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By Albert W. Deurbrouck

This report describes the preparation characteristics of the Pittsburgh and Upper Freeport coalbeds in Hancock , Brooke , Ohio , and Marshall Counties , W. Va . Over 4.5 million tons of coal was produced in these four counties in 1962. Most of this production came from the Pittsburgh coalbed . Twelve coal samples were collected for this study , 11 from the Pittsburgh bed and 1 from the Lower Freeport bed . Two of these samples could be upgraded to produce metallurgical - grade coal . The sulfur content of the Pittsburgh- bed coals was generally excessive --as high as 4.9 percent in the raw coal and 3.19 percent in the float 1.30 specific gravity fraction . The rank of the coals in this area ranges from high-volatile A to high-volatile B bituminous .

Jan 1, 1964

By E. W. Dean

A previous report of the Bureau of Mines* has supplied data for the physical and chemical properties of samples of crude petroleum produced in the eastern fields of the United States. It was issued as a preliminary chapter of a bulletin which is to cover the results of a survey of the entire country. The present report is a second preliminary chapter including figures that are available for the producing fields of the Rocky Mountain district. Work is being continued. with a series of samples from the States of Kansas and Oklahoma which will be described in a third preliminary chapter, to appear at a subsequent date. Acknowledgments. The obtaining of samples was rendered possible through the courtesy of representatives of a number of producing and refining companies operating in the Rocky Mountain district. The Bureau hereby acknowledges its appreciation of the hearty spirit of cooperation that was universally encountered.

Jan 1, 1921

By Stephen Krickovic

Air quantity-pressure and methane concentration surveys were conducted by the Bureau of Mines in accessible portions of an area being pillared in a Pittsburgh coalbed mine in West Virginia. These included two mined-out and three active butt headings and a bleeder system. The particular mine workings were started in virgin coal directly from a set of main headings; the main reason for the study was the difficulty usually encountered in adequately bleeding the gobs under such conditions. Although the two separate return airways in each active butt heading and the North and 1 Left bleeders contained acceptable methane concentrations (0.01 to 0.78 percent in the butts and 0.73 to 1.0 percent in the bleeders) with significant total methane removal (109 cfm in butts and 631 cfm in bleeders), there were relatively large areas in the gobs with possible minimal airflows. This condition appears to have developed from lack of systematic regulation of the airflow across the gobs and appears to indicate the existence of considerably more methane in the probably low flow areas in the gob.

Jan 1, 1973

By C. F. McCarroll

[Laboratory research and, control in the u?odnction an; utilization of petroleum and its product s have eqLmde& greatly during the past decade, rind much of the routine control and experimental equipment noirr requires the con-stant daily use of liquid nercury. In spite of this greater use, very little consideration has becn given to the hazard that might be occasioned by the toxic vapors of mercury unavoicl.a~l.p spilled or otherwise exposed to the atmosphere during the normcl 2rgced1u.e of ln30r~tor;~r operations. A sfmple visual exami~stion gf' sone of the laborztories reveals the prescnce of a considerable quantity of mercury in the craclcs of floors, on work tebles, ad on and mo7md eql~ipmeilt st.ads. Usually this yercurj ie contaminated with oily and dirt BO th~t it remint; in R finely divided state and a srnarl amount presents a relativell- lag? surface for evaporation. Since mercury shows meas~rable vo!-atility st a tempero.turc as lor^ 2s 8.5O F., mercury vapor will bo present in the atnosphere of anjr laboratory wbr.e mercury is exposed. promiscuously]

Jan 1, 1939

By A. L. Peyton

The Brewer mine, near Jefferson, Chesterfield County, S. C., was originally operated as a gold mine. As late as 1890 this mine was reported to have been one of the large gold producers in the southeast. Occurrence of topaz on the Brewer property was not reported until 1935, when it was discovered, by Parks3/ and Parks of the Federal Geological Survey while they were investigating gold deposits in the Piedmont province.

Jan 1, 1953

By W. M. Dressel

A simple, reliable field test for beryllium in rocks has been developed by the Rolla Metallurgy Research Center of the Federal Bureau of Minas. A small portion of the pulverized rock is fused with a sodium carbonate-sodium hydroxide flux in a wire loop. The fused mass is dissolved in water, a few drops of quinizarin solution are added, and the solution is viewed under ultraviolet light. A pink-to-orange fluorescence reveals the presence of beryllium in a sample containing as little as 0.013 percent beryllium (0.26 percent beryl). INTRODUCTION New and potential uses for beryllium make necessary a more intensive search for this metal, which is so similar to aluminum in its chemical reactions that it is not separated from aluminum in ordinary chemical analyses. The principal ore mineral of beryllium is beryl, a beryllium-aluminum silicate, which contains only 5 percent beryllium. This mineral is so similar to quartz in appearance that it is not always possible to distinguish one from the other in the field. While the distinction may be made easily with a petrographic microscope, few prospectors have access to such an instrument, and fewer still know how to use it.

Jan 1, 1960

By N. S. Dalal, B. Jafari, F. H. Y. Green, M. Petersen, V. Vallyathan

"Stable coal radicals (SCRs) were detected by electron spin resonance (ESR) spectroscopy in the lung tissue of autopsied coal miners. The SCR concentrations were measured in the lung tissues from 98 coal miners with and without (a) coal workers' pneumoconiosis (CWP), (b) cancer, and (c) a history of cigarette smoking. Concentrations of SCRs were also determined in the lungs of nonminer controls. The SCR concentration was related to longer mining tenure, CWP disease severity, lung cancer, and cigarette smoking. The mean concentration of SCRs in the lung tissues of miners with 30 ± 1.4 y of coal mining exposure was 5.3 ± 1.3 x 10"" spins/g versus controls who had a nondetec¬table level (< 10 15 spins/g). An increase in disease severity was accompanied by a progressive increase in SCR concentration. A SCR concentration of 4.8 ± 0.7 x 10"" spins/g was found for simple CWP (with moderate coal macules) versus 7.8 ± 4.6 spins/g lung tissue for complicated CWP (with progressive massive fibrosis). Significantly higher (i.e., 10 x 10"") concentrations of SCR in the coal miners' lung tissues were associated with an exposure history in the anthracite regions of northeastern Pennsylvania. These results in¬dicate a possible role for SCRs in the disease process. Furthermore, ESR appears to be an adequate methodology for the quantitation of coal dust retained in the lung and for distinguishing exposures to anthracite and/or bituminous coal.THE PREVALENCE AND SEVERITY of coal workers' pneumoconiosis (CWP) differ markedly between geographic locations, mines, and coal fields irrespective of comparable levels of exposure to coal mine dust These differences cannot be fully explained by the presence of silica and other minerals in the coal mine dust.' Rank of coal is also an important factor in the pathogenesis of CWP. Equally important is that the prevalence of CWP decreases from east to west in the United States,' and South Wales miners develop more severe CWP than miners in Scotland.' However, there are conflicting reports that cast uncertainty on the influence of rank of coal in the development of CWP."" These problems are complicated but will be solved as new technology emerges and as more is learned about the disease process."

Mar 1, 1992

By L. D. Wyant

[A convenient method for the, analysis of oil-wax mixtures has bean developed in the petroleum laboratory of the Bureau of Mines. This method has been found useful in studying the characteristics of the products obtained in petroleum refineries during the manufacture of ?wax distillate?, "foots oil", ?intermediate wax", and commercial paraffin. In this method ac-to-au is used as a selective solvent.]

Jan 1, 1924

By T. E. Bernard

The CO2-absorbent canisters used in four approved rescue breathing apparatus were investigated. A breathing machine was used to simulate human expiration with gas flow rates of 26, 37, and 48 1/min of 3.5% CO2 in air. The exit gas CO2 concentration, the pressure drop across the canister, and the exit-gas temperature were monitored. The absorbent capacities of the packed-bed canister designs were found to be dependent on flow rate within the range studied, while the capacities of the other designs were less affected. The radial canister had the least resistance to breathing while the complex bed design proved to be the most effective in utilization of the chemical. The overall results indicated that LiOH (lithium hydroxide) has the highest capacity for CO2 absorption among the absorbents tested. It can be used in a simple packed-bed design while maintaining acceptable levels of resistance and exit-gas temperature. Examination of oxygen supply with respect to CO2-absorption capacity suggested that it is desirable to closely match CO2-absorption capacity with the avail-able O2 supply to minimize the size and weight of rescue breathing apparatus.

Jan 1, 1979

By C. F. Ellis

Interest in the composition of automobile exhaust gases has been greatly accelerated by recent studies that have indicated that these gases contribute to smog formation in urban areas. Several analytical methods have been published for the analysis of the hydrocarbons in the exhaust gases, but similar information has not been published on the analysis of the oxygenated compounds. This report presents procedures for chemical analyses of certain oxygenated compounds, procedures for sampling the exhaust gases for these analyses, and the analytical results of some experimental work in which these procedures were used. A stationary 1956 model, 170 horsepower, V-8, dynamometer-mounted engine, operated to simulate vehicular cruise conditions, was used for the study. Exhaust gases produced from a regular-grade Midcontinent gasoline during 15-40- , and 60-mile-per-hour cruise operations were analyzed by chemical methods for formaldehyde, total aldehydes, total carbonyls, total alcohols, carbon associated with the oxygenated compounds, and the oxides of nitrogen. Experimental results indicate: 1. The range of concentrations of the total of the functional groups of oxygenated compounds, expressed as moles per million moles of water-free exhaust gases, is about 90-100; the concentrations increase with engine speed. 2. Aldehydes comprise about 80-90 mole- percent of the total of the oxygenated groups, and formaldehyde accounts for about 50 mole-percent of the total aldehydes. 3. The order of magnitude of the concentration of the carbonyls is the same as that for the aldehydes, indicating that ketones are not a major group. A colorimetric test indicates that methyl ketones Constitute about 2 mole-percent of the oxygenated compounds.

Jan 1, 1961

By Ludwig Schmidt

The policy of buying crude oil on a gravity basis , recently instituted by the major crude oil purchasing agencies in the Mid- Continent field , has caused a new and vital interest to be taken in the work of the U. S. Bureau of Mines for preventing evaporation of crude . From the early years of the industry oil men have recognized that the gravity of crude oil is usually an index of the gasoline content , but it has not been so generally known that the gravity of the crude oil decreases if evaporation is permitted . In 1919 the Bureau of Mines began a survey to determine the evaporation losses of crude petroleum in its various stages of handling from the well to the refinery , The results of this study are presented in Bulletin 200 ( Wiggins , J.H. , Evaporation losses of petroleum in the Mid- Continent Field , Bulletin 200 , U. s . Bureau of Mines , 1922. ) and Bulletin 225 ( Wiggins , J.H. , Methods of decreasing evaporation losses of petroleum , Bulletin 225 , U. S. Bureau of Mines , ( In press ) The findings of this survey were so startling that soon after the preliminary report had been published , several tank companies began manufacturing vapor- tight tanks for the purpose of reducing these important losses . Since that time the development of this type of apparatus has been so rapid that today , every oil trade journal carries numerous advertisements of vapor- tight tanks and equipment as well as technical articles dealing with various problems in connection with the elimination of evaporation losses , whereas three or four years ago the subject was scarcely even thought of. The present report has been prepared in response to numerous requests for information on the apparatus actually being used to prevent evaporation losses . At this time oil operators are also extremely interested in holding the lighter fractions in the crude oil in order to prevent a lowering in gravity . The practice of removing the vapors from crude- oil tanks by means of a slight vacuum and extracting the gasoline from them is not discussed here .

Feb 1, 1923

By Levent Ozdemir

The results of a laboratory research program aimed at the development of a water jet assisted drag bit cutting system for coal mine applications are presented. Two types of drag bits, a conical and a plow bit, were tested in a hard sandstone rock with jet pressures of up to 20,000 psi. Jet locations investigated were in-front and behind the bit. For each jet mounting location, three jet impingement distances with respect to bit tip were tested. The closest jet impingement location to bit tip was found most effective, providing the greatest force reductions on the bit. Overall, significant bit force reductions up to 50 percent were obtained with jet assist. Also observed was a drastic reduction in airborne dust when jets were employed.

Jan 1, 1986

By Walter Kawa

The hydrogenation of phenyl ether, benzyl ether, and phenyl sulfide in the presence of iron catalysts was studied by the Bureau of Mines to gain a better understanding of the role of iron catalysts in the hydrogenation of coal. The carbon-oxygen and carbon-sulfur bonds in these compounds may be similar to some of the carbon-oxygen and carbon-sulfur bonds in coal which react during the early stages of liquefaction by hydrogenation. Experiments were made in batch autoclaves for 4 hours; hydrogen was at a pressure of about 540 atmospheres. In the hydrogenation of phenyl ether at 400° C, metallic iron catalyzed both hydrogenolysis (splitting-hydrogenation) and nuclear hydrogenation (addition of hydrogen to aromatic rings) reactions, Products were principally benzene and cyclohexane. The activity of metallic iron was decreased by adding carbon monoxide or a reactive sulfur-containing organic compound. Ferrous sulfide catalyzed the conversion of phenyl ether to benzene, phenol, and small amounts of cyclohexane. Hydrogenolysis of benzyl ether was catalyzed by metallic iron and to a lesser extent, by ferrous sulfide at 250° C. No nuclear hydrogenation was observed with either catalyst. Conversion of phenyl sulfide to benzene was nearly quantitative in experiments made at 250° C with equimolar quantities of phenyl sulfide and metallic iron or iron as ferric oxide. Conversions of metallic iron and ferric oxide to ferrous sulfide were nearly stoichiometric. No reaction of phenyl sulfide occurred in the presence of ferric oxide and water, and very little occurred in the presence of metallic iron and water. Ferrous sulfide also catalyzed the hydrogenolysis of phenyl sulfide to benzene, but conversion was lower than in experiments with metallic iron or ferric oxide. The activity of ferrous sulfide was increased by adding water and decreased by adding hydrogen sulfide. The results of this study suggest that ferrous sulfide is an active form of iron when iron is used as a catalyst for the hydrogenation of coal.

Jan 1, 1963

By R. V. Ramani, K. Bode

"IntroductionThe theory of particle dispersion and deposition in turbulent flow is important to many fields of science and engineering. Dispersion has been studied in some detail since the early fifties (Taylor, 1954; Fischer, 1967; Osipov and Grekov, 1968; Skobunov, 1970 and 1973; Klebanov and Martynyuk, 1974). A broad research effort has also been underway in studying the mechanics of dry particle deposition. Friedlander and Johnstone (1957) proposed a theory, according to which particle deposition from vertical pipe flow could be described by an eddy diffusion transport followed by a final flight to the surface. There have been numerous revisions and additions to this original theory (Owen, 1960; Liu and Agarwal, 1974; Liu and llori, 1974; El-Shobokshy and Ismael, 1980) The mining process essentially consists of breaking in situ materials and transporting them out of the mine. An inherent characteristic of this process is the generation of fine particles. Fine airborne particulates are associated with a number of threats to the health of the miners; fine coal dust can also result in mine-wide catastrophic incidents such as dust explosions. For these and other reasons, it is important to understand the behaviour of airborne dust particulates, particularly their generation, entrainment, transport, dispersion, and deposition in the mine environment for their control.Mine related studies on dispersion and deposition have been few. Yet, several studies of gas and dust dispersion, diesel exhaust contamination, and methane ingress into mine workings have recognized the need for developing reliable parameter values for fundamental understanding of the phenomena (Da""Yes and Slack, 1954; Hodkinson, 1957; Hodkinson and leach, 1958; Mass and Wildschut, 1966; Airey, 1969; Courtney et al., 1986; Stefanko, Ramani, and Thakur, 1974; Stefanko, Ramani and Kenzy, 1977; Bhaskar, 1987, Bhaskar and Ramani 1990; Qin and Ramani, 1989; Shankar and Ramani, 1990)."

Dec 1, 1995

By Paul S. Schopf

The results of an experimental investigation into the possible use of medium energy acoustic fields (130 to 140 dB) to precipitate 1 to 10 micron particles is presented. The aerosol was produced with a LeMer generator using oleic acid and nitrogen. The sound field was a sinusoidal standing wave field in an acrylic tube, with light transmission data used for concentration determination. The results showed collection efficiencies of up to 80% on 2 micron particles with a residence time of 11.8 seconds at a sound pressure level of 139 dB re 2x10-5 N/m2. A discussion of the possible turbulent mechanism is made, as well as review and comparison with others? work.

Jan 1, 1972

This publication summarizes the research (in-house and contract projects) programmed by the Bureau of Mines for fiscal year 1985 (October 1, 1984-September 30, 1985) under its Health and Safety Technology Program. The objective of these projects is to provide an ordered and sequenced advance toward the Bureau&apos;s overall goal of providing the system technology required to create a more healthful and safer working environment for the Nation?s mining and minerals processing workers.

Jan 1, 1985

By M. R. Geer, H. F. Yancey

Fuel requirements of the Pacific Northwest have been increased greatly by the war . To the normal peacetime demands for fuel have been added the requirements of new industrial and metallurgical plants engaged in war production , the increased demand arising from expansion of existing industrial establishments , increased amounts of railroad fuel required to handle wartime traffic , and increased quantities of domestic fuel required by the influx of war workers . In the face of these augmented demands for fuel shipments of fuel oil have been curtailed , wood fuel which normally is an important factor in both industrial and domestic markets of the area is less abundant , and the production of coal in Washington has decreased sharply . The fuel requirements of the region have been met so far by shipping large tonnages of coal into the Pacific Northwest from Utah , Wyoming , Montana , and Colorado ; the quantity received from these States and Canada in 1943 amounted to 2,688,9124/ tons , 175 percent of the Washington production . or The proximity of the Washington coal mines to large centers of war production has resulted in widespread migration of miners to employment in shipyards and aircraft plants ; the ensuing shortage of miners largely accounts for the decreased production of coal in the State . Hence , strip mining , which requires relatively few workers and a shorter time for development , offers an attractive means of alleviating the local coal shortage and obviating the necessity of shipping coal from the producing areas of the Rocky Mountain States to the Pacific.coast . So urgent has been the necessity for augmenting local coal production that any coal property that promises to be amenable to strip mining , even though the coal may be inferior in quality , has warranted examination . Even low- grade coals that cannot compete in the normal market can be used locally , thus releasing better coals for shipment to critical centers. of consumption ... One such deposit of low- rank fuel examined by the Bureau of Mines is in western Lewis County , about 9 miles east of Toledo , Wash . The coal is lignitic and on the as - received basis has a heating value of 6,000 to 6,500 B.t.u. per pound . The property is of interest primarily because the physical conditions favor operation by stripping and offer opportunities for low- cost production with very low manpower requirement .

Jan 1, 1945

By Daniel D. Sweeney

The United States coal mining industry has traditionally experienced difficulty in controlling dust levels below the occupational exposure limit. While improvements in face ventilation and water spray nozzles have decreased dust exposures, approximately eight percent of experienced coal miners are still developing Coal Worker?s Pneumoconiosis. This investigation tested the feasibility of enhancing existing engineering dust controls by mounting a simple barrier on a longwall shearer that separated the operators from the cutting drums. The barrier was constructed and tested above ground at the National Institute for Occupational Safety and Health Pittsburgh Research Laboratory longwall gallery test facility. A 96-percent reduction of respirable dust occurred at the headgate sampling position when tested at 2.4 m/sec (480 ft/min). The average dust level decreased from 39 mg/m3 to 1.5 mg/m3 by utilizing the barrier.

Jan 1, 2009

By Paul T. Allsman

This paper describes metal- mining practices at the Harrington -Hickory lead - silver - zinc mine at Milford , Beaver County , Utah . The operations of the Harrington-Hickory incorporate a number of features that should prove of interest and value to other operators of small mines . These features include employee participation in profits , a well- laid -out electrical system, adequate financing , a well - balanced equipment and supply inventory , a well - organized system of bookkeeping , adequate roads , and good management . As crude ore is shipped directly to smelters and mills in the Salt Lake Valley , close attention is paid to see that the ore is segregated by classes and treated where it can bring the greatest not return . A combination of these features has resulted in maintaining relatively low costs, considering the grade and size of ore shoots at a time , during and following the war , when equipment , supplies , and labor were costly and difficult to obtain . The period covered in this report includes two war years and two years following , from April 1, 1944 to June 30 , 1947 .

Apr 1, 1949

By David Schlain

The galvanic corrosion properties of titanium in contact with commercially pure aluminum, copper, or type 302 stainless steel in some of the common organic acids were investigated. Acids used in these experiments were 10 percent formic, acetic, lactic, citric; 1 percent oxalic and tartaric; and 9 percent oxalic. Electrode-potential measurements and several types of galvanic couple experiments were carried out. Solutions were aerated by three methods: Flow of air, flow of helium, and natural aeration. Work was done at 35° C. with couples consisting of equal areas of the 2 metals. Titanium was resistant to corrosion in most of the organic acids studied, whether alone or in contact with a dissimilar metal. However, titanium coupled with aluminum did corrode in 1- and 9-percent oxalic acid solutions. Contact with titanium usually caused aluminum to corrode by galvanic action. Copper was subject to galvanic attack in 10-percent acetic acid with a flow of air. Contact with aluminum to some solutions in which titanium is ordinarily inert and noble with respect to aluminum caused titanium to corrode

Jan 1, 1956