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By R van Berkel

Regional synergies concern the capture, recovery and reuse of by-products, water and energy between industrial operations in close proximity. The Centre for Sustainable Resource Processing (CSRP) undertakes applied research to further advance regional synergies in the Kwinana Industrial Area in Western Australia in order to achieve greater efficiencies in water, energy and materials consumption and reduction in waste and emission generation. The Kwinana Industries Council (KIC) and its member organisations recognise water consumption and disposal as key environmental issues. Some 30 companies in Kwinana consume a total of more than 35 000 ML/yr of fresh water. Over the past years significant progress has been made towards the reduction of water consumption and improvements in effluent disposal. As part of the CSRP Kwinana Synergies Project, water balances for the ten major water consuming companies have been completed, including workshop sessions with company staff on water synergy opportunities. This work resulted in a set of synergy opportunities which are currently being pursued. In parallel to the Kwinana project, the CSRP has commissioned a supporting project that delivers a toolkit to guide a more targeted and less resource intensive way to identify feasible water synergy opportunities. One of these tools focuses specifically on water, and takes count of input and output water flows within a given industrial area to deliver listings of prioritised water synergy opportunities. This paper discusses the water mapping and workshop approach taken in Kwinana and its outcomes, which are to identify and evaluate water synergy opportunities. The results from the trial application of the developed Regional Eco-Efficiency Opportunity Assessment Toolkit are also presented.

Jan 1, 2006

By S Paciornik, G Schinazi, M H. de Pinho Maur-cio, M B. Vieira, O da Fonseca Martins Gomes, D T. Wagner

Vale (previously CVRD û Companhia Vale do Rio Doce) evaluates the microstructure of sinters in order to understand their characteristics and behaviour in the agglomeration process, and the correlation with conventional quality parameters. Efforts on image analysis development are in progress between Vale and PUC-Rio in order to improve both the qualitative and quantitative evaluation of a representative portion of material. In the present work, digital microscopy techniques were developed allowing this kind of assessment. Employing a motorised and computer controlled optical microscope, low magnification mosaic images covering complete sinter samples were automatically obtained. The mosaics provide a powerful qualitative overview of the whole sample while allowing low resolution quantitative evaluation of the major phases. In addition, quantitative results for phase fractions were compared for the same sample regions at three magnifications (5x, 10x and 20x objective lenses). A single field (1 x 1) at the lowest magnification corresponds to mosaics of 2 x 2 and 4 x 4 images at the higher magnifications. The automated system allows perfect registration between the mosaics and the single image. Changes in phase discrimination were evaluated as a function of optical resolution, and phase fractions obtained by interactive segmentation of the image histograms were compared. While finer dark phases, eg silicates, were only visible with the best optical resolution, coarser phases such as haematite and pores were measured at all resolutions. For haematite, magnetite, ferrite and pores, the largest relative error in area fraction, between the images obtained with the 5x and 20x lenses, was 12 per cent. The results for silicate were less accurate with a relative error of 44 per cent. The results indicate that digital microscopy provides a flexible method for qualitative and quantitative evaluation of these materials.

Jan 1, 2008

By Salmon P. T, Gilmour R

Commercial production of zinc started at the Pasminco Metals - EZ Plant, Hobart, Tasmania, in 1921. Since that time the capacity of the plant has been steadily increased to its present level of almost 220 000 tpa. Major areas of the plant have been successively upgraded over a number of years, (Roasters, 1969, 1975; Acid Plants, 1981; Casting, 1972; Residue Treatment Plant, 1971), but, until recently, the leach/purification area remained virtually unchanged from the time the plant was built. The major redevelopment of the hydrometallurgical plant began with fully integrated pilot plant testing of the proposed new circuit in 1981. The pilot plant incorporated the Low-contaminant Jarosite Process, and a new two-stage zinc dust purification procedure. In 1985, approval was granted for a major modemisation program which involved the complete replacement of most of the leaching and purification plants, and substantial improvements to the residue treatment plant. Construction of the first of the new plant sections, Strong Acid Leaching, commenced in 1986. This paper describes briefly the modernisation program itself, and the current method of zinc production at the PMEZ plant. The new plant sections comprise a Strong Acid Leach stage to improve lead residue grade; a Preneutralisation stage to reduce metal losses in jarosite; new filtration stages for both jarosite and lead residue; new Neutral Leach and Weak Acid Leach stages to replace old equipment; a new Solution Purification stage to replace the use of organic reagents to remove cobalt; and a new Gypsum Removal stage to cool the solution before electrolysis. At the completion of the modernisation program, only the electrolytic cellhouse remains of the early plant sections.

Jan 1, 1993

By V S. T Ciminelli

This work aimed at evaluating the acid rock drainage (ARD) potential of five samples of a Brazilian gold sulfide mine in a decommissioning process. Three of the most traditional ARD prediction techniques, Standard Acid Base Accounting (Std ABA), Modified Acid Base Accounting (Modified ABA), as static methods, and humidity cells as a kinetic method were tested. Both the Std ABA and the Modified ABA results indicated an acid generation potential for some of the studied samples. In the other cases the results were inconclusive. The five samples were then submitted to humidity cell tests during 27 to 30 weeks. At the end of the period, the leachate pH was stabilised in a range from 3.4 - 4.1 (four samples) to 5 (one sample). The presence of relatively high levels of sulfate and dissolved metals was detected throughout the operation, specifically, Ni and Zn, and less frequently, As. These findings are discussed with the help of the samples mineralogy and Eh-pH diagrams. The results obtained in this investigation indicated potential environmental risks of this mining area. In this particular case, the kinetic tests were shown to be essential to the identification of the samples ARD potential.

Jan 1, 2003

By A V. Nguyen

Spherical calcium dioleate particles (~10 ¦m in diameter) were used as AFM (atomic force microscope) probes to measure interaction forces of the collector colloid with calcite and fluorite surfaces. The attractive AFM force between the calcium dioleate sphere and the fluorite surface is strong and has longer range than DLVO (Derjaguin-Landau-Verwey-Overbeek) prediction. The repulsive AFM force between the calcium dioleate sphere and the fluorite surface does not agree with the DLVO prediction. Consideration of non-DLVO forces, including the attractive hydrophobic force and the repulsive hydration force, was necessary to explain the experimental results. The non-DLVO interactions considered were justified by the different interfacial water structures at fluorite- and calcite-water interfaces as revealed by the numerical computation experiments using molecular dynamics simulation.

Jan 1, 2005

By Bingwen Z, Fengyi K

The hydraulic-stowing mining method is most effective for mining thick coal seams. It is superior to the sliced cover- caving and artificial mining method and the fully mechanized sublevel-caving mining method for the following reasons - a much higher recovery rate is achieved, there is much less surface subsidence and roof pressure, there is no hidden danger of gob fire, and much less methane emission and coal dust problems, etc.. However, its superiority is overshadowed by its backward stowing technique which makes mechanisation of mining and stowing difficult, causes bleed water interference to production and to the environment and is uneconomic because of the high cost of stowing material. These disadvantages limited its application to coal seams that are difficult and not suitable to be mined by other mining methods. The remedy is in reforming it thoroughly to permit mining of otherwise unminable seams and this paper presents the reformation.

Jan 1, 1992

The sucessful use of sewage sludge in land rehabilitation has been established and there is an abundance of overseas information on sludge reuse. Unfortunately Australia is behind Europe and North America in establishing sludge reuse policies and regulations. In Victoria the EPA has no publicised regulations and no communicated policy for sludge reuse. In the absence of sound regulations the onus is firmly on the operators of sewage treatment works to ensure land application of sludge is safe for the environment.

Jan 1, 1992

The fluorspar deposits at Okorusu, Namibia are closely related to an alkaline igneous ring complex of late Cretaceous age (125¦7 Ma). The fluorite ores consist of relatively fine-grained purple replacement fluorite and subsequent coarser-grained purple and green vug-filling fluorite crystals. Homogenisation temperature measurements for 38 primary fluid inclusions shows that main stage purple to green fluorite crystals were deposited over a temperature range from 166¦C to 144¦C, and minor late yellow fluorite was deposited at lower temperatures from 132¦C to 128¦C. Homogenisation and freezing temperatures measured for 18 primary fluid inclusions shows that the fluorite-depositing fluids were less saline than Mississippi Valley-Type (MVT) ore fluids and overlap the lower temperature range of fluids that deposited epithermal ore deposits. Mining in three open pits (A, B and C) at Okorusu has gradually provided exposures which reveal that the fluorite orebodies have been emplaced primarily by the preferential replacement of carbonatites. Evidence for the replacement of carbonatite includes: replacement remnants of carbonatite within the fluorite ores; goethite pseudomorphs after the carbonatite minerals, pyroxene, pyrrhotite and magnetite, which are disseminated in the fluorite ores; andpartial replacement by fluorite of a large sill-like carbonatite body in the A pit. Electron microprobe analyses of minerals in unreplaced portions of the carbonatites show that their mineralogy consists of titaniferous magnetite, diopside pyroxene, apatite, biotite and calcite. Magnetite contains 6.97 per cent to 10.46 per cent TiO2, averages 8.44 per cent TiO2, and has an average V2O3 content of 0.35 per cent. At high magnifications under the scanning electron microscope (SEM), the magnetite shows abundant fine ulv÷spinel exsolution lamellae arranged in a cloth texture. Apatite contains moderately high fluorine contents that range from 3.21 to 5.0 per cent and average 4.2 per cent, and apatite crystals range in total rare earth oxides from 1.7 per cent to 2.61 per cent. Pyroxenes in the carbonatites are iron-rich diopside, and they contrast to pyroxenes in the fenites that are aegirine-augite. All of the microprobe analyses for mica crystals in the carbonatites give biotite compositions. Microscopic examination of fluorite concentrates from Okorusu provides mineralogical information important to the resolution of beneficiation problems. Fluorite ores that are related to carbonatites are typically accompanied by phosphorus benefication problems. The cause for the presence of phosphate in some of the Okorusu fluorite concentrates is a function of the presence of binary locked fluorite-apatite particles. The fluorite ores have also replaced marble locally in the A pit, especially along the A band in the B pit, and dominantly in the orebody proposed for the new C pit. Those ores are characterised by fine grain sizes, faint remnant bedding, lack of carbonatite mineral pseudomorphs and local presence of remnants of unreplaced marble. Concentrates derived from those fluorite ores are devoid of phosphorus, but commonly have elevated silica contents due the presence of free quartz. Carbonatite and marble were preferentially replaced by fluorite because the calcite was readily soluble in the presence of the fluorite-depositing fluids and the dissolution of calcite provided calcium for the formation of fluorite. 

Jan 1, 2008

By Boehme PW, Gregory OR

The results presented here show quite definitely that in the system investigated the intensity of dispersion is enhanced by switching the flow entry from bottom to sides of the packed trough. Since there is no reason to suppose that this would not be true generally then it is not surprising that the blast furnace dispersion data of Standish and Polthier lie above the data for packed columns with bottom fluid entry. In fact, on the basis of the present results, blast furnace dispersion results can never equal standard packed column behaviour but must always be above these. The result that the intensity of dispersion in the trough model is higher closer to the side ports than away from them is at variance with that of Standish and Polthier blast furnace results. Aside from the obvious structural differences between these two systems, it is thought that the presence of raceways and the tortuous path of the gas flow in the furnace may provide an answer. Clearly this is an important difference in the behaviour of the two systems and further investigations designed to clarify the position would have significant practical value. This would also give an indication of how the furnace D/ud values may be decreased along the whole height - assuming of course that this result gives the best overall performance of the furnace. However, there is to date no knowledge whatsoever about this aspect of blast furnace Technology.

Jan 1, 1975

Production of refined zinc (99.95 per cent) at the minesite without increasing greenhouse gas emissions is considered. As an example, exploitation of the full reserve of the McArthur River orebody is proposed, using the existing concentrator, whilst introducing radically innovative smelting technology. Bulk flotation of all the sulphide minerals is followed by smelting in a melt circulation reactor with tonnage oxygen. By smelting the high-energy pyritic concentrate and reacting the evolved sulphur dioxide with near-mine dolomite, a large amount of electricity can be generated. This is enough to supply all the requirements for the smelter itself, an air separation plant and a facility for compressing and liquefying carbon dioxide. Carbon dioxide is disposed of off-shore for enhanced oil recovery or by other means. The reacted dolomite fixes sulphur as an inert and environmentally acceptable solid residue. Treatment by these means leads to virtually zero gas emission smelting. The paper concludes with a vision for the future in which expansion of zinc smelting capacity is seen to be definitely needed.

Jan 1, 1998

Australian coal mines have spent considerable capital on dragline improvements over the last two years. This has included ~$30 M on UDD conversions, >$20 M on new buckets, boom upgrades, electrical upgrades, etc. This is a natural part of the response of mining companies to technology and replacement programs. Capital expenditure is a normal part of the ongoing success of most companies. There is however, a tendency for some people to rely on the capital alone to provide the ongoing improvements in equipment productivity. Implementing new technology through capital expenditure is only part of the equation in continuous improvement. For 80 - 90 per cent of the year, the operator controls the productivity achieved by the dragline. Variation between operators is huge. The average standard deviation in productivity is 12 per cent and maintenance impact is over 40 per cent. Robbins 2003, states: Contrary to what we were taught in grade school, we werenÆt all created equal. Most of us are to the left of the median on some normally distributed ability curve. Further, he states: The issue is knowing how people differ in abilities and using that knowledge to increase the likelihood that an employee will perform his or her job well. There are two options for reducing variability between operators; improving operator ability and getting the machine to take over what the operator is doing (automation). Dragline automation will be discussed, however, this paper will focus more on the æhuman factorÆ and how to establish a dragline with minimum variability between operators.

Jan 1, 2005

To discuss this relationship both the problems of the mechanisms of ore accumulation and the origin and cause of volcanism must be faced. Volcanic activity is associated with hydrothermal activity but the causes of volcanism are inseparable from the problems of the origin of magmas generally. To be more in accord with the inevitable reaction between water and silicates at high temperature, it is suggested that reconsidera- tion be given to the role of water in magmas such that our general concept of magmas becomes one of hot hydrous pastes rather than melts with water in them. It is claimed that a general concept of magmas as gelatinous hydrosilicate masses is a far better assumption because the rheological and diffusive properties of such materials enables an adequate explanation of a greater number of observations. It is consistent with the mergence of magmatic and metamorphic rocks and requires low to modest temperatures at the time of liquifaction allowing convergence with mobilised and disturbed sediment masses. The physical and chemical properties of both wet sediment pastes and magmas envisaged as hydrolised silicate masses are entirely dependent on the enormous internal surfaces of their disordered solvated components. Mechanical disturbance, such as reliquifaction

Jan 1, 1974

Cut and fillstoping using hydraulically placed mill tailings has become an essential feature of stoping operations in Kalgoorlie. ' Approximately 30 per cent of the total production is currently mined by this method. Fill is prepared by thickening or cycloning and is gravitated or pumped underground. The average pulp density is 70 per cent solids by weight, Recent cost reducing innovations are the use of steel passes, corrugated iron manways, polythene film sealing, and the replacing of vertical cement lined pipes with boreholes. TTTTTI rvr T Trim r l1TT

Jan 1, 1964

The Key Centre for Mines consists of the School of Mines of the University of New South Wales and the Departments of Geology and Civil and Mining Engineering of Wollongong University. The Key Centre for Mines/International promotes, markets and develops overseas activities in applied geology, mining engineering, mineral processing and extractive metallurgy specifically in response to the perceived needs in the region for mineral resource and other related earth-science based development. the Key Centre for Mines/International will be involved in the overseas marketing of formal courses; special training activities such as short courses and in-house programs; technical and educational consultancy; research and development projects, and in the establishment of regional links through twinning, exchange and various network arrangements with other organisations in the region. Activities which are now being developed include a training program for Korean mining engineers and geologists, teaching and curriculum development in the Mineral Resources Engineering Faculty of the University Sains Malaysia and a staff development proposal for the Department of Geotechnology of Khon Kaen University, Thailand

Jan 1, 1990

By S P, F Villanueva, R Palomo, D Meadows

During 2002, design and development of the worldÆs largest flotation cell was completed. The cell is the mineral industryÆs first 257 m3 flotation cell, and represents a major development in the design of larger flotation cells, with a 50 per cent increase in cell volume over the widely installed 160 m3 WEMCO« SmartCellTM flotation machine. It is anticipated, in the next few years, world-class copper sulfide concentrators will incorporate 257 m3 flotation cells in their rougher-scavenger flotation circuits. The prototype 257 m3 cell, No 250 SmartCellTM flotation machine is installed in Minera Los PelambresÆ existing rougher flotation circuit. The machine is located in front of the first cell in Row 1 and is followed by nine No 130 SmartCellTM flotation cells. The unit has been in operation since April 2004, and has proven itself in this duty. A key to the successful development of the equipment has been the emphasis placed on fundamental hydrodynamic scale-up criteria. Hydrodynamic factors include superficial gas velocity, water (pulp) circulation through the draft tube, and pulp mixing (distribution) characteristics. This paper will review the scale-up criteria of the No 250 flotation cell, and a case study will be presented on the in-plant testing of the equipment. The case study will document the metallurgical and hydrodynamic performance of the machine. It will also illustrate the economic benefits derived by incorporating larger flotation cells in a modern copper sulfide concentrator.

Jan 1, 2005

"DEEPHOLE " or "Longhole" drilling is the name given to the drilling of prospecting holes with the pneumatic hammer drill. The drilling bit is of the same form, and is prepared in the same way as ordinary rock drill steel, and is extended to the bottom of the hole by sectional hollow rods, through which water is forced.The cuttings from the hole provide a sample of the ground drilled.Deephole drilling was developed at an American mine where the cost of diamond drilling, owing to loss of diamonds, was excessive, and proved very successful, holes being drilled as deep as 220 ft., in limestone, at a cost of one dollar per foot. The use of the method in other mines, and in a variety of rocks, has since been described in the technical literature. From the published descriptions the following data are drawn:

Jan 1, 1930

Kensington is a joint venture between Echo Bay Mines and Coeur Alaska, a subsidiary of Coeur d'Alene Mines Corp. The venture is of equalparticipa- tion and is governed by a management committee with Echo Bay as the operator. The project site is 50 miles north of Juneau, Alaska on the eastern shore of the Lynn Canal. The mine and mill are being planned for a production rate of 4,000 stpd. Currently, probable reserves stand at just over 11.3 million tons grading 0.149 oz Au/ton. The project is now in final feasibility study with a production decision anticipated by the end of 1990. Commercial production would begin early in 1993. This presentation dis- cusses the anticipated mine, mill and support aspects of the project.

Jan 1, 1991

Exploration by Cyprus Minerals Australia Company (formerly Amoco Minerals) has successfully outlined significant Au-(Cu) mineralisation at Starra, 150 kilometres south-east of Mt. Isa. Mineralisation is stratabound and localized in deformed and metamorphosed ironstones (B.I.F?) and iron-oxide bearing schists of the mid-Proterozoic Staveley Formation. Over 90% of the presently outlined potential ore occurs in 4 discrete zones within a strike length of 3.5 kilometres. The inferred geological resource in these zones is approximately 6 million tonnes grading 5 grams per tonne gold and 2% copper. Roughly half of this is open-pittable, but more rigidly applied mining criteria will probably reduce the exploitable tonnage. Detailed infill drilling is in progress and a pre-feasibility study has commenced. The joint venture partners, Cyprus Minerals (75%) and Elders Resources (25%) expect to make a development decision by the end of this year.

Jan 1, 1986

By Fuerstenau DW

The flotation of pyrite in ethyl xanthate solutions is presented along with electrokinetic results. The results have been analysed in view of recently published thermodynamic calculations as well as other published data on the pyrite-xanthate system including adsorption and voltarnmetry studies. The flotation response of pyrite in xanthate solutions is characterised by two maxima, one at pH 4 and the other at pH 8-9. The acidic maxima is also associated with a reversal in the electrophoretic mobility of pyrite, probably due to the formation of ferric xanthate on the pyrite surface through chemisorption of xanthate ions while the basic maxima is not associated with major changes in the mobility and flotation at this pH can probably be attributed the adsorption of dixanthogen. It is concluded that there is not sufficient experimental evidence to conclusively attribute the lack of flotation response in solutions at near neutral pH to any particular phenomena, either kinetic or thermodynamic.

Jan 1, 1993

I feel a little like the Parson delivering his Sunday Sermon, chastizing his parishioners for not coming to Church. Those who need to hear me are absent.Nevertheless, I hope that if you agree with what I am about to say you will go forth and spread the word.We often hear of the impact mining has on the community. I prefer tonight to deal with the impact some community attitudes have on mining, and I want to point out that the results of these attitudes rebound to the detriment of our society. I want to deal particularly with regulation, taxation, and proflts.In a civilization whose standard of living is essentially dependent on an adequate and reliable supply of cheap metals and fuels, it should be evident to Blind Freddie that mining must be encouraged.I must express concern at the constraints inflicted on the mining industry by our community. We tend to blame Government for our difficulties, but we must recognize that Government acts merely as agent for the community. It is fair to say that in a free society, if Government actions do not reflect the demands of the electorate, then it doesn't stay the Government. It is important though for Government, in framing its policies, to ensure that it is not unduly influenced by the loud voices of minority groups.The people of our nation have every right to demand that our industry meet certain criteria to be allowed to operate. We all wish to live in a healthy and congenial environment, and to have our individual comforts protected. It is essential, however, that the community realizes that its demands on the mining industry are affecting Australia's prosperity.Each new regulation and each new tax or impost has its effect on investment, employment, and national revenue. Restraints result in an increase in costs which in turn raises the minimum value of a mineral deposit which is economically mineable. It results in minerals, which could be mined under more favourable circumstances, remaining in the ground, perhaps lost for ever.

Jan 1, 1978