Search Documents

By M. Moats

Copper electrowinning operations have dramatically improved their ability to produce high quality copper at low costs over the past several decades. Even so, some fundamental knowledge is still lacking that could allow operations to run even more efficiently. For example, a rule of thumb exists that estimates a current efficiency loss of 2-3% per gram per liter of iron in the electrolyte. While several laboratory studies have been performed that demonstrate this rule of thumb is likely true, no definitive relationship exists. In this paper, the first steps in developing a definitive relationship are presented. The effective diffusivity of ferric ions in synthetic copper electrowinning solutions was measured using chronoamperometry and the Cottrell equation. The effective diffusivity of ferric ion was determined as a function of electrolyte concentration and temperature. Synthetic electrolytes were then used in laboratory-scaled copper electrowinning experiments, where relationships between current efficiency and solution composition were found to exist under stagnant conditions. Key words: Copper electrowinning, Current efficiency, Chronoamperometry, Ferric ions

Jan 1, 2009

By Roger D. Sharpe

Oklahoma contains extensive resources of high-purity gypsum that were deposited in the Anadarko and Hollis basins during Permian time. The gypsum resources and reserves are estimated to be about 48 billion short tons and a; located in the western portion of the state. Oklahoma is the largest producer of gypsum products in the United States. The Blaine Formation and the Cloud Chief Gypsum contain several beds of minable thickness. Four stratigraphic units in the Blaine Formation are quarried in Oklahoma. The Shimer, Nescatunga, and Medicine Lodge Members are quarried in northwest Oklahoma. The Van Vacter Member, consisting of three gypsum beds, is quarried in southwest Oklahoma. The Cloud Chief Gypsum is quarried in the west-central part of the state. The gently dipping gypsum in the Blaine Formation generally crops out along low escarpments and is covered in the downdip direction by increasing overburden, consisting of sand, shale, and/or dolomite. Anhydrite occurs in the downdip direction under the thicker overburden. The Cloud Chief Gypsum crops out as hills, which are eroded remnants of a more widespread, massive sulfate unit. All of the gypsum produced in Oklahoma is extracted using quarrying methods. A variety of products are made from gypsum quarried in Oklahoma. The products are manufactured from uncalcined, calcined, and deadburned gypsum. Products vary from raw, ground gypsum used for agriculture, to high-value-added industrial plasters, cements, and fillers produced from calcined gypsum. A sampling of the many products manufactured from Oklahoma gypsumincludes: (1) agricultural-soil amendment; carrier for insecticides, pesticides, and herbicides; calcium supplement in animal feeds; (2) gypsum wallboard-common, fire-resistant, and water-resistant varieties; (3) industrialgypsum plasters-art and casting, pottery and ceramic, molding and tooling, crayons, wall patching; (4) industrial gypsum cements-oil-well cement, high-strength statuary, high-strength tooling, fiber-reinforced architectural, road and bridge repair; (5) food and pharmaceutical-filler and binder in aspirin and other medicines, yeast activator in brewing of beer, moisture absorbent in bread and pizza dough; and (6)portland-cement retarder-ground with clinker to control setting time.

Jan 1, 1999

By D. Shaver, M. N. Badonie, J. Newcomer, V. T. McLemore, E. Owen

Rare earth elements and critical minerals have recently become of great economic interest because of their necessity for many new technologies and recent geopolitical unrest affecting the supply and import of resources. The San Juan and Raton basins in northern New Mexico are two structural coal basins that contain elevated concentrations of rare earth elements and critical minerals. These two New Mexican coal basins will be assessed geochemically and petrographically to identify vectors of the rare earth element and critical mineral enrichment. Coalbeds, coal seams, overlying, and underlying rock units will be sampled and characterized to determine any economic viability. Historic data will be compiled into a new and comprehensive coal geochemical database, which will grow with new analyses, and serve as the dataset for this project; this coal resource database will be made available to the public.

Feb 1, 2023

By P. D. Chamberlin

Agglomeration for the heap leaching of gold and silver ores can be defined as the process of attaching fine ore particles (less than 100 mesh) to coarser particles so the fines are immobilized and uniformly distributed throughout the heap, thus making the heap more porous and uniformly permeable to the flow of a leaching solution. Agglomeration techniques and equipment to be described include drum and disc agglomerators, stockpile and belt agglomeration, and the use of vibrating deck and reverse running conveyors.

Jan 1, 1986

By S. C. Gaillard

Tailings are made of ground rock that is left over from removing valuable minerals. The tailings are usually fine particles that cause environmental issues for storage and disposal. Disposal of tailings is a growing concern, as more tailings are produced from the increasing demand for mined material (ITRC, 2008). This project proposes a way to convert the mine waste to a useful product. Tailings were selected from a South Carolina crushed stone quarry, the products of which are used for road beds, sidewalks, asphalt and driveways. These tailings were processed to generate synthetic aggregates for construction applications. The synthetic aggregate creates a product that could be used for many purposes, including aggregate for sidewalks, driveways, roads and building materials. Testing methods followed the North Carolina Department of Transportation (NCDOT) guidelines for physical testing of coarse natural aggregate, which are sieve analysis, Los Angeles abrasion, absorption, specific gravity and soundness test. The synthetic aggregate produced passed all tests for NCDOT and, in some instances, rated better than a natural aggregate. Using the tailings from the crushed stone and mining industry would convert the waste into a valuable, marketable product.

Jan 1, 2013

By M. I. Brittan

A technique has been developed that analyzes routine mill operating data to determine the key operating parameters responsible for gold losses to tails. These parameters represent the prime operating variables having a dominant effect on gold recovery. The technique quantifies these effects for the specific plant being analyzed, providing a tool to optimize recovery and costs and so enhance the mine?s cash flow. The quantitative relationships generated will be different for each ore and plant: every case is site-specific and has to be treated on its merits. Examples are provided to illustrate the considerable metallurgical and financial benefits which can be realized from optimization. The examples are taken from case studies of mills in four major gold mining districts of the world.

Jan 1, 2010

By Elif Emil-Kaya

Samarium (Sm), as one of the rare earth elements (REEs), has gained significant attention in the production of samarium- cobalt (SmCo) magnets due to their high corrosion and oxidation resistance, as well as their high-temperature stability. SmCo magnets find applications in various industries, including but not limited to national defense, aerospace, military and medical equipment. Sm and Co have been classified as critical metals due to their economic importance and supply risk. Recovering Sm from SmCo magnets is an effective method to ensure a stable supply. The present study investigates an integrated hydrometallurgical treatment and combustion process for the preparation of rare earth oxide (Sm2O3 ) powders from SmCo. Initially, SmCo powders are exposed to nitric acid, and the resulting slurry is selectively oxidized at 250 °C to obtain Sm(NO3)3 , Co2O3 and Fe2O3 . Subsequently, the selectively oxidized powders are leached with water to extract Sm. Sm2O3 powders are produced from the obtained leaching solution using an energy- and time-efficient solution combustion process. Finally, the optimal conditions for the production of Sm2O3 are identified, and the produced powder is characterized through X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) analysis.

Nov 1, 2024

By B. Mather

Discussion by B. Mather I was very glad to see an article on alkali-silica reactivity of concrete aggregate in Mining Engineering. It is a topic that should be reexamined every 45 or 50 years. The last paper (that I am aware of) that examined this topic in Mining Engineering was Rexford (1950), who, at the time, was chief of the Petrography Section, South Pacific Division Laboratory, Corps of Engineers, Los Angeles, CA. The paper was presented at the AIME meeting in Los Angeles in October 1948. Professor Leming's discussion generally reflects the current state-of-the-art; but it provides no references for more detailed information. I wrote a paper titled "How to avoid excessive expansion of concrete due to alkali-aggregate reaction," which was included in the Proceedings of the Second International Conference on Alkali-Aggregate Reactions in Hydroelectric Plants and Dams (Mather, 1995). In it, I emphasized that it was the hydroxide ion (not the alkali ion) that caused the pore fluid in the concrete to dissolve reactive silica, producing alkali-silica gel capable of taking up water, thereby, causing swelling and rupturing of the concrete. Excessive expansion will not occur unless there is a sufficient amount of potentially expansive alkali-silica reaction product and water. However, this will not occur unless there is a sufficient quantity of reactive aggregate and unless there is a mechanism by which the pH of the pore fluid can get well above the normal value of about 12.6. In many cases it is sufficient that the cementitious medium not only contains portland cement but also contains ground granulated blast-furnace slag (GGBFS) or a pozzolan such as fly ash, silica fume, metakaolin, volcanic glass or calcined shale - any of which may have been included for economic reasons. If, however, the person selecting the ingredients for concrete knows that the aggregate is reactive (with no alternate nonreactive aggregate available) and if the person knows that the only available portland cement has a high alkali content (i.e., more than 0.6% Na2Oe; Na2Oe = % Na2O + 0.658 x % K20), then it becomes irresponsible not to establish what reasonable precaution one should take. Professor Leming suggests using one of the following: 30% Class F fly ash, 50% GGBFS or 7% to 10% silica fume. My view is that one should prepare test specimens with the cement and aggregate to be used and then expose these both with and without at least two dosages of each of the various alternative materials (slag, pozzolan and lithium salts), so that the required dosage to control the expansion is established. Then, economic considerations can dictate the final selection. I would point out to the author that GGBFS is not a pozzolan and is not an admixture, but, rather, it is a latent hydraulic cement. An admixture is, by definition, a material other than hydraulic cement. I commend him for suggesting that aggregate producers should become more active in knowing about the reactivity of their products and the precautions needed to permit those products to be safely used in concrete. ? References Mather, B., 1995. "How to avoid excessive expansion of concrete due to alkali-aggregate reaction," Proceedings, Second International Conference on Alkali-Aggregate Reactions in Hydroelectric Plants and Dams, US Committee on Large Dams, Denver, CO, pp. 421-439. Rexford, E.P, 1950, "Some factors in the selection and testing of concrete aggregates for large structures," Mining Engineering, Trans. AIME, Vol. 187, pp. 395-402. Reply by M.L. Lerning Mr. Mather has once again provided a cogent and useful discussion. I am grateful to him for bringing these issues to my attention, as well as to the readers, and I am grateful for his discussion of several important factors in alkali-silica reactivity. Mr. Mather's discussion of the mechanism of alkali-silica reactivity (ASR) notes the critical role of the hydroxide ion. While the alkali hydroxides are highly soluble (reducing the solubility of the other primary hydroxide in pore solution, i.e., calcium hydroxide, and providing hydroxide ions that initiate alkali-silica reactivity), it is, as Mr. Mather quite correctly notes, the hydroxide ion that attacks the silica structure. This point was not clearly stated in my original article. As noted in the text, the requirements for mineral admixtures to mitigate or control ASR vary widely depending on the specific characteristics of the materials

Jan 1, 1998

By Fredy A. Elorrieta Agramonte, Gabriel von Rickenbach, Roberto Luis Fonseca, David Córdova Rojas, Rolando Romero, Rico Brändle

The mine’s economic life is dynamic by nature. Some factors that create this scenario are the need to recognize new exploitation areas, the evolution of the mineral prices and the development of new technologies to access them. The dynamics of mining development, especially in the underground environment, changes significantly as the stages unfold. In many cases the final solution differs greatly with the initial. The frequent presence of new conditions and factors often cause the mine to develop in a quasi-permanent transition stage, which could be characterized by the generation of dynamic micro-seismic events that could cause rockburst damage in some specific areas. Although they may be infrequent, these dynamic events can have an important adverse impact on mine safety and causes serious losses. Also, changes in the production schedule during exploitation could be a big issue if the problem is not effectively addressed. When the transition of the mine to an active micro-seismic environment begins as an unforeseen scenario, it is frequent to use static ground support systems as they are readily available. Traditionally, the support systems used are reinforced shotcrete with a middle layer of Welded Standard Wire Mesh (WSWM) and Chain Link Standard Wire Mesh (CSWM) of reduced gauges, i.e. wires less or equal than 4 mm in diameter. Although, this support system is used to control static instability problems, there is no good reference of its energy absorption capacity under dynamic load conditions, creating uncertainty in the effectiveness of controlling rockburst events. These support systems are analyzed at the present paper, testing the reinforced shotcrete layer with 4 mm diameter of WSWM and CSWN under dynamic load. Additionally, the influence of the use of high tensile strength steel wire in the meshes (HSWM) compared to the previous ones, is analyzed to assess the scope in controlling rockburst events and keeping the safety of underground environment.

Apr 26, 2022

By Rebecca Boakye, Zohreh Kazemi Motlagh, Virginia T. McLemore

The most significant uranium (U) deposits in New Mexico are sandstone-hosted deposits in the Morrison Formation (Westwater Canyon Member), where >169,500 short tons of U3O8 were produced from 1950 to 2002. In addition, >9076 pounds of vanadium (V, a critical mineral) and some molybdenum (Mo) were produced from these deposits. These and other U deposits (limestone-hosted, U-veins) in New Mexico also contain critical minerals. Critical minerals are mineral resources that are essential to our economy and whose supply may be disrupted; many critical minerals are 100% imported into the U.S. Some sandstonehosted, limestone-hosted, and U-vein deposits are elevated in heavy rare earth elements. One sandstone-hosted sample contained 0.3 ppm Re (critical mineral), 659 ppm Se and 408 ppm Mo. The arsenide five-element vein deposits in the Black Hawk district are mineralogically and texturally complex, low- to moderate-temperature, hydrothermal, structurally-controlled, Ag-Co-Ni-Bi-As bearing carbonate vein systems with local minor elements. Mineralized samples from Black Hawk contain up to 9970 ppm Ag, 8540 ppm As, 5690 ppm Co, 72,400 ppm Ni, 57 ppm Bi, 165 ppm Sb, and 32,600 ppm U.

Feb 22, 2026

By CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU, Shunliang Liu

With the depletion of mineral resources and the growing demand for metal resources from industrial development, the recovery of metal resources from secondary resources has attracted increased attention. Among all secondary resources, spent catalyst is one of the most important as it contains valuable metals such as vanadium, nickel, molybdenum, cobalt, and aluminum. Compared with the extraction of metals from minerals, the recovery of valuable metals from spent catalysts has the advantages of a simple process, a short production cycle, lower investment cost, and less environmental impact.

Apr 1, 2023

By Peter N. Calder

The selection of a slope angle for an open pit in rock has often been made without the benefit of a comprehensive engineering study. This is largely due to the fact that the hardware and procedures necessary for such a study have not been available. Recently this situation has been reversed. The application of borehole television and terrestrial photogrammetric devices has made possible the accurate determination of rock joint structure, on which stability calculations can be based. Another important aspect is the evolution of practical methods of conducting in-situ rock joint strength tests.

Jan 1, 1971

By Silas Li, Michael Harris-Gifford, Jason Choi, William H. Hansmire

Twin-bore tunnels with a single track in each tunnel are currently the most common subway tunnel configuration. However, a large diameter single-bore tunnel with two tracks separated by a center wall could replace twin-bore tunnels and introduce potential benefits but require necessary modifications to the subway system. In particular, a nominal 40-foot-diameter single-bore tunnel can be considered in lieu of nominal 20-foot-diameter twin-bore tunnels. This paper discusses the benefits and modifications introduced by replacing twin-bore tunnels with a single-bore tunnel, with respect to various elements of the subway related to the tunnel, stations, track, and tunnel systems.

Dec 1, 2022

By C. W. Schultz

Earlier publications from The University of Alabama have indicated that column flotation performance is improved when operating at low pulp levels and when the feed is directed into the froth phase. To validate these early observations a series of tests were performed in which the position of the feed entry to the column and the pulp-froth interface were systematically varied. The optimum grade-recovery relationship was achieved with high feed entry (WA) of column height) and very low pulp levels (<10% of column height). The position of the pulp-froth interface appears to be the more critical variable. When operating in this mode (1. e. at low pulp levels) column flotation becomes. in reality. a froth separation process.

Jan 1, 1991

By W. K. Choi

Using electrochemical techniques it was demonstrated that bioleaching of gold from refractory pyritic ores is a complex phenomenon. Many intermediate electrochemical reactions were found to be involved in the oxidation of pyrite, using cyclic voltammetry and carbon paste-pyrite containing electrode. Furthermore, the oxidation process was controlled by solid-state diffusion as suggested by chronoamperometric and chronopotentiometric measurements. Using the Sand&apos;s approach, the activation energy of solid-state diffusion was found to be = 22.4 kJ. After bioleaching, 96% gold was extracted from the leach resi¬due with a thiourea solution in 1 hour. A generalized model for the mechanism of pyrite oxidation has been presented.

Jan 1, 1990

By Sandro Moro, Giuseppe Tiberti, Giovanni Plizzari, Antonio Conforti

"During TBM operations, thrust jacks apply high-concentrated forces to the last installed precast segment. These loads generate a disturbed region in the precast segment under the thrust jacks, in which significant tensile stresses (defined as splitting or bursting stresses) occur perpendicular to the load direction. In addition, due to the demand of compatibility, the combined effect of TBM high-concentrated loads determines tensile spalling stresses in the area far from the loads. Therefore, local rebars or fiber reinforcement are required in these areas. This paper focuses on the study of the effects generated by high-concentrated loads exerted by TBM hydraulic jacks, mainly in terms of both spalling and splitting phenomena. Experimental tests on small-scale specimens showed that polypropylene fiber reinforcement significantly enhances both the bearing capacity and the ductility. Moreover, polypropylene fibers resulted in very effective control of compatibility cracks.INTRODUCTIONTunnel segments are generally reinforced by conventional rebars (RC segments) in order to resist the tensile stresses both at Serviceability (SLS) and Ultimate Limit States (ULS).In the two last decades, Fiber Reinforced Concrete (FRC) has been used in many precast tunnel segments (sometimes also in combination with conventional rebars). Steel Fiber Reinforced Concrete (SFRC) is generally used for these applications even though there is a growing industry interest on macro-synthetic fibers for structural applications. Conforti et al. (2015) showed that polypropylene (PP) macro fibers can be used as shear reinforcement in both wide shallow and deep beams. Referring to precast tunnel linings, very few early experiences are reported in literature. Bonalumi et al. (2015) developed full-scale tests on tunnel elements reinforced by PP fiber reinforcement and conventional rebars (hybrid solution). The design process of segmental concrete tunnel linings generally models the standard load cases of demolding, storage, transportation, positioning and embedded ground condition. In all these stages the ring can be modelled as simple curved beam elements (having a height equal to the lining thickness and a width equal to the segment length). During these loading conditions, flexural demand is generally limited; thus, in case of conventional RC elements, a rather low ratio of longitudinal curved rebars is usually adopted (?s of about 0.2-0.3%)."

Jan 1, 2016

By James Humphrey

There is a natural resistance to change in any form. When it comes to implementing a game-changing technology like autonomous haulage on an operating mine site, the resistance can at times appear insurmountable. Whether based on real information or misguided preconceptions, it?s essential that we don?t underestimate the effort it will take to overcome this resistance, while clearly recognizing when it?s worth the effort. These realizations did not happen overnight for sites where autonomous haulage has been implemented. Nor did they happen overnight for manufacturers of autonomous mining equipment. Caterpillar, for example, began building toward autonomy more than 30 years ago and had a truck operating in the mid-1990s. Lessons learned during those early years led to the realization that there was much more to be learned ? not just about the machines themselves, but about the systems and knowledge that must be in place for a successful implementation. Working closely with customers, initiating real-life demonstrations on mine sites, having discussions with regulatory agencies and other stakeholders ? these and many other activities were necessary before autonomy could be fully and successfully launched. After decades of effort, Caterpillar?s first official commercial autonomous mine site went to work in 2011 in Farmington, NM.

The mining and minerals extraction industries have often been demonized by the public as industries that put profits and production before people. It is true that the inherent danger of the work has led to more fatal accidents than anyone associated with the industry would care to remember. But, in stark contrast to what has often been said, the truth of the matter is safety is now the top priority of every miner, from the face of the longwall to the executive boardroom. Without safety, nothing else matters. This message was told and retold by representatives from some of the world?s top mining and petroleum companies from Oct. 11-13 during the inaugural Safety and Reliability in the Mining and Resources Industries Conference in Calgary, Canada. The meeting was hosted jointly by the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) and the Society for Mining, Metallurgy, and Exploration (SME). It was the first of a series of conferences to focus on these important topics. Next year, the conference will be held in Minneapolis, MN from Nov. 13-15.

Jan 1, 2011

By Andre Vien, SANDRO DAVID DI, Frank Laroche

In 1994, Claude Bazin presented a novel method for linking size data from milling models to the feed input of flotation models. It was achieved with the simple addition of a metal/mineral distribution–size distribution relationship. This allows grade and recovery predictions from a varying mine plan through product size distribution predictions. 

By A. Torrance, M. G. Seo

Velocity of detonation (VOD) is an important variable when evaluating the performance of mine blasts. Typically, for a VOD measurement, individual probes have to be loaded into each blast hole that requires a measurement, which increases the loading time and is not representative of the whole blast. Experimental studies of electromagnetic pulse (EMP) from the detonation of explosive charges show that electric and magnetic field signals are observed when chemical explosions occur in the air, at the ground surface, and in the underground. EMP has the potential to evaluate VOD of the whole blast without impeding the loading process. Due to a variety of physical causes which make the electromagnetic effects complex, measuring EMP of the detonation of explosive charges has not been fully studied yet. Five different antennae were tested with explosives, which are commonly used in mining industry. Among the five antennae, aluminum and copper tape, and wire were successful to detect the EMP. INTRODUCTION The measurement of the velocity of detonation (VOD) helps in evaluating and comparing relative performance of explosives in mine blasts. A VOD of an explosive is usually predicted by empirical mathematical equations or measured in-hole by VOD meters. However, conventional methods to measure a VOD have constraints: only a limited number of holes can be measured because cost of consumables for such systems is very high, and systems only allow a certain number of holes to be measured. The measurement cables have to be placed into the holes prior to loading with explosives which means that preparing to take the measurement is time consuming and has to be well coordinated with the mine. In order to evaluate VOD for a whole blast, there is a possibility of using electromagnetic pulse (EMP) from the detonation of the explosives. As there are many parameters that affect the generated EMP from explosive charges, measuring EMP of the detonation of explosive charges has not been fully studied yet. Most studies conducted relate to military related explosives, not the ones frequently used in mining industry. This research has been performed to have a better understanding of EMP from the types of explosives which are commonly used in the mining industry. To discover a way to detect EMP efficiently, five different types of antennae have been studied in the air and in the underground blasting conditions: coil, monopole rod, log periodic, wire, and aluminum and copper tape. LITERATURE REVIEW Conventional methods of measuring VOD Over the years, demands for more accurate theoretical predictions and physical measurements of the effects of the explosives have increased. Especially when both demand and commodity price decline, mining companies are keen to understand the effectiveness of explosives since it has a direct relationship with fragmentation, which influences their production rate. Since the 1940s, various methods have been devised to determine VOD of explosives.

Jan 1, 2019