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An Investigation into the Flotation Behaviour of Pyrrhotite Present in the Merensky Orebody

Sep 13, 2010

By M Salu

Ventilation control devices (VCD’s) and bulkheads are critical controls used for managing risk in underground coalmines. Following the Moura No. 2 mine explosion in 1994, the Queensland Mines Department required that the design of VCDs be based on live testing (such as in a mine testing explosion gallery) and more recently on numerical modelling using measured seal material properties. While the stipulated methods represent an idealistic solution, they are not practical to implement as solutions to daily challenges presented in underground coalmines.Not all VCD’s and bulkheads are placed in areas which have been mined to standard roadway dimensions. Operationally, VCD’s may be required to be placed close to intersections or require large dimensionally different areas (eg overcasts and pre-driven recovery road shutters) compared to the live testing or numerical modelling originally undertaken.This paper describes the various structural engineering methods utilised to account for the design of VCD’s where the operational requirements are non-standard. Siting and construction of VCD’s near the entry of cut throughs and geological structures requires additional design considerations. While VCDs constructed from a single material (eg sprayed mining plaster) are relatively straightforward to design, the addition of multiple openings (doors) or large pipes will complicate the structuralanalysis significantly.Temporary bulkheads used for the containment of grout such as for the construction of pre-driven recovery roads in coal mining have a significantly different risk profile to VCDs and should be designed accordingly. Recent failures and near-misses in such bulkheads have highlighted this issuefor the authors.The existence of an Australian Standard for Underground Mine VCDs and Bulkheads would go a long way to addressing many of the issues raised in this paper. Without a single, industry-accepted reference for VCD design, individual mines will have to continueto exercise their best judgements using whatever local expertise is available to them.

Oct 12, 2022

By Bodnaras G. E, Sceresini P. A

The Filblast Cyanidation Process incorporates the advantages of intense high shear mixing, high dissolved oxygen concentration and high pressure to achieve extremely rapid gold dissolution rates. This is made possible by the unique design of the Filblast gas shear reactor. The reactor is a rugged and compact in-line device. The outer casing is protected by a polyurethane coating and the internal parts are of wear resistant polymer. The largest unit built to-date has overall dimensions of 1200 mm length by 300 mm diameter and has a capacity of 150 dry tonnes per hour at 40 - 45 per cent solids. Service life at this throughput is at least three months. The process may further be applied to high temperature leaching of refractory gold ores or other metals. Wear resistant metal or ceramic materials would be employed for this duty. Four mines are currently employing the Filblast Process for treating a variety of ore types ranging from highly reactive, almost impossible to treat, pyrrhotite/arsenopyrite to deeply weathered clay ore which forms a highly viscous pulp. The effect of shear thinning has resulted in improved adsorption kinetics resulting in higher carbon loading and reduced soluble gold loss. Total tonnage treated is approximately four million. Operating costs which include leasing and maintenance charges for the Filblast and pump power costs are about 16 cents per tonne. This is equivalent to about ten per cent of savings. Laboratory scale units having capacities up to 30 litres/min are available for test work but laboratory testing techniques so far developed do not accurately reflect the oxygen and cyanide savings which have been achieved in the plant.

Jan 1, 1994

By McKenzie P

The techniques of geological control developed by the Coal Geology Sections of the Broken Hill Proprietary Company Limited and Australian Iron and Steel Proprietary Limited in providing geological service in the coilieries operated by these associated companies cover the provision of geological control for both planning and production in each of which the significance of geology has in the past been only poorly appreciated by the coal mining industry.While the adoption of similar techniques is well within the capacity of major companies there is considerable scope for the development of government geological services providing specialized assistance of this nature for smaller scale producers.INTRODUCTIONThe coal mining industry in Australia can instance many notable mistakes caused by failure to obtain sufficient geological information or by incorrect interpretation of available geological evidence both before the commencement of mining and during the progress of operations. Substantial development undertaken in, areas with insufficient or inferior coal reserves, difficult mining conditions caused by failure to adjust operations to geological circumstances, and the irregular development of mine workings caused by unexpected geological features, all bear witness to the lack of geological foresight by the industry.Along with the more widespread general use of applied geology, an increasing acceptance has developed during the past ten years of the valuable contribution which can be made by this science to the exploitation of coalfields. In spite of the advances which have been made, there is still a wide scope for further detailed application of geology throughout the coal mining industry in Australia.

Jan 1, 1963

Folklore suggests that oxidation is detrimental to sulfide mineral flotation, and in many instances is the reason given for values reporting in the tailing. However, while a considerable body of work examining galena oxidation is available in the literature there are very few studies that investigate the consequences of galena oxidation on its subsequent flotation in base metal sulfide ores. This work clearly demonstrates that pyrite forms a galvanic couple with galena, due to the large difference in their rest potentials, and results in accelerated oxidation of galena, particularly as the pyrite content of the ore is increased. The most obvious effect of the galvanic oxidation of galena by pyrite is the release into the system of galena oxidation products, providing an ample supply of lead ions available to activate gangue minerals, most notably of which in lead/zinc ores is sphalerite. The inadvertent activation of sphalerite by lead ions inevitably leads to the recovery of liberated sphalerite into the lead concentrate, and as a consequence a reduction in the lead concentrate grade. That is, a loss of selectivity for galena against sphalerite. If galena oxidation is excessive not only is there a considerable loss in lead concentrate grade, but also a marked decreased in lead recovery as the flotation rates of the gangue minerals increase, until they rival that of galena.

Jan 1, 2005

By AMIRA P588 Research Team

This contribution summarises new knowledge and data, obtained during a three year ARCAMIRA funded research project, on the mineralogical and geochemical characteristics of hydrothermal alteration associated with low sulfidation, gold-silver epithermal deposits. These data are used to develop exploration vectors for use at both deposit and district scales, plus techniques have been established to distinguish ore grade epithermal systems from barren or low grade systems. Deposits investigated were Ladolam, Papua New Guinea, Gosowong and Mt Muro, Indonesia, Cerro Vaguardia, Argentina and Bimurra and Twin Hills, Australia.

Jan 1, 2005

By C Li, K McDonald an, T Nicholson, C Brown

The relative reactivities of chars prepared from different coal samples at temperatures in the range 500 to 1150¦C were determined by measuring the rates of metallisation of a standard ilmenite concentrate. The results have been interpreted in relation to different measured physical and chemical properties of the chars. Char reactivities were found to correlate with the maximum specific surface area (SSA) of the chars, obtained from plots of SSA versus temperature. Weathering of coal samples gave higher reactivities which correlated with higher SSAs. Experiments using recycled chars showed that the high internal SSAs developed during earlier reduction reactions provide no benefit in terms of increased metallisations. The important role of char hydrogen contents in controlling low temperature metallisation rates was demonstrated. Chars prepared from different rank coals had the same hydrogen content when prepared at the same temperature. Ilmenite metallisation rates had a linear dependence on the hydrogen content of the chars. Large differences in the slopes of the metallisation versus H2 content curves for different chars were interpreted in terms of SSA variations and catalysis of the gas reactions by dispersed metallic iron particles in the chars. A simple test based on magnetic separation of the char was shown to give an indication of enhanced reactivity due to contained metallic iron.

Jan 1, 2001

Traditionally, capital costs of major resource development projects have been estimated as a single amount to which a percentage accuracy has been assigned based on the method of preparation of the estimate, that is, on the amount of information available to develop the estimate.However, there is a growing recognition of the importance of a probabilistic approach to capital cost estimates, and of a more rigorous calculation of estimate accuracies and of the presentation thereof. Accuracies can be expressed with more certainty as a percentage of the estimate amount where the percentage represents one standard distribution on the probability curve for the capital cost of that specific project. Thus confidence levels can be stated for various estimated amounts - for example, it can be stated that there is an 85% chance that a stated amount will not be exceeded, or a 90% certainty that a (higher) amount will not be exceeded. Moreover, the right skewness of the probability distribution curve for most projects can be readily recognised and reflected in the evaluations. This enables senior executives and board members to have a clearer understanding of investment uncertainties, and the possible magnitude of commitments.

Jan 1, 1990

By J Sykes, W Treasure, A Saleem, A Trench, S Ulrich, R S. Davies

Below-ground technical complexity remains a traditional source of project challenge. Above-ground challenges then augment this complexity, including in the domain of commodity marketing. All challenges must be solved to produce quality, saleable, ex-mine product. The situation is further complicated in that technical complexities are not independent of each other, so complexity is best regarded as a system rather than a series of isolated factors. Additional above-ground challenges to mining projects are also increasingly sourced from societal and environmental factors, locally and globally. These challenges not only confer project complexity, but have their source in larger, global wicked problems. Finally, financing and resourcing of projects represents an ever-present challenge for all but the highest-quality mineral deposits. CITATION: Trench, A, Davies, R S, Saleem, A, Sykes, J, Treasure, W and Ulrich, S, 2018. On the sources of complexity in contemporary and future mining projects, in Proceedings Complex Orebodies Conference 2018, pp 65–66 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By Player R. L

Measurements of the rate of PbO reduction from high lead metallurgical slags were made under laboratory conditions using graphite, a CO-50%CO2 gas mixture and metallic iron as reductants. The results show a transition in rate-controlling step at low PbO contents (i.e. 6 wt.% PbO). At medium to high PbO contents in the slag, the reduction rate was found to be strongly affected by the slag chemistry, temperature and reductant type. The effect of stirring and hence mass transfer in the slag phase on the reduction rate of PbO was found to be insignificant at medium-high PbO contents. Attention is drawn to the importance of chemically controlled reaction rates at the slag-gas interface. Parallels between these results and test work on a 5 tph scale have been briefly drawn.

Jan 1, 1989

Separation of Nickel and Cobalt from Manganese, Magnesium and Calcium by Synergistic Solvent Extraction - From Batch Tests to Pilot Plant Operation The synergistic solvent extraction system consisting of Versatic 10/LIX63/TBP was used for the separation and purification of nickel and cobalt from synthetic laterite leach solution after iron removal. Very encouraging results were obtained for separating nickel and cobalt from manganese, magnesium and calcium. In batch tests, the organic composition of the synergistic system was optimised and very large synergistic shifts for nickel and cobalt were observed. The ?pH50(Mn-Co) and ?pH50(Mn-Ni) values were as large as 1.65 and 2.40, respectively. The extraction and stripping kinetics of nickel and cobalt was fast. Semi continuous extraction tests were conducted with a pH profile of 5.5/6.1/6.5 in three stages at 40¦C. The nickel and cobalt extractions reached 99.9 per cent with only 5 mg/L Ni and <1 mg/L Co left in the raffinate. With two stages of scrubbing, only 2 mg/L Mn and less than 1 mg/L Mg and Ca were left in the scrubbed organic solution. With two stripping stages, the stripping efficiencies of Ni and Co reached over 95 per cent. A fully continuous pilot plant operation was conducted successfully for 280 hours. With an O/A ratio of about 2 and a pH profile of 5.5/5.8/6.0/6.3 for the four stages EX1/EX2/Ex3/EX4, both nickel and cobalt were almost completely extracted. Using a pH profile of 5.4/5.0 for SC1/SC2, the manganese scrubbing efficiency was over 96 per cent. Using three strip stages, over 98 per cent Ni and 99 per cent Co were stripped with only 64 mg/L Ni in the stripped organic solution. The nickel concentration in the loaded strip liquor reached 83 g/L, resulting in a ?Ni of over 28 g/L. The chemical stability of the system was also assessed over 12 weeks under proposed industrial operating conditions. Operation exclusively under strip conditions at 50¦C and 40¦C resulted in LIX63 oxime half lives of 1.1 and 2.1 years, respectively. Operation exclusively under extract conditions at 50¦C and 40¦C resulted in oxime half lives of 0.26 and 0.82 years, respectively. Losses of Versatic 10 were less than four per cent.

Sep 13, 2010

By A Black, A de Jo, J Cavanagh, J Harding

Acidic and metal-rich waters have been discharging from Sullivan Mine, West Coast, New Zealand since the closure of the mine during the early- 1990s. This has resulted in a decrease in pH from a background of 4.5 to 2.8 and an increase in metallic elements in nearby Rapid Stream. In addition to the chemical effects on Rapid Stream, a study of freshwater macro-invertebrates revealed the absence of most biota downstream from the discharge. An attempt is being made to use the Sullivan Mine as a case study of problem and remediation analysis.

Jan 1, 2003

By J Jackson, M F. Young

"Ore is the economic portion of a mineral deposit that can be extracted economically. Hence an ore type is a classification of the ore based on one or more dominant characteristics in order to enable communication between unit operations and/or technical disciplines.In project evaluation, ore types are often defined early based on geological observations by geologists and initial metallurgical testing is based around this classification even though a number of processing options can be under evaluation. However, the geological drivers of performance for each of these processes can be very different and the ore type classification for one process may not be relevant for another. In operations an ore type, as either defined in the project evaluation phase or those that evolve with additional knowledge, is unlikely to provide the knowledge required across all the unit operations. The ore type has a meaning to someone but does not necessarily for all unit operations across the value chain.Geometallurgical or orebody knowledge has evolved through the consideration of multiple processes within the value chain, the improved understanding of variability of process performance within ore types and the effect on the complexity of the mineral extraction processes. Furthermore orebody knowledge has been moving from personal based knowledge and understanding to a more process oriented approach where measurement and spatial and process performance modelling is playing a greater role. Advances in mine planning and scheduling allow for both detailed analysis of the block model and the expected extraction processing attributes across various time scales. This capability of analysing and describing the complexity still requires to be communicated to the various unit operations, which may be beyond the traditional classification of an ore type.The limitations of an ore type and potential alternatives to enable the relevant information to be communicated to the relevant groups are outlined through a number of case examples across the value chain.CITATION:Jackson, J and Young, M F, 2016. Ore Type – Everything to Someone but Nothing to Anyone, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 267–274 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By M A. Wells

The various mechanisms by which phosphorus (P) occurs and is distributed within banded iron formations (BIF)-derived iron ore are examined. In unenriched, precursor BIF P occurs predominantly as discrete grains of primary apatite. In high-grade ores hosted mainly by the Brockman Iron Formation, P occurs in three main forms:1. as secondary apatite;2. other submicron, P-rich phases (eg Rare earth containing minerals (REE), vivianite, strengite,wavellite) present in pore networks; and3. as P occurring with iron oxides, in particular, goethite.However, the presence of secondary P-bearing phases does not contribute signifi cantly to the total P level in iron ore, and it is P associated mainly with goethite, which represents the most common occurrence of P in these ores.No direct evidence for the replacement of Fe by P within the structure of synthetic goethite has been demonstrated. Therefore, it is most likely that in iron ores P associates with goethite in occluded form as adsorbed PO4 3- species or as discrete P-bearing minerals, such as strengite, wavellite or vivianite, in ultra-fine, micro-pores or within intra-domain regions of multi-domainic goethite. Such occluded P is not easily extracted with commonly used lixiviants, such as weakly alkaline leachates. Recent development of a low temperature-alkalie/water leach extraction method has been successful in reducing not only the P content, but also amounts of Si and Al inthe initial ore. Refi nement of such a method to commercial application will have enormous benefit in realising the economic potential of large tonnages of high-P (ie >0.07 wt per cent P) bearing iron ore.

Jul 11, 2011

Study on Iron Ore Sintering with High Proportion of Specularite Concentrates Specularite iron ores have poor hydrophilicity and ballability as well as bad high-temperature reactivity, which restricts the large-scale application in the sinter and pellet production. In order to make the best use of the specularite concentrates, a novel process of Composite Agglomeration Process (CAP) is applied in this research. By the CAP, the percentage of specularite concentrates in the sinter mixture is increased to no less than 40 per cent as well as the coke breeze dosage is reduced by 0.3 per cent~0.6 per cent. Moreover, all the sintering indexes are obviously improved compared with the traditional sintering process. Researches on the metallurgical performances shows the finished composite agglomerates are high-quality burdens for blast furnaces. This investigation can provide an effective route to utilize the inferior specularite concentrates in the sintering.

Sep 13, 2010

By H Lieberwirth, M Pfeifer, F Heinicke

HPGRs (high pressure grinding rolls) have been developed within the last decades for energy efficient processing of a wide variety of ores. Special interest has been raised by projects increasing the capacities of processing plants by installing HPGRs prior to ball mills. Bond ball mill tests have been used for decades as a base for ball mill dimensioning in mineral circuits. For final CAPEXOPEX considerations of the processing circuit, one key question is about the level of grinding energy split between HPGR and downstream grinding stages. This is especially interesting if the downstream process comprises multiple grinding stages combined with separation steps. The paper presents investigations on grinding energy consumption, size distribution and microfracturing of HPGR products, which affect the efficiency of the whole comminution and sorting process.

Aug 24, 2022

By C J. Hogan

Increasing demand for fine grinding to improve mineral liberation and metal recovery and the need for stricter control of the environmental impact of tailings deposition poses problems for tailings disposal. This has led to an increasing number of investigations of properties of tailings and their disposal. This paper describes laboratory model testing undertaken on Macraes mine flotation tailings to provide information on tailings behaviour under conditions of subaerial deposition. The in-place density or 'dry density' of the impounded tailings and the impoundment depth relationship are important for utilisation of the available impoundment storage facility and results of dry density to depth relationships are given for the Macraes mine tailings impoundment.

Jan 1, 1993

By A E. Petts

Record iron ore prices and a renaissance of infrastructure in the Pilbara have Flinders Mines poised to move from explorer/developer to an iron ore producer. The potential of the company’s Pilbara Iron Ore Project was first highlighted by the announcement of Rio Tinto’s Caliwingina North deposit to the north and the Fortescue Metals group’s Serenity deposit in the southeast. The success of Flinders Mines’ exploration has been based on incorporating landscape studies into an existing geological framework, and using this to understand the iron-rich materials that were emplaced during the Tertiary. The development of the Delta and Eagle deposit resource models highlights this process. There are three main mineralisation styles at the project; detrital iron, channel iron and bedded iron deposits. They have textural and mineralogical similarities with comparative deposits in the region. Gaining an insight into the geological processes unique to detrital iron deposits and more distal channel iron deposits has been important to understanding the geometallurgy of the mineralisation. The model sits comfortably with other regional oregenesis models and allows a contextual framework to be developed around the timing of deposition of the Fe-rich detritus and pisolitic nodules that dominate the deposits. The exploration model also allows Flinders to explore more effectively for bedded iron mineralisation developed prior to, and since the development of the Tertiary weathering landscape.

Jul 11, 2011

By J Player, G Sweby, S Webber, E Jones

Seismic systems are a tool for the monitoring and forecasting the rock mass response to excavation. Common issues encountered at mine site audits and reviews are: how to design an effective seismic system, implementation of the design, interpretation of seismic source results and understanding the reliability of the seismic source. These issues are often a function of several items including: • Experience of site personnel in undertaking seismic system design. • Personnel not envisioning multiple phases of system expansion to understand system robustness issues. • System design/expansion occurring in response to damaging seismic activity rather than planned expansion of a system • The mine access development is often localised in comparison to the total orebody being mined hence, planning sensors in longholes in advance of development rather than in short holes close to development will improve the three-dimensional aspect of the network. • Limited site processing of the seismic event data, hence engineers do not see the uncertainty associated with event location, size, source and system layout. Mine site users require a framework to appreciate the challenges and limitations in locating large events. For example, event locations are given as precise measurements (to the nearest centimetre) whereas the volume of deformation resulting in the event often has dimensions of tens of metres or more (as defined by the source radius). A stronger awareness of the uncertainty of rock mass yield within large seismic sources will assist site users in the interpretation of rock mass damage. The encountered design and implementation errors are reviewed and discussed with a practical set of rules presented to provide a robust seismic system that provides consistent results and increases the user’s understanding of uncertainty in source location and size. The authors’ experience across multiple mine sites, seismic systems and damaging seismic events over a 30 year period has been summarised into practical rules for site personnel of all experience levels.

Nov 29, 2022

By M Jones, G Corder, A C. Keith

"Sustainable development has become an issue of ever increasing importance to the mining industry. The Ernst & Young (EY) mining industry risk radar regularly shows several sustainability elements in the top ten risks, with social license the number three risk in the 2014/15 survey. This is supported by the Fraser Institute survey results of 2013 showing that 36 per cent of responding companies indicated public opposition had affected their permitting and approvals process.Addressing these issues in a strategic way across a mining business that is then translatable to actions at operational level has remained an elusive goal in the industry. In addition the environment and community issues are commonly viewed as somewhat separate from financial and production issues and as a compliance cost rather than a value add. In their Harvard Business Review paper of 2011, ‘Creating Shared Value’, Porter and Kramer outline changes in thinking required for companies to improve their business sustainably through considering the societal issues impacted by their operations and products. Along the lines of ‘doing more with less’ companies’ value chains can be redefined to reduce energy, transport, water or other resource usage leaving additional resource for societal usage and/or reducing environmental impacts. This paper explores the linking of the holistic Five Capitals-based approach with the creating shared value (CSV) concept to help businesses unleash the benefits of innovation. Previous papers have demonstrated the potential for Five Capitals approach to create strategic value through sustainable development. Building on previous work, this paper provides an overview of the current status of holistic approaches to mine management and presents the application of the CSV concept on an African mine currently undertaking capitals-based strategic planning. The paper also demonstrates the value that has been created through utilising this approach and proposes improvements for changing the way the industry tackles and delivers benefits related to sustainability issues.CITATION:Keith, A C, Corder, G and Jones, M, 2016. Strategic sustainable development – creating shared value in the mining industry, in Proceedings International Mine Management Conference, pp 249-264 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 22, 2016