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By Y. H. Cheng, H. EI-shall, S. Gupta, N. A. Abdel-Khalek

A 14.6 cm (5.75 in.) diameter by 1.83 m (6 ft) tall laboratory-size column is used in flotation of Florida phosphates of different feed sizes. In this paper, the effects of different parameters on the flotation efficiency of coarse particles (belt feed, -1.4 + 0.5 mm, i.e., 14 x 35 mesh) under negative bias are discussed. Parameters included collector dosage, frother type and dosage, and conditioning water, which contained a residual concentration of collector. Flotation tests were performed using statistical designs. The results strongly suggest that flotation performance is dependent on the used combination of reagents. Interactions between frothers and the collector and, consequently, the flotation efficiency were found to be dependent on frother type and presence or absence of conditioning water. Under the negative bias, an excellent recovery of more than 98% of phosphate was achieved in concentrates of high grade (above 31% P205) from such feed of coarse particles.

Jan 1, 1999

By Ronald J. Thomas

Prior to 1974, bauxite-producing countries were poorly informed about important aspects of the bauxite/alumina/aluminium industry. This placed them at a disadvantage in negotiations over the development of the industry with interested parties. Since the formation of IBA, its member governments have acquired a fuller awareness of the structure and operation of the industry. The role of IBA is to enlarge the relevant information base of member governments, to act as a forum for the exchange of information on the industry and to form a focal point for multilateral discussions on problems in the industry with corporate interests and with governments of consuming countries.

Jan 1, 1984

By L. Max Scott

[INTRODUCTION] The significance of gamma exposure to uranium miners has been recognized only in the last few years. Most ore deposits which have been underground mined, were 1% or less U308. Full-time mining of this grade ore can result in exposure exceeding 1 Rem per year. Several companies in Saskatchewan are planning to mine recently discovered ore bodies which contain ore pods in excess of 10% U308. The purpose of this paper is to present dose data which can be used to estimate gamma exposure from high-grade ore deposits, and to present mining techniques which will minimize miner exposure. [Dose Estimates] When one has a point source of radiation, the conventional laws of isotropic emission and the fall of dose with square of the distance, make dose calculations relatively easy. However, if one has an area source of infinite thickness, the assumption must be made that a uniform gamma flux is being emitted from all faces of the source (Figure 1). Dose from gamma emission would fall off only due to air attenuation up to such a distance at which the source can be considered to be a point source (usually 10 times the largest dimension of the source). For short distances, such as to the cab of ore-moving equipment, the dose reduction would be negligible. Assumptions: 1) Radium and gamma-emitting daughters are in secular equilibrium with uranium. 2) All gamma radiation is emitted from radium and its daughters. 3) Average gamma energy of 0.8 MeV. 4) Uranium ore has a linear attenuation coefficient of 0.212 cm-1, similar to that of Si02(sand). 5) Uranium ore density of 3.0 gm/cm3. 6) One curie of radium emits 6.84 x 1010 photon/sec(l). 7) One percent uranium ore contains 1 x 10-8 Ci/cm3 of radium. 8) Each MeV of 0.8 MeV photon results in a dose of 2.10[ ]10-3 mRem/hr. per MeV/cm2 -sec. 1) 9) Minimum ore depth 100 cm. 10) Linear attenuation coefficient instant for radium gamma of 0.374 cm -1 [ ] The photon flux from a radioactive slab is computed as follows: [Flux = photon/cm3 3(1) 2u S] [where, us is the linear absorption coefficient of s the source (uranium ore).] Thus, 1% uranium ore, in the form of an infinite slab, emits 1613 photon/cm2-sec, which results in a dose rate of 2.71 mRem/hr. Since the dose from an infinite slab is the same as a dose from an infinite radius right circular cylinder, the only correction needed from the above dose rate is for finite radius and point of dose above the end of the cylinder (Figure 2) [Dose = mRem/hr. {E2(bl) - E2(b3) - [(E2(b1sec[E] -E2(b3sec[E]]cos[O](1)]

Jan 1, 1981

By Richard F. Hammen

Mineral extraction from sulfide ore deposits usually leads to the combined action of oxygen and water on the newly exposed ore. The result is acid mine drainage, a low pH solution of various metal sulfate salts and sulfuric acid. Paradoxically, the valuable metals dissolved in acid mine water are a liability because they are too toxic for discharge but too dilute to recover economically. The expense of compliance with water quality release standards has reduced the profitability of many mining operations. Solid phase extraction (SPE) columns have been developed to extract metals from acid mine water. These columns are designed to remove the toxic elements from water and recover the metals as purified fractions. This article describes the results of a Phase 1 bench-scale project to test the performance of the SPE columns. The tests were conducted with water collected from the abandoned Berkeley Pit copper mine in Butte, MT.

Jan 1, 1993

By Kenneth S. Johnson

Oklahoma is the only; state in the nation that is currently producing iodine. The iodine is extracted from iodine-rich natural brines being pumped from deep wells drilled into Pennsylvanian sandstones in the Anadarko basin of northwestern Oklahoma. Woodward Iodine Corp., started in 1977, was the first plant in the United States built for iodine recovery since the 1930s. At present, three companies are operating four iodine-producing facilities in northwestern Oklahoma. The combined production of these facilities, 1,321,000 kg in 1997, is about 26% of the U.S. annual consumption. Iodine is present in concentrations ranging from less than 100 ppm (parts per million) to as much as 1,560 ppm in brines in various Paleozoic strata in the subsurface of northwestern Oklahoma; these concentrations are exceptionally high, and are well above those of any other known brines in the world. Strata with the highest iodine content in the area (Mississippian limestones) have low permeabilities, and thus would yield only small amounts of brine. On the other hand, the lower Morrow sandstones (Lower Pennsylvanian) have a relatively high permeability and are capable of yielding large quantities of brine that average 300-350 ppm iodine. The Morrow brine reservoir was deposited in shallow-water-marine and intertidal-shelf environments and now is buried 6,000-10,000 ft below the land surface. Production is localized to Morrow channel deposits confined to an Early Pennsylvanian paleovalley that is 1-2 mi wide, is about 70 mi long, and is referred to informally as the "Woodward trench." All three companies are producing iodine-rich brines from Morrow sandstones in three different parts of the Woodward paleovalley, and one of the companies also is extracting iodine from oil-field brines coming from several petroleum reservoirs near Dover, about 80 mi east of Woodward. The basic extraction method employed by Woodward Iodine Corp. was used in Louisiana and California operations in the late 1920s. This method is commonly called the air-stripping process. Lower Morrow brine containing dissolved sodium iodide is pumped to the plant through a series of pipelines, where by-product natural gas is separated and processed. The brine is then acidified and subsequently oxidized with chlorine to convert the iodide to iodine. The iodine is air stripped and reabsorbed with sulfur dioxide and water, converting it to hydriodic acid, or process liquor. The process liquor is then processed, using chlorine once again, to crystallize the iodine as a solid. This is then melted and frozen to form a solid product, which is packaged in 110-lb (50-kg) drums and shipped to end users throughout the world.

Jan 1, 1999

By K. Hanumantha Rao, K. S. E. Forssberg, F. Su

The influence of reagents dosage, pH, temperature, and particle size on the kinetics of apatite flotation response from magnetite has been investigated. The first-order models characterizing rectangular distribution and fast and slow distributions (F-S model) of floatabilities gave an excellent fit to the results of apatite flotation when compared to other models. However, the latter model is found to be better than the former in the goodness of fit and also in the description of flotation performance. The kinetic parameters in the F-S model are estimated by using a nonlinear least squares fitting program. The ratio of fast and slow rate constants is observed to be an important parameter for identifying the optimum levels of the variables and to outline the selectivity between apatite and magnetite. The influence of collector dosage is realized from the model parameters by relating it to the fraction of slow- floating particles. An attempt has been made to describe the apatite flotation behavior with the determined model parameters.

Jan 1, 1999

By J. Alvarez, S. H. Castro

The feasibility of chalcopyrite-pyrite separation in the flotation of a chalcopyritic copper ore, at reduced surface tensions regulated by methanol, was investigated. It was found that with methanol dosages from 0.5% to 1.5% v/ v, the chalcopyrite might be effectively separated from the pyrite, without use of other flotation reagents and pH regulators. However, under this simple condition, the chalcopyrite recovery was only around 50%, recommending the use of other reagents to reinforce the collector action. Low dosages of different collectors were tested, including SF-323 (Shell Float), S-6588 and S-7251 (Cytec), and S-701 (Molycop). Very promising results were obtained with low dosages of the collector S-701 and 1% v/v of methanol in the pulp, which evaluated against a reference test, gave similar copper recovery, higher Mo recovery and higher depression of pyrite. Consequently, this is an alternative process which does not require the use of lime to depress pyrite.

Jan 1, 1995

By D. Puckett

The feasibility of maintaining equipment location, personnel location and vital statistics in surface and underground mining operations has increased with advances in radio frequency identification (RFID) technology. The paper addresses the use of this technology, relatively new in the mining industry, to track surface equipment in mine pits, loading points, and processing facilities. Specific applications are discussed including a simplified and a complex truck tracking system and an automatic pit ticket system. The paper concludes with a discussion of the future possibilities of RFID technology in mining, such as monitoring biofeedback of personnel (heart and respiration rate, body temperature, exertion level, etc.) repetitious movements to study work habits, and logging air quality via personnel sensors.

Jan 1, 1996

By K. Hanumantha Rao, K. S. E. Forssberg, B. -M. Antti

Selective flotation of muscovite from a material containing muscovite (15.4%), biotite (13%), and siliceous gangue (quartz and feldspar), using a mixed collector system of sodium oleate and dodecylamine acetate has been described. Muscovite is found to float in preference to biotite, when the pulp is initially conditioned with oleate followed by amine at basic pH values. The results indicate that a product containing 63% muscovite with a recovery of 93% can be obtained, while using 75-150glt of oleate and 96 g/t of amine. The biotite grade and recovery are found to be around 30% and 20%, respectively. A good selectivity between muscovite and siliceous gangue is obtained. A final product containing 95% muscovite with an overall recovery of 75% is obtained when the flotation concentrate is subjected to magnetic separation. These studies indicate the possibility of separating muscovite from biotite by using a mixture of collectors.

Jan 1, 1991

By M. M. Rajkovich, L. Adams, J. J. Zaluski, S. Gardner

In 1998, a group called Kentuckians for the Commonwealth filed an Administrative Petition with the Kentucky Natural Resources and Environmental Protection Cabinet to designate 8,903± hm2 (22,000± acres) on Black Mountain, which contains the state's highest point, as unsuitable for mining. A fast track legislative process was triggered that could have "taken" 91 Mt (100 million st) of coal reserves or, in the alternative, imposed severe restrictions on mining. Even with all parties represented by reasonable individuals, this process can be extremely cumbersome and expensive. The legal and technical preparation for this unusual hearing process as well as issues and strategies of the negotiated resolution are reviewed

Jan 1, 2002

By David M. Shaw, John C. Franklin

A 32-channel warning system for high working level, fan operation, and airlock-doors has been constructed. The working level monitors have a microcomputer for accumulating the pulses, converting to working level, and triggering an alarm at a variable set point and at one working level. The system also detects when underground fans lose power or air doors are open. The system can detect changes in air velocity which indicate surface fan failures or changes in the ventilation system. Using this alarm system, the ventilation engineer will be alerted prior to excessive levels of radon daughters being reached so corrective action can be taken.

Jan 1, 1981

By David Corkum, David Hatem

Subsurface construction projects are risky ventures and the decision to deliver a project using the Design-Build model does not eliminate those risks. Differing site conditions, inadequate design, and delays will continue to plague some projects. The Design-Build procurement model, however, presents a broad opportunity to allocate those risks much differently than in the familiar Design-Bid-Build model. Starting with a philosophical approach to risk and reward, this paper discusses the continuum of possible risk allocation strategies. It concludes with a proposed optimum strategy in terms of the project’s overall economic efficiency, and points to the dispositive contractual provisions that serve to contour the risks.

Jan 1, 2003

By James Watson Baxter

Fluxes are used to promote pyrometallurgical processes that rely on adhesion (soldering or brazing) or fusion (gas and arc welding) to join metallic surfaces. In the adhesive processes, the metal surfaces to be joined are not melted; the join is formed using a filler metal with lower melting point than the base metal. Fusion welding involves use of heat in excess of the melting point of the base metal. The fused joint may be achieved either by simply fusing together metal surfaces brought in contact with each other or by introducing additional molten metal of similar composition to form a fused joint. ADHESIVE PROCESSES--SOLDERING AND BRAZING In order for molten filler metal, solder or braze, to spread in a manner that creates a successful join; the work surfaces on the base metal must be thoroughly cleansed. Fluxes remove stubborn oxide films and other surface contaminants, promote wetting of the work surfaces, add fluidity to the solder or braze, and enhance workability and ease of spreading. Brazing processes involve higher temperatures than those reached in soldering. Brazing fluxes, which must remain active and effective at the higher temperatures, differ from those employed in soldering. Some common fluxes used in adhesive processes are rosin for soldering tin and electrical connections, hydrochloric acid for use in soldering galvanized iron and other zinc surfaces, and borax for brazing. Soldering and brazing are similar processes, the primary difference being the temperature at which the joining operation is carried out. Soldered joints, produced with low-melting-point fillers (solders) that melt and flow at temperature less that 450°C (Althouse et al., 1988) can sustain loads of 1 to 1.7 MPa for extended periods of time (Anon., 1966). Brazing involves the use of filler materials with melting points commonly above 500°C and generally provides stronger joints than those obtained with solder. Both processes require local application of heat to melt and spread the filler so that the molten filler can wet (adhere to) the base metals by alloying and diffusion. Soldering Soldering is a means of joining metals by adhesion using a metallic bonding alloy as the filler, commonly a mixture of lead and tin. However, the adhesion of solder depends more on its ability to be keyed into minute surface irregularities than on alloying. The most familiar application is to provide and secure electrical connections. Soft solders can range from 1 to 70% tin with the remainder mostly lead. However, for general-purpose, soft-solder work, the alloy is commonly 50% lead-50% tin. Higher lead contents provide a wider range in the melting temperature and, for this reason, a 60% lead-40% tin alloy, which yields a mushy mixture, is used for wiped joints in lead sheet and pipe work. Conversely, 40% lead-60% tin alloys are used in soldering tin and other low- melting-point materials for which a narrower range of melting temperature is required. There are numerous other solder compositions such as tin-silver, 95% tin-5% silver and antimony-tin, 95% tin and 5% antimony (Carlin, Jr., 1992). Heat needed to melt and spread the solders is commonly provided by electrically heated, copper-tipped soldering irons or by means of torches; the solder is applied by hand, usually face-fed by means of wire. For wiped joints in plumbing and lead-cable splicing, the solder is manipulated with cloth pads. The molten solder wets the joint surfaces and is drawn, by surface tension, into minute fissures and capillary openings. Other applications involve use of induction heaters and furnaces with pre-shaped solder appropriately placed prior to fluxing and heating. In some processes, the joints are immersed in molten solder. Constituents and Role of Soldering Fluxes: Soldering fluxes generally fall into one of three categories: highly corrosive fluxes, intermediate fluxes, and noncorrosive fluxes. These same categories are sometimes designated inorganic, organic and rosin-based respectively (Althouse et al., 1988). Common constituents of each group are discussed briefly below. Corrosive Fluxes (Inorganic). Work with aluminum, magnesium, stainless steel, high alloy steel, aluminum bronzes, and silicon bronzes is carried out at temperatures in the upper portion of the range for solder operations. Soldering these materials requires use of highly active, corrosive fluxes to remove and prevent the formation of the especially stubborn, hard, oxide films that form on these materials upon exposure to the atmosphere. The corrosive fluxes consist of inorganic acids and salts that are applied either as pastes or dry. They are active at elevated temperatures and, since they remain active after the soldering is completed, must be completely removed. The main constituent of most corrosive fluxes is zinc chloride with a melting temperature well above the solidus temperature of most commercial tin-lead solders. It is made by the action of hydrochloric acid on zinc. When zinc chloride is used alone, un- melted particles of this corrosive salt get caught up in the joint and weaken it. For this reason, other inorganic salts such as ammonium chloride (NH4Cl) or sodium chloride (NaCl) may be added to lower the melting temperature. A mixture of zinc chloride and ammonium chloride is very effective because the excellent oxide reducing properties of ammonium chloride and the protective action of the molten zinc chloride combine to produce a fluxing action superior to that achieved when either is used alone. In addition to zinc chloride, ammonium chloride, and sodium chloride; common con-

Jan 1, 1994

By M. Bunch

Today?s mine operating managers face an incredible challenge of meeting the forever increasing legal and regulatory requirements for mining projects. Managers know that meeting compliance of these requirements is just a starting point of assuring sustainability for the project. So how do today?s managers meet these requirements while at the same time focus on continuous improvement in Health & Safety, Environmental, Costs & Production, Labor Relations, Social Corporate Responsibility, and Quality? This paper outlines means by which managers can take control of their operation through the implementation of an integrated Business Management System (BMS) and lay the foundation of a continuous improvement culture in their organization.

Jan 1, 2010

By John F. MacDonald, John W. Critchfield

This paper describes the shield excavation of twin transit tunnels, through soft ground, in downtown Seattle. The tunnels are 6.5 m (21.25 ft) diameter and 1525 m (5000 ft) long. Initial support consisted of expandable precast concrete segments, followed by a final lining of cast-in-place concrete. Waterproofing was provided by a PVC membrane installed between the initial support and the final lining. During the course of the excavation a variety of methods were used to control the ground and limit settlement. These included deep wells, vacuum well points, eductor wells, chemical grouting, compaction grouting, jet-grout underpinning, and extensive instrumentation.

Jan 1, 1989

By O. A. Bascur

Based on current sedimentation theory an on-line thickener model was developed and coupled with an extended Kalman Filter to obtain additional information such as the compression zone level and concentration, a corrected underflow concentration, the inventory, and some rheological information. The on-line model was installed and tested for robustness for periods up to three days in an industrial environment giving good results. Emphasis was given to signal processing and selecting the appropriate input variables for filtering. The analysis of the thickener from a phenomenlogical point of view provides for better operation, establishes the limiting operating conditions, and assists in the design of control strategies.

Jan 1, 1986

By Terence G. McCusker, E. Roy Anderson

A four-mile length of interceptor sewer tunnel in Manhattan has finished sizes ranging from 10'6" to 14'6" horseshoe. Mixed face conditions were anticipated in three areas and encountered in five. All were short but since the tunnel lies well below the water table and failures would involve important utilities, major structures and human lives, great care had to be exercized in choosing a construc¬tion method. Chemical consolidation was selected as the best approach with compressed air working as a backup system. Initially grouting was accomplished from within the tunnel, but treatment from the surface was more successful and was later adopted. The soils consisted largely of impermeable weak silts and it was found possible to inhibit access of water to this material so that it could be controlled by breasting within the tunnel without loss of stability. It is concluded that in the interlayered permeable and impermeable soils encountered, chemical grouting would successfully stabilize the working face. INTRODUCTION An interceptor sewer is currently under construction along the entire length of the west side of Manhattan. When complete, the tunnel will intercept and divert to a treatment plant (also under construction) a daily flow in excess of 200 million gallons per day. About 9 miles of the interceptor sewer is in tunnel and the remain¬der is cut-and-cover construction. The tunnel is almost entirely in Manhattan schist but where its alignment crosses major faults at comparatively shallow depths, mixed face and earth conditions are

Jan 1, 1997

By C. Patrick, D. Puckett

The feasibility of monitoring the locations and vital statistics of equipment and personnel in surface and underground mining operations has increased with advancements in radio frequency identification (RFID) technology. This paper addresses the use of RFID technology, which is relatively new to the mining industry, to track surface equipment in mine pits, loading points and processing facilities. Specific applications are discussed, including both simplified and complex truck tracking systems and an automatic pit ticket system. This paper concludes with a discussion of the future possibilities of using RFID technology in mining, including monitoring heart and respiration rates, body temperatures and exertion levels; monitoring repetitious movements for the study of work habits; and logging air quality via personnel sensors.

Jan 1, 1999

By Fernando Pendás, Jorge Loredo, Alumudena Ordóñez

Water derived from mine-tailings typically contains high concentrations of H+, SO4, Fe and other metals, and it frequently suffers a decline in pH and the development of acidic mine drainage (AMD). A paper describing the results of a series of laboratory experiments with real AMD and a subsequent field trial with a in situ pilot system to assess a potential method for remediating tailings-derived water is presented here. After testing different organic substrates, residence times and flow conditions during two years to determine the most appropriate treatment for a polluted Spanish AMD, a pilot scale system combining SAPS, ALD, oxidation/sedimentation ponds and an anaerobic wetland was designed. Preliminary analyses of effluent samples indicate acidity and metal removal is occurring within the system, although sulphate removal is not complete. The results of this small-scale field trial suggest a potential cheap, long-term alternative for remediation of acid mine drainage.

Jan 1, 2000

Surface characterization techniques, i.e. contact angle measurement, atomic force microscopy (AFM) surface force and surface imaging measurement, were applied to investigate the molybdenite surface in aqueous solution. It was shown that the cleaved basal surface of molybdenite was very hydrophobic with a 92 degree water contact angle. The non-polar component of the solid surface free energy is 50.52 mJ/m2 while the polar components are almost zero. The solid surface was not reactive and was only weakly charged at the pH 6. When the aqueous media changes from water to 1×10-4 M KEX solution, the measured contact angle, adhesion force and surface roughness all increase slightly. However, ethanol rinsing made the surface change back to the bare substrate. It was suggested that the hydrophobic chemical, i.e. dixanthogen, which was shown in the morphology of patches by the AFM image, physically adsorbed on the hydrophobic molybdenite surface through the hydrophobic interaction.

Jan 1, 2009