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By F. P. Haver

The Bureau of Mines is developing a leach-electrolysis procedure to produce Special High Grade (SHG) zinc from sulfide concentrate without the generation of sulfur oxide gases. Chlorine-oxygen leaching of the concentrate yields zinc chloride (ZnCI2) which, after purification, is electrolyzed in a fused-salt cell to obtain molten zinc metal and chlorine gas for recycle. This paper describes a laboratory-scale investigation made to develop a procedure for electrowinning zinc metal from ZnC12. Zinc chloride by itself is not a suitable electrolyte because it fumes badly above its melting point and is a poor conductor of electricity. Other salts therefore must be added to prevent fuming and improve the conductivity. Optimum results were obtained with a KC1-LiCl-ZnCl2 bath at 500° C, using a current density of 5 amp/in2 and an electrode spacing of 0.5 inch. Under these conditions, SHG zinc was produced at a current efficiency of 94.3 pct and an energy requirement of 1.16 kwhr/lb. Fused-salt electrowinning eliminates the need to handle and melt cathodes and increases the production of metal per unit cell volume through the use of higher current densities than are possible with aqueous electrolysis.

Jan 1, 1976

By Jr. Sillers

This is the third report of investigations dealing with the application of electrolytic manganese to steel-foundry practice and the seventh in a series of reports dealing with tests to establish the technological acceptability of electrolytic manganese in the iron and steel industries. The work was carried out by Metallurgical Division of the Bureau of Mines as part of an extensive program for the development and utilization of domestic ores. The electrolytic manganese used in the tests was produced by the Bureau at its Boulder, City, Nev., pilot plant by the process developed by the Bureau of Mines.

Jan 1, 1949

By G. H. Gronhovd

This is the final report on a research program to develop a pilot plant gasifier for slagging gasification of lignite at high pressures and to obtain process data under various operating conditions. An operable pilot plant was developed, and the test results show that lignite is well suited for the process. Tests were run at pressures from 80 to 400 psig, and the results indicated that pressure had little effect on gas composition or the material requirements per unit gas produced. Gas production rates as high as 26,000 scfh/sq ft of reactor area were obtained at 300 psig, but limitations on auxiliary equipment prevented full-capacity operation at 400 prig. In several tests lignite having a 37-percent moisture content and 2,500° F ash-fusion temperature was successfully gasified. Refractory materials were found to have a short life in contact with high-temperature slag, and a water-cooled taphole was developed. Exploratory tests with coking coal were unsuccessful.

Jan 1, 1970

By W. K. Tolley

This report presents data collected during research by the Bureau of Mines on corrosion of grinding media. Corrosion rates of eight alloys commonly used in grinding media were tested in synthetic mill water using an ultrasonic grinding device especially designed for this work. Electro-chemical measurements showed variations in corrosion rates for these alloys between 9.8 mpy for medium-carbon steels and 0.14 mpy for high chromium white irons. Bureau data are discussed along with data from the literature to indicate that corrosion causes less than 10 pct of the wear of grinding media in commercial grinding mills. A comparison of corrosion rates for various types of grinding media shows that alloying elements and electrochemically active inclusions in steel affect the corrosion behavior of the media.

Jan 1, 1984

By Charles D. Litton

This U.S. Bureau of Mines report details the results of a series of large-scale experiments where small coal fires were used to ignite the conveyor belt at air velocities ranging from 0.76 to 6.1 m/s. In the tests, electrical strip heaters imbedded within a pile of coal were used to heat the coal to a point of flaming ignition. The flaming coal subsequently ignited the conveyor belt located approximately 5 to 10 cm above the coal pile. During the tests, temperature, CO, and smoke levels were continuously measured in order to determine both alarm time and level as the fire intensity progressed through the stages of smoldering coal, flaming coal, and flaming coal plus flaming belt. Analysis of the data leads to certain conditions of air velocity and sensor alarm levels that are required for early detection of conveyor belt entry fires. Two nomographs are presented, which define sensor alarm levels and sensor spacings as a function of belt entry cross-sectional area and belt entry air velocity.

Jan 1, 2010

By V. E. Homme

Low- and high-temperature reduction techniques were employed by the Bureau of Mines in study of conditions favorable to the formation of massive titanium crystals. '1,1,2 low-temperature method, feeding molten sodium to solidified titanium lower chloride-sodium chloride, produced higher quality and high quantity crystalline metal. The percentage of crystalline titanium was increased with increasing reactor diameter, melt depth, and titanium dichloride concentration. The high-temperature technique, feed molten sodium to melts above 8000 C, producing needle-type crystals of lower quality and with less consistent results than the low-temperature method. Layers of titanium foil, sponge, fine needles, wool, and crusts of sin-tered granules were formed during the earl, -art of the low-temperature reduction, and massive crystals were produced beneath this barrier in the latter part of the reduction. Crystalline titanium having an average hardness of Bhn 76 and representing 58 percent of the total titanium was obtained. Lamellar crystals up to 1 1/2 inches long with a hardness as low as Bhn 54 were also produced. A second-stage reduction for reclaiming titanium from offgrade sponge is described. Titanium produced by this method was comparable in quality to that from sodium reduction of titanium tetrachloride.

Jan 1, 1966

By E. C. Lane

During the past 15 years the Bureau of Mines has made and published several hundred analyses of typical petroleums and has developed a system of interpreting the analyses and of classifying crude oils. In describing crude petroleum frequent reference is made to the "base" of the oil, a usage the petroleum industry has found convenient. As part of its general study of the characteristics of crude oils, therefore, the Bureau of Mines has developed a system of classifying them according to "base." This system as first published in 19274 was limited to four classes and in its original form is no longer considered adequate. Since the system was first published the Bureau has analyzed a large number of crude oil-, including representative samples from nearly every important producing field in the world, and has found that the system of classification could be revised and amplified to advantage. The revised system is presented herein. Bulletin 2916 states that many oil producers and refiners use the word "base" much as it is used in pharmaceutical work. For example, the "base" or "basis" of an ointment or salve is the fatty material (lard, petroleum, or lanolin) used as a vehicle or carrier for the active medicinal principles. Apparently many of the pioneers in the petroleum industry considered crude oil similar in nature to these medicinal products in that it consists of a semisolid, nonvolatile base and 1 volatile portion can be distilled off to make gasoline, kerosene, and other products. Many crude oils when chilled slowly deposit a waxy material (paraffin); this fact may have been one reason for the use of the term "paraffin base" in referring to such oils. Almost all of the petroleum first discovered in the United States was of this nature; not until the oil industry was extended to California and along the Gulf coast was petroleum found that contained no wax but apparently did contain asphaltic material Accordingly, these oils were known as "asphalt-base" oils. The use of this term, however, seems unfortunate, as better-grade oils of this type contain little if any asphalt; the descriptive term "naphthene base" now seems to be a more desirable term than "asphalt base." The term "intermediate base" is also used commonly in referring to oils intermediate in oharacteristios between those of paraffin and naphthene base.

Jan 1, 1935

By Robert E. Barieau

General expressions for evaluating practically all the thermodynamic properties of a fluid from a single equation of state are derived. Most of the formulas are expressed in terms of the compressibility factor, with this factor being an explicit function of the temperature and the molal density. Similar expressions are given using reduced variables.

Jan 1, 1967

By C. L. Klingman

In extracting helium from natural gas at Bureau of Mines helium plants, a continuous analysis of the helium content of inlet and outlet gas streams is required to determine extraction efficiency. An analyzer, using established principles of gas chromatography to effect the analysis, has been developed by the Bureau of Mines to meet this need. It will record the helium content of inlet or discharge gases from helium-extraction plants every five minutes, continuously, without the attendance of an operator. A 25-inch column of activated charcoal is used as a partitioning agent; nitrogen is the carrier gas; and a hot-wire, thermal-conductivity cell is the detector. A 1.0 mv, strip chart indicates the unbalance of the detector cell, Sample size is 0.37 cc, and carrier gas flow rate is 75 cc, per minute. Significant improvements in helium extraction have been demonstrated by using the chromatograph in three helium-extraction plants.

Jan 1, 1961

By J. W. Griffith, J. L. Stauffer, L. M. Demers, D. C. Kuhn, S. Riliog

"The relative activation of eicosanoid production which results from the exposure of the alveolar macrophage (AM) to mineral dusts is thought to be a key factor in the pathophysiology of occupational lung disease. We compared in vitro basal and silicastimulated production of prostaglandin E2 (PGE2) and thromboxane A2 (TXA2) by AM from normal humans and non-human primates (Macaca nemistrina). In addition, we instilled mineral dusts directly into one lung of the non-human primate and evaluated AM eicosanoid production at two week intervals following dust instillation. Unstimulated AM from humans produce more PGE2 and TXA2 than do AM from M. nemistrina. However, in vitro exposure of AM from both species to silica dust produced a qualitatively similar increase in TXA2 production accompanied by no change in PGE2 production. Sequential analysis of AM eicosanoid production following a single bolus exposure to bituminous or anthracite coal dusts, titanium dioxide (Ti()i) dust or crystalline silica showed marked variability among individual non-human primates in qualitative and quantitative aspects of dust-induced eicosanoid production. However, the rank order of potency of the different dusts (silica> anthracite> bituminous) correlated with epidemiological evidence relating the type of dust mined to the incidence of pneumoconiosis. These studies suggest that the non-human primate may serve as a model for the study of both the role of eicosanoids in the etiology of dust-induced occupational lung disease and the biochemical basis for individual variability in the response of lung cells to mineral dust exposure. IntroductionOccupational inhalation of mineral dust can lead to chronic debilitating lung disease ( 1,2). One of the key components of the disease process is thought to be the interaction of mineral dust with the alveolar macrophage (AM) and the subsequent release by the AM of inflammatory and fibrotic substances (3,4). Chronic inhalation of mineral dust, depending on the type and amount of dust, may then produce a situation in which ongoing inflammation, accompanied by the destruction of functional lung tissue by products of activated AM and polymorphonuclear neutrophils, stimulates the production of nonfunctional matrix by lung fibroblasts.The AM produces several oxygenated derivatives of arachidonic acid (AA) which may play important roles in dust-induced lung pathophysiology (5,6). In previous studies in the rat, we found that prostaglandin E2 (PGE2). thromboxane A2 (TXA2) and leukotriene 84 (L TB4) were the major AA metabolites produced by AM (7). PGE2 is associated with pro-inflammatory activity (8) as well as anti-fibrotic activity since it downregulates interleukin -1 (IL-1) and tumor necrosis factor (TNF) release by AM (9-11). TXA2 is known to stimulate platelet activity, cause bronchial and vascular smooth muscle contraction (12) and to possess chemotactic activity (13). LTB4 is chemotactic for neutrophils and monocytes (14) and has been suggested as an additional regulatory factor in the release of TNF by AM exposed to silica dust ( 15)."

Nov 1, 1995

By D. G. Lee

Diesel particulate matter (DPM) often contains small amounts of metal as a minor component but this metal may contribute to adverse health effects. Knowledge of the mechanism for particle formation as well as the size preference of the trace metals is critical to understanding the potential for health concerns. To achieve this, the size and the composition of each particle should be optimally measured at the same time. Single particle mass spectrometer (SPMS) would be the best tool for this objective. In this paper, we therefore will introduce new findings about the mechanism and distribution of the trace metals in DPM, derived from a study where an SPMS was used to analyze freshly emitted DPM. KEY WORDS : Single particle mass spectroscopy, Diesel particulate matter, Characterization, Metal contents

Jan 1, 2006

By Edward F. Fries

The U.S. Bureau of Mines is conducting research that will lead to computer-assisted mining equipment. This research will facilitate improvements in safety by relocating workers from dangerous areas and will increase production by providing more accurate control with less downtime of equipment. A Bureau-developed microcomputer network enhances this research by permitting a group of diverse computers to interact with a mining machine as well as with each other over a common data link. The network is composed of specially integrated off-the-shelf hardware and industry-standard operating system and programming languages. Using the network, researchers can conduct various experiments with the mining machine using a diverse group of sensors, computers, and micro controllers. This report gives a brief background on the Bureau's work in computer-assisted mining, followed by discussions on the network hardware and architecture and the network packets, and an analysis of network operation.

Jan 1, 1992

By John W. Sweeney

Shales and clays from Illinois were sampled, tested, and evaluated to determine feasibility of producing lightweight aggregate by rotary-kiln methods. Sampling procedures and the 1 ,,,y of the Pennsylvanian shale units are discussed. Chemical, X-ray spectrographic and X-ray petrographic analyses were run on the samples to determine if a correlation existed between chemical mineralogic composition and expansion. Preliminary expansion testing was conducted in a muffle furnace. Rotary-kiln tests were conducted in a 16- inch by 14-foot rotary kiln. The weight of the aggregate ranged from 27 to 59 pounds per cubic foot. Concrete cubes employing the aggregate were tested to determine the qualities of the concrete. Compressive strength of the concrete using the 7-bag of cement cement per cubic yard mix, after autoclave curing for 6 hours, ranged from 2,950 to 6,750 psi. No correlation was found between the chemical, X-ray spectrographic, and X-ray and petrographic analyses and expansion, Sixteen samples made suitable lightweight aggregates in the laboratory rotary kiln. The expansion temperature range of eight of the samples was extremely narrow, and difficulties would probably be encountered in processing these materials commercially.

Jan 1, 1965

By John J. Sammarco

Illumination plays a critical role in an underground miner?s safety because miners depend most heavily on visual cues to recognize hazards. Mobile mining machinery, located in the miner?s peripheral field-of-view (±10° to about ±60° off-axis), may pose potential pinning and striking hazards. The main objective of this research was to determine if there were peripheral visual performance improvements for the detection of moving objects when using cool-white light-emitting diode (LED) cap lamps as compared to incandescent (INC) light bulbs commonly used in miner cap lamps. The cap lamp variable of interest is the spectral power distribution (SPD); the illuminances were normalized by a diffusion filter. The second objective was to determine if age is a factor for peripheral visual performance. This is important because the workforce is aging ? the average miner age is about 43 years old. Thirty subjects participated in the study; ten subjects each in the age groups of younger (18 to 25 years), middle (40 to 50 years), and older (50+ years). Visual performance was quantified by the subjects? speed and accuracy of response to detect the rotation of high-contrast (white) circular targets located 3.83 meters (m) away at -20°, 40°, and 50° off-axis. The speed of detection and the number of missed target rotations (accuracy) were measured. The prototype LED cap lamp results were best with a 11% to 15% improvement compared to the INC and LED cap lamps respectively. Age does appear to be a significant factor. For the middle and older age groups?, target movement detection time increased 75% and 60% and the number of missed targets increased 500% and 450% respectively in comparison to the youngest age group. The results also suggest that target location is a significant factor. The subjects? target movement detection time for the 40° and 50° target movements increased 16% and 69% respectively as compared to the -20° target.

Jan 1, 2008

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing clay mining, crushing, and grinding methods and costs at various operations throughout the United States. These papers are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that in many instances publication of total production costs may cause embarrassment to the individual operator as well as to the industry as a whole. On the other hand, operating costs are essential to a technical discussion and study of the methods employed. The attention of the reader is called specifically to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. The following report deals with the methods employed by the Malvern Clay Co., Malvern, Carroll County, Ohio. The author wishes to acknowledge the assistance of the following persons: H. C. Ross, vice-president and general manager, and H. C. Dormer, secretary and treasurer.

Jan 1, 1937

By Harold J. Barnett

In January 1948 , the Secretary of the Interior directed that a study be made of energy resources and requirements that would provide a basis for continuing appraisal of the adequacy of the Department's programs in the energy field . That this instruction was timely has been demonstrated by the increasing interest being evidenced by Congress , industry , labor , and the public in the future of the energy segment of our national economy . Several studies of individual energy sectors have appeared . Various legislative proposals have been made in Congress for obtaining more information on this subject . Substantial interest in energy projections is not , of course , a recent innovation . Energy availability and consumption are strategic factors in peacetime prosperity and growth and in our national defense as well . The past generation's literature of earnest public discussion and of legislative consideration of matters involving energy projections is very extensive . This is an exploratory study produced in the Program Staff of the Office of the Secretary of the Interior in the first half of 1949 and revised recently to take account of certain of the preliminary energy data from the 1947 Census of Manufactures and critical comments . It is offered at this time solely as a technical contribution in economic research technique . As the Bureau of Mines has recently undertaken to revise this preliminary study , critical and other comments are invited .

Oct 1, 1950

By J. R. Long

The Federal Bureau of Mines has pioneered the work of preparing ductile titanium on a large scale and has also determined the basic properties of this new and most interesting metal. A number of reports (1, 2, 3: 4, 5) have al-ready been published, and considerable interest has been aroused in a number of industrial and research laboratories. Some of these laboratories have also published results of their work on the pure metal. Although the properties of titanium itself are quite promising, it is apparent that considerable improvement may be expected by alloying titanium with other metals. That is, pure metals in general have shown relatively large improvements in properties when alloyed with other metals and titanium is not considered to be an exception to the rule. Therefore, the emphasis of the investigations now under way in the Federal Bureau of Mines Laboratories has been placed on the study of the alloys of titanium, particularly the titanium-rich alloys. While the main interest is in the properties of such alloys, proper direction and evaluation of the work require at least a rough outline of the phase boundaries of the alloy systems involved.

Jan 1, 1949

By M. J. Ankeny

Coal-mine haulage ranks second as a cause of coal-mine fatalities, and the prevention of such accidents will materially improve progress in safety in the coal-mining industry. Beginning March 1950, Federal coal-mine inspectors were made responsible for completely investigating all fatal accidents in and around coal mines. During these 10 months, Federal coal-mine inspectors investigated 447 fatal accidents. This is a study of 121 of the fatal haulage accidents investigated, which constituted 27 percent of fatalities from all causes. Haulage employees represent only 12 to 15 percent of mine personnel, but, on the basis of accident frequency, their work is the most hazardous in coal mines. Fatal haulage accidents occurred in 53 bituminous coal-producing counties representing 14 States and Alaska. The physical conditions represent a cross section of' producing coal beds. Mining and transportation methods vary, from those of small hand-loading mines to those of modern mechanized mines.

Jan 1, 1951

By E. C. Lane

During the past 15 years the Bureau of Mines has made and published several hundred analyses of typical petroleums and has developed a system of interpreting the analyses and of classifying crude oils. In describing crude petroleum frequent reference is made to the "base" of the oil, a usage the petroleum industry has found convenient. As part of its general study of the characteristics of crude oils, therefore, the Bureau of Mines has developed a system of classifying them according to "base." This system as first published in 1927 was limited to four classes and in its original form is no longer considered adequate. Since the system was first published the Bureau has analyzed a large number of crude oil, including representative samples from nearly every important producing field in the world, and has found that the system of classification could be revised and amplified to advantage. The revised system is presented herein.

Jan 1, 1935

1.0 SCOPE AND REGULATIONS 1.1 This specification covers the minimum requirements for material handling and associated equipment including design and materials. 1.2 This specification requires compliance with all federal, state, local laws and regulations which may be applicable including the Occupational Safety and Health Act, Construction Safety Act as well as rules, regulations and standards of the Secretary of Labor.

Jan 1, 1979