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By C. M. Chang, H Gu, J. A. Barrera-Godínez, T. J. O’Keefe

The inability to economically separate Fe3+(aq) from a variety of liquid effluents is a major Concern for the primary metals industry. A unique solvent extraction process, galvanic stripping, has been developed to address this problem. The galvanic stripping of iron from D2EHPA using only a 5~10 g/L H2SO4 solution is achieved after Fe3+ is directly reduced to Fee, in the organic phase using zinc metal additions. To date, the primary focus of the laboratory research has been on optimizing the parameters that control iron removal. The results from these studies have now been, used to make a preliminary design for a continuous flow process that is envisioned for zinc industrial applications. Specific quantitative data are shown for the use of a Zn-Ph cellos° in the iron-reams al process. Some introductory results on electrochemical potential measurements and impurity distribution with solution cycling are also giiven.

Jan 1, 2000

By R. A. Jankowski

Laboratory tests were conducted to evaluate the silica collection efficiency of flooded-bed scrubbers using six different filter panel designs at two operating velocities. Test results indicated that reductions in filter density negatively impacted respirable dust collection. Silica collection efficiency for the least-dense filter was as much as 33 % lower than the collection efficiency of the most-dense filter. At the low operating velocity, the least-dense filter allowed more than 40% of the respirable silica dust in the scrubber intake air to pass through the unit and back into the mine environment. Operation of the scrubber at the higher test air velocity increased silica collection efficiency regardless of the filter panel tested The density of the filter panels also impacted the quantity of air moved through the scrubber, with higher-density filters reducing scrubber airflow. For each filter, the relationship between dust-collection efficiency and air-moving capacity must be considered to determine the overall effectiveness for each mine application.

Jan 1, 2000

By S. Kesler

Rössing Uranium Limited has operated since 1976 a large open pit uranium mine and extraction plant at a remote site in the Namib desert, South West Africa/Namibia. The geology (Berning, I., et al. Economy Geology) and the technical aspects concerning mining, grade control and metallurgy have previously been described (Rössing Uranium, Mining Magazin and Whyllie, R.J.M. "Rössing Uranium reaches rated production", World Mining). The improvement of leach 'extraction has been reported in 1984 (Kesler, S.B. et. al. "Uranium extraction at Rössing") and the installation of a central process control system has been described (Kesler, S.B. et al. "The introduction of a central process system at Rössing"). At the beginning of 1983 a decision was made to develop a computer system for metallurgical plant optimisation which included mass and volumetric balances, analytical assays for up to 5 chemical elements and the costs for the major consumables. Within 10 months this computer system was developed and implemented. A large number of test runs were made and computer studies were undertaken. The metallurgical division now has a scientific tool for production; planning for actual comparison with plant results and for strategic investigations and decision making.

Jan 1, 1986

By T. Leftwich, G. Faison, K. Pavlich, R. Borden, S. Pavlou

Recent regulatory and policy initiatives under the Resource Conservation and Recovery Act (RCRA), and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), will have a significant effect in risk reduction requirements for the mining and minerals processing industry. For example, Congress is considering regulating 20 special wastes from the processing of ore and minerals through RCRA Subtitle D and TSCA. The performance of risk analyses and environmental planning at mining projects is often driven by Federal and state regulatory standards. Recent regulatory and policy initiatives by the Environmental Protection Agency under the Resource Conservation and Recovery Act (RCRA), and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), will have a significant effect on environmental planning and risk reduction programs for mining and minerals processing. Regulatory programs implemented under other Federal laws including the Safe Drinking Water Act, Clean Water Act, and Clean Air Act will also impact industry practices. This paper provides: 1) a brief overview of mining waste and mining waste management, and 2) a description of these regulatory initiatives and a discussion on the impacts of new requirements on environmental and risk reduction programs in the mining industry.

Jan 1, 1992

By D. L. Jones, S. Knoerr, J. Mansanti

The Buckhorn Mine in Nevada currently treats oxide ore using heap leach methods, but exploration has identified sulphide reserves which are refractory in nature. Preliminary testwork was conducted on the sulphide material to screen potential pre-cyanidation treatment methods. Processes evaluated included pressure oxidation, biological oxidation, nitric acid oxidation and roasting. An initial economic and process analysis of the results concluded that roasting was the only viable process, and only if the roaster off-gases were converted to soleable sulphuric acid. Further economic analysis indicated that roasting of the whole ore was more attractive than pre-concentrating by flotation, followed by roasting of the concentrate. These results were generalized to show that for high sulphur ore a roaster/acid plant combination is more attractive that either of the other options, ie. pressure leaching or bioleaching, provided the by-product acid is soleable.

Jan 1, 1990

By C. Abbruzzese, L. Piga, P. Fornari, S. Ubaldini, R. Massidda

The effects of certain variables on the extraction of gold by thioureation have been investigated on a quartzose gold-bearing ore using a statistical multifactorial strategy. The factors taken into consideration were milling time (which corresponds to a given grain size), oxidant concentration, thiourea concentration and liquid/solid ratio. The influence of these four variables was ascertained first by a full factorial design at two levels for each variable (16 runs). This permitted the estimation of first-order effects of the factors affecting the process. Then 9 runs were added whose levels were both in the centre of and outside the axes of the previous plan thus originating a central composite design. This permitted estimation both of second-order effects of the factors involved and of parameters of a second-order polynomial model. The results show that extraction of gold depends only on milling time and oxidant concentration, at least in the experimental range considered. The equation fitting experimental data, as calculated by the least squares method, allows a response surface to be drawn. Due to the low gold grade of the ore (6 ppm) statistical analysis could lead to contradictory results, hence strict observance of Gy's rules for sampling and very accurate and precise chemical analyses were required.

Jan 1, 1995

By G. M. Wilemon, Swanton. R. G.

The Bureau of Mines is investigating the leaching of phosphate values from Florida phosphatic clay wastes using sulfuric acid (H2SO4) as the leaching agent and methanol as the solvent. Acid-alcohol leaching studies were done using research-grade apatite to investigate potential causes of flow extractions. It was found that a barrier layer formed on the surface of the apatite. Initial discovery of the barrier layer was made by analyzing pure apatite samples before and after leaching using an optical microscope. Subsequent Fourier Transform Infrared (FT-IR) analyses proved the coating was calcium sulfate hemihydrate (CaSO4•1/2H2O) and that unreacted apatite existed beneath the coating. Scanning electron microscope (SEM) photographs depict the CaSO4• 1 /2H20 morphology as long slender crystals adhering to the apatite surface. It was also shown that grinding the leached tailings and leaching again in the H2SO4-methanol system resulted in additional phosphate extraction.

Jan 1, 1992

By Steven A. Tesdahl

Maintenance means keeping equipment running or restoring it to operating condition. However, the 21st century will usher in a broader need for equipment management, a cradle-to-grave strategy to preserve equipment functions, avoid the consequences of failure and ensure the productive capacity of equipment. Profitable future mining operations will have reduced the 35% of operating costs typically spent on maintenance and the unfavorable impact of downtime that often multiplied these costs by 300%. They will survive those operations that tried to carry outdated "maintenance" thinking beyond the year 2000. These surviving operations will have applied modern management techniques, technology and information to align the efforts of people with the needs of equipment. Future managers will use equipment management as an integral part of an overall production strategy. They will see it as a means of raising productivity, improving performance and minimizing downtime to maximize profitability. This global thinking will characterize all operations planning to survive in the competitive world of mining of the next century.

Jan 1, 1998

By R. L. Grayson

The Office for Mine Safety and Health Research, National Institute for Occupational Safety and Health is responsible for providing research leadership in the prevention of mining work-related illness, injury and death. Planning of the NIOSH FY99 research program focused on the comprehensive collection and risk analysis of fatality, injury and illness data according to commodity and mine type. This data, coupled with the mapping of information obtained from stakeholder meetings over several years, provided the basis for prioritizing research needs. Results of the combined analysis were compared to the FY98 program to identify surveillance and research gap areas. The FY98 research program was then assessed according to commodity and mine type and compared with exposure assessments, traumatic fatality rates, injury rates and employment trends in each commodity-mine type combination to gain insight into the potential balance of the future research program. This paper presents the methods, data and results of this planning process.

Jan 1, 2002

By G. H. Schnakenberg

In 1986, the US Bureau of Mines (USBM) embarked on a major research effort to develop technology that could substantially reduce worker exposure to face hazards by simply relocating the equipment operators to an area of relative safety. This reduced-exposure mining system (REMS) research effort enhances the USBM's ongoing health and safety efforts aimed at reducing and controlling dust and noise and reducing accidents through training and better mining practices. This paper reports on the progress made on the developing research and demonstrates the technologies required for the computer-assisted teleremote operation of continuous mining machines, haulage systems and roof bolting machines.

Jan 1, 1998

By D. A. Rice, R. G. Swanton, A. May, O. C. Carter

As part of a cooperative effort between the US Bureau of Mines and the Florida Institute of Phosphate Research (FIPR), with input from the phosphate industry, the conversion of phosphogypsum to sulfur is being investigated. The proposed process incorporates a thermal reduction of phosphogypsum to calcium sulfide (CaS) and a hydrometallurgical treatment to convert calcium sulfide to ammonium bisulfide (NH4SH), which is then oxidized using a catalyst to produce elemental sulfur. The paper summarizes the results of continuing laboratory studies using an activated carbon catalyst which was loaded with sulfur through oxidation of ammonium bisulfide solution. The extraction of the sulfur that forms in situ on the catalyst is a key area in the development of the sulfur recovery process. Two approaches for removing the sulfur are being investigated: (1) thermal treatment to volatilize sulfur. and (2) leaching the sulfur using liquid anhydrous ammonia. The research has shown that it is technically feasible to recover over 90% of the sulfur from the carbon by either volatilization or ammonia leaching. Locked cycle testing has demonstrated that the carbon has the potential to be recycled after ammonia leaching.

Jan 1, 1987

By John A. Herbst, Per-Olaf Samskog, Jan Bjorkman, Yi Chang Lo

The study described here is concerned with the development of a model for the simulation and optimization of a rod milllpebble mill circuit. A series of laboratory tests was conducted to investigate the effect of critical operating variables. The pebble mill model structure used was a population balance type which accounta for impact breakage and fines production from pebble wear. Model parameterization and verification were performed using data obtained in batch tests and in a plant test campaign. The model developed was found to provide accurate predictions of plant-scale grinding. The prediction errors are less than 21 for the product size and 31 for the mill power required to achieve that product with a mill volume scale-up of 14,000 to 1. These results indicate that accurate extrapolations from laboratory batch data to plant scale performance are poaaible using the population balance model and scale-up prediction procedures for pebble mill circuits as well as ball mills. Preliminary indications are that the new model developed here will provide vital input for pebble mill optimization and process control as well as pebble mill design.

Jan 1, 1990

By C. L. Karr, D. E. Goldberg

This paper considers optimization of the design and operation of an air-injected hydrocyclone (AIHC) via a genetic algorithm (CAI. The AIHC is a mineral separating device, developed by the U.S. Bureau of Mines, that combines the selectivity of flotation with the capacity and simplicity of hydrocyclones. GA's are search procedures based on the mechanics of natural genetics. Computer results demonstrate the ability of a GA to rapidly locate design and operating parameters that improve AIHC performance. A computer model of the GA-designed AIHC predicts improved recovery over that currently being obtained with an AIHC in operation at the U.S. Bureau of Mines Tuscaloosa Research Center.

Jan 1, 1990

By I. E. Zevgolis

A comprehensive critical review on the subject of sulfates-induced swelling behavior of lime-treated soils is presented in this study. Starting with the description of a well documented case study, the mechanisms behind the swelling behavior and the factors that affect this behavior are discussed. Then, the major experimental methods of sulfates content determination are briefly presented. Finally, an attempt is made to categorize sulfates level and equivalent risk for civil infrastructure. The paper indicates that limited work has been done, not only on identifying safe conditions for use of chemical stabilizers in presence of sulfate rich soils, but also on developing materials and methods to avoid, or at least mitigate, the problem.

Jan 1, 2008

By Y. C. Kim, M Nataraja, J. T. Buckley, D. H. Tiktinsk

The Nuclear Waste Policy Act of 1982 (NWPA) assigns the U.S. Department of Energy (DOE) the responsibi1it.y of locating, constructing. operating, closing and decommissioning a nuclear waste repository. Prior to submittal of a licensee application to the U. S. Nuclear Regulatory Commission, the DOE is required by 10 CFR part 60 to conduct a program of site characterization for the site to be described in such application. Site characterization includes an exploration and research program in the field and laboratory to determine the geologic conditions and ranges of those parameters which are necessary for determining the suitabi1it.y of the site as a geologic repository. The information thus collected should be able to establish with reasonable assurance that the public and environment will be adequately protected from the hazards associated with a repository at the site. This paper demonstrates by example a geostatistical approach which, on the basis of the existing limited data base, can be used to evaluate (1) whether existing information on a certain parameter is adequate to be considered representative. (2) if additional information is required, where should the additional sampling or testing be performed, and (3) whether the new1.y acquired data along with the existing information constitute representative data.

Jan 1, 1986

By Gerhard Sauer, Heimo Gold

The main advantage of the New Austrian Tunneling Method over conventional drill and blast techniques, TBMs and shields is its outstanding flexibility. Many different support concepts help to cope with all but the most adverse conditions. A considerable variety of unique additional support measurements provide a functional tool when dealing with particularly difficult conditions or restricting requirements. The resulting adaptability of NATM with respect to geometric and geologic changes is a cornerstone to providing an economic design and to a safe and unhindered execution of the tunnel work. To take best advantage of this flexibility and to emphasize its cost-saving capacity, NATM explicitly extends the design period into the construction phase. In accordance with corresponding ground classes or other anticipated conditions, a number of basic support categories and an array of additional support measurements are established during the actual design phase. The decision for applying a particular support category at a specific location and for necessary additions to the given support scheme, however, is regularly made on site after each advance, and is determined by the key persons involved in the construction. Contract documents must reflect this approach to facilitate the execution of the work and to curtail construction costs. Biased distributions of risks, however, can adversely effect the envisioned benefits. Consequently, the respective responsibilities of engineer, contractor, and client need to be redefined.

Jan 1, 1989

By K. H. Al-Rawahy

Mineral resources comprise of metallic, non-metallic, and fossil fuels. Our civilization, and the associated economic and industrial developments are inherently dependent on the availability and use of minerals. This is evident from historical development and identification of civilization eras throughout human history: the stone age, the iron age, the bronze age, and the current computer age. This paper deals with the depletable fossil fuel sector of minerals; this is represented by crude oil, natural gas, and coal. Fossil fuels provide approximately 80% of total global primary energy supply; the rest being provided by renewables (wind, hydrothermal, solar), nuclear, and biomass. Economic, industrial, and population growth will, inevitably, lead to an increase in demand for energy. In general, per capita energy consumption is correlated with per capita income, with the US showing the highest energy use per capita, and South Asia having the lowest. This paper examines the underlying interrelated issues (factors) of energy reserves, production, scarcity, depletion, economic, and technological factors and impact on long term availability and thus sustainability. Is it possible to extend the time to economic depletion of these resources? This will have an impact, direct or otherwise on total energy availability, and the inter-temporal allocation of the resource. Specific economic and physical parameters relevant to mineral supply and their respective impact on depletion, and inter-temporal welfare are investigated. These variables include own price, substitute price, population, income, technical innovation-both on supply as well demand, and resource substitution.

Jan 1, 2007

By Z. D. Yu, J. E. Gebhardt, D. I. Phillips, S. X. Jiang, R. Z. Zhang

The potential application of flotation for the treatment and processing of a fine-particle coal stream was investigated for the Chaili Coal Washery of the Zaozhuang Coal Mine Administration, Shandong Province, China. A goal of the test work was to evaluate the application of the Microcel™ flotation column and compare its performance to conventional flotation. Small-scale flotation tests were performed in the laboratory and on-site with fine coal slurry samples from the plant thickener underflow, i.e., the washing plant's undersized reject material. Flotation tests were conducted on-site with a 7.6-cm diameter Microcel™ column and with small-scale conventional cells. Column flotation tests were performed to determine a recovery-grade relationship for the fine coal feed, which contained about 24% ash, and to obtain sufficient data to enable scale-up to a large diameter unit. A primary objective as to establish the maximum throughput capacity of a Microcel™ flotation column while operating to produce a clean coal product with ash content of 7.5-7.8%. Results of the test work indicate that this product quality could be achieved at feed rates of 15-19 tph to a 3-m diameter Microcel™ flotation column. Lower ash products, i.e., 5-7% ash, were obtained but at lower column throughput capacities. Comparative flotation tests, conducted with conventional flotation cells, indicated that a product ash of only 8% or greater was achieved in a single-stage test.

Jan 1, 1995

By Robert H. Shannon

Coal is the primary fuel for U.S. electric per generation -- over 78% of U.S coal production. In 1987 over 56% of electric per generation was from coal-fired plants. Areas of concern confronting the expanded use of coal for per generation include environmental, political and the nation's energy security and economy. These matters and available alternatives and options directed to the expanded use of coal are reviewed.

Jan 1, 1989

By G. J. Olson, K. S. Noah

A combined physical/biochemical process for the precombustion removal of 13 inorganic hazardous air pollutant (HAP) precursors, i.e., Sb, As, Be, Cd, Cr, Cl, Co, F, Pb, Hg, Mn, Ni and Se, from coal was tested. Biochemical processes for removal of HAP precursors from coal potentially offer advantages of deeper cleaning, more specificity and less coal loss. The slurry column is a second-generation process for the beneficiation o f fine (60-mesh x µm coal by a combination of physical separation of mineral matter and biooxidation of pyrite. Sixty-seven percent removal of pyrite from a 60-mesh Pittsburgh #8 coal was achieved at a 35% (w/w) slurry concentration and a five-day reactor residence time. Ninety percent of the heating value of the feed coal was recovered. Among the HAP precursors of most concern, over half of the Se, As and Hg were removed from the feed coal. From 40% to 70% of most HAP precursors were removed from the feed coal. Hg in the feed coal was reduced from 0.12 to 0.054 ,µg/g in the product coal, while waste coal contained 0.24 µg/g.

Jan 1, 2000