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By Alexander May

The Bureau of Mines conducted studies to determine if phosphogypsum, a waste material from the processing of phosphate rock, contains hazardous toxic materials as defined by the Environmental Protection Agency (EPA) and whether leaching of these toxic materials and radium may occur. Samples of the phosphogypsum stockpiled material were evaluated using the EPA extraction procedure, atomic absorption, neutron activation, x-ray diffraction, and chemical and physical means. Radiological tests performed used both the germanium-lithium and emanation methods. The data show that the phosphogypsum stockpiles are not hazardous toxic waste as defined by EPA criteria. Trace elements and radium are not leached from the phosphogypsum stockpiles. Absorption of trace elements and radium by phosphogypsum is the major reason for their not being leached. The standard error of measurement of radium concentrations was 4.7 pCi/g.

Jan 1, 1983

By S Henderson

The Thames gold-silver deposits are part of the Hauraki goldfield, situated within the Miocene to Pliocene calc-alkaline Coromandel Volcanic Zone (CVZ). The Waitangi vein system is one of the mineralised ore shoots in the Thames district. The Thames gold deposits are characterised by shallow level epithermal vein mineralisation with phyllic to advanced argillic alteration assemblages and abundant sulphide minerals including pyrite, arsenopyrite, chalcopyrite, galena and sphalerite. Gold occurs as electrum in association with sulphide minerals. Microprobe analyses.of sphalerite grains from the Waitangi deposit mostly range from 0.8 to 1.5 mole % FeS, although one sample contains 9.5 mole % FeS. Arsenopyrite from Waitangi yields a range from 33.1 to 34.6 atomic As (%). There is no discernible correlation between the FeS content of sphalerite and gold grade in the Waitangi deposit suggesting that gold deposition is probably not controlled by changes in temperature and activity of sulphur aS2 that control the FeS content of sphalerite. The possible causes for gold deposition are thought to be boiling, mixing and changes in pH. Sulphur isotope analyses of mixed sphalerite-galena and sphalerite-galena-ehalcopyrite samples yield a narrow range of d34SCDT values (-1.0 to 0.9 ë;n=5), whereas late spongy pyrite gives unusually light sulphur isotope values (-16.7 to -27.9 ë; n=4). The sulphur isotopic values of base metal sulphides from Waitangi suggest that the sulphur was derived from a magmatic source. However, the source of light sulphur in the late pyrite grains is not known. Preliminary fluid inclusion+studies indicate homogenisation temperatures between 173¦ and 284¦C and salinities of 0.23.0 NaCI equiv. wt % (uncorrected for C02). Vein quartz at Waitangi yields d18OSMOW values from 6.8 to 12.7 ë (n=23). The calculated oxygen isotopic composition of ore fluids is between -2.1 to 3.8 ë at 250¦C and -0.1-5.8 ë at 300¦C. Oxygen isotope analyses have revealed significant variations in d18O values with elevation and gold grades. Zones of gold enrichment coincide with a zone of variable oxygen isotope values at the top of the vein system, where boiling and/or fluid mixing most likely occurred. Oxygen isotope values varying with gold grades within the Waitangi conduits suggest that d18O values may be useful in targeting bonanza grade gold mineralisation in epithermal vein systems.

Jan 1, 1993

By R. A. Hill, J. D. Pitts

"Long distance slurry pipeline systems have been successfully trans-porting steam coal, iron concentrates, copper concentrates and limestone for an aggregate of nearly 60 years and nearly three billion ton-miles annually. A phosphate concentrate pipeline is nearing start-up and systems for coking coal, lead/zinc concentrates and fly ash are planned. The solids pipeline concept, first patented in the early 1900's and commercialized in the 1950's, is now a proven technology providing an economic, environmentally pleasing and safe method for long distance bulk transport.The challenge for larger tonnage and longer distance movements of solids, for traversing increasingly rugged terrain in grass roots mineral developments, for transporting untried materials and for shipping more economic forms of proven materials still remains. This has necessitated continued refinements and optimization of the technology. The economic and environmental incentives for slurry pipelines when compared to other transport alternatives has justified substantial activity in this area. The scope of planned systems in coal, iron and other minerals is indicative of the firm place slurry pipelines will have in worldwide mineral development.In this presentation, the state-of-the-art in long distance slurry pipelines is reviewed with a focus on major systems of interest to the mineral processing industry. An overview of new developments in the application of this concept is presented, and finally, a projection of the future of pipelines in mineral development both worldwide and in Canada is discussed."

Jan 1, 1978

By John D. Morgan, Sylvain J. Pirson

An instantaneous and continuous analysis of a mineral suspension should be of great value in controlling various mineral preparation processes. Described herein is a method of analysis based on the use of high-frequency alternating current, which, under certain restrictive conditions, could be of use. Theoretical Considerations In a suspension of conductive minerals, the electrical effect primarily responsible for the variations in electric conductivity is the capacitance. In Fig Ia, let an alternating voltage E be applied across two electrodes F and F', between which are two rows (S and T) of mineral particles, all of approximately the same size, immersed in a fluid. Let the number of rows of particles between the electrodes be R and the number of particles in each row be N. If A is the area of a particle, D is the distance separating two particles, and k is a constant depending on the fluid, the capacity, CO, of the particle system will be given by: KRA C°= ND Referring now to Fig Ib, let R, the number of rows, be held constant, but let N, the number of particles in each row (S and T), be increased X-fold. The capacity, C1, of

Jan 1, 1949

By M. Prats

Most of the information available on the heat efficiency of hot fluid injection processes, both water and steam, has been obtained from calculated temperature distributions in the pay zone and adjacent formations. The usual approach has been to write the heat balance equations in terms of the temperatures, and then to introduce whatever simplifications are necessary to help obtain an analytical or a numerical solution. In either case, the assumption has often been made that the vertical thermal conductivity in the flooded interval is infinite, so that the temperatures within the flooded interval are then independent of vertical position. Because it was first made by Lauwerier,l and has been used extensively since, this assumption will be referred to as the Lauwerier assumption. Excellent reviews of the literature on the heat efficiency of hot fluid injection processes have been given by Spillette,2 Flock et al.,3 and Ramney.4 Of course, the most significant contributions take into account the effect of a finite vertical thermal conductivity on the vertical temperature profile. The most general analytic expression for the heat efficiency of a hot fluid injection process is that of Antimirov5 who considers injection of a heated incompressible fluid into a reservoir through an arbitrary number of wells. The rate of heat injection into the reservoir, as well as the injection temperature, is an arbitrary function of time. The geometry of the horizontal flow is arbitrary, although the reservoir is considered to be of uniform thickness and properties and to be of infinite areal extent. Heat transfer within the reservoir is by horizontal convection and conduc- tion, and by vertical conduction. In the formations adjacent to the flooded interval, heat transfer is by conduction in any direction. Thus, the available expression for the heat efficiency due to hot water injection has been developed for rather general conditions. This degree of applicability has not been obtained for other thermal recovery processes. By making the Lauwerier assumption we have been able to obtain expressions for the heat efficiency that are essentially independent of the thermal recovery process, be it steam, hot-water, or underground combustion. Clearly, then, the approach followed here is more restrictive than that of Antimirov5 in that it uses the Lauwerier assumption. At the same time less restrictive assumptions are made about the horizontal heat transfer mechanisms, either in the flooded interval or in the formations adjacent to it. The main difference between our approach and that of other investigators is that the heat balance in the pay zone is expressed for the pay zone as a whole rather than for a volume element within it. The Lauwerier assumption is introduced after the problem is developed along these lines as far as possible. The details of the development of the heat efficiency are given in the Appendix, while the main features of the model are discussed in the next section. Results and their implications are discussed later in a separate section. The Model Certain assumptions have been made to determine

Jan 1, 1970

By Mandy Korff

Walls consisting of CFA-piles are often used for vertical cut offs for building pits. Several methods of installation and geometry may be used and sizes, depths and strengths of walls necessary vary widely. Based on experience with secant CFA-pile walls in The Netherlands, requirements for this type of wall can be set with a risk management view to it. This paper describes those requirements, based on specific local conditions.

Jan 1, 2006

By N. T. Rempe

Proper use of natural resources is multiple use. Underground space resulting from mineral extraction offers opportunities for deep geologic waste disposal (DGWD) which can solve many environmental problems. U.S. government projects plan to use specially mined excavations to dispose of radiotoxic and mixed waste. DGWD takes careful planning, technology transfer, and true partnership between waste generators and mine/repository operators. Using the experience, accumulated by domestic projects in preparation, and by foreign repositories in operation, U.S. mines can claim their rightful share of the growing market for DGWD.

Jan 1, 1996

By L. C. IlsLey

Cooperation between the United States Bureau of Mines and the Safety in Mines Research Board of Great Britain, continuous since 1924, has made possible this and other papers on safety subjects. Grateful acknowledgment is made to representatives of the Safety in Mines Research Board of the Mines Department for their assistance in arranging visits to several mine-safety stations, and to F. H. Wynne, Deputy Chief Inspector of Mines, Great Britain, for arranging visits to mines in Great Britain, Belgium, France, and Germany. During the summer of 1927 the writer had the privilege of visiting the mine-safety testing stations in Great Britain, Belgium, Germany, and France, in the order named. All of these countries have large coal mines, many of which are rated as gassy. Therefore, when the installation of electrical equipment is contemplated, each of these countries is confronted with the same safety problem as in the United States - the development of electrical equipment that will not ignite gassy mine atmospheres, should such atmospheres through neglect or accident surround the equipment. The means used by those countries in safeguarding gassy mines should therefore be of general interest to safety engineers in American coal mines, and it is proposed to give a brief survey for each of the four countries mentioned. The first of these surveys will cover conditions in Great Britain.

Jan 1, 1929

The physical setting and background to mining operations on Misima Island and the overall plant lay-out are outlined. Developments and changes made to each section of the plant are described as they were encountered during commissioning and initial operation.

Jan 1, 1991

By Manuel Gomez, V. F. Parry, John B. Goodman

"INTRODUCTION The need for an accurate and precise analytical method for determining moisture in coals of high water content has been recognized by the coal industry as well as the fuel technologist. Interest in this particular phase of coal technology extends back to the early work of German investigators on the brown coals of Central Europe. Studies by these workers led to the establishment of a direct immiscible liquid-distillation method 4/ as the accepted moisture determining technique in European laboratories. Direct moisture determining methods, those methods that utilize various techniques to drive off the water from a given sample of coal and either collect the water in a calibrated receiver or selectively trap the water driven off in a suitable absorber, have found little favor in the United States. They have been treated merely as research tools.5/ The problem of moisture determination in low-rank coals of the United States has not been given much consideration because such coals contribute only about 2 percent of the total United States production. With renewed activity in low-temperature carbonization and with the growth of interest in coal and coal-tar hydrogenation, the American coals of lover rank containing 20 to 40 percent bed moisture will be subjected to extensive investigation. If the low-rank coals of the United States are to be accurately appraised, the need for qualitative and quantitative analytical proceeded becomes more pronounced. These coals, especially the lignites of Texas and North Dakota, are highly susceptible to oxidation, a process that proceeds to a greater or less extort when low-rank, high-moisture coals are treated by oven-drying methods. The extent of this atmospheric oxidation has been described and evaluated by numerous workers. 7/In many respects, the problem of moisture determination in low-rank coals, those found in the United States and the high-moisture coals of Central Europe, is similar. Conversely, the problem of moisture determination assumes a different aspect when the coals of the eastern and the middle-west sections of the United States are considered. Present methods, the loss in weight gravimetic-type procedures, serve adequately to test these low-moisture coals. The determination of moisture in coals containing 20 to 40 percent water should be approached from a direct method rather than from an indirect gravimetic-type procedure because of the oxidative tendencies of these coals and the demonstratrated inability of a loss-in-weight technique to remove all the water in a given sample of coal."

May 1, 1953

By Robin B. Dill, Mark Pelletier, Daniel J. Dobbels, Subodh Bhaumik, Daniel J. VanRoosendaal

Although primarily cut-and-cover excavations are required for replacement of the existing elevated I-93 interstate highway through the heart of Boston for the Central Artery/Tunnel (CA/T) project, some mined tunnel construction was also undertaken. The mined tunneling conducted was the 22-m-wide northbound roadway structure which passed below a 20-m-deep operating underground subway station that was built in 1913. The innovative underpinning scheme used to support the subway station during construction resulted in the successful mining beneath the subway station with negligible vertical settlement. Two grouting galleries were carefully mined below the subway structure, and pre-grouting of the granulary, pervious glacial soils and weathered bedrock was carried out from these galleries. The reinforced concrete walls of the underpinning structure were constructed within three stacked drifts that were sequentially mined below each grouting gallery. After 11 cross adits were mined between the grouting galleries, cast-in-place post-tensioned girders that spanned between the stacked-drift walls were constructed to support the subway station. The stacked-drift walls also provided lateral support for the 22-m wide by 29-m long by13-m high opening beneath the girders.

Jan 1, 2001

By Marshal Scherba

Coal seams approximately 7 feet, 9 feet and 20 feet thick at depths of 250, 600 and 1,000 feet respectively were detected using high resolution seismic reflection techniques. Investigation of seismic profiles indicates that good data are required to delineate faulting with only 20 feet of throw but that faulting with 50 feet of vertical displacement can be detected with poor data. Data acquired from dynamite charges fired in water saturated media were clearly superior to that acquired using charges dry tamped in 10 and 20 foot holes.

Jan 1, 1977

By Sushil Bhandari, Amit Bhandari

Blast optimization in open-pit operations is a task that often remains at a theoretical stage. Indeed, when it comes to operational blast design and onsite implementation, time restrictions and field conditions make it difficult to execute a planned pattern accurately and optimization according to local conditions is even more difficult. For example, adjusting a drill pattern to a complex face geometry is not something that can be easily undertaken on site. Blasters and engineers will do their best trying to distribute boreholes over the bench and even then, it can take them hours to achieve an acceptable layout. Similar situations occur with delay sequences, when trying to adjust them to address selectivity or vibration issues. For these reasons, operational blast design will often remain at a very basic level and the required adjustments are laid aside due to the difficulty of implementing them on site.

Jan 1, 2019

By P E. H Gregg, R B. Stewart

Restoration trials established in 1985 included a treatment where pasture seed was sown directly into fertilised tailings. After seven years, accumulated soil data was used to compare physical and chemical changes in the plots with the original tailings control area nearby.   A known amount of annual fertiliser additions over the seven year period allowed nutrient balances to be calculated. Losses of S and P were relatively high at 72% of applied S and 28% of applied P. Calculations show that at least 240 kg N/ha/yr was fixed by clovers and this is likely to be under-estimated given that the calculation did not allow for leaching losses.

Jan 1, 1993

By G. Zhu

The straight Y-shaped silica nanorods have been synthesized on Si wafer by thermal chemical evaporation of mixed powders of silica and graphite at 1300_ and condensation on Si substrate without assistance of any catalyst. The synthesized samples were characterized by means of scanning electron microscopy, transmission electron microscopy. The results suggested that the straight Y-shaped silica nanorods have uniform diameter about 50-200nm and neat smooth surface. The growth of such silica nanorods may be a result of the fluctuation of external conditions and internal structure faults causing a change in the growth direction of silica nanorods developed.

May 1, 2008

By John G. Palmer

Continued development of an especially impregnated silica gel capable of reversible chemical detection of carbon monoxide (CO) was reported. The affects of changes in mine-related ambient conditions on the detection catalyst's response were explored. Temperature, humidity, and several interfering gases were found to affect the detection catalyst. The interferents include hydrogen sulfide, nitrogen dioxide, acetylene (and methylacetylene), and ammonia. High humidity decreased the detection catalyst's sensitivity to carbon monoxide for some formulations. Increasing temperature generally decreased the reaction time of the detection catalyst with carbon monoxide. Badges and carriers for the visual presentation of the detection catalyst were constructed. Several variations of these devices included provisions for absorbants and filtering agents which help protect the detection catalyst from gaseous interferents. A variety of catalyst support agents were tested in an effort to find the most suitable. Included were alumina, magnesium oxide, magnesium silicate, and several forms of silica gel. In addi tion to free-flowing forms of these sorbents, thin layer chromatography plates coated with cellulose, alumina, and silica gel and newly developed PTFE entrained silica gels were examined. A limited physical, chemical, and mechanistic characterization of the detection catalyst and the materials used to prepare it has been carried out. Metal component ratio studies, spectral, analytical, pH, and rate measurements were done.

Jan 1, 1982

By G. E. Pearse

Reports, discussions, a written contribution and two written replies are presented from 11 sessions on: Safety and compressed air; Ground movements; Geotechnical; Channel Tunnel (2 sessions); Machines; Case histories; Transport tunnels; Case studies; Site investigation; and Undersea tunnels

Jun 13, 1905

By Philippe Dumont

?Lay out of the tunnel section ?General ?Geology ?Tunnels methods ?Stations constraints ?Impacts on tunnels ?Design ?Programs

By J. F. Wright

During the last three years prospecting has been active in southeastern Manitoba and a number of interesting gold, nickel and copper deposits have been discovered within an area 90 miles north of the international boundary, and extending about 40 miles westerly from between mileage 60 and 110 on the Manitoba-Ontario boundary. As known at present, two-thirds of this area of 2,000 square miles is underlain by pre Cambrian granite and granite gneiss and is not likely to contain mineral deposits of economic importance. The remaining one-third is underlain by metamorphosed sediments and lavas (greenstones), penetrated by the granite and granite gneiss and, at various localities, cut by bosses, sills, or dykes of gabbro, diorite, granodiorite, and other types of intrusives. The nickel, copper, and gold mineralization accompanied or followed the intrusion of these different rock types. The gold deposits are limited in distribution, so far as known, to the northern part of this prospecting area and occur along Manigotagan and Wanipigow rivers. These deposits have recently been described in some detail, (3) and therefore only the copper and copper-nickel deposits of the southern part of this area, along Oiseau and Maskwa rivers, will be described in this paper.

Jan 1, 1925

By M R. Stevens

The Kauri Block (Hauraki Hill) andMatawai Valley epithermal vein systems, near Coromandel township, are hosted by hydrothermally altered Miocene andesites and Mesozoic greywackes of the Coromandel VolcanicZone. The hydrological setting of both geothermal systems was probably that of an andesitic volcanic arc. Two types of veins are recognised: 1. Simple veins composed of fine comb quartz, and 2. Complex (breccia) veins composed of vein fragments of sulphide-bearing, chalcedonic silica cemented by saccharoidal and fine comb quartz.   Pyrite, arsenopyrite, marcasite, and gold form the ore minerals. Both deposits historically exploited hypogene and supergene bonanza gold.   At Hauraki Hill, breccia veins up to 7m wide contain abundant fragments of recrystallised colloform banded-crustiform textured quartz veins ('Golden Cross' style) and were probably major channels for ascending deep mineralising fluids. Alteration assemblages are zoned with the higher elevations of Hauraki Hill-Bunkers Hill characterised by strong kaolinite alteration whereas deeper levels are dominated by illitic clays.   At Matawai, complex veins and hydrothermal breccias pinch and swell, and inflect, within a total width of veining and alteration that exceeds 50 m. The greywacke host rocks are altered to an assemblage of illitesmectite, quartz, chlorite and pyrite although there are pockets of kaolinite.   The proposed genesis of veins and ores in both deposits invokes episodic rapid mixing (quenching) of hot mineralising reservoir fluids with cool acid condensate waters, whilst acidification and increased fO2 triggered gold deposition. These hydrothermal systems heated up during their later stages and at Matawai visible gold was deposited from a late mesothermal stage. The main conclusion is that the northwest CVZ has excellent potential for large gold deposits (= 30 tonnes contained gold).

Jan 1, 1993