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By Gerald A. Munson, Fremont F. Clarke

DURING recent years the use of lithium has expanded greatly in industrial, chemical, and metallurgical fields, while at the same time modernized methods of mining and refining lithium have increased production. Technical literature includes many papers describing the geology and mineralogy of lithium deposits. Mining and beneficiating problems, however, have not been thoroughly described. Published reports have failed to emphasize that one of the chief reasons lithium minerals were not extensively mined until recently is the difficulty of beneficiation. Four lithium minerals of pegmatites and the lithium-sodium-phosphate byproduct from the brines at Searles Lake, Calif., have been sources of lithium. Among the pegmatite minerals, only spodu-mene and petaline are known to occur in deposits large enough to support large tonnage operations. Spodumene, a lithium-aluminum-silicate, is the principal lithium mineral mined in the U. S. Lithium Corp. of America, during its rapid development and growth, has successfully employed three different methods of concentration: 1) hand sorting, 2) Heavy Media separation, and 3) froth flotation. Each method, though economic in its sphere, is becoming outdated as extractive techniques improve. The most recent development has taken place at Lithium Corp.'s new operation in North Carolina, where the extractive process yields lithium compounds directly from mined rock without an intervening concentrating step. Until 1954 Lithium Corp. mined only in the southern part of the Black Hills of South Dakota, where the various types of lithium-bearing pegmatite could be used to develop untried processes of beneficiation. Concentrates from these operations are shipped to the corporation's chemical plant in St. Louis Park, Minn., where actual extraction of lithium and production of commercial compounds takes place. Nature of Deposits The geology of the southern Black Hills pegmatite deposits is admirably presented by a U. S. Geological Survey publication.' Only the factors pertinent to exploitation need be mentioned here. Lithium Corp. has been interested primarily in three deposits, the Edison, the Mateen, and the Longview-Beecher No. 2. The history of these deposits dates back to the mining boom of 1880 to 1900 in the Black Hills, when most of the deposits were prospected for tin by the ill-fated Harney Peak Tin Mining Co. The three deposits described here, however, lay idle and unwanted until Lithium Corp. opened the Edison mine in 1943 and the Mateen and Longview-Beecher No. 2 in 1951. Edison Deposit: The Edison deposit is about a mile southeast of Keystone, S. D., on the northeastern flank of the Harney Peak uplift. The deposit consists of no less than four and probably at least six separate pegmatites that coalesce in a central mass from which the individual pegmatites finger outward and downward in complexly folded schist and gneiss beds of the country rock.

Jan 1, 1956

By W. G. Jewitt

YELLOWKNIFE, the most northerly Canadian gold mining district, is once more in the throes of a boom. Touched off by spectacular and well-publicized diamond-drilling results on the property of Giant Yellowknife Gold Mines, Ltd., mining companies and the general public are competing for mining claims and for the shares of companies owning mining claims in the area, with little regard for values. Such a stock-market boom has various unfortunate consequences but undoubtedly one beneficial result is that considerable amounts of money are made available for serious development. The Yellowknife mining area lies on the north shore of Great Slave Lake, in the Northwest Territories, at a latitude of approximately 62°30' north. The topography is a low-relief phase of that usual in the Canadian Laurentian shield. Roughly, one third of the surface is lake-covered, one third muskeg or overburden, and one third is bare

Jan 1, 1944

By P. Somasundaran

INTRODUCTION Large amounts of mineral values are discarded today as fines and ultrafines, because of inadequate technology to process them economically. Most conventional mineral processing techniques fail in the sub-sieve range. Fines respond poorly to processes such as flotation either due to change in mineralogy and surface composition or even simply due to the direct effect of their smallness in size on collision and adhesion rates between them and air bubbles. Indeed if the poor flotation is due to the smallness in size, a solution must rest in aggregating the fines. Inorganic electrolytes as well as polymers have been successfully used as flocculants in the past for obtaining increased flotation of colloidal material from waste water effluents. In mineral beneficiation, this technique can be profitably used if the process of flocculation can be made to take place selectively. The power of the selective flocculation technique has already been proven, with the successful application of it in the case of beneficiation of low grade iron ore by the Cleveland-Cliffs Iron Ore Company and potash ore by Cominco. The process holds tremendous potential when it is followed by flotation, elutriation, etc. Today its application is, however, limited to the above two cases and it has become clear that a full understanding of the process will prove helpful for developing solutions to various problems that exist both at the basic and applied levels. In this paper, principles that are known to govern selective aggregation processes such as selective flocculation, carrier flotation and spherical agglomeration will be examined and areas of uncertainties will be identified.

Jan 1, 1979

By J. Van Steveninck, A. C. Pols, R. Feenstra

In the course of time, an increasing number of investigations on jet cutting all kinds of material, such as rock,1,2,3 metal,4,5 and wood6 have been reported to serve various applications. A number of papers have been published on these subject, 7,8,9 some of which refer to jets purposely containing abrasives, termed 'jetted particle drilling'.7 Since such abrasives complicate fluid handling considerably and do not appear to be absolutely necessary for making holes, only conventional drilling fluids have been considered. A large part of our investigation has been performed with the aid of three laboratory-type drilling machines, which permit tests on both micro-bits (1 ½ in. ) and full-scale bits (6 ½ -9 5/8 in. ) . In view of the application of jets in deep holes, care has been taken to simulate hydrostatic pressures as they exist in the field on the hole bottom. These have been found to have a major effect on the bit-penetration rate for various drilling fluids.

Jan 6, 1974

By Daryl R. Tweeton, Jerry R. Riding, Grant Buma, Frank J. Rosswog

In situ solution mining of uranium has environmental advantages over conventional mining. The leaching of uranium, however, alters the ground-water quality in the aquifer where the mining occurs. Currently, regulations require that the ground water be restored to approximately its original condition. This paper, a summary of a study funded by the Bureau of Mines, reviews the state of the art in restoring ground-water quality after in situ uranium leaching. Current restoration practices discussed include disposal of liquid wastes in deep disposal wells and evaporation ponds, producing from all wells during restoration, and recirculating water purified in surface plants. Methods for predicting the effectiveness and cost of current techniques are presented. Possible alternative techniques are also described. Two restoration operations are discussed.

Jan 1, 1979

September steel production established a new record for a 30-day month with 9,034,000 tons. It was the highest of any month since March. Output of ingots and steel for castings was 535,000 tons more than was poured in August 1952, and 373,000 tons over the total for September 1951. Prime Minister Daniel F. Malan touched a gold button to start South Africa' a first uranium plant into production on the premises of the West Rand Consolidated Gold Mine, near Krugersdorp, Transvaal, 25 miles west of Johannesburg. Uranium oxide is being extracted from mine tailing after removal of the gold. Thirteen gold mines in the region are scheduled for uranium production. Defense Materials Procurement Agency signed an agreement-with the Bagdad Copper Corp., Bagdad. Ariz., for expansion of the firm's facilities to enable delivery of at least 27 million lb of copper a year and 91,0000 lb of molybdenite. It is said that the company will spend about E million on the expansion.

Jan 1, 1952

By D. A. J. Swinkels

The problem of determining oxygen levels in liquid steel to aid in deoxidation control has received general attention for a number of years. Work in this direction started at the B.H.P. Central Research Laboratories early in 1967 with an evaluation of sampling techniques followed by vacuum fusion analysis to determine the oxygen content of the samples (1). It was found that these techniques had a number of drawbacks if they were to be used for deoxidation control. The method of analysis was rather too slow to allow effective control and measured total oxygen level rather than dissolved oxygen. Furthermore, the results were found to be very variable due to slag entrainment in the samples. Attention therefore turned to the galvanic cell method using a solid oxygen ion conductive electrolyte such as cubic stabilised zirconia. The ionic conductivity properties of electrolytes such as (ZrO2) 85 (CaO).15 had been studied by a number of investigators and had already been applied to the measurement of oxygen activity in gases, in lower melting metals such as copper, lead, tin, silver, alkali metals and indeed the first studies in steel had been made (2,3). Since then the results of a number of studies in the development of an expendable oxygen probe for steel have been reported (4-9).

Jan 1, 1972

The history of surface mining is essentially that of mining coal, copper, and iron ores and the non- metallic minerals, i.e. clays, gypsum, phosphate rock, sand, gravel and stone. The accompanying table comparing world production with that of the U. S. indicates that two thirds of the 8.8 billion tons of ores mined throughout the world come from surface operation. Assuming that the stripping ratio for surface mining in the U. S. applies equally to world production, then over 21 billion tons of waste, or a total of nearly 27 billion short tons of material are mined annually in the world by surface methods. Several factors are significant indicators of economic and technologic trends in surface mining. Among these are increasing production, a shift in emphasis from underground to surface mining, a decline in the grade and quality of some crude materials and, with few exceptions, an increase in the productivity of labor.

Jan 10, 1967

By Leland H. Johnson

THE Tennessee Coal, Iron & Railroad Co.'s ore mines began experimental tests with trackless mining units early in 1947. The units had many weaknesses to overcome, but are now well beyond the experimental stage and are becoming a necessity to ore seams that are amenable to this type of equipment. The development of this type of mining with the problems of increased underground supervision, maintenance, and training personnel, along with the benefits derived, are discussed.

Jan 12, 1950

By B. B. A. Luzzat

ALUMINUM is today the most widely used of the nonferrous metals. The technical literature on the aluminum smelting process is, nevertheless, very meager, so that anyone interested in the subject cannot rely on more than a couple of dozen publications.' The patent literature is equally scarce; most patents refer to the production of alumina from aluminum-bearing ores, while not more than a few score significant patents deal with the electrolytic reduction of alumina, which is the real core of the aluminum smelting industry. The "reduction phase" is, from a technical and a scientific point of view, much more interesting than the "alumina phase", which, in effect, is only a combination of such well-known chemical operations as dissolving, precipitating, filtering, drying, and calcining. The electrolytic reduction of alumina, on the other hand, has features which do not appear in any other metal smelting operation. Some of them are of great technical and scientific interest even for those not directly engaged in the production of aluminum. The purpose of this paper is to describe in some detail the basic facts and developments of the reduction phase of aluminum smelting. Two Aspects of the Electrolytic Process The raw material for the reduction process is alumina (Al2O3) . Its purity in general runs as high as 99.50 pct or more. Small differences in the chemical composition generally do not affect the reduction process.* Of more importance are the physical prop- erties of the alumina, since they affect not only its rate of solution in the molten bath but also its heat insulating power.† In the following pages, un- less otherwise stated, it is assumed that a standard "Bayer" alumina is used. The reduction process, by which alumina is broken down into its components, may be roughly defined as its electrolysis in molten cryolite. The oxygen separates at the anode, and the aluminum at the cathode, which forms the bottom of the electrolytic cell. The electrolytic cell (or pot) where the process is carried out is a strongly reinforced steel box. The

Jan 1, 1951

As already announced, the Arizona Meeting of the Institute is to be held from the 18th to the 25th of September. There will be a special train from New York City to Arizona and return, to take members and guests of the Institute to the meeting. The Committee in charge consists of Walter Douglas, Chairman, Cleveland E. Dodge, John C. Greenway, Arthur S. Dwight and Julius Kruttschnitt, Jr., and while the plans of this Committee are not complete, it may be announced that the train will be run with the requisite number of Pullman, dining and baggage cars to accommodate those who desire to go, which will accompany the party during the entire week of the Arizona Meeting as per the following program, including, of course, the visit to the Grand Canyon. As soon as details have been worked out, a circular will be issued giv¬ing full information concerning the trip.

Jan 7, 1916

By Robert W. Thompson, Darry A. Ferguson

In August, 1977 the United States Congress passed Public Law 95-87 which has been commonly referred to as the Surface Mining Control and Reclamation Act (or SMCRA). This title is somewhat misleading in that the act creates as many regulatory requirements for underground coal mines as for surface coal mines. How- ever, this paper will concentrate on the effects of SMCRA on designs and stability for various activities of surface coal mines, specifically those concerning "Disposal of Excess Spoil". In the past, the objective of most laws and regulations applicable to the mining industry has been to achieve goals of safety or environmental concerns for all types of mining. However, SMCRA is unique in that it sought to regulate-all-activities of coal mining from initial data gathering, exploration, mine design and facilities design to reclamation activities and design. More specific to the stability of the activities of surface coal mining, special criteria for design and construction performance standards have been promulgated for the construction and maintenance of roads, dams and embankments, coal processing waste, ex- cess spoil piles, backfilled reclamation and pit slides. The criteria for design for the previously mentioned facilities has been enumerated by regulations and in many ways restrict the use of site specific design parameters. The restrictions imposed by regulations significantly inhibit the engineer's ability to develop the best practical and economical design and in some cases may re-

Jan 1, 1983

By H. B. Muller

Single stage autogenous grinding of run-of-mine ore was selected by Broken Hill South Ltd., parent Company of Cobar Mines Pty. Ltd. for the concentrator to treat 60,000 tons per four weekly period of copper and complex copper-lead-zinc sulphide ores from the C.S.A. Mine at Cobar, Australia. Ore is mined by mechanised horizontal cut-and-fill stoping and is prepared for grinding by crushing under- ground in a 60 in. x 48 in. jaw-crusher set at 5 in. closed side setting. The ore is reduced to 80% minus 76 microns in two parallel sections each of one 22 ft. dim. x 7 ft. long autogenous grinding mill, powered by a 1,250 H.P. motor, operating in closed circuit with a single stage 20 in. dim. cyclone. Broken Hill South's original concept of the concentrator required the maximum use of reliable instrumentation, centralised control, and the minimum of manning. To achieve this objective the control room, housing the process recorders, alarms, closed circuit television monitors and all the control equipment, overlooks the grinding and flotation sections, and the whole plant is serviced by a public address system. The grinding units and associated equipment are located in the open and are serviced with the aid of a mobile crane and a mobile hydraulically-operated liner lifting device.

Jan 1, 1970

By A. B. Stickney

UPWARDS of 200,000 engineers in this country are sufficiently interested in engineering as a profession to have joined a society, but not over 10% of them belong to any one society. There is a widely-felt need of an over-all organization of all the societies to act as spokesman for all engineers on matters of common concern. On a local basis, over 100,000 engineers in 35 metropolitan areas have organized themselves into local councils, and are doing an effective job of intersocietal co-operation within their sphere of activity. In the last few years much has been said and written about a similar organization on a national scale. Everybody wants iteverybody is talking about it-it's in the air-it's coming-it's inevitable. Although it is no longer necessary to talk about why or whether there should be such an organization, there is no such unanimity about what it should be like. This paper outlines a proposed organization by answering four questions-who, how, what, and who will pay for it.

Jan 1, 1946

By David E. Hyatt, Christopher H. Cox, Franklin T. Davis

INTRODUCTION The composition of water used in the flotation process has always been of primary interest to the flotation metallurgist. It is by alteration of the chemistry of the water introduced to the process that flotation separation is effected. In only a few cases has it been necessary to treat available water prior to use in the process. In the past, flotation tailings were treated for the removal of solids via the tailings dam and water decanted from the dam was either recirculated to the process or discharged to the surface water system. The choice of recirculation or discharge was based upon water availability, effect of recycle water on the process, and economic considerations. The Federal Water Pollution Control Act Amendments of 1972 have charged the United States Environmental Protection Agency with establishing effluent limitations from point sources of discharge into the navigable water of the United States. A detailed study, sponsored by EPA, of the water of ore processing plants took place in 1974 and 1975 and guidelines for these plants will presumably have been published by the time this paper has been presented(1). The action of many of the individual states preceded the EPA in this attempt to regulate the quality of the water discharged from industrial point sources. Even with recycle of tailings water, some water is discharged from tailings dams into the substrata and at least one state is currently preparing guidelines for the quality of water discharged into the substrata.

Jan 1, 1976

By Grover J. Holt

IN order to provide a clear picture of the development of the sink-and-float process of concentration as applied to the iron ores of Minnesota, a few pertinent facts should be brought out concerning the ores and the products of concentration. Iron ore is primarily a cheap commodity handled in immense quantities. The price of iron ore at present, based on a natural iron content of 51.5 per cent, varies from $2.55 to $2.70 per gross ton f.o.b. cars at the mine or washing plant in Minnesota. Last year 92,000,000 gross tons were shipped from the Lake Superior district (Minnesota, Michigan, and Wisconsin) to the furnaces. Concentrated iron ores have no greater value per unit of iron content than ores that can be mined and shipped direct from the shafts or open pits. For years only the higher grades of concentrating ores could be treated and sold in competition with the immense reserves of direct shipping ore available. These higher-grade "straight wash" ores required only the simplest treatment; namely, the washing out of fine sand from coarse ore particles. As the exhaustion of the "straight wash" ore is reached, rock is found replacing part of this sand, and the ore no longer responds to the former sizing treatment. Substantial tonnages of this marginal (jig ore) remained to be treated. Because of the limitations placed on concentrates by the furnaces-namely, low price of product and minimum amount of fines-iron-ore concentration has been and must continue to be a one-pass process. Only an increase in price or a change in structure of concentrates allowed by the ore consumer will encourage departure from this practice. Faced with the necessity of handling large tonnages, with the limitations mentioned, iron-ore research men have found their search for new and more efficient methods of treatment seriously handicapped and removed from the field of fine crushing. Sink-and-float treatment appeared to offer the best field in coarse concentration and has been proved by several plants to be well adapted to our problem. The use of ferrosilicon as a medium solid was decided upon. In our present practice, the ferrosilicon metal, carrying about 83 per cent iron, 15 per cent silicon and 2 per cent carbon and nonmagnetics, is crushed to pass 65 mesh and used without further sizing. When mixed with water the specific gravity of the medium may be controlled to within 0.02 per cent above or below the required gravity. Table I shows examples of a change in solid content of the medium for varying gravities. [ ] Table I is based on clean ferrosilicon, whereas some contamination is always present in the mill circuit, tending to

Jan 1, 1943

By G. D. Monk, W. C. Krumbein

The relation between permeability and the size parameters of unconsolidated sand is approached by considering sands as logarithmic frequency distributions having the basic parameters mean size and standard deviation. Sieve separates were mixed in accordance with the normal logarithmic probability law, so that the mean and standard deviation could be varied at will. Experiments were conducted in which one parameter was kept fixed and the other varied; in this manner the dependence of permeability on the individual parameters was evaluated. It was found that permeability can he expressed as the product of a power function of the mean size and an exponential function of the standard deviation. Earlier studies of the effect of size of particles on the permeability of uncon-solidated sand have shown that the permeability varies with the square of some average diameter. This was first pointed out by Hazenl in 1892 and verified by Slichter2 in 1898. Hazen's mean size was defined as the 10 percentile of the cumulative curve (i.e., size that is smaller than 90 pel cent of the distribution and larger than 10 per cent). Slichter's effective size, on the other hand, was found by Wilsey3,4 to agree with the 31 percentile. Fair and Hatch6 found that the geometric mean size of sieve separates yielded the same power function; Hulbert and Feben6 found that the permeability of sieve separates varied as the 1.89 power of the median diameter (i.e., the size associated with the 50 percentile of the cumulative curve). Relatively few studies included the effect of the "sorting" of the sediment on the permeability. It was recognized that the nature of the size distribution, in terms of the spread of the particles about the mean, affects the permeability, but no systematic investigations of this effect are known to the writers. Cloud7 demonstrated that the effect of the grain-size distribution on permeability is definitely measurable. In the present paper the authors investigate this relation analytically, and show that the effects of the size parameters on permeability may be predicted for at least a restricted set of conditions. Properties OF Sediments Recent investigations have shown that essentially all the geologically important characteristics of sediments may be expressed in terms of six measurable quanti-tities possessed by each clastic sedimentary particle. These attributes are: (I) size, (2) shape (sphericity), (3) roundness (angularity) , (4) mineralogical composition (density), (5) surface texture, (6) orientation. Each of these characteristics may be defined in several manners. Size may be expressed in terms of sieve mesh, settling velocity, volume, etc. Sphericity is a shape concept introduced by Wadell;8 it is essentially a measure of the ratio of the surface area of an equivalent sphere to the surface area of the particle. The same

Jan 1, 1943

By G. D. Monk, W. C. Krumbein

The relation between permeability and the size parameters of unconsolidated sand is approached by considering sands as logarithmic frequency distributions having the basic parameters mean size and standard deviation. Sieve separates were mixed in accordance with the normal logarithmic probability law, so that the mean and standard deviation could be varied at will. Experiments were conducted in which one parameter was kept fixed and the other varied; in this manner the dependence of permeability on the individual parameters was evaluated. It was found that permeability can he expressed as the product of a power function of the mean size and an exponential function of the standard deviation. Earlier studies of the effect of size of particles on the permeability of uncon-solidated sand have shown that the permeability varies with the square of some average diameter. This was first pointed out by Hazenl in 1892 and verified by Slichter2 in 1898. Hazen's mean size was defined as the 10 percentile of the cumulative curve (i.e., size that is smaller than 90 pel cent of the distribution and larger than 10 per cent). Slichter's effective size, on the other hand, was found by Wilsey3,4 to agree with the 31 percentile. Fair and Hatch6 found that the geometric mean size of sieve separates yielded the same power function; Hulbert and Feben6 found that the permeability of sieve separates varied as the 1.89 power of the median diameter (i.e., the size associated with the 50 percentile of the cumulative curve). Relatively few studies included the effect of the "sorting" of the sediment on the permeability. It was recognized that the nature of the size distribution, in terms of the spread of the particles about the mean, affects the permeability, but no systematic investigations of this effect are known to the writers. Cloud7 demonstrated that the effect of the grain-size distribution on permeability is definitely measurable. In the present paper the authors investigate this relation analytically, and show that the effects of the size parameters on permeability may be predicted for at least a restricted set of conditions. Properties OF Sediments Recent investigations have shown that essentially all the geologically important characteristics of sediments may be expressed in terms of six measurable quanti-tities possessed by each clastic sedimentary particle. These attributes are: (I) size, (2) shape (sphericity), (3) roundness (angularity) , (4) mineralogical composition (density), (5) surface texture, (6) orientation. Each of these characteristics may be defined in several manners. Size may be expressed in terms of sieve mesh, settling velocity, volume, etc. Sphericity is a shape concept introduced by Wadell;8 it is essentially a measure of the ratio of the surface area of an equivalent sphere to the surface area of the particle. The same

Jan 1, 1943

E. Hill, South Norwalk, Conn. (communication to the Secretary*) :—The phenomenon described by Dr. Ledoux, involving an apparently abnormal high temperature in the air-cylinders of compressors, has not been, so far as I know, discussed in technical literature. The common formula for the adiabatic compression of dry air does not account for heat suficient to flash ordinarily decent cylinder-oils, nor do the text-books include in their theoretical statements any quantitative consideration of the effect of leaks in the ideal machines which they contemplate. This lack I have endeavored to supply by preparing, in the form of a circular, for the use of the customers and correspondents of the Norwalk Iron-Works, a brief mathematical

Jan 1, 1904

By M. D. Everell

A study has been made of the relationships between grinding selection functions and physical properties of rocks, particularly the failure loads of irregular particles and the compressive and tensile strengths of large regular specimens. The rocks used were limestones of various structures and impurity contents, a carbonatite, and a high-purity crystallized calcite. The selection functions were obtained from carefully performed grinding experiments on selected narrow size ranges in various grinding machines-a laboratory batch ball mill, a Hard grove grindability machine, and a mill of the type suggested by Yang, Mempel, and Fuerstenau. The specific rates of breakage during milling and the failure loads of irregular specimens correlated well for the rocks studied. The testing of irregular particles is suggested as a means of predicting the behavior of commercial mills.

Jan 1, 1973