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Carbonatites - igneous carbonate-silicate rocks - host the world's major resources for niobium, phosphorous and REE (rare earth elements).Carbonatites represent the least common products of mantle and igneous processes and their emplacement is principally controlled by lithospheric domes and rift structures. Intrusive carbonatites frequently comprise carbonate-amphibole-apatite-pyrocWore assemblages, occur as plugs, cores, dykes, sills sheets, veins, pipes and irregular bodies, are gecichemically anomalous (Ba, Ca, Cl, F, Hf, Mg, Nb, P, REE, S, Sc, SO4, Sri Tb, Ti, D, V, Zr), are associated with alkaline silica-undersaturated igneous rocks forming carbonatite complexes, and display large, intensive alteration haloes. Also carbonatites are similar to limestones, prone to weathering, and may form thick laterite profiles.Magmatic ores (pyrocWore, apatite, bastnaesite, monazite, magnetite, baddeleyite, phlogopite, fluorite, calcite) and weathering related residual and supergene ores (pyrochlore, apatite, magnetite, anatase, vermiculite) are currently being mined on all continents except Australia. Australia is underexplored for carbonatite associated primary magmatic and especially residual-supergene ore deposits. Chances are very high for the finding of new carbonatite, occurrences and associated ores.

Jan 1, 1994

By G R. F Alvear Flores

Mineral resources are becoming more complex in composition and structure making it more difficult to produce clean concentrates for primary metal smelting. In parallel, providing technological solutions to the recycling and recovery of end-of-life materials is becoming more important in moving towards the goal of increasing circularity. The availability of fundamental thermodynamic data and advanced thermodynamic tools greatly assists in evaluating these complexities and their impact on existing and new processes. In addition, it is fundamental to support the economic performance of smelters. This paper describes several examples on how fundamental work can be applied to industrial processing..

Jun 17, 2024

By T Leach, F Kaiqiang

The Jianchaling gold deposit is located about 1200 km south west of Beijing in central China. The deposit was discovered in 1988 by the Northwestern Geological Exploration Bureau (711 Exploration Team). Sino Gold Limited, an Australian based company, developed the mine in 1998 and is currently operating a 1000 t per day underground mine, producing about 80 000 ounces of gold per year. The pre-mine resource for Jianchaling was 1.6 million tonnes at 9.85 g/t gold. The deposit occurs within the east-west trending Mesozoic Qinling-Dabie orogenic belt formed during the Yanshanian Orogeny. In the Jianchaling region, gold mineralisation is primarily hosted by regional west-northwest to east-southeast striking faults, the most important of which, the reverse sinistral F145 fault, hosts the larger gold deposits including Jianchaling. At the mine scale, the most important zone of mineralisation is localised within a shallowly north dipping dilation on the F145 fault. Proterozoic dolomite forms the hangingwall and serpentinite and talc schist the footwall to the fault. Within the footwall, serpentinite is the most important host rock to mineralisation. Initial alteration involves replacement of serpentine to dolomite ¦ pyrite, talc to ankerite ¦ pyrite, and magnetite and chromite to pyrite, the latter locally through a transitional hematite phase. Proximal to feeder structures, the carbonate minerals have undergone partial dissolution and replacement to quartz. Gold is related to arsenean pyrite and marcasite rimming and replacement of early-formed pyrite, and associated with iron release during the processes of dolomitisation, silicification and carbonate dissolution.

Jan 1, 2004

By Petersen V, Potke W, Polthier K

The paper reviews some of the aerodynamic factors in the blast furnace process and outlines the areas requiring further study. Detailed discussion is given to the pressure drop in both the dry and the wet zone of the furnace and an optimum coke size is suggested for minimum pressure drop. The effect of various charging sequences on the distribution of the gas in the furnace shaft is treated and notes on stack injection included. Flow phenomena limiting blast furnace output and the influence of aerodynamics on the movement of the bed in the furnace are outlined and these include fluidisation, flooding and raceway formation. A mention is made of alkalis, sulphur, zinc, softening, and oil injection and the mixed effect in blast furnace economics of increased tuyere velocity as problems requiring further research.

Jan 1, 1975

By Irving R. C

THE objective of the iron smelter is naturally the production of high quality iron at the lowest practicable cost. To enable this, large tonnages are put through the blast furnace, and, at the same time, the quality of the iron must be under definite control.The modern blast furnace enables these objectives to be attained. The description whieh follows sets out the general details of construction of such furnaces, and the operation at thc Broken Hill Proprietary Company's blast furnaces at Newcastle, New South Wales.The occurence of iron in many forms is so well known as to need no description. Modern civilisation may be said to be built on a foundation of iron, and, today, the production of iron and steel has beeome one of the world's industries.A short historical introduction will serve to show the evolution of the processes and apparatus since iron production assumed importance.There is no definite date fixed as to when iron was first made, or by what means it was first discovered. Perhaps prehistoric man threw iron bearing stone on to his fire, and these became reduced, Ieaving a soft metal behind, or more probably the first iron was of meteoric origin.There is evidence, however, to prove that it has been known for a period of 6000 years. Iron has been found in the Pyramids and its use was known to the early Eqyptians and later to the Hebrews, Assyrians, Greeks and Chinese. Following the Greeks, the Romans excelled in its extraction and uses in the manufacture of their instruments of war, and to this fact can largely be attributed the success of their many wars of conquest. As the Romans overran the rest of the then known world they carried the art with...

Jan 1, 1930

During induration of iron ore pellets produced from magnetite concentrates, there are many reactions occurring simultaneously. While the magnetite is being oxidised to hematite, carbonate fluxes are being calcined, leading to the formation of complex oxides. Calcination of fluxes and the formation of calcium and magnesium ferrites and silicates during the preheat stage can influence the magnetite oxidation process. As the calcination reaction proceeds quicker than oxidation at temperatures experienced during the preheat stage (700 - 1200¦C), the bulk flow of CO2 emanating from within the pellet should disrupt the diffusion of O2 to the magnetite reaction as the gas fluxes are similar in magnitude. This increases the time required for the oxidation of the pellet. Using an infrared rapid heating furnace, experiments were performed on heating individual magnetite green balls in an air atmosphere. These experiments showed that time played an important role in the extent of oxidation and calcination and temperature significantly influenced the initial evolution of high temperature phases such as magnesioferrite, calcium ferrites and calcium silicates. Understanding the kinetics of all these reactions for a particular pellet feed, and their interaction, is important for optimising the design of the induration furnace.

Jan 1, 2005

By Selischop F, Tredoux M

The distribution of platinum-group elements (pGEs) has been investigated in matte and slag samples from Waterval Smelter (Rustenburg Platinum Mines). The study showed that a strong preference of PGEs for alloy phases in matte represents a concentration mechanism that commenced in the furnace but can be considered a continuum from natural processes. Metal losses to fayalite (converter) slag occur by matte entrainment due to the mechanical capture of liquid sulphide droplets from the matte layer, and the exsolution of dissolved metal sulphide resulting from changes in the oxidation state of the slag. The latter is comparable to immiscible sulphide in basic magmas. However, the observed distribution of PGEs shows enrichment in metal phases of the matte. A mechanism is proposed whereby naked PGEs in silicate melts coalesce to form clusters which are stabilised by surface attachment of sulphur atoms. This envelope acts to 'draw the cluster into sulphide melts. Small particle melting effects permit PGE clusters to remain as liquids at magmatic and smelter temperatures.

Jan 1, 1994

The Ok Tedi Project has been planned as a selective mining operation since the Feasibility Study. The nature of the orebody, and the need to 'stage' the infrastructure buildup meant that initially the mill would process gol ore using a leach-CIP process, followed by parallel leaching of gold ore and flotation of copper ore, and finally all flotation of copper ore. Cutoff grades were applied to gold and copper ore of 1.0-1.3 g/t Au and 0.4-0.3% Tot. Cu. Since startup, unpredicted occurrences of sulphide copper and, to a Lesser extent, carbonaceous material, has necessitated significant additional short term drilling (other than at grade boundaries), and shift grade control in the pit to control contaminant levels. Remodelling of the orebody based on the most up to date variography and geological interpretation has had a significant impact on the reserves, and thus the whole project development strategy; necessitating the earlier processing of copper ores, and preflotation of the gold ore.This paper discusses some of these points in detail, and in particular highlights how unforseen geological occurrences coupled with processing restrictions can have significant impacts on ore reserves and the mine development schedule.

Jan 1, 1986

The mining of high-grade narrow vein deposits is a predominant field of activity in the precious metal sector. These types of deposits are located throughout the globe and have a significant presence in mining operations. The principle factor that has undermined the profitability and effectiveness of mining such ore zones is the substantial dilution that occurs when blasting with explosives during extraction. In order to minimise ore dilution, the thermal fragmentation mining method enables the operator to extract a narrow mineralised corridor, 30 cm to 1 m wide (according to the true width of the ore vein). By inserting a strong burner powered by diesel fuel and air into a pilot hole previously drilled directly into the vein, a thermal reaction occurs spalling the rock and enlarging the hole to 30 - 100 cm in diameter. This patented method produces highly concentrated ore, resulting in 400 - 500 per cent less dilution when compared to conventional mining methods. The mining method was conceived with the aim of mining ounces, not tonnes. This method of extraction, reduces the environmental impact of mining operations since much smaller quantities of rock are displaced, stockpiled, and treated using chemical agents. The fully mechanised equipment operated by a two-person team, maximises the effectiveness of skilled personnel, increases productivity, and reduces risks of injuries. Important economic benefits are generated for large- and small-scale mining operations alike. For large-scale operations, the mining method increases mining reserves, lowers the cost per ounce, and increases the total profitability of existing mine operations. The method also significantly lowers costs and risks of developing and mining small-scale deposits, requiring less investment capital, shortening the payback period, thus reducing the lending risk.  Combined with a small modular processing unit able to process between 100 - 300 tons per day, the method substantially lowers the financial break-even point for small-scale mining operations in a narrow vein environment. The company has been working with the technology at its Rocmec 1 mining site; results achieved and future developments are discussed.

Jan 1, 2008

This paper covers only the energy uses of natural resources and does not deal with non- energy uses, which in 1975 were of the order of 10 per cent of the total consumption of energy resources. The United Nations `J' Series of Statistics ex- presses each of the various forms of energy in terms of its coal equivalent in metric tonnes and this basis is followed in this paper. One tonne of black coal (referred to as tce) has been taken as the equivalent of the following. 29 X 109 joules or 27.5 X 106 Btu 0.68 tonnes or 4.8 barrels of crude oil 750 cubic metres or 26.5 X 103 cubic feet of natural gas 1 ò5 to 3.3 tonnes of peat or lignite (world average 2.54; Victorian brown coal 3 0) 8055 kWh (at 3.6 X 106 joules or 3412 Btu per kWh at 100% efficiency) 2660 kWh at 33% efficiency of generation 50 grams of uranium present in natural uranium reactors (see note later under nuclear energy) 0.8 grams natural uranium in breeder reactors Nuclear and hydro electricity are expressed as the coal equivalent required to produce, at 33 per cent efficiency, the same amount of electricity. In other words, electricity produced by these sources is converted to its coal equivalent at the rate of 2660 kWh = 1 tonne coal.

Jan 1, 1978

Looking back 25 years, the role of the drill and blast engineer in an Australian mine seemed relatively simple, with the primary focal points being scheduling of the drill rigs, oversize control, and budget control with respect to consumption of both explosives and drill consumables. The choice of explosive selection was relatively simple, though many mines were becoming involved in trials of slurry explosives, emulsion blends, and low density ANFO blends. Guidelines to assist the engineer towards specific fragmentation targets were scarce, environmental constraints were light, and computers were rarely found on the desks of any mining engineers. Wall control blasting was in its infancy, with the bulk of attention being given to appropriate slope design and little real attention given to factors such as explosive distribution, and optimum delay timing and sequencing. Quantitative measurement of blasting performance was rare. The science of blasting, for fragmentation control, wall control, and environmental impact control was about to be born, and was heralded in those years by intense efforts by the explosive manufacturers and a proliferation of research centres throughout the world. Since the early 1980s, the role of the Australian drill and blast engineer has gone through a major metamorphosis, and currently requires a greater depth of scientific understanding than any other specialisation within mining engineering.

Jan 1, 2004

By Hare S. M, Griffin P. T, O&apos

Chalcopyrite ore and converter slag treatment to produce copper concentrates is undertaken at the Copper Concentrator of Mount Isa Mines Limited. This concentrator was commissioned in May 1973, replacing the original No 1 Lead-Zinc Concentrator, for the processing of all chalcopyrite ore coming from Mount Isa Mine.Treatment of chalcopyrite ore at rates of up to 125 000 l/week is described here; the treatment of converter slag is described later.

Jan 1, 1993

By Perring CS, Vearncombe J. R, Ho SE, Groves DI

Large Late Archaean greenstone belts in Western Australia, Canada and Zimbabwe, contain abundant mesothermal gold, volcanogenic massive base-metal sulphide, and komatiite-associated Ni-Cu mineralization. These greenstone belts are similar in many respects to convergent and accretionary plate margins found in the Pacific rim; modem environments which are cor-respondingly rich in gold and base-metal mineralization. The giant gold placer deposits of the Late Archaean Witwatersrand Basin (the world's largest gold producer) formed in a foreland or retro-arc basin; in a similar tectonic setting to much modem placer mineralization around the Pacific. Gold and volcanogenic base-metal sulphide mineralization are abundant in Late Archaean terranes and the Pacific rim because1. gold mineralization is a product of convergent margin tectonics, and 2. accretion in convergent margin orogens provides the best chance of preserving base-metal mineralization related to submarine volcanism.It is therefore likely that the abundance of gold and base-metal sulphide mineralization in the Late Archaean reflects the widespread growth and sta-bilization of continental crust via tectonic processes broadly similar to those operating in the present Pacific basin.

Jan 1, 1990

By J P. Evert

Didipio gold-copper mine operation is situated in the island of Luzon, approximately 270 km north of Manila in the Philippines, in an area of high seasonal rainfall. The hydrogeological water flow model implied that there would be high connectivity between regional structures and underground operations. This model predicted that underground mine groundwater inflows were expected to quickly rise as the decline progressed to a peak of 510 L/s. Designing a capital pump station to deal with 510 L/s has its own challenges, however developing the decline down to the required level, always dealing with 300 L/s of water and constructing the pump station is extremely challenging and required a robust water management plan and mine design. When dealing with expected high volumes of water, underground mine design and scheduling plays a key role in protecting electrical infrastructure, equipment, secondary pumps, and the decline from flooding. A good drainage system and controlled dewatering plan is essential for safety and progress. This paper details the dewatering techniques and mine designs required to accomplish decline development with high water inflows as used in the Didipio project. It will describe the learnings and outcomes that are achievable with a flexible design, as new structures are mapped, and water intersections are increased. It also highlights the potential for adaptability in mine planning to provide evolving improvements or to evade problems that are expected from the constant reconciliation of data recorded during development.

Mar 29, 2023

By S M. J Koleini, F Hedjazi

The purpose of this research was to study the calcination of lead-zinc flotation tailings from the Angouran lead and zinc flotation plant in Iran as a pre-concentration step prior to hydrometallurgical processing of the oxidised tailings. There is an abundance of these tailings in the Angouran region and making use of these tailings would help preserve national wealth and also reduce the serious problems of environmental pollution caused by the tailings. At the optimal conditions of calcining at 750 - 800¦C for 45 minutes, the sample showed a mass loss of about 19 per cent. Mineralogical analyses showed that under these conditions the carbonate minerals including smithsonite (ZnCO3), calcite (CaCO3) and dolomite (Ca Mg (CO3)2) decomposed to their respective oxides. Hemimorphite (Zn4Si2O7 (OH)2.H2O) converted into willemite (Zn2SiO4) and this transformation postponed the formation of silica gel in the leach solution. The grade of zinc increased from 22.20 per cent to 29 per cent. These mineralogical changes resulted in desirable reactions in the acid leach process.

Jan 1, 2004

By Johnson N. W, Quast K. B

Over the years there have been occasional references in the literature to the activating effect of cyanide in galena flotation with xanthates. These have usually been associated with the processing of lead-zinc or copper-lead-zinc ores. Bubble contact curves for the pure galena-xanthate system show a flotation edge at pH 10.4 independent of sodium cyanide concentration which was thought due to hydroxyl ion, not cyanide ion.Flotation tests were conducted on samples of Mount Isa lead-zinc ore using varying concentrations of sodium ethyl xanthate and sodium cyanide. At low collector concentrations, galena recovery kinetics improved with sodium cyanide addition, and the higher the cyanide concentration, the higher the galena recovery rate. At higher collector concentrations, galena recovery rate was independent of sodium cyanide addition.For a given collector addition, the lead grade-recovery curve shifted to an improved position with increasing sodium cyanide level. For the same recovery there was an increase in the lead grade with increased sodium cyanide addition, and this increase was most dramatic at high sodium cyanide concentrations.The presence of sodium cyanide during the grinding of Mount Isa ore caused surface passivation of the iron sulphides and possibly the sphalerite.These sulphides, therefore, reacted with less of the oxygen present in the pulp, hence more oxygen was directed to the surface of the galena. This resulted in an enhancement in the total amount of xanthate adsorbed on the galena that is reflected in the improved flotation response of that mineral.

Jan 1, 1990

By M Paine

Work to date has shown that the use of Al2O3:SiO2 ratios is suitable for identifying potential gibbsite bearing samples. Subsequent confirmatory XRD analysis helps to refi ne this initial identification. Based on these methods, gibbsite has been mapped in two common settings:1. along steeply dipping faults, or2. in association with stratigraphic contacts where one unit is aluminous (eg dolerite dyke).On a microscale, the samples studied illustrate an association between haematite, and to a lesser extent goethite, and gibbsite. In these samples the dominant forms of haematite are discrete crystalline phases of either microplaty haematite or euhedral martite. Two dominant forms of gibbsite were observed:1. vein style gibbsite that cross-cuts (or infill’s cracks) in goethite ± martite iron oxide associations, or2. gibbsite intimately intergrown with and forming a matrix to microplaty haematite.Some of the gibbsite microstructures observed suggest that it may have formed during a very hydrous, possibly hypogene, stage of the deposit genesis. The presence of this crystalline gibbsite, and in particular its occasionally euhedral form, suggests that aluminium was at some stage remobilised, at least locally, and then precipitated from solution as gibbsite. These observations suggest that these has been a phase of gibbsite precipitation that may have had a close but complex relationship with regards to the timing of the mineralisation processes, rather than formation as a result of late stage lateritic weathering.

Jul 11, 2011

By Chenggang W, Junhua D

Fragmentation variation laws in loading and non-loading areas are obtained by cement block model blasting experiments under various stemming lengths. A reasonable ratio between loading length and stemming length is worked out according to minimum average fragment size. The present continuous loading structure, for its very long length to be stemmed, leads to insufficient fragmentation in the upper part of bench. So a new loading structure with bottom air cushion is put forward. The author analyzes blasting effects and processes of two loading structures' and proves that there exists a optimal length of air cushion.\

Jan 1, 1990

This paper examines the impact of the time value of money on the location of mining facilities, as examplified by a central processing plant serving several mines. Three approaches, the Euclidean-Distance Approach, the Gravity Centre Approach, and the Rectilinear-Distance Approach, commonly applied to a single facility location problem were employed in the study. The objective function in all three models was the updated value of the following three costs influenced by the processing plant location and defined within the framework of the continuous model of value representation and the continuous interest rate convention: I. the costs of transporting the useful mineral from the mines to the plant, 2. the costs of constructing the transportation links between the mines and the plant, and 3. the costs of maintaining these links over time. Results of the study show a substantial impact of the time value of money on both the processing plant optimal location and the opportunity cost of neglecting the time value of money in the locational considerations.

Jan 1, 1995

By Denholm W. T

The SMELT-2 package is specifically designed to perform on-line simulation of smelting processes. This paper describes its application to the simulation of continuous matte converting followed by reductive slag cleaning in SIROSMELT reactors. The matte, containing 50% Cu is assumed to be produced at the rate of 20 tph in a continuous matte smelting furnace such as an Outokumpu Flash Furnace, Noranda or Sirosmelt reactor. Two alternative fluxing strategies in the converter are examined, namely: ò conventional silicate slags, ò calcium ferrite slags, and the flow sheets associated with each strategy are discussed. A regular solution model is used in the present study to account for the variations in the activity coefficients of components in the slag.

Jan 1, 1989