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By John L. Sundstrom

Complete systems were designed -and are in operation to recycle the effluent streams and to remove impurities from tankhouse. electrolyte, Heavy em¬phasis was placed on making usable products from as many streams as poss¬ible at minimum capital and operating costs. Almost complete recycling: and reuse of water and sulfuric acid were paramount. Techniques used in-clude solvent extraction - electrowinning, evaporation - crystallization and filtration.

Jan 1, 1992

By Sebastiaan Peelman

NdFeB permanent magnets are the best available magnets used in many technology applications. However, at their end-of-life (EoL) most of magnets and the contained REEs are lost during the recycling of the bulk metals. The REEs are classified as the most critical raw materials in the European Union, and recycling of REEs from EoL products will reduce their criticality and contribute to the sustainability of REE. Various technological routes have been reported, but most of the methods are effective for highly concentrated magnets or magnet scrap, which is greatly dependent on expensive pre-dismantling processes. This paper presents various innovative metallurgical solutions to the effective REE recovery from current industrial practice for WEEE recycling, including the ferrous scrap from WEEE shredder products and shredder residues from computer hard disk drives. Both hydrometallurgical and combined hydro- and pyrometallurgical REE recovery routes are developed after demagnetization and physical upgrading.

By T. Shoji

"The human history is characterized by social development based on mineral and energy resources, and many conflicts to take the resources by power. This is shown by not only world wars but also many local conflicts as well as international supremacy.IntroductionThe world population after B. C. 10000, which is summarized in several papers, is approximated by four straight lines on a semilogarithmic diagram as shown in Figure 1 [l]. The annual rates of increasing are 0.0041, 0.071, 0.53, and 1.85 % from the old and young periods. The boundaries among four periods are approximately B. C. 4600, AD. 1670, and 1930. The start of the second period seems to correspond to the beginning of agriculture and cattle breeding. Precisely speaking, the usage of natural energy resources such as woods and domestic animals already began, but is inferred to have become common after the age. The third and fourth periods are characterized by the common usage of coal and oil, respectivety. Not only energy resources but also mineral resources including gold, copper, iron and others are also important for the human history.Mineral and energy resources have supported the development of the .human civilization, and have caused many conflicts because of this reason. Every day newspapers report conflicts, such as Chechnya, East Timor and Ache. We can easily point out the facts that the conflicts closely relate to mineral and energy resources. Groznyj, Capital of Chechnya, is located on the western margin of Caspian oil field. Many mineral deposits occur in Kavkaz Mountains running south of Chechnya. Subsea oil fields occur in Timor Gap located between East Timor and Australia. Ache is also one of oil fields in Indonesia. It is very difficult to state present conflicts independently of a political view of point. For this reason let us try to historically review the relation between mineral and energy resources and international domination and conflicts [2] based on many papers [3]."

Jan 1, 2000

By Christopher M. Moore

DK Recycling und Rohelsen GmbH converts 380 000 annual tonnes of iron containing waste materials Into pig Iron. Zinc Is the main reason that these materials are classified as waste. The materials are processed In the conventional way by making sinter which is then smelted in a blast furnace to foundry grade pig iron. The trick lies not in the unit operations which are quite standard but rather In the modifications made to the plant and operating procedures to cope with the much higher levels of tramp elements.

Jan 1, 1995

By F. F. Lins

There is a large use of mercury in Brazil by the gold miners in the so called "garimpos" (non registered mining operations), where it is usual to recover the gold contained in the gravity concentrates by amalgamation, which is highly deleterious to environment if not conducted properly. Unfortunately, this is a common practice there. After presenting in brief the modus operandi generally practiced in the garimpos and the environmental problems, this work reviews some of the research conducted in CETEM according to two approaches: (i) replace amalgamation by other processes and (ii) develop technology to treat mercury-contaminated soils and effluents. Conventional processes like froth flotation, to recover gold from gravity concentrates, and centrifuges were considered. Also as alternatives to amalgamation, innovative process like the recovery of gold by coal-oil agglomerates and a technology that is currently under development in our laboratory, called gold-paraffin process, are described in brief, some results presented and their potential use assessed. To reclaim sites already polluted a technology was developed to float mercury selectively from contaminated soils. The potential use of centrifuges to pre-concentrate the mercury is also discussed. The scope for applying the last techniques is to concentrate the pollutants in a small volume of mass which would be suitable for recycling or isolation from the environment. A prospective technology to treat contaminated soils, or mercury concentrates, is the immobilization of mercury by adding inorganics. Concerning the ionic mercury which may be present in effluents, precipitation of the ions and flotation of the precipitates are being studied.

Jan 1, 1994

By S. J. Thiele, T. Newton, W. Magalhäes, T. Takayama, J. Welsh

Companhia Paraibuna de Metais (CPM) is presently pursuing a zinc production expansion project. Besides increasing production, the goal of the project is to address existing problems while providing a platform for a proposed twofold increase in production in 2003/2004. Therefore, the current expansion strategy was formulated to address present and future requirements. Computer simulation modeling and full scale plant testing are being used to generate data to optimize the operating conditions and to perform a sensitivity analysis. The initial phase of the project, which will boost CPM's capacity to 86,000 t/y of marketable zinc, is to be completed in September 2000.

Jan 1, 2000

By W. G. Davenport

This chapter examines three minor influences on flash smelting's industrial oxygen and oil requirements, i.e.: (a) recycle of molten converter slag to the flash furnace (b) gangue oxides and carbonates (e,g, Ah03, CaC03) in the flash furnace feed (c) minor sulfides (e.g. NiS} in the flash furnace feed. It then examines the. sensitivity of our flash furnace calculations to previously ignored aspects of smelting chemistry -Cu, S and Fe304 in slag and 0 in matte.

Jan 1, 2001

By Stig Petersson

Slag from the converting of copper matte is usually recirculated to the smelting furnace. This recirculation generally causes disadvantages as magnetite-build-up in the furnace, accumalation of impurities as antimony, lead, nickel etc in the process. The treatment of converter slag in a separate furnace in order to recover the copper and nickel content would be of advantage from several points of view. At the Mining and Metals Division, Boliden, testwork has been carried out to treat converter slag from the PS-converters in a separate furnace. The tests have been performed in laboratory and pilot plant scale. The pilot plant tests have been carried out in a TBRC with charges of 5 tons. Based on these tests a full scale TBRC has been projected in order to treat the slag from the PS-converters. This slag will be reduced with copper concentrates to give a matte and a final slag low in copper and nickel. The background and data from the testwork are presented. Also the lay out, technical data and flowsheets for the projected process are shown as well as some production data from the Rönnskär smelter.

Jan 1, 1976

By G. H. Khoe

Neutralisation of acid uranium mill tailings with lime or other alkaline materials is usually practised to reduce the dissolved concentration of heavy metals and radio nuclides. Computer modelling of this process was carried out using the geochemical equilibrium code MINTEQA2. Computed dissolved metal and sulfate concentrations were compared with laboratory-based experimental data. It was found necessary to include the modelling of adsorption of trace metals (such as uranium and lead) by the precipitated ferric hydroxide in order to obtain acceptable concentrations in the neutralised liquors. There were limitations of the modelling exercise due to important aspects which were not addressed or properly accounted for such as chemical reaction kinetics and the effect of high ionic strength. These are discussed in the paper.

Jan 1, 1991

By Pinai Mungsantisuk

Keywords: Pd-Ni alloys, Pd-Fe alloys, Pd-Co alloys, Magnetostriction, Magnetic Properties The presence of congruent melting minima, the occurrence of ferromagnetic transition over a large composition range, and FCC type crystal structure make Pd-Ni, Pd-Co, and Pd-Fe based systems attractive candidates in our search for materials with no rare-earths, large low-field magnetostriction, and good mechanical properties. The presence of paramagnetic-ferromagnetic transition over a broad range of composition also provides opportunity for fundamental studies. In this work, we have examined the magnetic and magnetostrictive behavior of Pd-Ni, Pd-Co, and Pd-Fe alloys over the entire composition range. Alloy sample rods were prepared by arc melting and casting. X-ray diffractometer was used to obtain lattice parameter data. Magnetostriction was measured along the rod axis using strain gages. Magnetic properties were measured using a vibrating sample magnetometer.

Jan 1, 2005

By Luciano R. G. Santos

Keywords: biosorption, cadmium, copper, biomass, spent zeolite. The majority of the industrial activities produce some kind of solid wastes. In this work two industrial residues (spent zeolite and wood sawdust) were chemically modified to increase their heavy metals sorption capacities. Manilkara longifolia (a Brazilian plant known as parajú) sawdust was first treated with NaOH and modified with different citric acid concentrations (0.6-1.2 mol/L) at 120°C, for 90 min. Infrared spectroscopy confirmed the presence of carboxylate groups in the wood structure as result of their mixing. Similarly, spent zeolites were also submitted to a chemical treatment (NaOH) to remove carbon deposited during oil cracking and to recover its sorption capacity. Batch experiments carried out at ambient temperature showed that both materials present sorption capacity for copper and cadmium comparable to weak acid ion exchange resins. A maximum of 78 mg-Cd/g and 59.7 mg-Cu/g as well as 29.9 mg-Cd/g and 14.6 mg-Cu/g were observed for the sawdust and the zeolite, respectively. The results were modeled according to the Freundlich and Langmuir equilibrium isotherms and compared with results of other studies.

Jan 1, 2005

By Musa Karakus

Ceramic build-ups are synthetic mineral deposits formed in critical locations in or near the throats of inductor units in channel induction furnaces, the preferred melting and holding furnaces used in iron foundries. The build-ups are undesirable because they slow down melt circulation, increase power consumption and cost. and decrease the quality of the metal. This study involved the determination of the mineralogy of build-up samples and the quantitative measurement of phase abundance in those build-ups by cathodoluminescence microscopy. These undesirable deposits usually are hard and dense and contain variable amounts of entrained metallic iron. The non-metallic phases dominantly consist of oxides and silicates of several refractory elements, AI, Mg. Ca, Si, and Fe. Minor amounts of the sulfides of Ca. Mg, Fe and REE elements, especially Ce and La. and the oxides and silicates of Ce and La elements are locally present in the build-ups. The build-up samples were found to be ideally suited for study by cathodoluminescence, which has provided an easy means for rapid re-cognition of the phases present in the build-ups. The phase compositions were determined by electron microprobe analysis. The phases identified and their characteristic cathodoluminescence shown in the ceramic build-up samples were: spinel (bright green, blue-green, and red). forsterite (red and purple), periclase (dark reddish-brown, blue. and orange), corundum (red, blue, orange, and white), anorthite (yellow, yellow-green, blue, and blue-purple), hibonite or calcium hexaluminate (dark green), mullite (dull red-brown), gehlenite (deep blue), silica(dark brown, pink, purple, red. and blue), monticellite (light violet blue and light pale yellow-orange), silicon carbide (orange), oldhamite (bright yellow and orange). Ce-La silicate phases (purple), and glass (orange, dull red, and purple). Non-luminescent phases were: hercynite, Fe-oxides, Ce-La-oxides, Fe-sulfides, and metallic iron.

Jan 1, 1989

By G. Bjorling

After complete dissolution of chalcopyrite concentrate in sulphuric acid in presence of nitric acid the excess of the latter is expelled by a surplus of concentrate and the last traces of nitrate removed in the mother liquor after crystallization of the copper and iron sulphates. Zinc accumulates in the mother liquor from which it can be removed by solvent extraction of zinc sulphate as a pair of ions. After dissolution of the sulphate crystals in water the neutral solution is oxidized in an autoclave at 140°C where iron sulphate is thermally hydrolyzed; the iron-free solution is taken to copper electrowinning and the cell acid after partial evaporation recirculated with the mother liquor to the leaching circuit. Total recovery of copper is about 96%; other metals like zinc and iron are concentrated in industrially usable products. At a copper price of about 70 c/lb, the method appears to be profitable also in a small unit.

Jan 1, 1976

By Jae R. Lee

Keywords: Self-propagating high temperature synthesis, AlN, Powder synthesis The particle size and shape effects of starting raw powders on the synthesis of aluminum nitride by self-propagating high temperature technique under high nitrogen pressure were investigated with various AlN diluents and Al reactants. It was found that the structure of beds of the starting raw particles largely affected the pore channels for nitrogen gas infiltration as well as the passages for combustion propagation before and during the reaction, resulting in the morphology and purity changes of the synthesized products. The AlN product of purity over 98% with about 30 microns was obtained.

Jan 1, 2005

By Noel A. Warner

Modern steelmaking is based on direct use of oxygen in high intensity batch reactors. A totally new approach is proposed in this paper, based on the view that pursuit of high intensity is unlikely to lead to successful coal-based continuous steelmaking. By substituting carbon dioxide and water vapor as the oxidants rather than using oxygen directly, the intensity is greatly reduced. Accordingly. subsurface formation of carbon monoxide bubbles can be avoided by careful manipulation of the three participating rate processes, gaseous diffusion, interfacial chemical kinetics and liquid phase mass transfer. Steelmaking can then be carried out without explosive ejection of molten droplets and the generation of micro-spray but rather in a controlled and fumeless fashion. The vital component is the introduction of generic melt circulation technology. Three melt circulation loops in series are envisaged. Starting with a composite feed of iron ore fines, pulverized coal and lime flux, a metallized solid raft floating on molten iron is propelled out of the ironmaking loop onto the first of two downstream steelmaking loops. In the first, a liquid slag is formed, primary decarburization is undertaken not with oxygen but rather with CO2 and H2O and the melt is desulfurized. The semi-product stream enters the third melt circulation loop, where open-channel decarburization is effected along with dephosphorization to yield a low carbon steel product. Alternatively, the melt leaves the last loop to irrigate a packed tower countercurrent to argon at around 100 mbar to continuously produce ultra-low carbon (ULC) steel.

Jan 1, 2003

By L. R. Verney

A number of interrelated factors influence the economics of the sulphide smelting of copper, lead, zinc and nickel. This paper discusses these factors, mainly from a US point of view, and shows how they affect the cost of construction and operation of new and existing plants. The paper shows how metallurgical plant construction costs and the consumer price index have increased at a much faster rate than metal prices thereby making some metal mining and production operations within the USA, Canada and the EEC less profitable than operations elsewhere. This in turn inhibits new "grass roots" metallurgical developments. It is explained how retrofit of existing pyrometallurgical plants can be a more viable development than the construction of "green field" plants, especially if such retrofit improves, energy efficiencies, overall operating costs and reduces emissions of sulphur and other toxic wastes. Some aspects of metallurgical plant operation are examined, especially for copper and nickel, to show how changes in operating practices may develop in order to improve overall smelting economies, especially when developed in conjunction with objective retrofit. The paper also examines some financial aspects, especially insofar as the disparity between terms for loans offered to third world countries and the USA and the EEC are concerned and also comments upon the need, especially within the USA, for legislation to permit rapid depreciation of capital. Specific comments are made about environmental aspects, including the lack of uniformity of pollution control legislation and how environmental considerations may have some bearing of the location of future smelting operations.

Jan 1, 1983

By Michael B. Mooiman, David J. Kinneberg, Philippe Cettou, Leo W. Simpson, Pierre Ramoni

"The demand for high purity precious metals began with certain industrial applications having uncompromising requirements for quality and performance. As industrial uses proliferated and as the jewelry industry became increasingly sophisticated, the demand for high purity gold has reached the point where 99.99% is now the standard in the marketplace. A similar evolution is expected for other precious metals.In this paper, we examine both the production and use of high purity precious metals, specifically gold, silver, platinum and palladium. After defining what is meant by ""high purity"", we discuss the various analytical techniques used for measuring impurity concentrations. Next, we review process strategies employed by extractive metallurgists to produce high purity precious metals. Lastly, we describe some of the principal applications for high purity materials including thick films, thin films, bonding wire, thermocouples and jewelry manufacture.Precious metals have unique physical properties that, despite their expense (and the ever-continuing search for more economical alternatives), make substitution difficult if not impossible. These physical properties are dramatically affected by small concentrations of certain impurities. As long as manufacturers continue to demand quality and performance, there will be a need for high purity precious metals.IntroductionIn the precious metals industry, the qualifier ""high purity"" describes any specification over and above commodity grade. High purity specifications delineate lower limits on overall metal purity or upper limits on individual impurities or both. Sometimes, if these special requirements become commonplace, either because of improved refining technology or because of market pressures, yesterday's ""high purity"" material becomes tomorrow's commodity. This transition is now occurring with gold bullion and probably will soon occur with platinum and palladium as industrial use of these materials grows."

Jan 1, 1998

By Noel A. Warner

Modern steelmaking is based on direct use of oxygen in high intensity batch reactors. A totally new approach is proposed in this paper, based on the view that pursuit of high intensity is unlikely to lead to successful coal-based continuous steelmaking. By substituting carbon dioxide and water vapor as the oxidants rather than using oxygen directly, the intensity is greatly reduced. Accordingly, subsurface formation of carbon monoxide bubbles can be avoided by careful manipulation of the three participating rate processes, gaseous diffusion, interfacial chemical kinetics and liquid phase mass transfer. Steelmaking can then be carried out without explosive ejection of molten droplets and the generation of micro-spray but rather in a controlled and fume less fashion. The vital component is the introduction of generic melt circulation technology. Three melt circulation loops in series are envisaged. Starting with a composite feed of iron ore fines, pulverized coal and lime flux, a metallized solid raft floating on molten iron is propelled out of the ironmaking loop onto the first of two downstream steelmaking loops. In the first, a liquid slag is formed, primary decarburization is undertaken not with oxygen but rather with CO2 and H2O and the melt is desulfurized. The semi-product stream enters the third melt circulation loop, where open-channel decarburization is effected along with dephosphorization to yield a low carbon steel product. Alternatively, the melt leaves the last loop to irrigate a packed tower countercurrent to argon at around 100 mbar to continuously produce ultra-low carbon (ULC) steel.

Jan 1, 2003

By T. R. A. Davey

The technologies of lead, zinc and tin extraction have made varying degrees of progress over the past twenty years. Producers of all metals have faced increasing demands for reduction of pollution and environmental degradation, and the level of public concern is rising rather than abating. New processing techniques must therefore be not only economically feasible, but politically acceptable, even when the demands of "conservationists" and ?environmentalists? are unreasonable. A new generation of processing techniques has come into being, which do not rely on an expensive sintering stage, nor use metallurgical coke, which is difficult to make without serious pollution. They utilise intense reactors, conveying materials from one stage to the next preferably within an enclosed space, obviating fume emissions, and avoiding heat losses as far as possible. The acceptability of the new techniques? is increased if lowgrade or complex materials can be treated, along with a variety of returns and wastes. In addition, a good selling and servicing organisation seems to be as important as good process technology in determining the spread of the new processes. In the field of pyrometallurgical refining the need is for more general application of several recently developed techniques rather than a search for alternatives to the existing process technologies. However, there is a need for fundamental work investigating the phenomenon of oxygen anode overvoltage in the electrolytic zinc process, in order to make progress in the further reduction of energy consumption. There is also scope for further development and application of vacuum distillation to up-grade thermally produced zinc. This paper presents a personal view of processes which should be developed to overcome existing problems, as we approach the turn of the century,

Jan 1, 1990

By Zhao-cheng Liu

Iron oxide red pigment powders of high quality were synthesized from pyrite cinders. Iron ox-ide red pigment powders were synthesized by hydrothermal method from the precursor of Fe(OH)3 and Fe(OH)2 colloid, which were obtained after ammonia solution reacted with acidic leaching solution produced by the reaction of pyrite cinders with sulfuric acid. Effects of reaction concentration, reaction temperature, reaction time, pH value and n(Fe2+)/n(Fe3+) on main properties of oxide iron red were studied by experiments. The prepared particles were characterized by means of X-ray diffraction (XRD) and scanning electron microscope(SEM). The results revealed that the synthesized iron oxide red particles were _-Fe2O3 and pseudocubic with particle size of 0.50~0.75µm. Furthermore, the quality of iron oxide red pigment powders reached the first grade of national standard (GB1863-89 ).

Jan 1, 2009