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By P. A. Distin, Jr. da Silva

The history of commercial processes for zirconium/hafnium production and separation is reviewed. A new technology is then proposed as a potential alternative for zirconium/ hafnium separation in a simpler, cleaner way than achieved with current processes. Primary sources of zirconium always contain small amounts of hafnium that must be removed during production of zirconium metal for nuclear applications. This separation is usually carried out by a solvent extraction process, developed in the 1950s, that selectively extracts hafnium, as a thiocyanate complex, using methyl isobutyl ketone (MIBK). Environmental problems inherent to this process are the high aqueous solubility and low flash point of MIBK, and possible gaseous contaminants formation generated by the decomposition of the thiocyanic complexes in hydrochloric acid medium (H2S, HCN, mercaptan’s formation). The present work shows how these problems could be avoided by using organophosphorous extractants that were unavailable when the MIBK process was developed.

Jan 1, 1998

By Hans Chr Andersen

Almost every form of iron ore and carbon material has been used as a raw material in the production of pig iron in electric reduction furnaces. Experience derived from the operation of the large 33,000-kva. Tysland-Hole furnaces, however, indicates that production results are very much influenced by the raw material conditions. The author presents the principle pattern of the metallurgical structure of the interior of an electric pig iron furnace. On the basis of this, he discusses the variations of electrical and metallurgical conditions for the process which will take place with changing raw materials. The formation of a coke bed underneath the electrodes, and its influence on the furnace operation, is illustrated. Quality and grain size of the coke added to the charge will influence the build-up of the coke bed and will thereby also affect the electrical re-''Elektrokemisk A/S, Oslo, Norway. resistance and reduction potential in the furnace.

Jan 1, 1963

By A. R. Turner

AERIAL survey methods have made enormous technical advances and gained new recognition since World War II. Before enlarging on this statement and reviewing some of the uses of aerial survey in industrial development it is important to de-fine what is meant by "aerial survey". The subject will be discussed in the broadest sense and references will be made to the four sections that compose the overall field of surveying operations from the air. These are: 1. Aerial photography and photo-graphic mapping. 2. The use of airborne electronic instruments for geodetic distance measurement and the determination of ground elevations. 3. Airborne geophysical surveying. 4. The extraction of qualitative and quantitative information from aerial photographs through the processes of "reading", analysis and interpretation. Many sciences and techniques are combined in aerial survey operations. The tools of the business include aircraft, finely engineered cameras, elaborate film processing and printing equipment, ground survey instruments, precision stereo-plotting instruments, map -

Jan 1, 1961

By Bruce W. Smith

Non-contacting, radioisotope density and level gauges are discussed. The characteristics of the more commonly used isotopes, the techniques of detection and the methods of presenting information are reviewed. The gauge parameters of accuracy, response time and long-term stability are tabulated with reference to calibration techniques and operating requirements. Automatic control systems, both pneumatic and electrical, are used in conjunction with density gauges on filter feeds, and in thickener underflow and heavy media processes. These systems are described. Procedures for installation, start-up and operator training are outlined, along with considerations of preventative maintenance and service requirements. Typical gauge system costs, including capital expenditure, installation, start-up and service, are presented, wherever possible, in order to provide a basis of comparison with more conventional systems.

Jan 1, 1964

By W. B. Paton

Introduction For several reasons the accident history of Flin Flon has been quite unlike that of any other mine in northern Canada, and very much unlike that of the average American metal mine. Towards the end of 1928, the mining project that is now Flin Flon, and that is now in the very: forefront of Canada's big producers was launched; but, metaphorically, it was launched in a tempest of mining troubles. Each branch of the mammoth enterprise was beset with extraordinary difficulties, and the Safety Department had its relative share. Difficulties in Accident Prevention The unusually rugged contour of the plant site made roads, and even moderately safe pathways, out of the immediate question. The project established an industrial outlet for depression-stricken areas which hitherto had been essentially agricultural; but through that outlet poured labour whose working atmosphere had been the bald prairie, labour that knew nothing of safety consciousness, labour that had to be moulded to industrialism, labour in the raw. A considerable length of the ore-body lay under the eastern section of Flin Flon lake. Open-pit methods were adopted to work the upper limits of the ore-body, and consequently the eastern section of the lake had to be dammed and pumped dry. The subsequent difficulties and hazards created by silt deposit cannot be fully visualized. And, finally, there was a geographical hindrance: the ore-body was partly in the Province of Manitoba and partly in the Province of Saskatchewan. The workmen's compensation problem became intricate. Insofar as accident prevention is concerned, Flin Flon's young industrial life may be conveniently divided into three distinct periods, namely: (a) Construction (Nov. 1928-June 1930) (b) Tuning up, and production till the strike (June 1930-June 1934) (c) Production from the strike till the present time At the peak of construction, due to the usual labour fluctuations of big jobs, there was a weekly turnover of about a hundred men. A very large percentage were Central Europeans, most of whom could neither read nor write English. Consequently, an organized safety programme was out of the question.

Jan 1, 1935

By H. McIntire, R. Preston, D. Roberts

"Repeated 3D terrestrial digital photogrammetric surveys were conducted on hard rock mine pillars to characterize damage during secondary mining. Damage was quantified by measuring Depth of Failure, DOF, from spalling material and crack intensity, D21. These damage values were then correlated to visually assessed Pillar Damage Ratings and numerically estimated pillar loads. Measured damage, particularly Depth of Failure, correlated well with Pillar Damage Ratings. Numerical predicted pillar stress vs. damage exhibited the expected trend with shorter pillars being stronger. High resolution photographs and 3D models were also used to characterize damage mechanisms, which were found to be structurally constrained. INTRODUCTIONThe Doe Run companies Southeast Missouri Operations consists of six room and pillar lead mines (Brushy Creek, No. 29, Casteel, Buick, Fletcher and, Sweetwater) (The Doe Run Company, 2014). The mines are hosted in the Carbonates and Shales of the Viburnum trend with mining depths varying from 180 to 300 m. Pillars are commonly cut square with widths varying from 7 to 9 m and heights generally between 5 and 18 m, resulting in extraction ratios between 80 and 85% (Roberts et al., 1999). Figure 1 presents an idealized stratigraphic section through the Viburnum trend and Figure 2 shows a plan view of the five areas spanning the three mines included in this study."

Jan 1, 2015

By G. G. W. Thom, A. A. F. Schuldt

At The Steel Company of Canada, Limited, iron oxide dust from the basic oxygen open hearths is being collected by means of electrostatic precipitators. The utilization of this dust, which has been hampered by the presence of zinc and lead oxides and sulphur compounds, is made possible by direct reduction in a rotary kiln. The description of the dust collection system and the results of kiln tests are presented.

Jan 1, 1966

By D. Laguitton

The basic chemistry of a1•senic related to its dissolution and subsequent precipitation in gold-mine waste waters is discussed. The lime addition methods provides the most economic treatment of arsenical slurries, but requires a careful control of the oxidation of Asm into Asv, of the pH (>12) and the filtration of the precipitate. If arsenic levels below 0.5 mg/ l are required, a modification of the method by phosphate addition must be considered.

Jan 1, 1976

By S. U. Baltuch, E. G. Baltuch

"Ventilation in process buildings is key to proper mill function. Correctly engineered systems to evacuate surplus thermal energy from process areas allow optimized rates of air change, thus assuring the good functioning for the lifecycle of the process while demonstrating conformity with occupational hygiene standards. Computational fluid dynamic simulations, coupled with traditional calculations and physical modeling, can demonstrate to end users and assist engineers in the optimization of mill ventilation, reducing total installation costs while assuring that the proper solution is in place for the complete lifecycle of the process equipment. Results have been fully implemented on a number of steel mill and aluminium smelter applications and we continue to study, optimize, and innovate as new tools become available to provide the best possible engineered solutions for particular applications. INTRODUCTIONThe objective of this research project is the development and implementation of modern approaches and computational fluid dynamics (CFD) simulation in the engineering of green ventilation of hot process buildings. This will assure the predictive performance and improve the quality and ease of construction of industrial gravity ventilation equipment, along with the adjunct hot process buildings, while lowering the overall project costs and time to completion.In order for a hot process building, such as a steel mill, to properly function, heat must be extracted from within. This is accomplished by having air inlets at the bottom of the building and outlets at its apex. The reason for this is to maximize the potential chimney effect. When using stack (buoyancy) effect ventilation, the process heat becomes the driver. Therefore, increasing this distance (height) improves the ability of the heated airstream to utilize basic gravity for acceleration of the heat/air flow, allowing a regular number of air changes per hour while ensuring that the process environment remains weather resistant under normal operating conditions.This process has been understood since the time of King Charles I of England, who decreed in 1600 that buildings should have 10 foot ceilings and that windows should be made taller rather than wider to allow better smoke extraction.Figure 1 is a painting of the Bethlehem Steel Works in the 1860s, where the concept of air inlets and penthouses on the roofs for air outlet was already being put into practice. Figure 2 is an early photograph of the Pittsburgh Steel Works."

Jan 1, 2012

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By F. J. Hrach, K. P. Flynn, P. J. Miranda

"ST Equipment & Technology, LLC (STET) has developed a processing system based on tribo-electrostatic belt separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to other electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the triboelectric belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (300 µm) particles with very high throughput. The high efficiency multi-stage separation through internal charging/recharging and recycle results in far superior separations that can be achieved with a conventional single-stage free-fall tribo-electrostatic separator. The triboelectric belt separator technology has been used to separate a wide range of materials including mixtures of glassy aluminosilicates/carbon, calcite/quartz, talc/magnesite, and barite/quartz. Separation results are presented for selected industrial mineral sources. An economic comparison of using the tribo-electrostatic belt separation versus conventional flotation for barite / quartz separation illustrates the advantages of dry processing for minerals.INTRODUCTIONThe lack of access to fresh water is becoming a major factor affecting the feasibility of mining projects around the world. According to Hubert Fleming, former global director for Hatch Water, “Of all the mining projects in the world that have either been stopped or slowed down over the past year, it has been, in almost 100% of the cases, a result of water, either directly or indirectly” (Blin et al., 2013). Dry mineral processing methods offer a solution to this looming problem."

Jan 1, 2016

By Balakrishnan Nanthakumar, Marek Pawlik, Dennis Grimm

"The anionic flotation of a high-iron phosphate ore from Agrium - Kapuskasing Phosphate Operations was investigated through batch flotation tests in the presence of soda ash. The flotation data were supplemented by titration of the flotation pulp with soda ash, analysis of process water chemistry, and determination of the mineralogical composition of the ore. The results of lab tests were applied to the flotation circuit design allowing the flotation plant to efficiently process problematic ores. Process control measures (pH, conductivity) were also developed.Calcium cations and sulfate anions were identified as the dominant ions present in the process water when the difficult-to-process ores are beneficiated in the flotation plant. The concentrations of calcium and sulfate ions were consistent with the presence of a small amount of a calcium sulfate mineral in the ore although an oxidation/weathering process of iron sulfide minerals present in the ore could also be responsible for the observed water chemistry and subsequent flotation problems with the ores. The latter possibility suggests that the long-term stockpiling of such ores may have a highly negative impact on the flotation process.The role of soda ash in the flotation circuit is to precipitate metal cations from the pulp thus allowing the tall oil-based collector to selectively interact with the phosphate components.INTRODUCTIONPhosphorus minerals are the main source of this element for the production of fertilizers, and the froth flotation process is the most important technology for beneficiating phosphate ores. The flotation concentrate from Agrium-Kapuskasing Phosphate Operations (KPO) is transported to Redwater Fertilizer Operations in Alberta (also operated by Agrium) where the phosphate concentrate is converted into a phosphate fertilizer and other important chemical products. The KPO phosphate ores differ widely in mineralogy and phosphate grades, and are broadly divided on-site into three classes. The easy-to-float A-type ores do not pose any major flotation problems, but the B-type and “marginal” ores, which are quite common in the KPO igneous phosphate deposit, are not always readily-floatable using the current reagent suites and process parameters (pulp density, feed particle size, pH). In fact, marginal ores are presently considered impossible to process by flotation. A-type ores contain normally more than 15% P2O5 and less than 8% ferric oxide equivalent (Fe2O3). B-type ores are approximately of the same P2O5 grades as A-type ores but their iron content may reach 30% Fe2O3. Any material containing less than 15% P2O5 is rejected as waste rock."

Jan 1, 2008

By T. Donkin, B. Patterson, M. I. Guthrie, J. T. Ross

"The interest in the use of sensor-based particle ore sorting has increased significantly with the recent advances in the sorting technologies and higher capacities per unit. This technology has the potential to provide great value in processing lower grade ores from the mine whilst delivering higher grades to the mill as well as in upgrading waste rock into ore. Typically, the focus is on the amenability of the ore to ore-sorting and associated reductions in the consumption of energy, water and consumables. However, layout has a significant impact on the installed cost of a concentrator and the layout impacts from fitting an ore-sorting circuit into the concentrator plan need to be carefully considered. This paper examines layout considerations that play an important role in ore sorting projects. These include additional crushing and screening requirement, transportation of the rejected material back to the waste stockpile (mine fleet requirements) and effects on concentrator footprints.INRODUCTION Ore sorting has been practiced throughout history with an early report by Agricola in 1556. Metallic and non-metallic minerals were extracted from rocks by laboriously breaking them with hammers and picks and hand-picking selected material with higher grade off a table. The concept has not changed but the sorting technology has evolved significantly over the last 20 years. Ore sorting is usually a dry process in which a portion of the material is rejected based on mineral properties and/or grade. The methods used for sensing ore particles cover a large range of physical properties. A variety of sensors are available that differ on the discrimination technique that is used, which include: photometry, radiometry, conductivity, magnetism, microwave, X-ray transparency: X-ray transparency and luminescence and UV fluorescence (Sivamohan and Forssberg, 1991; Wotruba, 2006). There are two main ore sorting techniques: particle ore sorting and bulk ore sorting. According to Nadolski et al (2018), the potential for sorting is determined though analysis of grade heterogeneity within the orebody (greater heterogeneity represents more opportunity to add value to a project) at the scale of the intended sorting unit size."

Jan 1, 2019

By D. R. Jolley

"The selection of equipment for open-pit mining is an important decision which results in a considerable capital expenditure by the operator. The decision is complicated by the wide product range on the market. Certainly, equipment performance is an important criterion to consider in making the decision. Equally important, however, is the operating inter-relationship among the equipment. A poor balance increases production costs and waiting time as queues form at the bottlenecks. This inter-relationship is dependent on equipment performance, but it is also affected by management decisions (i.e. scheduling techniques).The purpose of this paper is to show how the computer is used to decide which equipment and operating decisions achieve the required production objectives at least cost. Actual mining of the pit is simulated over a period of time using different equipment and scheduling decisions. Production, waiting time and costs are evaluated for each alternative until the operator is satisfied that he has achieved the best result."

Jan 1, 1970

By Michael Magerstädt

Material loss by abrasion of contact surfaces of pipes, chutes, pumps, and other equipment in contact with ore is one of the main reasons for downtime of mining operations. Abrasion protection materials in use range from expensive tungsten carbide overlay to hardened steels, ceramics, as well as polymers, particularly polyurethanes (PUR). This paper describes abrasion protection products made from High Performance Polyurethane Elastomers. An interior pipe coating was developed that exhibited outstanding abrasion resistance and an extremely high adhesion to steel. Years of field testing in oil sands tailings as well as applications in slurry lines (e.g., phosphate slurries) have proven the performance of this material. A proprietary field joining process was developed and successfully applied in the field. This joining process requires only one field weld per joint very similar to the joining of uncoated pipe. No internal re-coating is necessary adding savings during pipe laying to the significant savings of reduced down time. Using the building-kit chemistry of polyurethane synthesis, similar high performance elastomers were used to extend the life time of ball mills. An intelligent system was developed in which wear parts contain sensors reporting the actual wear thereby optimizing maintenance interval leading to significant cost savings for the operator. Test data as well as field experience with High Performance PUR Elastomers for abrasion protection in mining are presented.

Aug 1, 2013

By J. Budac, R. Kofluk, S. Mankasingh

Stainless steels such as 316L or 304 are normally relatively resistant to attack by nitric acid. However research at Sherritt International’s Fort Saskatchewan Operation reveals that when the stainless steel is immersed in an aqueous system in which nitric acid is used to dissolve metals such as cobalt or nickel, the steel can be seriously corroded. Sherritt is patenting a simple process for arresting the corrosion via the use of copper. This process is expected to substantially eliminate corrosion in processes where nitric acid is used to dissolve metals attached to a stainless steel substrate.

Jan 1, 2014

By Charles J. Zablocki, Robert J. Kamilli

"Buried, possibly mineralized granite cupolas at the Silsilah tin deposit in Saudi Arabia (lat. 26°06&apos; N, long. 42°40&apos; E) have been successfully located using a closely spaced electric-field-ratio profiling technique. In this study, electrical fields at 27 and 270 Hz across grounded electrodes spaced 50 m apart were measured along six traverses. This method is interpretable by inspection, unlike the dipole-dipole technique, which requires mathematical modeling for interpretation.In the study area, the technique allowed the authors to identify and distinguish among unroofed granite cupolas, cupolas with their aplite-pegmatite apical contact zones intact, strong (quartz-rich) and weak (relatively quartz-poor) greisens, dikes, faults, and pervasively argillized rocks.This method should be useful in the valuation of other shallow mineral prospects in similar settings in other parts of the world, especially deposits for which the location of vertical contrasts is important, such as veins or mineralized zones associated with the apexes of small igneous cupolas."

Jan 1, 1993

By J. van Deventer

Volatile gold prices in the face of rising costs for mining and refining is causing the mines to look for new ways to reduce costs and increase recoveries. This task is complicated by the fact that the gold in hereto unexploited reserves is associated with increasingly complex ores - either preg-robbing, refractory, associated with high concentrations of copper, or all of the above. Ion exchange resins can play a significant role in this quest for improvement. Although ion exchange resins have been used in Former Soviet Union (FSU) countries for the recovery of gold for many decades, it is still not widely used in the Western World. Synthetically manufactured ion exchange resins can be tailor-made to suit the chemical and mechanical characteristics of a specific application. As such, ion exchange resins can be used in a variety of solution matrices (e.g. cyanide, thiosulphate and acid), and process designs (recovery from clear liquor after solid-liquid separation or directly from the leached pulp). In this paper, a number of applications are discussed along with a review of recent developments in ion exchange technology.

Jan 1, 2014

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By L. F. Haven

"The desirable shovel speed-torque curves are described, along with the characteristics of the more important electrical components used to approximate these curves. A particular shovel regulator system combining these components is discussed in detail and some of the advantages and disadvantages of the system are given.INTRODUCTIONIN 1959, STATIC CONTROL was for the first time successfully applied, installed and operated on a mining machine in North America. Since that time, a great deal has been learned about this control by the people maintaining these machines as well as by the de-signers.In 1961, the first SCR (Silicon Controlled Rectifier) or thyristor control system was installed on an excavator. This control differed from the earlier static control in that thyristor excitors supplied the generator fields directly. The development of thyristors of a sufficient rating to supply amounts of phase-controlled power to the generator fields eliminated the bulky Mag. Amp. -Rectifier combination previously used."

Jan 1, 1969