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By T. R. A. Davey

The fundamental principles by which bismuth may be removed from lead by pyrometallurgical processes are enumerated. Qualitative discussion of the phase diagrams concerned is followed by presentation of quantitative diagrams. Brief mention is made of the practical aspects. Data presented show how chemical lead (<0.005 pct Bi) may be produced by the Jollivet, Dittmer, and Kroll-Betterton processes. BISMUTH is an element whose properties are very similar to those of lead, and its minerals are associated to a greater or lesser extent with nearly all the major lead ore deposits of the world. In consequence, the lead produced contains bismuth unless a special debismuthizing process is practiced. There does not appear to be any published comprehensive review of the effect of bismuth as an impurity on the properties of lead, and there is some uncertainty as to the beneficial or detrimental effects of small amounts of bismuth in lead used for particular applications. Standard specifications of most countries stipulate a maximum bismuth content of 0.005 pct for chemical lead. With one exception, this specification is met only by lead producers whose ores are relatively bismuth-free, or whose refineries are electrolytic. In lead for certain applications a higher bismuth content is preferred by some fabricators.&apos; In contrast to the refining for silver, copper, and antimony, the refining for bismuth does not usually result in a large overalil economic gain from the sale of byproduct. Thus, debismuthizing is customarily practiced only if market conditions demand a lead with a bismuth content lower than that produced by classical refining; i.e., softening, desilverizing, and zinc refining. Until this century, debismuthizing was carried out only a:; an incidental result of desilverizing, as later described. This century has seen the development of the Betts electrolytic process—the only successful one of many electrolytic processes proposed and patented —and a number of precipitation processes based on the pioneering work of Kroll,&apos; although only one of these, the Kroll-Better ton process,&apos; is in wide commercial use today. It is proposed in this paper to deal only with the pyrometallurgical processes, excluding those based on aqueous electrolysis. Historical Background Prior to 1833 silver (and incidentally bismuth) could not be removed from lead. To recover silver from rich bullion, the only course available to lead refineries was to cupel the bullion, forming a slag of litharge. The first slag tappings or skimmings, on reduction, yielded soft lead of very low silver and bismuth contents. Intermediate skimmings yielded a lead of somewhat higher silver and bismuth contents, which could if desired be recupelled. The last skimmings yielded a litharge very high in bismuth, which could by successive oxidation and reduction cycles be separated into high purity bismuth, and lead returns. This oxidation reduction process, with modern operating techniques, can still be used today to produce a portion of a lead refinery&apos;s output of very low bismuth content, as discussed later. In 1833 Pattinsone discovered that lead bullion could be purified of silver and bismuth by fractional crystallization, the primary lead crystals formed by partial freezing being purer than the melt. Repeated processing in pans produced a lead containing as little as 0.02 pct Bi. The simple explanation of this

Jan 1, 1957

By Robert W. Waytulonis

The Federal Bureau of Mines contacted 29 organizations--mine maintenance departments and equipment manufacturers--concerning service experience and construction of diesel exhaust-gas water scrubbers. Scrubbers are used primarily on mobile diesel-powered mining equipment subject to 30 CFR 36. Because the scrubbers cool exhaust gas and act as flame arresters, their failure would compromise safety in underground mines. Scrubber maintenance problems and frequency and modes of failure were identified, and construction materials and techniques were evaluated. Three failed scrubbers were randomly selected from two cooperating mines, and their modes of failure were determined. In conjunction with failure analyses, mine water and scrubber water solution samples were chemically analyzed to characterize corrosive properties. Sludge and mineral deposits and different types of corrosion and metal fatigue were identified as problems leading to scrubber failure. The corrosion process is explained; maintenance practices, construction materials, and manufacturing methods that could be used to reduce premature failures and allow longer effective scrubber life are identified; and basic changes in scrubber design are suggested. If type 304 stainless steel is used throughout the scrubber and regular maintenance is performed, long, dependable service can be expected. Other materials such as 304L, 316, or other more exotic steel alloys may be necessary under certain conditions.

Jan 1, 1982

By David C. Kraft

Helical piles and ground anchors were used to meet critical design and constructability requirements for an urban forest Canopy Walk at the Atlanta Botanical Garden, Atlanta, GA. The 12-foot wide pedestrian walkway path was to be nestled among the treetops of a forest, extending to 600 ft. in length, and soaring 40 ft. high above the forest floor. Of particular concern during construction was that the foundation system for the temporary steel shoring system had to be non-invasive to the subsoil, could not damage the forest floor, trees, root systems, or foliage, and upon completion of the concrete walkway pour, could be removed, again without disturbing the subsoil. Accubrace, Inc. designed and installed all the helical foundation types, as well as provided steel braces, typically used in Tilt-Up building construction, for the walkway project. The braces, some extending to 43 ft. in length, were used to provide lateral support against wind loads for the walkway form. In addition, the braces acted as secondary support for lateral loads during the placement of wet concrete along the 600 ft. length of the walkway. Helical foundation products installed included vertical compression piles, ground anchors for tension rods, and ground anchors for the braces. The installation of the piles and anchors was particularly challenging since the forest floor elevation varied as much as 50 ft. due to the presence of a ravine. Information is provided on the subsoil conditions, required loads, design, installation, and acceptance criteria for each helical product type installed for the project. The results of vertical and lateral load tests on the helical piles in the pre-construction phase, conducted in conformance to project specifications are presented. Photographs to illustrate the nature and complexity of the project are included. The concrete pour for the walkway was successfully completed on December 12, 2009, and the walkway was opened for visitors in May, 2010.

Jan 1, 2011

By R. O. Pynnonen

This publication presents a study by the Federal Bureau of Mines of 494 accidents in open-pit iron-ore mines, beneficiation plants, and shops of the Lake Superior district from March 1949 to June 1956. These accidents caused 499 lost-time injuries, including 12 fatalities. A similar Bureau publication, Information Circular 7744, Analysis of 346 Accidents, Underground Iron-Ore Mines, Lake Superior District, was published in April 1956. Accident reports were analyzed by the Bureau to show the causes of in-juries and the unsafe practices or conditions that caused the accidents. Also shown are the time charges, times of occurrence, ages of the injured by job classification, and experience of the injured in mines and on the job being performed when hurt. Detailed information is presented on approximately 27 percent of the total number of disabling accidents that occurred in open-pit iron-ore mines, beneficiation plants, and shops in the district during the period covered. The text also contains tabulations of the accident experience and graphs with straight-line injury-frequency, injury-severity, and fatality trends for the period 1946-57.

Jan 1, 1959

Hydraulic fluid power systems are advantageous whenever power output must be accurately and safely controlled. The load movers, cylinders, jacks, rotary actuators and hydraulic actuators in these systems can be made to smoothly and accurately start, stop, reverse, hold position or move steadily under heavy and variable loads or torques. Because hydraulic systems are simple, compact, reliable, and low cost compared to other power methods and because they can deliver controlled power anywhere on the machine to which a hose can be routed, they are a pan of almost every type of machine found on a coal mining section. Some of the functions they perform are positioning drill booms, driving drill pots on roof bolters, positioning curter booms, raising, lowering, and swinging conveyors, driving conveyors on continuous miners, raising, lowering, and applying sustained loads to longwall roof supports, and advancing the face conveyor and roof supports in longwall mining operations.

Jan 1, 1982

By T F. McConachy, B I. A McInnes, R A. Binns

Within the last decade, major research discoveries have been made in the submarine realm of magmatic and hydrothermal activity of arc-backarc systems in the southwestern Pacific. These include identification of numerous particulate-poor, gas-rich (CO2-CH4) hydrothermal plumes emanating from arc front volcanoes, actively forming porphyry-copper-gold style mineralisation, and new backarc spreading systems erupting alkali basalt-trachyandesite magmas. Major goals of these studies have been identification of modern analogs to ancient volcanogenic massive sulfide ore bodies, and quantification of the volatile fluxes though supra-subduction zone systems.

Jan 1, 2002

By Y. Mitani, M. Xie, G. Zhou, T. Esaki

The assessment of landslide instability and risk has become a topic of major interest for both geoscientists and engineering professionals as well as for local communities and administrations in many parts of the world. In this paper, based on a new developed Geographic Information Systems (GIS) grid-based 3D deterministic model and taken the slope unit as the study object, the landslide hazard is mapped by the index of the 3D safety factor. Assuming the initial slip as the lower part of an ellipsoid, the 3D critical slip surface in the 3D slope stability analysis is obtained by means of a minimization of the 3D safety factor using the Monte Carlo random simulation. The failure probability of the landslide is calculated by an approximate method in which the distributions of f,c and the 3D safety factor are assumed to be in normal distributions. The assessment of the earthquake triggered landslide hazard is done by the dynamic displacement analysis using the index of the Newmark displacement. All the calculations are implemented by a computational system call 3DSLOPEGIS in that a GIS component is used for fulfilling the GIS spatial analysis function. Besides the results of 3D safety factor and probability, the possible landslide body and boundary can be three-dimensionally quantitatively identified. L’ estimation des glissement de terrain et des risques impliqués est devenu un des principal sujet de préoccupation pour les géotechniciens, mais aussi pour les ingénieurs specialisés ainsi que pour les communautés et administrations locales dans de nombreuses région du monde. Dans cette étude, basé sur un modèle de maillage 3D et une approche déterniniste couplée au Système d&apos;Information Géographique (SIG), étudiant la stabilité des versants , le lieu d&apos;étude à risque est maillé suivant le facteur de sécurité calculé en 3D. En supposant que le glissement initial soit la partie inférieure d&apos;un élipsoïde, l&apos;analyse de stabilité pour le glissement critique 3D d&apos;un versant 3D est obtenu grace à une minimisation du facteur de sécurité en 3D utilisant la méthode de simulation aléatoire de Monte Carlo. La probabilité d&apos;un glissement de terrain est calculée par une méthode approximative, supposant la distribution de c, f et du facteur de sécurité 3D normale. L&apos;estimation d&apos;un risque de glissement de terrain causé par un tremblement de terre est faite grace à une analyse du déplacement dynamique suivant l&apos;index de Newmark. Tous les calculs sont effectués par le biais d&apos;un système de calcul appellé 3DSLOPEGIS dans lequel te GIS est utilisé pour gérer l&apos;analyse spatiale. En plus de cela, les résultats du coefficient de sécurité en 3D, des probabilités, le terrain susceptible de glisser, et ses limites, peuvent être quantitativement évalués en trois dimensions. Die Bewertung von Erdrutsch-Instabilität und risiko sind zu einem Thema von großen Interesse für sowohl Geowissenschaftlern und Ingenieuren als auch von Gemeinden und Verwaltungen in vielen Teilen der Welt geworden. In dieser Arbeit, basierend auf einem neu entwickelten Geografische Informationssysteme (GIS) gitterbasierten 3D deterministischen Modell und mit der Böschung als Untersuchungsobjekt wird die Erdrutschgefahr durch den Index des 3D-Sicherheitsfaktors kartografiert. Unter der Annahme, dass der erste Rutsch der untere Teil eines Ellipsoiden ist, wird die 3D kritische Schlupfoberfläche in der 3D-Böschungsstabilitätsanalyse mit einer Minimierung des 3D-Sicherheitsfaktors mit der Monte Carlo Zufallssimulation erhalten. Die Fehlerwahrscheinlichkeit des Erdrutschs wird mit einer Annäherungsmethode berechnet, bei der die Verteilungen von f,c und dem 3D-Sicherheitsfaktor als innerhalb normaler Verteilungen angenommen werden. Die Beurteilung der Erdbeben-ausgelösten Erdrutschgefahr wird mit der dynamischen Verdrängungsanalyse mit dem Index der Newmark-Verdrängung gearbeitet. Alle Berechnungen werden mit einem Berechnungssystem mit der Bezeichnung 3DSLOPEGIS ausgeführt, bei dem eine GIS-Komponente zum Erfüllen der GIS räumlichen Analysefunktion verwendet wird. Neben der Ergebnissen des 3D-Sicherheitsfaktors und der Wahrscheinlichkeit kann der mögliche Erdrutschkörper und der Umfang dreidimensional quantitativ identifiziert werden.

Jan 1, 2003

By E. DeLilia

For the past 30 years, surface mines have moved toward more highly mechanized, automatic systems that continuously mine overburden and ore to in-crease productivity, lower operating costs and minimize manpower needs. To achieve these goals, mine operators must be involved in every step of the machine procurement process. Several factors are involved in making the machines operate economically and efficiently: ? Prudent engineering. ? Proper planning. ? Realistic feasibility studies. ? Effective specification. ? Thorough training of the mine personnel.

Jan 1, 1995

By B. W. J. van Rensburg, M. J. Schmidt

Bulk materials handling systems are extensively used in the mining and minerals industry, where a fairly high incidence of structural failure is experienced, notwithstanding design compliance with appropriate standards. A number of case studies are explored to demonstrate how insufficient controls or protection systems have contributed to structural failures on mobile bulk handling equipment. The importance of design integration across engineering disciplines is highlighted. The revision of ISO 5049-1 (1994) is proposed to provide specific rules and guidelines pertaining to machine protection systems. It is further recommended that the structural design engineer of the original equipment manufacturer(OEM) fulfils a more prominent role during the final acceptance and handover of mobile bulk handling equipment, with specific reference to protection systems.

Jan 1, 2015

The mining industry in Australia frequently uses the services of specialist engineering and managing contractors and consultants for a majority of the work required for project development, from feasibility studies to project commissioning. The project owner&apos;s prime objectives are to achieve predictability and competitive advantage for their project. As the majority of this work will be carried out by contractors, the effective evaluation, selection and management of these contractors in the most appropriate forms of contracts is an essential ingredient to project success. The first stage to project development should be for the owner to examine its own resources to establish the role that it will fill and thereby identify the role and scope of contractors&apos; involvement. Once the owner has developed this work plan, the selection of contractors and consultants should be structured to ensure that the owner acquires the appropriate expertise and experience to achieve its project objectives. The sequence of selection procedures is: 1. Pre-qualification of prospective contractors according to the owner&apos;s adopted criteria, through the use of a pre-qualification questionnaire. 2. Evaluation by the owner tender board according to predetermined mandatory criteria. 3. Preparation of tender documents for submission to qualified contractors. 4. Evaluation of tender submissions by the owner tender board using a pre-determined, weighted matrix of technical and commercial criteria. 5. Final selection and contract negotiation.

Jan 1, 1990

When studying minerals degrees at university, all the emphasis is towards sending the graduates into the bush to work at a remote mine; however, that is not the only option available to new graduates. There are positions in equipment supply companies, commercial laboratories, research organisations, engineering companies and contractors of many types. The aim of this paper is to show metallurgy graduates that there are non-mine site based career options available to them that offer outstanding career development. This is illustrated by outlining the research being undertaken by Magotteaux Australia and by telling the story of a graduate metallurgist working in MagotteauxÆs small research group. Magotteaux is an international supplier of grinding media and wear resistant components for the mining industry. The Australian research group is focused on determining the effects that the choice of grinding media has on subsequent processing, for example flotation and leaching, by using newly developed tools and techniques.

Jan 1, 2006

By C. H. Mathewson

MY treatment of the subject of "Metals of the Future" is imaginative rather than statistical or scientific, because reliable information concerning useful concentrations in the form of ore deposits of by far the majority of the elements does not exist and the chemical, physical, and mechanical properties of the unfamiliar metals are recorded only in fragmentary and uncertain form or not at all.

Jan 1, 1944

By M. Cohen, P. E. Beaubien, D. Caplan

Addition of 1 pct Mn to Fe-26 CY ca/(ses a12 increase in scaling rate at 870° and 1090°C. Whereas only the rhombohedral oxide, formrs on tire manganese-free alloy, with manganese present major amounts of the spinel .Mn0 . Pro-duced through which diffusion is more rapid. At 1090°C the scale formed OH Mn is highly, irregular due to blistering and sintering, This is a second cause of faster oxidation Since much of the blistered oxide does not participate as part of the protective layer. The oxide phases that form at different times depend on the degree to which the surface metal has become depleted, in manganese by preferential oxidation. PREVIOUS work has demonstrated that the oxide scales formed on chromium steels at high temperature consist of both spinel and rhombohedra1 phases and may contain considerably more manganese, especially in the spinel phase, than is present initially in the alloy.&apos; It has further been observed that a binary Fe-26 Cr alloy scaled less rapidly than an equivalent commercial steel and formed no spinel.&apos; However, it is not established if manganese in chromium alloys actually promotes formation of spinel nor if it affects oxidation resistance. It seemed expedient to try to evaluate the specific effect of manganese by oxidizing an Fe-26 Cr alloy containing a small manganese addition under the same experimental conditions as used for the manganese-free alloy.&apos; EXPERIMENTAL Table I shows the composition in weight percent of the Fe-26 Cr-1 Mn alloy and of the Fe-26 Cr alloy used as reference. The alloy with manganese was prepared from the vacuum-melted Fe-26 Cr alloy by remelting in vacuum with the proper manganese addition. The ingot was rolled to strip and specimens 1.1 by 0.035 by 5 cm and 1.1 by 0.5 by 4 cm cut out or machined. As previously described2 the specimens were smoothed by abrading through 600-grit Sic paper, electropolished in acetic-perchloric acid (20 to 1) to remove 10 p of metal, annealed at 1100°C in 20 torr of purified argon, and electropolished to remove a further 10 p of metal. They were then either rinsed in water and methanol and blotted dry or immediately etched for 45 sec in deoxy-genated 4 N HC1 under cathodic polarization at 10 pa per sq cm. Oxidation runs were carried out in a vertical tube furnace in a flow of purified oxygen at 1 atm while the weight increase was recorded continuously on a* automatic balance.3 Alter 98 hr at 870.C or 20 hr at 1090"C the specimens were removed to flowing argon and observed microscopically for evidence of spalling as they cooled. Subsequently they were examined by X-ray diffraction, the oxides analyzed chemically, and metallographic cross settions prepared. RESULTS Figs. 1 and 2 show the oxidation curves of Fe-26 Cr-1 Mn at 870&apos; and 1090C. The Fe-26 Cr reference runs are shown as dashed curves. Experimental details of the six runs are included in Table 11. The first 20 hr of run 1 is repeated in Fig. 2 to show the effect of temperature. At 8&apos;70°C the weight gain for Fe-Cr-Mn is about twice that of Fe-Cr (curve 1 vs curve 2, Fig. 1). Both alloys show regular oxidation curves. On parabolic coordinates (right-hand scale of Fig. 1) the

Jan 1, 1965

The development of a noise attenuated compressed air driven fan is described. The fan, which employs the jet reaction principle, possesses blade extension pieces which penetrate into an acoustically treated annular chamber. The dominant noise source, namely the air jets, is thereby partially suppressed. In addition, the increased moment arm of the jets leads to an improved propulsion effect which contributes to the improved aerodynamic performance of the unit.A typical measure of the improvement of this type of auxiliary mine ventilation unit is a 4 per cent increase in efficiency and a 10 dB (A) drop in sound level for a fan duty of 0&#183;5 kPa and 1600 litre/s. This degree ofattenuation corresponds to at least halving the loudness level, a subjective noise measure.

Jan 1, 1973

By Ronald W. Schaefer

This report describes operations at the Rosiclare Fluorspar Works of the Aluminum Co. of America at Rosiclare, Hardin County, Ill. The works include the Fairview mine, the fluorspar mill, and related facilities. The publication covers exploration, development, mining and milling practices, mine-drainage problems, and other activities and is presented as part of the Bureau of Mines series of publications on mining and milling practices in various parts of the United States. The Rosiclare fluorspar area, for its size, has been the largest producer of high-grade fluorspar in the United States and probably in the world. The vein system in this area is over 5 miles long and 1/2 mile wide, and ore has been found as deep as 900 ft.

Jan 1, 1961

By J. L. Schwendeman

This is the final report of work done under contract H0210060 for the U. S. Department of the Interior, Bureau of Mines. This program was to show the feasibility of using plastic liners containing sand and other fillers as a means of roof support in coal and other mines. This laboratory study was conducted in two phases, namely: Phase I, directed toward determining which state-of-the-art resin systems might have utility as a means of roof support in a coal mine, consisted of a canvass of resin manufacturers to learn which resins were available commercially that might have utility for this application. The resins submitted by the manufacturers were evaluated in a number of simple tests to define which of them would be most suitable for roof support use.

Jan 1, 1972

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1955 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 116 samples of aviation gasoline and for 38 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers&apos; 1955 production in their laboratories and the results submitted to the Bureau of Mines for compilation. The products of 20 manufacturers of aviation gasolines and of 16 producers of aviation jet fuels are represented.

Jan 1, 1956

By Hargraves A. J

The paper outlines events at the Collinsville State Coal Mine, Queensland, leading to the practice of full face multiple shotfiring in bord and pillar development places. The 1954 disaster is referred to, and factors involved in simultaneous shotfiring in coal are discussed. Promising preliminary multiple shotfiring tests at the Colliery are described, as well as the resulting routine measures adopted, and the changes involved. The subsequent inducing of two outbursts under safe conditions by remote multiple shotfiring is given as justification for the changes made.INTRODUCTIONFollowing a disastrous instantaneous outburst (1.0.) of coal and gas at the Collinsville State Coal Mine in 1954, the necessity for inducer shotfiring for the control of possible further outbursts was established. However this mine, immediately classified as gassy after the 1954 outburst, is subject to the general restrictions pertaining to gassy mines which at present preclude the use of inducer shotfiring due particularly to the non-existence of a permitted exploder for more than six shots, and further, because permitted multipleexploders are not designed for remote firing through long lengths of cable. This situation was met by arresting or reducing progress in the production places, thereby reducing the danger of outbursts while means were being considered to achieve overall maximum safety.In August 1957 two full faces were successfully blasted in experimental simultaneous rounds. In June 1958 four full faces were blasted, and in October 1958 full face grunching without prior cutting, Le. inducer shotfiring, was introduced in No. 1 Tunnel as a production feature. In March 1960 it...

Jan 1, 1960

By Nikolaus Schneider

"Abstract: The combination of failure in joints of diaphragm walls and their exposure to water pressure may have far reaching effects ranging from water leakage to the risk of catastrophic loss of stability for the retaining wall and civil structures behind it. Investigations of imperfect joints in diaphragm walls have led to the development and testing of a quality tool to monitor the joint integrity of diaphragm walls during construction. By applying independent mechanical sensors (“joint inspector”) to the steel frame of hydraulic or mechanical grabs, it is now possible to record the surface conditions of exposed primary joints during the construction of secondary panels. This allows for the implementation of corrective action during the construction process should joint quality not indicate a watertight connection to the adjacent panel. The joint inspector, used for different types of stop ends, was tested on a full scale test field at several construction sites. The implementation of this new quality tool drives a new quality standard for deep excavations in inner city areas.General introduction to diaphragm wallsDiaphragm walls are reinforced concrete elements constructed using bentonite slurry to temporarily support an open trench in the ground. They are used in two main fields of application in civil construction, as foundation elements for vertical and horizontal loads (barrettes) and as retaining walls for excavation pits.Particularly for deep excavation pits in inner city areas, diaphragm walls are used as temporary or permanent walls of retaining walls. Alternative retaining wall systems would be secant pile walls, sheet piles or soldier piles, but these have disadvantages in structural strength when compared to diaphragm walls. If the vertical load of existing buildings next to the excavation pit has to be accommodated, the most practical solution can be found using diaphragm walls supported by prestressed anchors, steel struts or slabs."

Jan 1, 2014

By J. B. Clark

In multiphase ternary diffusion studies, plots of the variation bf the composition on the isotherm constitutes one of the most effective methods of presenting experimental results, especially if such plots are made in a manner which relates the composition path on the isotherm with the diffusion layer structure in the couple. Unfortunately, if different conventions for plotting are used serious misinterpretations occur readily, causing apparent disagreement between investigators who actually share the same viewpoint. A common convention for mapping these diffusion paths is needed at this time because with the increasing use of the electron-probe X-ray microanalyzer, a much greater number of ternary diffusion studies can be expected in the near future. In an effort to prevent unnecessary confusion in the future litera- ture, a convention for these plots is proposed, as outlined below. A hypothetical example of the use of these conventions is given in Fig. 1 where the path of composition through the diffusion structure of the 100 pct A/50 pct B, 50 pct C couple is plotted on the appropriate isotherm of the ABC system. The lower case letters relate the region in the diffusion layer structure to the appropriate composition on the ternary isotherm. 1) The diffusion path is plotted on the isothermal section corresponding to the diffusion temperature of the couple. 2) The terminal compositions of the plotted diffusion path are the initial compositions of the couple halves—provided infinite boundary conditions are maintained. If, in either couple half, infinite conditions are not maintained, then the path terminates at the composition of the exterior surface of the couple. If, at this surface, the composition varies with time or if the plotted path is time dependent, then the diffusion time should be noted beside the plotted path. 3) A solid line crossing a single phase field (e.g., line a-b in Fig. 1) denotes an existing layer of that phase in the diffused couple. 4) A dashed line crossing a two-phase field parallel to the tie lines (e.g., line g-h) represents an interface between the two phases with interfacial compositions designated by the ends of the tie-line. The line represents no spatial extent. 5) A solid line crossing a two-phase field so as to cut tie lines (e.g., line b-c or line j-k) represents a locally equilibrated columnar two-phase layer. The solid line should cut those tie lines which correspond to the lateral interfacial equilibria along the columnar

Jan 1, 1963