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By Hun-Joon Sohn

Chemical metathesis and electrochemical reductive conversion of chalcopyrite in the presence of cupric ions were studied in sulfuric acid solutions for temperatures up to 90°C. The process results in the displacement of iron in the chalcopyrite lattice by copper ions with rejection of ferrous ions to the aqueous phase. The rate of reaction was found to be very slow, requiring subsieve-sized particles for extensive reaction to occur. The reaction was insensitive to copper ion concentration. Stirred ball milling of chalcopyrite introduces lattice strain. The reaction rate with strained particles was markedly higher than with annealed chalcopyrite. The reaction rate was found to be diffusion-limited, showing two distinct reaction stages corresponding to the formation of CuS (covellite) followed by Cu1.8S (digenite). The experimental activation energy for the first stage was 102 J (24.4 kcal) and the second stage 123 3 (29.4 -kcal) per mole. The rate-controlling process is diffusion of lattice ions, probably iron. The enhanced rate after milling is attributed to a recrystallization process which provides new paths for diffusion along dislocations and grain boundaries.

Jan 1, 1984

By L. Yuan, J. H. Rowland, R. A. Thomas

"Hydrogen (H2) gas released during battery charging can result in cross-interference for carbon monoxide (CO) sensors used for early fire detection and compromise the integrity of the mine atmospheric monitoring system (AMS). In this study, a series of laboratory-scale and full-scale experiments were conducted to evaluate the responses of different CO sensors to H2 gas. In the laboratory-scale experiments, constant H2 concentrations in the airflow, from 100 to 500 ppm, pass through sensors. While in the full-scale experiments, increasing H2 concentrations generated as a byproduct from charging the batteries at the battery charging station rise to the sensors under different ventilation scenarios. The H2 concentrations at the CO sensor location were measured using H2 sensors and were correlated with the CO sensor response. The effects of ventilation and sensor location on the CO sensors responses were also analyzed. The results of this study can help mining companies to select appropriate CO sensors and improve the deployment of these sensors to ensure the safeguard of underground miners. INTRODUCTION As many types of battery-powered mining equipment such as scoops and shield haulers are used in underground mining operations, charging stations are required to charge the equipment batteries. These batteries are of lead acid chemistry. A safety issue exists with the battery charging stations as all lead acid batteries produce flammable H2 gas during the normal charging process. Overcharging or excessive heat can quickly cause batteries to produce even more H2. If H2 is not appropriately diluted or dispersed, it builds up, and the risk of fire and explosion increases. Mine Safety and Health Administration (MSHA) regulation (30 CFR Part 75.340) requires that battery charging stations should be housed in noncombustible structures or be equipped with a fire suppression system. When a fire suppression system is used, the battery charging stations must be ventilated with intake air that is directed into a return air course or ventilated with intake air that is monitored for CO or smoke using an AMS. The monitoring of intake air ventilating battery charging stations should be done with sensors that are not affected by H2."

Jan 1, 2018

By S. A. Lolon, J. F. Brune

"INTRODUCTION In underground longwall coal mining, the mined-out areas or gobs frequently contain methane which can form explosive methane-air mixtures. Historically, there have been many events of mine fires and explosions recorded in the United States and other countries that have demonstrated the existence of such explosive mixtures, herein referred to as Explosive Gas Zones (EGZs), inside and around the perimeter of bleeder-ventilated longwall gobs (Loane et al., 1975; Lynn et al., 1986; Elkins, et al., 2001; McKinney et al., 2001; Dziurzynski and Wasilewski, 2012; Brune, 2013). The risk of mine explosions can increase if the EGZs migrate out from the gob into the surrounding mine entries. Several factors can induce EGZs outflowing from the gob, but the most common cause is the fluctuating barometric pressure. Atmospheric pressures change regularly every day but can fluctuate abruptly and become increasingly hazardous in adverse weather conditions. Other sudden pressure changes can result from roof falls, failing ventilation controls and fan outages. Any such fluctuation of mine ventilation pressure will disturb the pressure differential between the gob and the surrounding mine workings and may cause EGZs to outgas from the gob. The correlation between major mine explosions and abrupt barometric pressure changes has been studied and confirmed for explosions in coal mining countries including the United States, South Africa, Australia, and Poland (Hosler, 1948; Boyer, 1964; Kissell et al., 1973; Fauconnier, 1992; Hemp, 1994; Wasilewski, 2014; Belle, 2014; and Lolon, 2017). Disastrous mine explosions appear to happen more frequently during stormy weather, which, in the United States, typically occurs during the late fall and winter seasons. ROOT CAUSE AND EFFECT OF GOB BREATHING Gob breathing is the result of the pressure differential between gob internal and external pressures caused by external atmospheric pressure fluctuations that occur naturally as a result of gravitational and thermal forces in the atmosphere (Lindzen and Chapman, 1969). Other major and sudden pressure changes may be caused by fan failures, failures of ventilation controls or roof falls can also cause an unexpected gob breathing. Normal barometric fluctuations occur every day but usually do not pose an explosion risk as they occur gradually so gob pressures have sufficient time to equilibrate. More extreme fluctuations associated with cyclonic weather systems and storms often result in more rapid and larger drops or rises in barometric pressure (Hosler, 1948; Fauconnier, 1992). A study by Lolon (2017) found that the timing of historical mine explosions showed consistency with the occurrence of abrupt and intense barometric variations."

Jan 1, 2018

By A. C. Barlow

The use of deep wells for waste disposal is not a new technique. The production phase of the oil industry has been using this method to dispose of unwanted oil field brine since the 1930's The adoption of this method by other branches of industry, however, to dispose of manufactured wastes is a relatively new development, but one which is finding increased use (2). Deep well waste disposal is not an ordinary technique even though it is finding relatively wide application. In fact, just the opposite is true; it is still a rather extraordinary measure. It is not now, nor is it ever likely to be a disposal method which can be assured of success before it is tried.

Jan 1, 1964

By Albert F. Duzy

Recently there have been some problems associated with hot coal in shipments from the USA to overseas markets. This paper will serve several functions. First, a brief review is presented, together with a selective bibliography. Second, a thorough discussion of coal oxidation is covered. Third, potential effects of storage are presented and, lastly, methods are suggested for the safe storage and bulk transfer of coal. The scope includes coal storage for power plants.

Jan 1, 1983

By Randall C. Divito, Craig R. Eckdahl, Bruce D. Wagener, Joseph Klejwa

The existing Central City Tunnel was built primarily in the 1930s with a small portion as old as the 1880s. It conveys stormwater in downtown Minneapolis. It is a 4,400-ft long tunnel located 80 feet underground. The Central City Tunnel has experienced surcharging and surface overflows during heavy rainfall events. This paper presents the details of tunnel and shaft design for the new Central City Parallel Tunnel to mitigate the overflows. The design considered hydraulics and geotechnical engineering for the structural geologic conditions including the weak Saint Peter Sandstone and overlying strong Platteville Limestone. Ground conditions resulted in tunnel designs including large flat-back box tunnels and unique cathedral-shaped tunnel sections.

Jun 13, 2023

By John J. Mulligan

Coal is found in every major geographic region throughout Alaska and in two offshore areas. Since about 1852 over 100 small mines have opened and closed. Last years production was almost entirely from one mine in central Alaska. Clearly the utilization of Alaska's abundant coal resources presents political, economic and technical problems that are far from solution. Location and Physical Features Figure one illustrates the geographical and geological similarity between Alaska and western United States. The Arctic region of Alaska generally resembles Wyoming and the Dakotas. The Brooks Range is an extension of the Rocky Mountains. The Central region of Alaska between the Brooks Range and the Alaska Range bears a general resemblance to the basin and range country of western United States. The Southcentral and Southeastern regions has a similar resemblance to the Sierra Nevadas and the west coast of the United States.

Jan 1, 1982

By H. T. Mulryan

Talc is used as an essential ingredient in a variety of plastics applications ranging from polyester body patch compounds through polypropylene automotive, appliance and household furniture components to high performance parts made from liquid crystal engineering resins. This paper focuses on polyolefin applications, the three-tier market for talc in polypropylene, the effects of various tales in typical compounds and trends in each market segment. Emphasis is given to emerging markets, examples of which are polypropylene compounds that mimic higher cost resins, and polyethylene films. Customer requirements for tales for these purposes are discussed.

Jan 1, 1994

By Norman A. Nadel

Those of us who have directed our efforts toward the construction of tunnels have long maintained that tunnel construction is more closely an art than it is a science. We have spent time underground with hard-bitten, tobacco chewing shift bosses and superintendents who have made seat-of-the-pants decisions at the face which have been based upon their long experience underground coupled with uncanny intuition. The courage and skill of these men in the performance of their art is legendary. Without question, they have constituted the backbone of the tunnel construction industry. But just as John Henry, the steel driving man, despite his stout heart and dedication to his task, was supplanted by the steam drill, I fear that our tunnel stiff, at least as we have known him, will become an endangered if not extinct species. The reason for this is clearly that tunnel construction is slowly but inexorably making the transition from being an art into being a science, and more and more its performance is requiring the services of scientists as opposed to artists. The tunneling art has been undergoing change for many years, and yet until recently the changes have not been basic. We have improved the way we do the same old things. For example, John Henry would be flabbergasted if he saw the rock drills we use today. He would not have engaged in the legendary drilling contest with one of our modern drills, He would have simply conceded defeat.

Jan 1, 1970

By R. Mensah-Biney

The adsorption of gold-thiourea complex onto a cation exchange resin, Amberlite 252, has been evaluated in a batch stirred reactor. The observed non equilibrium saturation capacity was 3.20 meg Au/g dry resin (620 kg/t) whereas the equilibrium ion exchange capacity was only 0.53 meq/g (103 kg/t). The enthalpy of adsorption was 4 -25 kJ/mole under equilibrium conditions and increased to 20-200 kJ/mole under non equilibrium conditions. Under non equilibrium conditions, the adsorption capacity of the resin decreased with increasing temperature and increasing thiourea concentration and increased with increasing gold concentration. This dependence of adsorption capacity on thiourea concentration and temperature may be a useful tool for elution of gold from the loaded resin. Scanning electron microscopy revealed evidence of deposition of elemental gold on the loaded resin under non equilibrium conditions. The proposed mechanism for "adsorption" of gold-thiourea complex onto this cation exchange resin consists of an ion exchange reaction followed by a reduction of the exchanged gold complex to elemental gold on the surface of the resin.

Jan 1, 1997

By K. N. Han, M. C. Fuerstenau

Challenges in five major areas of hydrometallurgy are presented and discussed. These are: leaching low-grade oxide and sulfide ores; oxidative leaching of sulfide concentrates; processing refractory ores; bacterial leaching and processing: and secondary metal recovery.

Jan 1, 1989

By J. B. Gwiazda

Maintenance of a constant load setting throughout longwall support units and selection of the proper initial bearing capacity depending on the type of roof strata are the basic factors that ensure good performance of roof support in a longwall. These requirements can only be met by hydraulic support. The greatest advantage of hydraulic support is achieved when uniform pressure is imposed on the roof throughout the length of the longwall. Such support, however, is provided only if each of the support units acts with the same force against the roof, i.e., has the same setting load. In such cases, the roof behaves like a uniform plate without bending and shearing stresses, thereby ensuring an undisturbed structure. Without a positive set value system, achieving an equal setting load for all units of the longwall support is impossible. Due to alterations of the feed line pressure of support units as well as some reasons related to man's psychology, operators extend the height at different setting loads. This produces nonuniform roof stress, and disturbs the structure. Consequently, the roof usually cracks. The author has developed a positive set value system, which is described in this Technical Note. Selection of the setting load Two pressure values in the feed lines are usually applied in longwall hydraulic systems. Lightweight support is fed by 25 MPa (250 bar) liquid, while heavy duty units receive a nominal pressure of 31.5 MPa (315 bar). Such pressure is required not only for the props but also to power the adjust¬ment jacks and the advancing ram. If the feed pressure is too low, there will be difficulty in shifting the unit despite the inversion system of the advancing rams. On the other hand, for many roof types, the feed pressure often appears to be too high when applied as the setting load pressure. An excessive setting load acts too strongly against the roof, crushing weak strata close to the roof. The author has recognized a case where an excessive setting load destroyed not only the nearby roof strata but also the strata above a 2-m (6.6-ft) sandstone layer. In addition, an excessive setting load relieves the side¬walls, increasing the resistance when using cutting machines. As a result, the yield of coarse coal is diminished, and increased fines dominate in the final product, lowering its economic value. As indicated, selection of the proper setting load, depend¬ing on the mining and geological conditions of the extracted seam, is extremely important. In some mines, measures applied to prevent disturbances include reduction of the feed line pressure by adjusting the feed pump valve. The disadvantage accompanying reduced feed line pressure is more difficult operation in advancing the ram. Due to the reduced feed line pressure, the force of the advancing ram is much lower than the designed value. Other designs suggest using a third feed line. However, installation of supplementary valves on the support units is required, a time-consuming and expensive procedure. The disadvantages of the powered supports are eliminated by a system designed by the author. So far, such a method of setting load control has not been used in any type of support. Setting load control unit The designed positive valve set for prop loading and the setting load control correspond to existing control systems for hydraulic powered support. The layout of the unit connected to the hydraulic prop control is presented in Fig. 1. The unit is marked LIDS. It incorporates three valves that may operate separately or connected. Valve A automatically opens and closes with liquid flow in the prop feed circuit. The valve is opened when the canopy touches the roof and closed when the support unit is withdrawn. Valve B serves as the setting load control. Valve C automatically opens and closes the flow in the line connecting the under-piston space of E to the prop F with the separator G. The valve block of each support prop is marked BZ. The UDS unit is connected by the hydraulic lines to the F prop control circuit. A valve is connected by H to pressure line J and by K to the G separator. In the UDS-3 version, line L is connected to M, linking the over-piston space of F prop with the G separator. Valve B is linked with valve A by a connector; it is also connected to the under-piston space E of prop F by line P. Valve C is fixed between lines K and P, connecting space E of prop F with the separator G. When setting the support, the liquid flows from line J through separator G, the BZ valve, and valve C to the space E of prop F. When reaching the roof with the canopy, valve A is opened and C closes. In this way it is impossible for the operator to cause the liquid pressure in space E of prop F to reach the level of line J. The prop pressure is set by valve B of the UDS unit. When withdrawing the support, valve C is automatically opened and A closed. Three UDS units have been fabricated and are designated

Jan 1, 1990

By T. Tamagawa, I. Iwasaki, N. X. Fu, M. Kobayashi

A three-stage fluidizing-bed process consisting of chlorination, selective oxidation and sulfur chloride conversion was tested for processing chalcopyrite concentrate. It was found that the use of excess oxygen was essential for the stable operation of the oxidation reactor. The excess-oxygen gas inevitably causes the oxidation of the sulfide concentrate in the chlorination and sulfur chloride conversion reactors. A new flowsheet is proposed to separate the chlorination and selective oxidation steps with separate flow paths of the fluidizing gases, thereby, preventing the passage of excess-oxygen gas in the chlorination and sulfur chloride conversion reactors. The feasibility of the proposed flowsheet was demonstrated in a laboratoryscale fiuidizing bed setup.

Jan 1, 2002

By J. M. Keane

SMEThis loaner is concerned with important criteria relative to the design of small flota¬tion concentrators. For the purpose of this discussion a small flotation concentrator is defined as a facility having a designed ore feed rate of 1,000 metric tons per day (MTPD), or less. The decision to design and construct a small flotation concentrator is the culmination of a series of logical steps relative to the ex¬ploitation of a potential ore body. The information required for a rational and timely decision regarding plant design and construction is usually contained in a feasibility report. The information required in a thorough feasibility report has been summarized (1) (2) as follows: Type of mine or plant and proposed daily, monthly, and yearly production of all intermediate and final products. Quantity of indicated ore reserves. Location of project illustrated by a map showing surroundings, trans-portation facilities, and existing utilities.

Jan 1, 1980

By Milton Hood

The Copper Flat Property is located approximately 6 miles NE of the small town of Hillsboro in Sierra County, N. M. (Fig. 1). Hillsboro was the center of considerable mining activity in the late 1800's and early 1900's following the discover, of gold bearing vein deposits and later discovery of, placer gold along the east slopes of the Animas Hills. The Copper Flat orebody is a porphyry type deposit occurring in a small quartz monzonite porphyry stock that has intruded the center of a circular andesite plug (Fig. 2). The primary ore mineral is chalcopyrite. By-product values are contained in gold, silver and molybdenum.

Jan 1, 1983

By Roland B. Drugge

The adaptation of pelletizing processes involves the coordination of various factors such as temperatures, gas flows, productions, etc., in order to obtain optimum performance. The consequent problems are considerable due to the large number involved as well as the lack of knowledge of their correlation. It is therefore essential to establish a fundamental theory which takes into account the heat transfer phenomena and the secondary factors which are relevant to the properties of the product. Straight grate and grate kiln pelletizing processes involve heating of a stationary bed on a travelling grate. The heat transfer conditions are therefore of primary importance. This is why this article pays particular attention to conditions which obtain when a stationary bed is heated, in which certain special reactions occur. The conclusions drawn from this penetration of the heat transfer phenomena can be expressed in postulates acting as guide-lines for the establishment of proto-typal processes. Examples of elaborating such processes are also given in the article. Some operational experience at LKAB are also given.

Jan 1, 1975

By Roland W. Merwin

The Bureau of Mines has studied the possibility of using the heap leaching process for treating the gold ores in the sedimentary beds of northeastern Nevada. This paper summarizes all available information on the technical and economic feasibility of heap leaching oxidized ores from these beds, past industry application of vat leaching, results of recent Bureau of Mines and industry tests on heap leaching ores from this region, and requirements for planning the proper application of heap leaching. Preliminary tests on representative samples of ores from the region show that a satisfactory recovery of gold can be obtained by heap leaching the ores with cyanide at a relatively coarse size. Significant deposits of gold ore occur in sedimentary beds of various locations over an extended area 40 miles wide and 200 miles long in northeastern Nevada. The area is centered 40 miles west of and runs parallel to the leading edge of the Roberts Mountain thrust fault system, a prominent geologic feature in the area. The general locations of past and present gold mining operations are shown in figure 1. (slide 1)

Jan 1, 1969

By Robert L. Bates

The field of industrial minerals and rocks includes such a wide diversity of materials and occurrences that communication is essential to foster a sense of "belonging? among geologists and other professionals. Besides, exchange of ideas and information is essential in meeting the needs of an ever-expanding world economy. A survey of the field shows to what an extent such communication--especially in the form of conferences and their proceedings--has increased during the past 25 years.

Jan 1, 1995

By Michael J. Pratko

The bulk handling industries have long been plagued with problems in their attempt to obtain one of their major goals - the maximum efficiency for which a bulk handling flow system was designed. Mentor Dynamics Ltd. is an international firm with offices in Canada, Japan, and the United States. Mentor Dynamics Ltd. is in the business of solving the "why not" of a system and engineers the solution for the problem. Studies of the varied difficulties encountered with bulk flow systems indicate that 90% of all flow problems fall into one or more of the following categories: abrasion, impact, sticking, and/or inadequate design. These problems can occur with a myriad of bulk solids: coal, gypsum, aragonite, phosphate, fly ash, ore. Solutions to the problems are as varied as the problems. The proper lining material, ceramic, urethane, rubber, and/ or ultra high molecular weight polyethylene, must be coupled with the correct fastening system, annular ring and 'F' cap, weld washer, button head fastener, weld studs and/or nuts and bolts.

Jan 1, 1982

By W. M. Lewis

Product losses to tailings ponds have long been a source of frustration for the mining and utilities industries. The utilization -of the Lewis Econosizer to recover lost products has proven to be very cost effective through reduced acreage requirements, cleaning costs and increased production. The unit is successfully operating in coal, aggregates, industrial minerals, clay, fly ash, heavy minerals and many other ores. Utilizing an upward flow of slurry in a free settling environment, particles stratify within the unit according to settling velocities and are removed as sized products. Ultra fines or clarified water is removed off the top of the unit. The Econosizer requires no power and only minimal maintenance.

Jan 1, 1998