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By E. O. Chisholm

Synopsis The colour changes effected in a solution of dithizone by trace amounts of copper, lead, and zinc mineralization provide a sensitive field test for these metals. The method has been used with success by the United States Geological Survey to trace zinc orebodies under residual soils. The dithizone test is used here on samples of non-residual soil overlying a gold-bearing zone in which the gold is associated with disseminated sphalerite, galena, and chalco-pyrite. A gold-bearing zone was successfully traced under overburden ranging from a few inches to five feet in depth by means of this method. The method may prove useful in guiding preliminary trenching through light overburden, by outlining the extent of copper, lead, and zinc mineralization. Introduction The dithizone test affords a rapid, simple, and delicate test for the presence of zinc in soil and water and is suitable for use under field conditions. It has recently been used with success by the United States Geological Survey to outline a zinc-rich area in the residual soil over a primary zinc deposit in Tennessee. The purpose of the present study was to ascertain whether the method could be used to trace a gold-bearing zone, containing associated zinc mineralization, under shallow, non-residual, glacial overburden. The results obtained indicate that the method can be used to guide preliminary trenching in overburden up to six feet in depth. Tests made of the water near lake-shore outcrops also indicate that favourable prospecting zones may be located from the water, within five feet of the shore. It is felt that this simple field test should find a wider use in prospecting, because, under certain conditions, it can outline favourable zones and thereby reduce the amount of blind trenching necessary. The following pages describe the type of deposit tested, the method used, the .results obtained, and the difficulties encountered by a novice in the use of this chemical procedure. The author is indebted to the officials of Nor-Penn Mines, Limited, for their co-operation while the tests were being made; to the late Richard Bouska, Kenora prospector, for helpful suggestions; and to F. W. McCamus, University of Toronto undergraduate student, who ably assisted with the work.

Jan 1, 1950

By T. Backers

In fracture mechanics modeling the rock mass is seen as the combination of rock material and fractures, which are evident on different scales. The activation and propagation of fractures dominates the stability and performance issues as well as fluid flow potential. Once fractures have started to grow into each other and create through going separations, stability of rock engineering constructions may be violated. Further, as fracture mechanics inherently incorporated a scaling law in the form of the participating fracture length, scaling issues can be more accurately mirrored. This contribution highlights some examples of application of a fracture mechanics based code on some rock mechanics issues such as numerical laboratory experiments, borehole stability or the creation of fluid pathways due to underground constructions. The results show explicitly the creation of fractures and connection of existing ones, and hence the safety and performance issues. It has to be concluded that the basis for frequent application of fracture mechanics on specialized challenges in Geomechanics is laid, and the needs for future developments are defined.

May 1, 2009

By José L. Carvalho

"Time-dependent swelling deformation of several shaley rock formations in Ontario is a wellknown phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. The swelling phenomenon appears to be related to ion exchange between the rock porewater and the surrounding water.The swelling potential is expressed as the percent swelling strain that occurs per log cycle of time, in either the vertical (perpendicular to bedding) or horizontal (parallel to bedding) directions. In addition, the swelling potential is also noted to be stress dependent. In practice, therefore, the conditions required for swelling are (i) the accessibility to water, and (ii) an outward salt concentration gradient from pore fluid of the rock to the ambient fluid. The relief of in-situ rock stress during excavation serves an initiating mechanism (Lo and Micic, 2010).INTRODUCTIONTime-dependent swelling deformation of several shaley rock formations in Ontario is a well-known phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. Swelling is also controlled by the inter-particle bonding; if the bond strength exceeds the osmotic pressure, swelling will not occur, and vice-versa. The bond strength can be reflected by the calcite content which forms cementation bond between rock particles."

Jan 1, 2015

By E. Özberk

Uranium minerals are often associated with iron minerals, and during the hydrometallurgical processing of the uranium ores, iron plays several significant roles. The presence of Fe(III) in solution promotes the oxidative acid leaching for the recovery of uranium. The control of the distribution of impurities in milling and refining is also affected by dissolved iron. When rejected from the process streams, iron usually collects other impurities and contributes to the stabilization of the wastes for final disposal. These roles of iron, as they relate to current uranium processing operations, are discussed in detail, and some broad and historical perspectives are also presented.

Jan 1, 2006

By R. H. Schonewille

One of the many challenges in developing new metallurgical processes is choosing the best option for validating process design parameters and establishing the process operating window. Historically this has been achieved by constructing pilot or demonstration plants of considerable size and complexity, to enable integrated operation of all key process units for a significant duration. While this would appear to be the best option for minimizing technical risk, it is often impractical from a perspective of cost, schedule, resources or bulk sample acquisition. Such an undertaking can even provide a false sense of security, as the optics of running a complete scaled-down version of a commercial plant suggest a high level of process understanding, regardless of the challenges encountered during operation. Xstrata Nickel has undertaken numerous process development and improvement projects over the past 15 years to support green field project development and continuous improvement in existing operations. The approaches used have included; computer simulation, cold flow modeling, construction of pilot test units in third party facilities, commercial plant referencing and the more conventional construction of integrated test plants. Regardless of the strategy employed, the keys to success have included; managing stakeholder expectations, involving the commercial plant design engineers in the planning stage, anticipating subsequent data and sample requirements and most importantly, constructing and operating complex demonstration plants only as a last resort. This paper provides examples of various process development approaches used by Xstrata Nickel and discusses the rationale specific to each project.

Jan 1, 2011

By Sazol Das, Hany Ahmed, Ganesh Bhaskaran, Zhuoru Wu

"Friction stir welding (FSW) process in lap configuration for dissimilar materials has been developed and tested for steel to aluminum joining. A novel cylindrical tool was designed for improved material flow. The joining of steel to high strength 5xxx and 6xxx aluminum was carried out by FSW technique using optimized process parameters. The microstructure, micro-hardness, joint strength and corrosion properties at the weld interface have been investigated. Optical and scanning electron microscopy reveled a well layered structure at the interface and lap shear tests of the welds showed excellent fracture resistance. Neutral salt spray tests for up to 500 hours (ASTM B117) were carried out on the bare steel to aluminum FSW joints, which did not show neither evidence of corrosion at the weld interface, nor any degradation of the weld strength. The FSW lap configuration was applied to prototype commercial vehicle structural component whereby a steel stiffener insert was friction stir welded to high strength 6xxx aluminum alloy. The interface microstructure showed layered root without any steel shattering in aluminum side. A finite element study was carried out to quantify the benefits where it was found that the stiffness increases by 76% under bending loads and 36% in torsion loads.INTRODUCTION Energy preservation and environmental issues, namely carbon footprint and legislation around emission in transportation industries has led to a growing need to use of lightweight materials such as aluminum and magnesium alloys along with various grades of steel in structural application, while still maintaining their strength and crashworthiness. Assembling dissimilar materials within integrated structure is thus a stringent requirement related to optimum performance. In order to achieve an efficient technology of joining dissimilar materials such as aluminum to steel, it remains difficult to select an effective welding process for a given joint configuration. The use of aluminum in transportation industries for structural component is not exclusive in a design and is almost always used along with various steel grades for a mixed materials solution, thus dissimilar aluminum/steel lap joining is of great interest since this is widely used in the assembly of parts (e.g. pillar, frame rails, chassis, body in white (BIW), CAB, etc.)."

Jan 1, 2018

By G. H. K. Pearse, R. P. Taylor

The Big Whopper, one of only four giant economic rare metal pegmatites worldwide, is set to become a producer of the highly valued lithium mineral petalite (LiAlSi4O10) used in glass, ceramics and the specialty glass-ceramics familiar as Corningware® and the new ceramic stovetops. The deposit has a strike length of 1.5 km, a width of up to 80 m and a resource, open in all directions, of 11.6 Mt, grading 25% petalite. It is amenable to open pit mining and Avalon Ventures Ltd. holds a patent on a flotation process that produces an exceptional quality petalite product. The project will also produce: superb quality Na-feldspar which, too, finds use in glass and ceramics; the unusual Rb- K-feldspar for high voltage porcelain insulators; tantalum, in high demand for electronics; lepidolite, an ore of rubidium; and mica and tin. A positive prefeasibility study has been completed and it remains only to undertake bulk sampling and a full feasibility study.

Jan 1, 2001

By Don Thompson

It isn?t a lie if you don?t tell the whole truth The pictures National Geographic didn?t print Other photos National Geographic didn?t print?

May 1, 2009

By Hiroyuki Sano, Hiroshi Chida, Katsuya Toda, Takafumi Sasaki

Saganoseki Smelter & Refinery is one of the largest copper producers in Japan to produce 450,000 tons of new copper annually. Saganoseki used to operate six PS converters with "4 Hot-2 Blow" scheme, but managed to change its operation to "3 Hot-2 Blow" scheme with four PS converters, while maintaining the same production capacity. To achieve the operational change, the following improvements have been carried out; 1) Extending service life from 220 to 350 batches, 2) Shortening cycle time by increasing the blowing rate and the matte grade, 3) Reducing environmental impact by applying sophisticated fugitive gas collection system and 4) Saving energy by waste heat boiler’s modifications. The operational change has been successfully executed, and results in drastic productivity increase and cost reduction. Currently, Saganoseki is maintaining the efficient and consistent operation with 4 PS converters. This paper describes the above-mentioned improvements for increasing productivity and the recent operational conditions of the PS converters.

Jan 1, 2015

By H. E. Frimmel

Abstract - Most of the gold in the Late Archean Witwatersrand Basin is of detrital origin but, in its present form, it is metamorphosed. The only relict detrital features preserved are the morpho­logical characteristics of some placer gold particles. Regional burial metamorphism in the shallower and deeper levels of the Witwatersrand Supergroup reached temperatures around 300°C and 350°C at pressures between 2 kbar and 3 kbar, respectively , estimated from phase relations, chlorite-chloritoid exchange thermometry and chlorite thermometry . Metamorphism of the gold involved compositional homogenization of individual gold particles and partial recrystallization. Various infiltration events caused the partial mobilization of the gold at slightly lower temperatures, between 240°C and 300°C. These infiltrations can be related to crustal extension during the deposition of massive carbonate sequences of the Transvaal Supergroup (around 2.5 Ga), and later to the emplacement of the Bushveld Complex, and to the Vredefort event around 2.0 Ga ago. The mobility of the gold was dependent on the sulfur fugacity prevailing in a particular horizon which, in turn, was deter­ mined by the amount of pyrite (and other sulfides) present in that horizon. With the sulfur fugacity being controlled by stratigraphy, low fluid:rock ratios in a pyrite-rich horizon were most conducive for the mobilization of the gold. Thus, long-range gold mobilization in the Witwatersrand Basin can be expected to be the exception rather than the rule.

Jan 1, 1994

By J. E. Gill

THE 1938 season was marked by a distinct lull in exploratory activity in the Province of Quebec. Quebec was not unique in this respect, but the condition appears to have been more acute here than in most other parts of the Dominion. Various causes may be suggested to account for this. The general disturbance in political and economic conditions throughout the world has certainly had an adverse influence. Uncertainty induced by changes in the mining laws of Quebec in 1937 contributed. A third cause was the belief, now held by many, that the easily accessible deposits in the main producing belt extending eastward from. the Rouyn district have now all been found and that new discoveries in this field will henceforth come more slowly and more expensively. A fourth is the lack of conspicuous success by companies and individuals who have interested themselves in less accessible areas to the north, notably the Chibougamau district. A fifth, the unattractive appearance, as viewed on published geological maps, of the vast area extending northward to Ungava bay and Hudson strait. A sixth, the attraction of such speculative funds as were available to the Northwest Territories, where spectacular finds were reported in the fall of 1937. Whatever may be the relative importance of these causes, languor in exploration will ultimately be reflected in production returns. This appears, therefore, to be an opportune time to take stock of the general position of the Industry in the Province and to consider ways and means of counter-acting those conditions which are now impeding, or will in the near future impede, its expansion. At the request of the Institute Secretary, Mr. Carlyle, I have prepared a brief summary of accomplishments to date and a discussion of some of the geological aspects of the problem.

Jan 1, 1939

By T. G. Joseph, M. J. Bolster

ABSTRACT This paper explores passive seismic measurement as an alternative, nonintrusive approach to conducting annual brake testing on surface mine sites. Dictated by the test site location, this evaluation adhered to the brake testing procedure as per British Columbia occupational health and safety regulations. Results showed excellent correlation to those reported via conventional practice: Comparing stopping distance, time, and velocity for the proposed instantaneous passive seismic versus conventional approaches, less than a 0.5% variance was evident. A viable alternative, the passive seismic approach, allowed an entire fleet of trucks to be sequentially evaluated for annual brake testing without disrupting operations by installing mechanical testing equipment.

Jan 1, 2012

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Jin-Young Lee

"Global population is a key factor in future energy requirements, especially considering the important elements of global energy resources, electricity production, the accessibility/non-accessibility of electricity, greenhouse gas emissions and the states of nuclear reactors. Everyday human requirements depend on industrial products, and industries need a considerable amount of electricity to run. Nuclear fuel is inexpensive and bolsters industrial growth. As uranium reserves are being consumed rapidly, an alternative source of energy in the nuclear industry is thorium. Here, primary energy supplies by various sources from 1993 to 2011 as well as estimates of future needs to 2020 are discussed. This study finds that primary energy sources are mainly fossil fuels, renewables sources, and nuclear and hydro energy. In addition, growth depends on increases mainly in renewable sources.Recovery of thorium from its ores by using hydrometallurgical routes were described and discussed. The final part of this paper was presented a case study of the thorium extraction from Korean monazite ore leach liquors by using Prieme JM-T diluted in A150 diluent as an extractant system. And possible separation of the thorium from rare earths (REs) and base metals were calculated by measuring of separation factors and finally, the recovery of thorium from loaded organic of Prieme JM-T was established.THORIUM IS FUTURE NUCLEAR FUEL?Global energy consumption is increasing everyday with the high population growth, high industrialization of numerous countries and the higher level of good and services consumption that follows it. If we look at specific sectors of the economy, oil consumption grew by 0.8 million barrels per day, globally, whereas the increase was 0.4 % for natural gas and coal 1.8 % for nuclear power and just under 2.0 % for hydroelectric power (Asheley 2009). Use of renewable sources of energy for power generation and transportation increased by 3% in 2014 (BP 2015)). Thus alternative source of energy must be identified and developed to meet this increasing demand. Thorium is a potential one for the nuclear industry."

Jan 1, 2016

By D. H. Flather, J. W. Hendry, K. Drover

Black Hawk Mining Inc. has completed a comprehensive program on the prediction and management of acid rock drainage (ARD) at their Keystone Gold Mine (Keystone) near Lynn Lake, Manitoba. The program, initiated in 1994, followed a phased approach utilizing initial acid-base accounting (ABA) results and subsequent laboratory kinetic testwork to define site-specific sulphide oxidation and neutralization consumption rates in waste rock. Net acid generating waste rock at Keystone was defined through the kinetic testwork as waste rock yielding a net potential ratio (NPR) of less than two. A preliminary waste rock management program based on blending of potentially acid generating and acid neutralizing waste rock was advanced. Subsequent refinement of the management program followed the analysis of over 1580 ABA samples collected from individual blast holes during the initial bench development phase of the Keystone pit. Uncertainties in actually achieving adequate blending within the dumps at a mining- scale resulted in the development of a revised waste rock management program based on segregation. Recognizing that any successful management plan requires that the ARD characteristics of the waste rock be identified prior to in-pit blasting, the extensive ABA database was utilized to develop a rapid characterization scheme. By implementing a characterization scheme based on total sulphur concentrations and fizz rating, waste rock could be quickly segregated without delaying the natural flow of ore from the pit. Interestingly, it also became apparent that gold values were strongly correlated with total sulphur, such that traditional fire assays were supplanted with a simple and more cost-effective total sulphur determination. The program highlights the importance and benefits of collecting and exploiting data beyond that necessary to acquire appropriate development permits.

Jan 1, 2000

By Derrick Hunter, Pat Feighan, Keith Chrystall, David Wells

"Equipment which may be remotely operated, has some degree of on-board intelligence, and which for periods of time may operate autonomously, is referred to as telerobotic. Recent advances in electronics, computers and hydraulic equipment have dramatically reduced the cost and simplified the process of converting standard industrial equipment to telerobotic control. The benefits of telerobotic equipment include improved safety by removing the operator from dangerous situations, reduced maintenance costs and increased productivity. This technology has been proven in various military, nuclear, and police applications.The surface mining industry has expressed an interest in automation and is characterized by a willingness to use remotely operated equipment, however, the majority of telerobotic equipment currently in use is experimental or prototypical. Potential applications of telerobotic equipment for surface mining include remote operation of equipment near dangerous high walls and other unsafe areas, utilization of robotic trucks for routine hauling operations, and control of jointed equipment. In addition, component technologies of telerobotic systems are relevant to various forms of condition monitoring, operator feedback systems, and vehicle positioning.Attention must now be directed toward resolving more complex problems associated with enhancing feedback to the operator, improving the man/machine interface, and ultimately, improving efficiency. Removal of the human operator from the work site introduces significant complications in replacing the sensory inputs that an operator normally uses to efficiently run his machinery. These can be difficult to define and even more difficult to replicate remotely and may include restrictions pertaining to vision, hearing, and touch.In cooperation with Defence Research Establishment Suffield and the Alberta Research Council, Robotech Industries Ltd. is pursuing the development of additional technologies to further enhance an operator’s ability to control remote telerobotic equipment. These developments include a head-mounted display, additional control station displays and improvements to coordinated motion control software. Prototypes of these developments are expected to be completed and tested by the fourth quarter of 1997."

Jan 1, 1996

By A. J. Sinclair, N. Champigny

"The Cinola gold deposit in the northern Queen Charlotte Islands, British Columbia, is in a clastic sequence consisting of a lower shale of the Late Cretaceous Haida Formation and an overlying interbedded sequence of pebble conglomerate and coarse-grained sandstone of the Middle Miocene Skonun Formation. Both formations are intruded by a stock and dykes of porphyritic rhyolite. Two K-Ar model ages indicate mineralization and probably porphyritic-rhyolite intrusion at about 14 Ma (middle Miocene). A splay of the Sandspit fault system constitutes the footwall on the west of the deposit.The Cinola deposit can be classed as Carlin-type based on features such as (1) small particle size for gold, (2) Tertiary age of mineralization, (3) element abundances (e.g. high Hg), (4) dominantly argillic alteration, (5) a structural setting associated with major faults, (6) porosity of the host rock and (7) spatial and possibly genetic association with felsic intrusions. Gold is widespread and occurs mainly as grains of< 0.5 11-m in silicified sedimentary rock, and in quartz veins. Locally, coarse > 100 11-m particles of native gold occur in quartz veins, especially in strongly brecciated porphyritic-rhyolite. Ore minerals are mainly pyrite and marcasite, but include small amounts of chalcopyrite, sphalerite, galena, pyrrhotite, cinnabar, tiemannite (HgSe), rutile, magnetite, hematite and limonite in addition to native gold and electrum. No silver minerals have been found; silver was found in gold particles in amounts varying from 6.2 to 24.2 weight per cent. Alteration products are sericite, illite, kaolinite and chlorite, with abundant quartz of several stages.The host rocks, specifically the Skonun Formation, formed as an alluvial plain facies in a braided river system discharging into a marine basin in early Middle Miocene time. During the Middle Miocene, this sequence was intruded by a rhyolitic stock. The highly porous and permeable Miocene clastic sequence apparently provided an optimum setting for the development of a large geothermal system, the energy for which probably derived from the rhyolite stock. Mineral deposition followed a well-defined paragenesis, which, from oldest to youngest, is: (1) precipitation of iron sulphide minerals, and early quartz; (2) several stqges of quartz veins, with deposition of sphalerite succeeded by galena, chalcopyrite and visible gold. Micron-size gold was precipitated throughout these two stages of mineral deposition. Argillitization of the host rocks probably in part coincided with the mineralization and continued during cooling of the geothermal cell.In-situ reserves have been estimated at 41.1 million metric tons averaging 1.85 g Au/tonne using a cutoff grade of0.86 g Au/ tonne."

Jan 1, 1982

By A. Bowles

The process of accumulative roll bonding (ARB) has been applied to wrought magnesium alloy AZ31. Accumulative roll bonding results in severe plastic deformation of sheet material. In AZ31, this process leads to the refinement of the microstructure by dynamic recrystallization. The refinement of the microstructure results in an improvement in mechanical properties with potential for producing materials for superplastic forming. In this work AZ31 was bonded with up to 64 layers and the potential of roll cladding with aluminium was also investigated. The development of microstructure and the mechanical properties are reported here.

Jan 1, 2006

By O. A. Bascur

Several new hydrometallurgical plants have been built in the past years, new processes and equipment as well as advanced process control systems are being used to deal with the increasing requirements of safety, quality and production. Plant Information Management Systems are now being recognized as a key infrastructure component of the plant, giving the management, the operators, process engineers, finance, maintenance, and regulatory agencies an integrated view of the operation and providing the links for the (increasingly) multidisciplinary organization. This paper reviews several implementations of Plant Information Systems; real time performance management infrastructure examples are reviewed as a key component of business strategies, such as Mine to Port Planning and Supervision, Metallurgical Mass Balances, Solvent Extraction Composition Statistical Process Control, methods to minimize organic losses, reduce variable costs and to improve metal extraction. Several examples are provided to illustrate how companies are using the real time and historical information from assets and metallurgical processes to enable and empower people to improve the operations quality, safety and throughput, as well as continuous improvement and innovation initiatives.

Jan 1, 2007

By F. C. Grensing, W. R. Crib

Copper-15 Nickel-8 Tin alloy is a relatively modern material, having been discovered in the 1970’s. It has complexities with casting, hot working and interdependent solid state phase transformations. A key to the high reliability manufacture of wrought rods, bars, plates and tube is the casting technology, which limits segregation, promotes microstructural uniformity and enables hot working. The EquaCast® continuous casting process has enabled the production of a broadening variety of wrought forms with typical yield strengths ranging from 100 to 180 ksi (690 to 1241 MPa) depending on size, shape and temper. This paper reviews the characteristics of wrought Copper-15 Nickel-8 Tin products which have registration in AMS specifications (4596 and 4597) and MMPDS-04 (CN-1) for use in aircraft. The design limits, microstructures, fracture characteristics and tribological behavior will be examined. This alloy system is emerging as a material of choice for aircraft bearings, corrosion resistant oil and gas exploration components, machinery and demanding off-road equipment applications. ToughMet® 3 is an alternative or upgrade to conventional moderate and high strength aluminum bronze bearing alloys.

Jan 1, 2010

By B. S. Ignasiak, Dennis Carson

"Laboratory study of the behaviour• of binary coal blends shows that coke strength is more closely dependent on the distribution of ""reactive"" oxygen in the parent coals than on their proximate, elemental or petrographic compositions, and it also appears possible to qualitatively predict coke strength from information about reactive oxygen. Proceeding from this recognition, experiments were carried out to test the possibility of preparing metallurgical cokes from binary blends in which non-caking hvb coal was substantially freed of reactive oxygen by prior heat t1•eatment under controlled conditions. The results indicate that such blends can yield surprisingly strong cokes and that coke strength may be amenable to further improvements by modifying the size distribution of the pre-heated component and the rate at which it is charred."

Jan 1, 1976