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By R. W. Freedman

The Bureau of Mines has developed a gas chromatographic method for the rapid and accurate determination of oxygen, nitrogen, carbon dioxide, methane, and, if present, carbon monoxide in mine air. This method replaces such presently used gas-reaction types as the Haldane or Orsat analysis, offering advantages in terms of precision, accuracy, speed, and convenience.

Jan 1, 1968

By Nicholas P. Kripakov

The U.S. Bureau of Mines examined the applicability of existing material models to solve practical geotechnical mining-related problems by solving a yielding pillar stability problem considering confining effects on strength. Numerical difficulties normally encountered with modeling strain softening behavior were eased with a simplified computational procedure using a quasi-elastic approach to account for residual strength after initial failure. Although in agreement with a confined-core pillar design method using actual mine conditions that include mine layout geometry, overburden geology, and rock properties of the deposit and surrounding structure, the results cannot be verified because measured field data are not available at this writing.

Jan 1, 1981

By Tobias W. Goodman, Joseph Cervik

This Bureau of Mines report investigates the horizontal trajectory of boreholes drilled in coalbeds using the rotary drilling technique. Test holes drilled in coalbeds showed that the path of a borehole in the horizontal plane depends on drilling assembly configuration, drill bit rotation, and coalbed geologic features. An assembly that contained an 18-ft (5.53) long drill collar and two centralizers had the best horizontal stability evidenced by trajectories that deviated less than 16 ft (4.9 m) from a target at 1,000 ft (305 m). Removal of one of the centralizers resulted in a loss of control of hole trajectory in the horizontal plane. Generally, holes tended to turn to the right, presumably because of right-hand rotation of the bit. Deviations from the original bearing line were as much as 200 ft (61 m) or more at a depth of 1,000 ft (305 m).

Jan 1, 1988

By J. T. May

The Federal Bureau of Mines investigated the extraction of lithium from hectorite-type clay deposits found on the Nevada-Oregon border. Two clay samples were used in the investigation; one contained 0.36 pct Li and the second contained 0.64 pct Li. The purpose of this laboratory-scale research was to determine how these clays responded to different extraction techniques. Extraction techniques investigated were sulfuric acid leach, sulfuric acid bake-water leach, and roast-water leach procedures with cholorides, sulfates, carbonates, and combinations of these reagents. The processing characteristics of the clay samples showed significant variations, and no one technique was effective for both materials. Lithium extractions near 90 pct were achieved during these exploratory studies.

Jan 1, 1980

By A. J. Kraemer

The Bureau of Mines for a number of years has been carrying on an investigation of properties of crude petroleum from producing, fields in the United States and the Western Hemisphere, and has published a series of reports on these fields, including oil fields of Oklahoma2. Acknowledgements Thanks are due to R. R. Brandenthaler and Peter Grandone, of the Petroleum Experiment Station of the Bureau of Mines, at Bartlesville, Oklahoma, who reviewed the manuscript and contributed valuable suggestions. The samples were analyzed under the direction of E. C. Lane at the Bartlesville station of the Bureau of Mines.

Jan 1, 1927

By J. W. Eckerd

Metal production rates of 42 to 45 tons per day were obtained with hollow-core anthracite briquets in an experimental blast furnace. Tuyere pressures were about the same for both coke and briquet operations, but from 150 to 175 pounds more of briquets were required per ton of metal than were needed with coke. Furnace operations were comparatively smooth, furnace hanging occurring less often than in previous tests with anthracite briquets. Dust production was substantially higher than with coke, however, and metal quality could not be controlled by corrective burdening and moisture control.

Jan 1, 1968

By Garrett R. Hyde

Sintered yttria and sintered dysprosia can be used to make single-component thermistors having typical thermistor geometries and operable in the temperature range 500° to 1,200° C. However, at these temperatures, instability of platinum electrodes can contribute a slight aging effect if the thermistor is kept near 1,200° C for long periods. Typical characteristics at 500° C for an yttria disk thermistor 12 mm in diameter and 2 mm thick are a resistance of 12.4 megohms and a temperature coefficient of resistance of -3.8 percent per degree C. Typical characteristics at 500° C for a dysprosia thermistor of the same dimensions are a resistance of 1.84 kohms and a temperature coefficient of resistance of -1.6 percent per degree C.

Jan 1, 1970

By Howard E. Parkinson

An environment monitoring and communication system has been installed in the Bruceton Mine, and research is under way to improve mine safety. Standard day-to-day mine communications are available, along with additional systems installed to permit experimentation with wireless radio, through-the-earth phones, along-the-roof paging, and mine face machinery communications. Research is continuing and the essential concepts for a dependable whole mine communication system, providing simple environment monitoring, improved day-to-day communications and post-disaster communications, will be demonstrated in a larger mine with about 900 feet of overburden.

By Robert M. Doerr

In a process being investigated by the Bureau of Mines for recovering alumina from domestic nonbauxitic resources, calcined kaolinitic clay is leached with hydrochloric acid. Iron impurity in the clay is coleached and is removed in a solvent extraction step prior to crystallization of aluminum chloride hexahydrate, which is subsequently thermally decomposed to alumina. The FeCI3-HCl stripping liquor from the solvent extraction step is unsuitable for discharging to the environment; furthermore, economics requires recovery of the contained chloride values. In the present research, it was shown that the stripping liquor can be reacted with calcined clay to yield AlC13 in solution, plus precipitated iron oxides, residual silica, and unreacted excess clay as mixed solids. For the recovery of the AICl3 solution, the slurry could be separated or returned to the clay-HCI process stream at the solids washing step that follows primary HCI leaching of the clay. For the range 20° to 99° C, the time (t) (103 sec) required to react the waste liquor with excess clay, for essentially complete iron precipitation, depends on the absolute temperature (T) chosen, according to the expression t = e[(9.000/T) -23.5J. (1) Alumina was tried as a reagent alternative to clay but was not very effective, even under pressure and at high temperatures.

Jan 1, 1982

By E. Chin

Natural gas was Bangladesh's only significant exploited mineral. A few other minerals or mineral-based commodities were produced for local consumption. The most valuable were nitrogen fertilizer, salt, cement, and clay for brick.2 The most important mineral industry development of 1987 was the start of modest production of crude oil, the first discovered and produced in the country. PRODUCTION AND TIADE Production of natural gas from the nation's huge reserves continued to increase but was limited by the lack of residential and industrial demand. Gas reserves of 7 trillion to 16 trillion cubic feet were sufficient for far more production than the country could efficiently utilize for many years. The country's consumption-to-reserves ratio was one of the lowest of the developing nations. Mineral exports have been insignificant, comprising a small amount of nitrogen fertilizer. Nitrogenous fertilizer exports could become important when planned new capacity comes on-stream. Mineral imports were dominated by crude petroleum.

Jan 1, 1989

By John Ward Smith

Oil-yield data are presented for core samples from Colorado Corehole No.1, drilled by the Bureau of Mines and the Atomic Energy Commission in a previously untested oil-shale area near the northern edge of Colorado's Piceance Creek Basin. Continuous oil shale 2068 feet thick, averaging 18.41 gallons of oil per ton of shale and representing 1.8 billion barrels of oil per square mile, occurs at the core site.

Jan 1, 1968

By Rollien R. Wells

A REPORT of technological advancements restricted to a specific 12-month period is impractical. Inherent in the nature and development of technology is the element of time; rarely can a new process or product be attributed to a particular year. An overall picture of general trends and pattern changes, however, is indicative of technological growth. This paper presents selected observations and discussions of current metallurgical research and practices in an attempt to develop' such a picture. Of the estimated $16.5 billion spent for research and development in the United States in 1962, at least 80 percent was earmarked for the aircraft, electronics, chemical, and machinery industries. Much of the effort was of the end-use variety and was oriented closely to the national defense and aerospace programs. Only a small fraction of the total research money was directed to studies of the utilization and improvement of metals. Even if the investigations in allied fields such as solid state physics are included, the total research expenditure for metal and mineral materials barely reached $500 million. An additional $200 million was spent by industry and government for development of minerals recovery and processing methods.

Jan 1, 1963

By Joseph Cervik, J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus has been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural under- ground environment.

Aug 1, 1970

By R. E. Mussler

Electrowinning of copper from chloride solutions in a diaphragm cell was studied by the Bureau of Mines. The copper powder product was shaken periodically from the cathode and removed from the bottom of the cell. The effects of copper concentration, brine concentration, copper chloride species, and cell voltage were investigated. Power consumption of 1.1 and 2.1 kW-hr/kg were obtained with cuprous and cupric chloride solutions, respectively.

Jan 1, 1975

Enhance hydraulic fragmentation technology by developing alternative grout sealing methods. Traditional grout scaling methods rely on chemical adhesion and require large contact areas to restrict high-pressure fluids. Fluid injection into rock requires economical and effective seals. With economical and effective seals, rock is easily fractured in tension by high-pressure fluid injection (fig. 1). Approach An innovative grouting technique was developed and tested by the Bureau. Slowly hydrating expanding chemicals are placed within a borehole and around a section of high-pressure tubing. Testing was conducted using 9/16-inch-OD smooth-walled injection tubes in 1.5-inch-ID holes. Seal lengths weir less than 10 inches and curing times were less than 24 hours.

Jan 1, 1989

Develop improved blasting practices that can help to curb overbreak in highwalls at surface mines, thereby reducing the hazards of rock-falls to workers and equipment, The Problem The serious hazard in surface mining is the falling of rock from highwalls. Poor highwall stability is caused in part by geologic conditions, but often is aggravated by faulty blasting practices, where the explosive energy not only fractures the rock to be excavated, but also damages the rock that borders the excavation. This reduces the general stability of the hlghwall and increases the rockfall potential. The probability of injury to mine workers or damage to equipment associated with exposure to the highwall increases with the height of the highwall and the extent of its overbreakage. Most rockfalls occur in the first 15 days after a new highwall is exposed. This statistic is significant since most of the work below a highwall is done during this period. The area of greatest hazard is within 25 ft of the toe for rocks that fall vertically, and up to 90 ft from the toe for falling rocks that are deflected by the highwall during their descent, The workers most frequently involved in such accidents are dozer operators, ground laborers, and shovel operators or oilers.

Jan 1, 1985

To more rapidly and economically prepare solutions for chemical analysis, of a wide range of ores, slags, minerals, and metals. Approach A Simple pressure-dissolution system was devised using an inexpensive, heavy wall plastic bottle containing a sample in an acid medium. Using the technique, a complex silicate sample can be dissolved in less than 1 hour. How It Works A weighed portion of a sample, ground to minus 100-mesh, is placed into a polycarbonate or polysulfone plastic bottle. A mixture of hydrochloric acid, nitric acid, and hydrofluoric acid then is added. The bottle threads are wrapped with a layer of Teflon tape to prevent leakage, and the bottle cap is screwed on tightly. The sealed bottle is placed in a balling water bath. In the hot water, the plastic bottle acts as a pressure vessel to contain the pressure generated inside it. This technique should only be used by trained experienced people who are familiar with the hazards of hot acids under pressure. After being cooled in cold water, the resulting solution is brought to the final volume by adding 1.5 weight-percent boric acid solution to the bottle. The cap is replaced, and the bottle and solution is reheated. Precipitated fluorides, as well as any residue, are dissolved by the fluoride-boric acid reaction. The resulting clear solution then is suitable for spectro-photometric examination or other analysis.

Jan 1, 1980

By D. E. Hirsch

A systematic procedure for separation, characterization, and semiquantitative analysis of high-boiling petroleum distillates was developed by the Bureau of Mines and applied to a 370° to 535° C distillate of Wilmington, Calif., crude oil. Separation procedures employed were isothermal and molecular distillation, chemical treatment, silica-alumina adsorption, and gel permeation chromatography. Characterization and analysis were accomplished by gel permeation chromatography correlations and mass and nuclear magnetic resonance spectrometry. These data should be useful in improving petroleum processing and utilization and in achieving the energy conservation inherent therein.

Jan 1, 1974

Provide the mining industry with a wireless surveying system for increasing efficiency in the drilling of methane drainage or exploration boreholes. Approach The Bureau of Mines has pioneered the technique of methane control by drilling long, horizontal drainage holes from within the mine complex. It was recognized during the early drainage projects that a major portion of the drilling operation was dedicated to hole surveying. In some cases more time was actually being spent on the surveying operation than on drilling. The large amount of time required for hole surveying was the result of having to pump an instrument to the bottom of the hole, then retrieve it with an attached wire line. Naturally as hole depth increased, so did the amount of time needed to perform the survey operation. If the survey operation could be improved it was obvious that overall efficiency in drilling of long, horizontal methane drainage holes would be greatly increased. The Bureau of Mines, therefore, developed, fabricated and tested in an operating coal mine a permissible wireless survey system specifically designed for small diameter methane drainage drilling. The prototype survey system was completed in 1982 and was given the IR-100 Award by Industrial Research and Development Magazine. A second generation survey system is currently being constructed using updated state-of-the-art electronic technology. The second generation system will be more portable, more reliable, easier to maintain, and less costly.

Jan 1, 1984

By Arthur M. Hartstein

The Bureau of Mines, through contract with Ultrasystems, Inc., obtained data on the oxidative degradative behavior of a number of materials used in coal mines. Tests were performed using a stagnation burner arrangement. Materials examined included those used in typical coal mining operations such as (1) polyvinyl chloride-containing materials. (2) neoprene compositions, (3) rigid foams (urethanes/isocyanates), (4) miscellaneous materials (including jute, fiber glass, and polyethylene), (5) coal, (6) fluids (phosphate esters, organic esters, oil-water emulsions), and (7) composites. The composite comprised a mixture of a phosphate ester fluid with (1) coal, (2) a representative polyvinyl chloride sample, or (3) a neoprene-type composition. A number of decomposition products are identified that could represent a potential health hazard to miners including HC1, CO, SO2 and H2S, if they were generated to exceed toxic levels.

Jan 1, 1974