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Carbothermal Reduction and Nitridation of Ilmenite Concentrates and Chlorination of the Reduced Samples

Sep 13, 2010

This work was instituted to investigate the microscopic structure of brown coals by means of microtome sections cut from them. It was found to be essential to impregnate the coal with some material prior to cutting, because of its powdery and crumbly nature. Of a number of impregnating materials tried, e.g., glycerine gum, gelatine, by far the most satisfactory was paraffin wax. Samples of brown coals for section cutting must be moist. When obtained, they should be put immediately into air-tight tins, and, if they are not to be used for some time, it is desirable to keep them under water containing a small amount of formalin. If the sample is allowed to dry in air, it becomes too hard to be cut. It cannot be softened again even by prolonged soaking in water.PREPARATION OF COALSmall rectangular, blocks were cut from the sample with a chisel and a strong scalpel. The largest block prepared was 3·2 x 2·5 x 0·6 cm. The faces of the block from which sections were to be cut were approximately levelled before treatment. The block was then painted carefully on all sides with two coats of warm aqueous agar, approximately 2 %. This prevented crumbling and breakage of the block during treatment. When the agar was set, the block was placed in water, and all the air removed with a vacuum pump. The water was replaced first by alcohol, then by chloroform, by the usual step transference of a series of liquids, in each of which the block was placed for 24 hours: Ethanol %, 10, 20, 30, 50, 70, 85, 95, 100 (three changes); Ethanol-chloroform, 3: 1, 1: 1, 1 : 3, chloroform pure (three changes) '. The blocks were then embedded in paraffin of melting point 56-58°C. Fresh...

Jan 1, 1947

By B Lindqui, M V. Knyazev, L S. Tsemekhman

Gipronickel Institute JS that is a Research and Development Centre affiliated to the worldclass Norilsk Nickel Mining and Metallurgical Company, and Outokumpu Technologies AB (Boliden Contech AB) have jointly developed the reconstruction project of Pechenganickel metallurgical operations using a two-zone Vanyukov furnace. The international expert group appointed by the Nordic Investment Bank has examined the project. The project financing should be partly executed by the Norway government. Current annual rate of sulfur dioxide emissions is 100 000 t. The aim of the project is to reduce it to 12 000 tpy. Pechenganickel Combine is owned by MMC Norilsk Nickel. Currently it produces nickel high-grade matte from sulfide copper-nickel concentrate with up to ten per cent MgO content. The existing production is in accordance with the following flow sheet: agglomeration û electric furnace smelting with matte production û converting in horizontal converters. Annual production capacity is about 36 000 t of nickel in high-grade matte. Converter gases report to sulfuric acid production. The principal results of studies on high magnesia materials smelting in two-zone Vanyukov furnace, engineering solutions, and technical and economical parameters are offered.

Jan 1, 2004

The Blackwater Coal Mine is a modern open cut operation using large draglines for over- :)urden removal and shovels, loaders and trucks to mine and haul coal to the crushing and coal ?reparation plant. Operations at the mine are described in sequence following through overburden removal to the railing of product coal from the mine site. The close operating connection between the mine and washery, which results from the blending of raw coal into clean product via the qashplant bypass system, is stressed. Some features of special interest at Blackwater Mine, such as land reclamation and slope stability,are outlined.

Jan 1, 1974

With the sinking of the new No. 3 Shaft and the increasing depth and northward movement of the mining operations, improved ventilation of the mine workings became necessary and it was decided to sink a new upcast ventilation shaft midway between No. 2 Shaft and No. 3 Shaft.The shaft is finished to 16 ft. internal diameter and connects with the mine workings at the 2,600-ft. level. It is lined with unreinforced Concrete approximately 12 in. thick. The shaft sinking routine was drilling, blasting and mucking by hand using a 27-cub. ft. capacity bucket. The concrete lining was poured in conjunction with the sinking and was normally finished within 30 to 50 ft. of the shaft bottom.

Jan 1, 1957

By Hara Y, Arino S, Nakamura M, Tachimori M

The theoretical and experimental studies have been done to clarify the hearth flow of iron and slag. The results of dissections show that the hearth can be treated as a packed bed of coke hav- ing good permeability with a coke-free layer at the bottom of the hearth. 3-dimensional numerical calculations of hearth flow with and without a coke-free layer are carried out, and the results are assured by a water model simulation. The influences of a coke-free layer on the iron flow and the discharge route of iron and slag are examined. The 3-dimensional flow pattern can be represented simply by the travelling time, which depends on characteristically the profile of coke-free layer and the quantity of iron in the hearth. Those flow parameters could be obtained by the results of radioisotope tracer test ( Co for iron flow, and Sc for slag flow) at several furnaces. As a result, it is found that the coke-free layer repeats the cycle of appearance and disappearance at several-month intervals. This cycle corres- ponds to large temperature fluctuation at the bottom of hearth. The relation between iron flow and skull (solidified iron, coke and deposited graphite mixed layer) on the hearth brick was studied by the model experiment and the thermal analysis based on the indications of thermocouples installed in the bottom of the hearth. If a thin coke-free layer is formed on the skull, a fast iron flow is generated in the layer, and melts away the skull. The growth and melting of skull produces the fluctuation of thermal load on a bottom brick, causing brick Damage.

Jan 1, 1981

By Eisele TC

Horizontal perforated-plate baffles were shown to improve the cleaning efficiency of a flotation column when processing coal from two sources. The baffles consisted of flat plates with holes large enough to avoid plugging problems, and they improved the washing efficiency by making the flow patterns in the column closely approach plug flow. Tests with varying amounts of baffle open area showed that the optimum was between 30 and 40 per cent open area, which effectively prevented backmixing without seriously reducing capacity. The baffled column had previously been tested under ideal conditions with good results (87 per cent pyrite rejection at 85 per cent combustiles recovery), and so the tests reported here were intentionally run with difficult-to-float coals to determine the benefits of baffling under adverse conditions. For an original coal feed containing 38 per cent ash and 3.23 per cent total sulphur, the baffled column could recover 84 per cent of the combustibles while rejecting 84 per cent of the ash and approximately 54 per cent of the pyritic sulphur. Without baffles, the column recovered 88 per cent of the combustibles while rejecting only 76 per cent of the ash and 45 per cent of the pyritic sulphur. Subsequent tests with a dye tracer showed that the baffles reduced entrainment by approximately a factor of five, while the recovery was reduced by only a few per cent. Overall, the loss of capacity due to the baffles was more than offset by the improvement in product quality.

Jan 1, 1993

The discovery of copper and nickel sulphides in the Riwaka Complex in 1967 led to considerable exploration activity by a number of companies. Various exploration techniques used by these companies are summarised and discussed. Activity of these companies shows that mineralisation is mainly confined to the southern, ultramafic section of the Riwaka Complex where geological mapping recognised sixteen units within, or associated with the Riwaka Complex. Significant pyrrhotite, pentlandite chalcopyrite mineralisation is restricted to biotite feldspar pyroxenites and to clinopyroxenite units. Lesser and more erratically distributed pyrite chalcopyrite pyrrhotite mineralisation occurs in poikilitic pyroxene hornblendites, melanocratic gabbros, and in marginal diorite lenses. It is suggested that a linear belt of layered ultramafic and mafic rocks described in Fiordland by Williams (1974) may be a southern extension of the Riwaka Complex. The Riwaka Complex has been classified as belonging to the Picritic subtype, (Tholeiitic suite), of Naldrett and Cabri, (1976), and as such it is concluded that it exhibits substantial potential for the discovery of economic copper and nickel deposits. It is considered that the complex is a multiphase differentiated intrusion emplaced in a major tensional fracture zone that developed in a relatively stable tectonic environment, namely a succession of middle Paleozoic shallow water shelf sediments. Based on sparse available evidence it is suggested that the Riwaka Complex was intruded in the lower to middle Permian. It is further suggested that the tensional fracturing was initiated by the onset of subduction process which were responsible for the development of the Permian volcanic arcs and ophiolite belt in the north west Nelson area.

Jan 1, 1977

By Koppe J. C, Costa J. F C L

This paper compares different results for overburden volume estimation assisted by geoestatistics, particularly using kriging methods. The main goal is to obtain the most reliable digital terrain model for the calculation of the overburden volume. The data was collected on an irregularly spaced grid and interpolated values were calculated to provide a denser, more regular data set before volume estimation. The field work was developed at the Butia-Leste Coal Mine, southern most Brazil, where an accurate survey was done using a total station theodolite with electronic data collector. The study was developed in five main steps: data acquisition, exploratory data analysis, spatial continuity measurements, point and block kriging estimation and verification of the results. Data acquisition was carried out on a 5 x 5 in grid. This dense grid provides an exhaustive data set of the real terrain against which data subsets can be compared for the various interpolation procedures and volume calculation. This provides an interesting insight into the influence of the number of data on the estimation error. Univariate statistics were used to compare each data subset and the exhaustive dataset. Ordinary kriging on the data subsets followed by contouring was carried out using Geoeas and Surfer software respectively. A subroutine written in C provided the link between the files generated in Geoeas and subsequent contouring routines embedded into the Surfer package. Omnidirectional and directional variograms were modelled defining the parameters for kriging estimation using Geoeas. Different variogram models were checked through cross validation prior to kriging. A comparison between the magnitude of the differences in volumes calculated with the different DTMs was attained. These final result indicates the sensitivity of the volume obtained to the number of data points. As the number of data points increases the estimation error decreases, but at some point there is no significant decrease in the final volume with the collection of additional data.

Jan 1, 1995

By Johnson N. W, Ralston J, Lauder D. W, Smart St C R

The flotation behaviour of the Hilton ore of Mount Isa Mines has been examined in the presence of two collectors (sodium ethyl xanthate (Ex) and sodium diisobutyldithiophosphinate (3418A)) over a range of flotation Eh values and collector additions. Tests were also conducted in the absence of collector to determine the relative contributions of natural and self-induced floatability of the major minerals in the feed. In these tests the influence of metabisulphite on the self-induced floatability of the minerals was also determined. Attention focussed on optimising the selectivity of galena flotation. It is shown that the Hilton ore sample contained lower levels of naturally hydrophobic iron sulphide minerals than are generally contained in the Mount Isa lead-zinc ore. Furthermore, the self-induced floatability of galena was less than that exhibited by the galena in the Mount Isa lead-zinc ore. Sodium metabisulphite (MBS) reduced the self-induced flotation of galena but had no effect on the natural floatability of the iron sulphide minerals.

Jan 1, 1991

When lying over 200-250m depth, many seams and surrounding strata are gassy enough to create mining difficulties , particularly in highly productive longwalls as well as in their development headings. In addition to the gassiness of seams or stra- ta in the outgassing volume around working, the shape expansion and limits of this one influences much the intensity of gas emission. These charac- teristics of outgassing volume differ very much ac- cording to the permeabilities of the seams and strata encountered by their fracturation due to mi- ning. Moreover, the shape of the outgassing volume is very much modified by the rate of advance of the face. In nearly impermeable deposits, gas flows from a limited outgassing volume. When the rates of advance of a face are medium or low, the shape and dimensions of this volume do not change very much and outgassing volume is translated progressi- vely with the face advance. This explains why, in the past, it was observed that there was for each seam an average steady specific emission of gas, round which the volume of gas evolved per mined ton or per mined unit area, calculated over a cer- tain time, was oscillating. Combined with a statisti- cal irregularity coefficient, this allowed prediction gas of emission and thus to take decisions for air ventilation, drainage, and eventually production.

Jan 1, 1988

By Lovitt M

Ora Banda Gold Mine is located in the Eastern Goldfields of Western Australia. Mining is carried out underground by sublevel open sloping resulting in large open stopes. A Mass Blast of approximately 250 000 tonnes was carried out in July 1994 to recover a rib pillar between two stopes, and the crown pillar between the underground mine and the abandoned open pit above. Strategic development within 50 m of the blast consisted of two ventilation shafts and the main decline. This development required careful design and prediction of the blast results. This paper describes the design of the blast, the prediction of the likely effects, the measures taken to reduce the risk to important development, and the results of the blast.

Jan 1, 1995

By Trois P

A fully instrumented and bench-mounted diamond drilling machine, purpose designed and built, has been used for investigating the effect of aqueous solutions of various chemical compounds when used as drilling fluids. The rocks investigated were andesite, basalt and granite, the chemical compounds were alkylamines, with various hydrocarbon chain lengths, aluminium chloride and dioxane. Rotation speed seems to be one of the major factors affecting the emergence of mechanochemical effects as the results obtained with aluminium chloride clearly indicate. Penetration rate is either unaf- fected or enhanced by the presence of certain compounds, such as aluminium chloride. On the other hand, penetration rate diminishes when the drilling fluid contains dioxane and exhibits an apparently unpredictable behaviour with alkylamine solutions, although it appears that an increase in hydrocarbon chain length usually equates to an increase in penetration 1. Full Professor, Mining and Mineral Dressing Department University of Cagliari - Italy 2. Associate Professor, Mining and Mineral Ikea- sing Department University of Cagliari û Italy rate. Rock texture seems to have a pronounced effect on test repeatability. With hexadecy- lamine acetate solutions in concentrations ranging from 10-5 to 5 .10-4 molò dm 3 and 41.88 radòs-1 rotation speed, 46 % increments in penetration rate of andesite were observed, with respect to water, whereas penetration rate decreased in basalt by as much as 60¦%o when a dioxane solution was used as drilling fluid. An interpretation of the observed effects is proposed in the light of current knowledge of solid state physics and physical Chemistry.

Jan 1, 1992

By James S. E

Financial risk of environmental problems is the key to many important business decisions within the mining industry. Massive uncertainty makes it difficult to choose a strategy for managing environmental problems to reduce corporate financial exposure to environmental impairment. A correct and practical method exists to clarify the risks and help make decisions. A case study on an insurance problem illustrates the method.The approach used is to translate existing data on environmental problems into probabilistic expressions of financial risk, and organise the expressions to reveal alternative solution strategies for the insurance problem.

Jan 1, 1993

By Hoppe AJ

Drilling and shooting techniques at Moura open-cut have evolved over a period of 16 years and are the result of hard earned experience combined with established practices and consul- tation with professional services. The wide range of overburden types encoun- ted in the field requires varying methods to achieve the best results at all times. Safe working conditions for the employees and protection of mining equipment is of para- mount importance and close liaison is maintain- ed with the Department of Mines Queensland to keep abreast with changing legislation. Drill patterns, charging profiles, types of explosives and ultimate results are des- cribed in detail along with a resume of equip- ment. Costs of drilling, labour and explosives are also analysed with a total of approximately 20c per cubic metre of shot ground. Future developments and improvements to facilities are also outlined.

Jan 1, 1978

By Bedford D. J

The post pillar cut and fill stoping method has been adopted by King Island Scheelite for the extraction of the main Dolphin orebody. The orebody is a massive, tabular deposit varying from 10 to 50 metres in thickness, and dipping at approximately 30¦ towards and under the sea bed. The mining method was selected for 1. maintenance of hangingwall support under the sea bed; 2. maximisation of first stage ore extraction; 3. flexibility of mining, allowing maintenance of grade and selective mining around waste bands within the orebody, and 4. compatibility of existing equipment both with stoping and the on-going underground mine development programme. Stope parameters were established on the basis of initial rock stress analyses, and since the undercut phase of mining the stoping programme has been monitored with various types of deformation measuring devices installed in a series of large diameter boreholes.

Jan 1, 1977

By Kyle J. H, Browner R. E

The selective adsorption of gold cyanide by the weak base ion exchange resins, PAZ-4* and Duolite A-7*, the neutral polymeric adsorbent, Amberlite XAD7*, and the strong base resins, PAZ-8 and IRA-400+ have been studied in both low and high salinity waters, and performance compared with activated carbon. The selectivity of the neutral polymeric adsorbent and activated carbon for gold decreased in highly saline water, while the selectivity of weak and strong base resins for gold increased in highly saline water. This supports the contention that the adsorption mechanism for neutral polymeric adsorbents and activated carbon is the same. Copyright

Jan 1, 1992

An integrated mining equipment development organisation is typified by Deutsche Montsn Technologic of Essen, Germany. working on improvements in reliability, production and control in coal mines. Examples of recent mining advances are in mechanised roadheading, in different approaches to cutting technology, and in low height roof bolting.On the longwall face the mechanics of cutting are related to supplied energy as well as to dust make. In conveying both armoured face conveyors and conveyor belts are monitored. Roof support is not neglected and the continuous pumping of stowage slurries provides further options for longwall support. Surveying developments, particularly the gyro-theodolite, directional drilling. and shaft vehicle monitoring provide further examples of advances in control in coal mining activities.

Jan 1, 1991

Western Australian tin deposits are similar to those of other Precam- brian terrains in that they are mainly associated with rare-metal pegmatites, in which cassiterite is found with minerals containing any or all of the elements Ta, Nb, Be, Li, Cs, Rb and the rare earths.. They differ from Phanerozoic deposits where cassiterite occurs in quartz veins, greisens, dis- seminations in granite or sulphide lodes, and is associated with minerals containing W, Mo, Bi, Sb, As, Ag, or Cu. The main tin production in Western Australia has come from the Pilbara Block where the more important tin- bearing pegmatites are related to a younger granite phase, and from Green- bushes where large albite pegmatites intrude ?Proterozoic metamorphic rocks. The more important tin deposits in the Pilbara Block, and those in the Halls Creek and Murchison Provinces, are related to granites which are richer in Si and K and poorer in Ca, Mg, Fe and Ti than 'average granite'. The tin granites tend to have higher than average contents of Sn, Rb and Li.

Jan 1, 1973

The Indonesian province of Papua is a remote jungle-clad region covering the western half of the mountainous island of New Guinea. Despite being relatively under-explored to this day,Papua is home to the greatest mineral success story of the 20th century. The Grasberg/Ertsberg minerals district atop the central dividing range contains the worldÆs largest reserve of both copper and gold (Freeport-McMoRan Copper and Gold, 2002). With large mines at Ok Tedi,Por gera and Lihir,and many well-delineated resources such as Frieda River,Wafi and Hidden Valley, neighbouring Papua New Guinea,the eastern half of New Guinea has enjoyed sustained exploration campaigns for gold and copper since the mid 1960s. The combined Grasberg and PNG exploration successes can be measured in terms of ounces of gold produced over the last decade versus available landmass,conf irming the island of New Guinea and surrounding islands as a world-class destination for gold explorers. Yet despite this obvious regional prospectivity and the profitability of the Grasberg operation, a sustained exploration effort in the Papua province in Indonesia has not been achieved. Periodic political constraints, poor infrastructure, high costs, operational challenges, social and environmental concerns and lack of immediate exploration success often impact exploration investment decisions. Accordingly a lesser number of mineral occurrences have been documented in Papua compared to those seen along tectonic strike in geologically similar Papua New Guinea.

Jan 1, 2004