governing the selection Paid operation of primary-crushing equipment is essential to the economical production of a satisfactory material.

Jan 1, 1939

By Charles Zahn

Direct mass spectrometric determination of alcohols in the presence of hydrocarbons has not been possible because of the similarity of hydrocarbon and alcohol mass spectra. Experiments have demonstrated that by converting the alcohols to their trimethylsilyl derivatives, characteristic mass spectra are obtained free of interference from hydrocarbon ion fragmentation. Hexa- methyldisilazane is the reagent selected for the conversion, An improved method of preparing the reagent is given, Mass spectrometric determination of alcohols as trimethylsilyl ethers now is not only possible without prior separation from other materials, but the range of the room-temperature mass spectrometer is also extended to include the C10 alcohol region. Water does not interfere because it is converted to hexamethyldisiloxane, which has its own distinctive mass spectral peak, Experience indicates that other compounds such as glycols, amines, and phenols probably could also be determined by mass spectrometry of their trimethylsilyl ethers. Studies on the similar detemination of phenols in coal oils have been started, When mass spectrometry is not available, gas-liquid chromatography of alcohols before and after their conversion to the trimethylsilyl derivatives probably could be performed. The preparation and properties of the trimethylsilyl derivatives of 23 alcohols, 2 glycols, 3 amines, and 1 mercaptan are detailed. INRODUCTION During investigations by the Bureau of Mines at the Pittsburgh Coal Research Center relative to the development of Fischer-Tropsch processes, complications were encountered in the mass spectrometric analysis of alcohols in hydrocarbon oils. The fragmentation peaks of the alcohols and the hydrocarbons were so similar that an accurate analysis was not possible, Since involved separation techniques are necessary to isolate alcohols from hydro-carbons for separate determinations, efforts were turned to the search for a

Jan 1, 1962

By R. A. Strehlow

This is the final report for U.S. Bureau of Mines contract HO-122122, which was in effect from June 30, 1972 through January 4, 1976. The work resulted in the design and construction of a large laboratory scale coal dust burner and the use of this burner to study gaseous and coal dust flammability. A new technique for determining gas phase flammability was developed and the effect of solid and gaseous suppressants on the propagation of coal dust flames was studied. In addition, a technique for measuring the C/H ratio in the flame was developed and the C/H ratio that was measured in a coal dust flame on this burner showed that the burning process was preceeded by pyroysis of the coal dust. Both experimental and theoretical studies showed that radiative trans-port is very important to the propagation of a coal dust flame.

Jan 1, 1977

By Martin D. Conyac

A 1984 Bureau of Mines investigation identified ho mineral resources in the Wilderness Study Area (WSA). However, four prospects in the WSA contain anomalous amounts of copper and silver minerals; one had traces of gold. Stratabound copper-silver occurrences appear to be prevalent. Quartz veins in the WSA locally contain trace gold, and one mine adjacent to the area produced some gold in the late 1800's. The WSA is underlain principally by Precambrian and early to middle Paleozoic quartzites, argillites, dolomites and limestones that have been complicated by faulting, generally tilted northeastward, and thrust southeastward over sequences of late Paleozoic sedimentary rocks. The stratabound copper-silver occurrences and gold-quartz veins are in Precambrian and Cambrian rocks in the western part of the WSA, as are similar deposits regionally. Sand and gravel, and limestone are abundant, but plentiful resources of these commodities are nearer established markets. In November 1983 there were 5 small groups of current claims oh the WSA boundary; none are patented claims. Probably less than 35 claims have been located within the WSA, mostly in the northwestern portion; hut over 100 claims have been located outside, near the northwestern boundary. Oil and gas leases nearly surround the boundary and 6 extend up to 1 mile into the study area. There has been no recorded mineral production from within the WSA. From 3 to 5 miles to the west, several lode nines in the Johnnie district have produced several million dollars worth of gold from quartz veins, and some silver and lead from galena-calcite veins. These veins generally trend northeasterly and dip northwesterly and probably do hot extend into the study area.

Jan 1, 1985